Abstract: The present invention relates to a process for the production of a cellular composite, and to the resultant cellular composites. This process comprising (A) preparing a mixture of a polyisocyanate, water, and, optionally, one or more additives; (B) adding this mixture under low shear mixing to inorganic hollow microspheres; (C) completely filling a mold with the mixture; and (D) heating the mold containing the mixture to a temperature of from 100 to 280° C., thereby forming the composite.
Type:
Grant
Filed:
February 13, 2002
Date of Patent:
April 3, 2007
Assignee:
Bayer MaterialScience LLC
Inventors:
Kieth G. Spitler, David D. Steppan, Howard S. Duff
Abstract: Black polyurethane foams that exhibit higher strength black colorations without the need for concomitant increases in black colorants therein are provided. Such a resultant jetter black foam article is possible through the unexpectedly effective introduction of small amounts of certain toner compounds or combinations that exhibit specific measurable appearance characteristics. Such toners exhibit at least one absorption peak within a specific range of wavelengths (e.g., from about 560 to 610 nm) and specific ranges of half-height bandwidths (from 40 to 130 nm). Furthermore, such a compound or combination of compounds, is preferably liquid in nature (at room temperature) or in dispersion form and may thus be easily incorporated within target polyurethane precursor compositions for admixture with either black pigments (or dispersions thereof), black polymeric (liquid) colorants, or both.
Abstract: The present invention relates to a method for preparing a polyurethane foam, which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, and an acid-blocked tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein and wherein the tertiary amino alkyl amide catalyst of formula I is acid-blocked.
Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, a gelling catalyst, and a tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein and wherein the tertiary amino alkyl amide catalyst of formula I is acid-blocked.
Type:
Grant
Filed:
December 2, 2003
Date of Patent:
March 13, 2007
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Juan Jesus Burdeniuc, Mark Leo Listemann
Abstract: A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing a blowing agent comprising a C4 or C5 hydrocarbon, or mixtures thereof, with an average molecular weight of ?72 g/mole and a boiling point in the range of 27.8 to 50° C., and a silicone surfactant comprising a polyether-polysiloxane copolymer represented by the following formula: (CH3)3—Si—O—(Si(CH3)2—O)x—(Si(CH3)(R)O)y—Si(CH3)3 where R=(CH2)3—O—(—CH2—CH2—O)a—(CH2—CH(CH3)—O)b—R?, and where R? is H, (CH2)zCH3, or C(O)CH3; x+y+2 is 60–130; x/y is 5–14; z is 0–4; the total surfactant molecular weight, based on the formula, is 7000–30,000 g/mole, the wt % siloxane in the surfactant is 32–70 wt %, the blend average molecular weight (BAMW) of the polyether portion is 450–1000 g/mole, and the mole % of ethylene oxide in the polyether portion is 70–100 mole %.
Type:
Grant
Filed:
December 15, 2003
Date of Patent:
February 27, 2007
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Wayne Robert Furlan, Mark Leo Listemann, Joan Sudbury-Holtschlag, Thomas John Markley, Gary Dale Andrew
Abstract: A method for producing a rigid polyurethane foam, which comprises reacting a polyol with a polyisocyanate in the presence of an amine catalyst and a blowing agent, wherein as the amine catalyst, at least one amine compound having at least one type of substituent selected from the group consisting of a hydroxyl group, a primary amino group and a secondary amino group in its molecule, or N-(2-dimethylaminoethyl)-N?-methylpiperazine, is used, and as the blowing agent, 1,1,1,3,3-pentafluoropropane (HFC-245fa) and/or 1,1,1,3,3-pentafluorobutane (HFC-365mfc) is used.
Abstract: A structural element of closed-cell polyurethane rigid foam, with good thermal insulation and improved sound absorption is achieved by means of surface depressions satisfying specified criteria.
Abstract: The invention relates generally to a stable flexible latex foam. The latex foam will contain at least one polymer having a plurality of hard domains and a plurality of soft domains, a micelle forming agent, a hydrocarbon propellant substantially free of dimethyl ether, and an agent which is a solvent for said micelle forming agent and an emulsifier for said hydrocarbon propellant.
Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, and a tertiary amine amide catalyst composition represented by formula (I): wherein A, R1–R6, and n are defined herein and wherein the tertiary amino amide catalyst of formula I is acid-blocked.
Abstract: Process for preparing flexible polyurethane foam by reacting an MDI-based polyisocyanate and a polyether polyol with a high oxyethylene content in a mold.
