Abstract: A polymer alloy material is produced by a process including the step of heating a powdered precursor material comprising polymer particles having an average particle size less than about 1000 .mu.m to a temperature less than the melting point of the polymer at a pressure of at least about 5 MPa to produce the polymer alloy material. Preferably the powdered precursor material is produced by mechanically milling a polymer to provide a powdered precursor material having an average particle size in the range of from about 0.5 .mu.m to about 200 .mu.m. The invention is particularly suited for processing a single polymer or a mixture of two or more polymers which are otherwise difficult to process at a temperature less than the melting point of the polymer.
Type:
Grant
Filed:
June 19, 1992
Date of Patent:
November 22, 1994
Assignee:
University Technologies International Inc.
Abstract: A positive-working light-sensitive composition whose solubility in a developer is increased by irradiation of light, which comprises:(a) a vinyl ether compound having at least one group represented by the following formula (A); ##STR1## wherein R.sup.3 represents a linear or branched alkylene group having 1 to 10 carbon atoms and n represents an integer of 0 or 1;(b) a compound capable of being decomposed by irradiation of an actinic light ray or a radiant ray and releasing an acid; and(c) an alkali-soluble polymer, the light-sensitive composition having high sensitivity to light and permitting the use of light of a wide wavelength range.
Abstract: Diamino ureas having the formula ##STR1## wherein each ring is saturated and includes 3-5 carbon atoms and n alkyl substituents R of 1-4 carbon atoms each and n for each ring is 1-4, a method of using these materials as chain extending agents in the manufacture of poly(urethane/urea)s or polyureas, and polymers having at least one constituent unit derived from such diamino ureas are claimed.
Type:
Grant
Filed:
March 31, 1993
Date of Patent:
November 15, 1994
Assignee:
OSi Specialties Inc.
Inventors:
Richard M. Gerkin, Forest A. Richey, Jr.
Abstract: Object: The present invention was conceived in light of the above-described prior art. The object of this invention is to provide a method for preparing optical-grade polycarbonate compositions, which method is able to prepare with good productivity optical-grade polycarbonate compositions that have not only excellent clarity and water resistance, but also excellent retention stability such as heat stability and hue stability when molten and a low content of inclusions and impurities, and that undergo little heat deterioration.Constitution: The method for preparing optical-grade polycarbonate compositions according to this invention, which method comprises the melt-polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of a catalyst, followed by the addition of additives [B] while the polycarbonate [A] obtained as the reaction product is in a molten state, and mixing.
Abstract: A wet strength resin composition is comprised of an aminopolyamide-epichlorohydrin acid salt resin having a total organically bound chlorine of up to 0.7% by weight of the resin. The amount of total organically bound chlorine present is controlled by the process parameters.
Abstract: A positive-working radiation-sensitive mixture is disclosed that contains(a) a compound that forms strong acid on exposure to actinic radiation that is an ester of a sulfonic acid or sulfonic acids of the formula R--SO.sub.3 H or R'(--SO.sub.3 H).sub.2 with 2,4-bistrichloromethyl-6-(mono- or dihydroxyphenyl)-1,3,5-triazine of the formulae I and/or II: ##STR1## where R is an optionally further substituted (C.sub.1 -C.sub.10) alkyl, (C.sub.5 -C.sub.10)cycloalkyl, (C.sub.6 -C.sub.10)aryl, (C.sub.6 -C.sub.10)aryl- (C.sub.1 -C.sub.10) alkyl or (C.sub.3 -C.sub.9)heteroaryl radical, R' is an optionally substituted (C.sub.1 -C.sub.10)alkylene, (C.sub.6 -C.sub.10)arylene or (C.sub.3 -C.sub.9)heteroarylene radical, and n is 1 or 2,(b) a compound that contains at least one acid-cleavable C--O--C or C--O--Si bond, and(c) a water-insoluble polymeric binder that is soluble or at least swellable in aqueous alkaline solutions.
