Abstract: A polyurethane insulation foam composition is disclosed herein. The polyurethane insulation foam comprises: (i) an aromatic isocyanate compound; (ii) an isocyanate reactive compound; (iii) water; (iv) a tertiary amine compound; (v) a hydrophilic carboxylic acid compound; (vi) a halogenated olefin compound; (vii) a stabilizing compound, and (vii) optionally, other additives.

Abstract: A rigid polyurethane foam formulation comprising a polyol composition comprising, by weight based on the weight of the polyol composition, more than 70% of at least one polyester polyol having an average hydroxyl number of from 150 to less than 300 mg KOH/g and an average functionality of at least 2; a blowing agent comprising water and an auxiliary blowing agent; a silicone copolymer surfactant; from 1% to 5% by weight based on the weight of the polyol composition, of a cyclic siloxane having a surface tension less than 21 dynes/cm at 25° C., wherein the weight ratio of the cyclic siloxane to the silicone copolymer surfactant is from 0.6 to less than 2.27; a catalyst, and optionally a flame retardant; and a polyisocyanate; such that the isocyanate index is in the range of from 180 to 500; a rigid polyurethane foam formed from the foam formulation; and a method of forming a rigid polyurethane foam.

Abstract: The present invention provides a stabilising composition, comprising: a) a first phenolic antioxidant comprising one or more phenolic compounds having the structure of formula (I): ?wherein R1 is a linear or branched alkyl group having from 12 to 20 carbon atoms; and b) one or more second phenolic antioxidants independently selected from: ?a mono-hydroxybenzene having lower steric hindrance than the first phenolic antioxidant; ?a di-hydroxybenzene; and/or ?a tri-hydroxybenzene.

Abstract: A stable dispersant and an application thereof in preparing copolymer polyols, the preparation method for the stable dispersant including the steps of 1) contacting a polyol with a dianhydride compound for reaction so as to prepare an adduct; 2) performing a ring-opening addition reaction on the adduct obtained in step 1) and an epoxy compound to prepare a stable dispersant; the dianhydride compound does not contain a double bond that may copolymerize with an olefinically unsaturated monomer, while the epoxy compound contains a double bond that may copolymerize with an olefinically unsaturated monomer, the polyol is a polyester polyol and/or a polyether polyol, preferably being a polyether polyol. The stable dispersant obtained by means of the described preparation method has a multi-active site anchoring function, and is applied to the synthesis of copolymer polyols to obtain copolymer polyols having relatively uniform particle size.

Abstract: A biodegradable foam which includes a polyester-based polyurethane foam and a mixture comprised of a soil-dwelling carbon-digesting bacteria embedded in a carrier compound. The mixture of the soil-dwelling carbon-digesting bacteria is homogenously dispersed throughout the polyester-based polyurethane foam. This biodegradable foam exhibits biodegradation rates higher than a polyester-based polyurethane foam absent the soil-dwelling carbon-digesting bacteria.

Abstract: The use of long-chain citric acid esters as additives in aqueous polymer dispersions for production of porous polymer coatings, preferably for production of porous polyurethane coatings, is described.

Abstract: This invention relates to thermoset, thermal insulating panel, pour-in-place and pour-in-place foams having desirable and unexpectedly low thermal conductivity, and to compositions, method and systems which use and/or are used to make such foams comprising: (a) providing thermosetting foam forming component and a blowing agent for forming predominantly closed cells in the foam, wherein the blowing agent comprises: (i) cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzm(Z)) and cyclopentane, with the HFO-1336mzzm(Z) and cyclopentane in the blowing agent together comprising at least about 50% by weight of the total of all components in the blowing agent and (ii) the weight ratio of HFO-1336mzzm(Z) to cyclopentane in the blowing agent is from about 45:55 to less than 68:32 and (b) forming foam from said provided foamable composition.

Abstract: The present invention relates to the field of polyol components suitable for forming polyurethane foam, in particular two component polyurethane foam the resulting foams and methods for their production. The present inventors found gaseous hydrohaloolefin containing polyol components possessing improved shelf-life properties, in particular polyol components comprising a gaseous hydrohaloolefin blowing agent, a nitrogen catalyst and a tin catalyst, wherein the tin catalyst comprises a sulfur atom. The present inventors also found that the shelf-life is further improved if the nitrogen catalyst is at least partially protonated by reaction with an acid, such as an organic acid.

Abstract: The present disclosure relates to a process for preparing polyurethane moldings, including the steps of providing a reaction mixture (M), including at least one polyisocyanate, and at least one component with two functional groups which are reactive towards isocyanates, introducing the reaction mixture (M) into a mold and allowing the reaction mixture (M) to react to form a polyurethane molding. In the first step, at least one additive selected from vegetable oils is added to the mixture (M). The present disclosure also relates to a polyurethane molding obtained or obtainable according to said process and the use of a polyurethane molding according to the invention as sole of a boot or part of a sole of a boot.