Type:
Grant
Filed:
July 24, 2002
Date of Patent:
January 30, 2007
Assignee:
Huntsman International LLC
Inventors:
Gerhard Jozef Bleys, Eric Huygens, Jan-Willem Leenslag, Herman Eugene Germain Moureau
Abstract: Foam blowing agent blends containing trans-1,2-dichloroethylene and one or more hydrofluorocarbons are provided, as are foam compositions containing such blends. The resulting foams exhibit dramatic improvement in fire performance.
Abstract: The invention relates to flame resistant rigid foams and formulations useful for the production thereof. The polyol formulation must include at least one substance which is inert with respect to isocyanates, does not deplete the ozone layer and has a boiling point below 55° C. and a reaction product of at least one compound with an aromatic ring, at least one aldehyde or ketone and at least one primary or secondary amine. This polyol formulation is reacted with an isocyanate, optionally with other commonly used additives, to produce rigid flame resistant foams.
Type:
Grant
Filed:
March 10, 2003
Date of Patent:
November 28, 2006
Assignee:
Bayer Aktiengesellschaft
Inventors:
Rolf Albach, Michael Brockelt, Juan Cirujeda-Ranzenberger
Abstract: A process for producing a finely cellular polyurethane foam by mixing a first ingredient comprising an isocyanate compound and a second ingredient comprising a compound containing an active hydrogen group, characterized by comprising adding a nonionic silicone surfactant containing no hydroxyl group to at least one of the first ingredient and the second ingredient in an amount of 0.1 to 5 wt %, excluding 5 wt %, based on the total amount of the first ingredient and the second ingredient, subsequently agitating the surfactant containing ingredient together with an unreactive gas, which has no reactivity to isocyanate group or active hydrogen group, to disperse the unreactive gas as fine bubbles to prepare a bubble dispersion and then mixing the bubble dispersion with the remaining ingredient to cure the resultant mixture and forming finely cellular structure into the resultant polyurethane foam by the fine bubbles of the bubble dispersion.
Abstract: Energy absorbing flexible foams can be produced by reacting an isocyanate with a first polyol, prepared at least in part by an active double metal cyanide catalyst and a second polyether polyol is prepared at least in part by a basic or acidic catalyst.
Type:
Grant
Filed:
October 3, 2002
Date of Patent:
August 22, 2006
Assignee:
Bayer Corporation
Inventors:
Neil H. Nodelman, David A. Radovich, Albert Magnotta, Carl E. Holsinger
Abstract: The present invention relates to polyol dispersions with long-term stability, to cellular polyurethane moldings produced therewith, to processes for their preparation and to their use.
Abstract: A viscoelastic foam is provided having an amine-based polyol system to impart strength, recoverability and endurance to the foam, and an appropriately selected trifunctional non-amine-based polyol system to provide flexibility to the foam. The combination of amine-based and non amine-based polyols provides a viscoelastic semi-rigid foam with excellent impact and recovery properties, recovering to substantially 100% of its initial volume and shape following an impact, yet with high rigidity and stiffness so that it is effective at absorbing high as well as low-energy impacts. A method of making the above viscoelastic foam is also provided. In a preferred embodiment, the foam is made using an allophanate-modified MDI prepolymer in order to provide the isocyanate in liquid form at standard temperature and pressure in order to simplify the production of the invented viscoelastic foams.
Abstract: A composition and method for consolidating aggregate material is disclosed. The method includes introducing a reaction composition into the aggregate material and allowing it to reach on form a polymer which binds the aggregate together. The composition includes polyol, isocyanate, and ester.
Abstract: Disclosed herein are compositions useful for introducing metal carboxylate salts as catalysts into systems useful for producing polyurethane and polyisocyanurate foams. The methods permit the introduction of such catalysts in the absence of substantial amounts of water which otherwise cause inferior foams to be produced. A method for producing foam employing the catalysts are also described.
Type:
Grant
Filed:
July 30, 2003
Date of Patent:
May 23, 2006
Assignee:
Huntsman Petrochemical Corporation
Inventors:
Robert A. Grigsby, Jr., Robert L. Zimmerman, Ernest L. Rister, Jr.
Abstract: Disclosed is a composition for preparing a rigid polyurethane foam having a good demolding property by defining polyol component and catalyst component. The polyol component comprises 40˜60 wt. % of polyol obtained by polymerization with an organic oxide using sorbitol as an initiator, 5˜10 wt. % of polyol obtained by polymerization with an organic oxide using ethylene diamine as an initiator, 20˜30 wt. % of polyol obtained by polymerization with an organic oxide using toluene diamine or toluene diamine and triethanol amine as a single or a complex initiator, and, optionally, 5˜20 wt. % of multivalent polyol of an ester structure, and the catalyst component is chosen in a group comprising a foaming catalyst, a gelling catalyst, a trimerization catalyst, a mixed form of the foaming catalyst and the gelling catalyst, and compound thereof.