Type:
Grant
Filed:
June 9, 1992
Date of Patent:
November 15, 1994
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Georg Pawlowski, Horst Roeschert, Walter Spiess, Klaus-Juergen Przybilla
Abstract: Powder-form preparations of surface-active alkyl glycosides contain 5 to 65% by weight of a surface-active alkyl glycoside and 35 to 95% by weight of an inert inorganic support. They are produced by mixing the crude product obtained in the industrial production of the alkyl glycosides with water and an inorganic particulate support, for example silica, chalk or sodium chloride, and drying the resulting mixture. Preferred powder-form preparations contain 20 to 50% by weight of the alkyl glycoside and 50 to 80% by weight of an inert inorganic support.
Type:
Grant
Filed:
December 21, 1993
Date of Patent:
November 15, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Karlheinz Hill, Franz Foerg, Hermann Koerner, Josef Penninger
Abstract: A photopolymer useful in preparing water-developable, solid printing plates is prepared by preparing a urethane prepolymer by reacting polyoxyalkylene diols or polyester diols, or a mixture thereof, with an excess of diisocyanate, followed by chain extending the resulting prepolymer mixture with an alkyldialkanolamine, then reacting the chain-extended product with a hydroxyalkyl(meth)acrylate. The resulting photopolymer is suitably formulated with additional photoactive (meth)acrylate monomers or oligomers and photoinitiator for casting or extrusion on a substrate to form a flexographic printing plate. Following UV exposure of the plate through a negative, unexposed areas can be removed by washing with a slightly acidic aqueous medium, to give a plate with a desirable relief image. The use of the aqueous washout solution as opposed to organic solvents minimizes pollution problems.
Type:
Grant
Filed:
January 12, 1993
Date of Patent:
November 15, 1994
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Truc-Chi T. Huynh-Tran, Ronald J. Kumpfmiller, Cynthia L. Ebner
Abstract: A continuous method for the in-situ polymerization of plastic in an elastomeric material in a form suitable for reinforcing the elastomeric material is provided. The method comprises feeding elastomer and a monomer or monomer precursor of a reinforcing material into a mixing device, mixing the elastomer and the monomer or monomer precursor vigorously, initiating polymerization, and causing the monomers to continue to polymerize until the polymer solidifies when the melting point of the polymer produced exceeds the mixing temperature of the elastomer, terminating polymerization.
Type:
Grant
Filed:
April 26, 1991
Date of Patent:
November 15, 1994
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Richard G. Bauer, Donald J. Burlett, Joseph W. Miller, Jr., Gordon R. Schorr, Pradeep M. Bapat
Abstract: A process for preparing high molecular weight arylene sulfide polymers by dehydrating an aqueous mixture of a sulfur source and a cyclic organic amide to form a dehydrated mixture, contacting the dehydrated mixture with a dihaloaromatic compound to produce a polymerization mixture, polymerizing the polymerization mixture and recovering the arylene sulfide polymer wherein an aqueous alkali metal carboxylate mixture is added to the polymerization mixture after the conversion of the dihaloaromatic compound is about 40 percent to about 30 minutes prior to entering into termination of the polymerization.
Abstract: Resin compositions of improved dispersibility and mechanical properties are obtained by polymerizing a polymerizable compound (A), insitu in a melted thermoplastic resin (B), in the presence of a dispersant (C) reactive or compatible with at least one of the resin (B) and polymerizate of (A).Suitable dispersants include those represented by the general formula (1) or (2)R.sub.1 --L(X--M--X--L).sub.n X--M--R.sub.2 (1)R.sub.1 --L(X--M--X--L).sub.n --R.sub.2 (2)wherein R.sub.1 and R.sub.2 are groups, such as hydrocarbyl acyl, alkoxy, hydroxyl, mercapto, amino, epoxy, isocyanate, carboxylic, carboxylic anhydride, carboxylic halide and aldehyde groups; L and M are residues of a polymer having a number average molecular weight of about 500-about 3,000,000, the difference in solubility parameter between the residue L or M and the resin (B) or polymerizate of (A) being not more than 0.
Abstract: A process for the production of a material having an increased molecular weight relative to the diepoxide starting material the material being either a hydroxy-terminated or an epoxy-terminated material comprisinga) reacting a diepoxide with a dihydroxy compound, in the presence, as catalyst, of a triflate salt of a metal of Group IIA, IIB, IIIA, IIIB, or VIIIA of the Periodic Table of Elements (according to the IUPAC 1970 convention);b) de-activating the triflate salt catalyst; andc) optionally advancing the material produced in step b), with an aromatic diol or phenol.