Abstract: This invention relates to novel macromers that comprise a polyether polyol having (meth)acrylate unsaturation. These novel macromers are the polymerization product of a glycidyl (meth)acrylate, with a polyether polyol, and optionally, an alkylene oxide, in the presence of a double metal cyanide catalyst. This invention also relates to preformed stabilizers prepared from these macromers, and to polymer polyols prepared from these novel macromers and novel preformed stabilizers. The present invention also relates to processes for preparing these compositions, to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

Abstract: The present invention is directed to a method for preparing a thermoplastic polyurethane having a low glass transition temperature. The process according to the present invention comprises the steps of providing at least one polyol composition (P) comprising a poly-?-caprolactone polyol (P1), and a second polyol (P2) which is different from the first polyol (P1), and reacting the at least one polyol composition (P) with at least one polyisocyanate (P1) and at least one low molecular weight diol (CE) optionally in the presence of at least one catalyst (CA) and/or at least one additive (AD) to obtain a thermoplastic polyurethane. The present invention is also directed to the thermoplastic polyurethane obtained according to the process of the present invention and the use thereof in extruded articles and injection molded articles.

Abstract: The present invention relates to thermoplastic polyurethanes obtainable or obtained by a process comprising the reaction of a thermoplastic polyester (PE-1) with a diol (D1) to give a composition (Z1) comprising a polyester (PE-2), and the reaction of the composition (Z1) obtained in step (i) with an isocyanate composition (I1) comprising at least one polyisocyanate, and with a polyol composition (P1), where the polyol composition (P1) comprises at least one polycarbonate polyol (PC1), and also to a process for the production of the thermoplastic polyurethane. The present invention further relates to a composition comprising a thermoplastic polyurethane of the invention and at least one flame retardant.

Abstract: Mechanically strong, biodegradable and reusable aerogels are disclosed, which can be made with a cross-linked cellulose ester, and which exhibit a low density and high porosity. The aerogels disclosed herein may be used as sorbent materials and can be modified with a hydrophobic and/or oleophilic agent.

Abstract: Storage-stable two-component polyurethane or polyisocyanurate spray foam compositions are disclosed, said compositions comprising: (a) an A-side component comprising one or more polyisocyanate and one or more catalyst; and (b) a B-side component comprising one or more polyol; and further comprising one or more hydrohaloolefin blowing agent in either the A-side component or the B-side component, or in both; wherein both the A-side component and the B-side component, separately, generate less than 600 ppm of fluoride ion after two weeks of aging at 50° C.

Abstract: This invention provides stable polyol compositions at all states and these compositions are stable for at least 24 hours, in some cases for more than 6 months. There is also provided polyol mixture compositions that may be uniformly blended under manufacturing conditions within a time period of less than eight hours, typically less than two hours, i.e., stable—polyol mixtures. The invention provides a composition and a method for making stable polyurethane foams. The polyol mixture comprises at least two polyols of different polyoxyethylene content, catalyst, at least one ethoxylated alcohol of the following formula: RO(CH2CH2O)nH, wherein R is C1-C31 linear or branched alkyl, n is an integer equal to or greater than 1; and wherein the at least one ethoxylated alcohol has a hydrophilic-lipophilic balance (HLB) value equal to or greater than about 3.7.

Abstract: A thermoplastic polyurethane (TPU) foam product with high flatness, and a preparation method and a use thereof are provided. The TPU foam product is prepared by processing aliphatic thermoplastic polyurethane (ATPU) beads with a melting range of 20° C. to 50° C. and a melting point of 90° C. to 160° C. by a physical gas foaming process to obtain foamed ATPU beads and heating the foamed ATPU beads with a heat source to make the foamed ATPU beads fused. The TPU foam product with high flatness has a density of 0.08 g/cm3 to 0.8 g/cm3 and a flatness value of less than 2 mm, and the flatness value is determined by a fixed-length ruler. The TPU foam product not only has high flatness such that diversified designs are allowed for a surface of the product, but also has high resilience.

Abstract: A thermally-insulating composite material with co-shrinkage in the form of an insulating material formed by the inclusion of microballoons in a matrix material such that the microballoons and the matrix material exhibit co-shrinkage upon processing. The thermally-insulating composite material can be formed by a variety of microballoon-matrix material combinations such as polymer microballoons in a preceramic matrix material. The matrix materials generally contain fine rigid fillers.

Abstract: Described herein is a method for producing a PU foam insole, including the following steps of: (1) pouring the raw materials used to form a PU foam into a mould, reacting to obtain a PU sheet, where the height of the mould cavity is from about 1.0 to about 1.6 times of the total thickness of two finished insoles; (2) splitting the PU sheet into two halves in the horizontal direction to obtain two pieces of PU insole material, where one surface of the material has open pores, and the other surface of the material has a skin; and (3) attaching a piece of fabric onto the surface having open pores of the material obtained in step (2). Also described herein is a PU foam insole produced by the method.

Abstract: The invention generally pertains to the use of polyurethane foam blown by at least one blowing agent having a boiling point at atmospheric pressure of between ˜?50° C. to less than ˜5° C., including miscible blends thereof, which passes all United States Coast Guard Title 33, Part 183 specifications wherein the buoyant force of the froth polyurethane or polyisocyanurate foam is not reduced more than 5% after exposure to being immersed in a fully saturated gasoline vapor atmosphere, in reference fuel B, in reference oil No. 2, and in a 5% solution of Na3PO4.

Abstract: A Schiff base-containing chain extender may be a diol having a Schiff base or a derivative thereof, as well as a polyurethane produced using the same and a modification method thereof, and a polishing layer including a polyurethane and a polishing method using the polishing layer.