Type:
Grant
Filed:
December 9, 1991
Date of Patent:
November 8, 1994
Assignee:
Ciba-Geigy Corporation
Inventors:
William M. Rolfe, Michael R. Thoseby, Bryan Dobinson
Abstract: A urea-formaldehyde resin useful as a binder for making a variety of products, and of a method for making the resin. The resin is prepared by reacting formaldehyde, urea, triethanolamine, and optionally ammonia in a two-step process, first under alkaline conditions and then under acidic conditions. The urea-formaldehyde resin thus produced has good resistance to hydrolysis, cures quickly without smoking, and is characterized by low formaldehyde release.
Abstract: The present invention relates to polyesters which are particularly suitable in coating compositions which are sprayed with compressed fluids which act as viscosity reducing diluents.
Type:
Grant
Filed:
July 16, 1993
Date of Patent:
November 8, 1994
Assignee:
Union Carbide Chemicals & Plastics Technology Corporation
Inventors:
John N. Argyropoulos, Cheryl C. Bone, Charles W. Glancy
Abstract: Polymer electrolytes are described that comprise a sulfonated aromatic polyether ketone, e.g. of the formula II ##STR1## where A is from 0.2 to 1,c is from 0 to 0.8, anda+c=1.The polymer electrolytes are prepared by dissolving an aromatic polyether ketone in 94-97% by weight sulfuric acid and adding a sulfonating agent, e.g. oleum, to the solution until the sulfuric acid concentration is from 98 to 99.9% by weight.
Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprise the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a second monomer (a core monomer) such as a dihydric phenol for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, characterized by having a single core, in a single processing step.
Abstract: This invention relates to novel multifunctional oxetanes, i.e., compounds having multiple oxetane groups, which are useful as initiators in the preparation of star polymers and polymer cascades containing energetic groups. In addition, this invention relates to a process for the preparation of star polymers and polymer cascades, whereby novel multifunctional oxetanes act as initiators in the formation of theses polymers. The reaction of these initiators with various propagating, high-energy oxetanes, such as 3,3-bis-(azidomethyl)oxetane (BAMO) and 3-nitratomethyl-3-methyloxetane (NMMO), gives star polymers with varying molecular weights and functionalities. The star polymers and polymer cascades of the present invention are useful as binders in high-energy formulations.
Type:
Grant
Filed:
December 11, 1992
Date of Patent:
November 8, 1994
Assignee:
Aerojet-General Corporation
Inventors:
Thomas G. Archibald, Roland P. Carlson, Aslam A. Malik, Gerald E. Manser
Abstract: An epoxy resin composition comprising (i) an epoxy resin, (ii) a phenolic curing agent, (iii) an organophosphorous curing agent, (iv) alumina, and (v) a separating means for separating the organophosphorous curing agent and the alumina, which may be a coating over the surfaces of the organophosphorous curing agent.
Type:
Grant
Filed:
March 24, 1992
Date of Patent:
November 8, 1994
Assignees:
Nippondenso Co., Ltd., Shin-Etsu Chemical Co., Ltd.
Inventors:
Akira Shintai, Hiroshi Shibata, Toshio Shiobara, Koji Futatsumori, Seizi Katayama, Yasutaka Yoshida
Abstract: The present invention discloses thermoplastic resins and methods for producing said resins utilizing a single component tertiary amine catalyst system. More particularly, the invention discloses resins such as high molecular weight polycarbonate resins that are produced by a solventless melt condensation reaction between diphenyl carbonate (DPC) and bisphenol A (BPA) in the presence of tertiary amine catalyst.
Abstract: A graft copolymer is produced by grafting both at least one perfluoroacrylate and at least one N-(oxymethyl)acrylamide, e.g., IBMA, onto a poly(oxyalkylene) composition. This graft copolymer is water dispersible prior to crosslinking while after crosslinking, it becomes a highly durable hydrophobic and oil repellent coating for fibers, textiles, and the like.
Type:
Grant
Filed:
November 27, 1991
Date of Patent:
November 8, 1994
Assignee:
Karlshamns AB
Inventors:
Robert Miller, James L. Williams, George H. Greene