Patents Examined by John M. Cooney, Jr.
  • Patent number: 7199168
    Abstract: The present invention relates to a process for the production of a cellular composite, and to the resultant cellular composites. This process comprising (A) preparing a mixture of a polyisocyanate, water, and, optionally, one or more additives; (B) adding this mixture under low shear mixing to inorganic hollow microspheres; (C) completely filling a mold with the mixture; and (D) heating the mold containing the mixture to a temperature of from 100 to 280° C., thereby forming the composite.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: April 3, 2007
    Assignee: Bayer MaterialScience LLC
    Inventors: Kieth G. Spitler, David D. Steppan, Howard S. Duff
  • Patent number: 7199164
    Abstract: Black polyurethane foams that exhibit higher strength black colorations without the need for concomitant increases in black colorants therein are provided. Such a resultant jetter black foam article is possible through the unexpectedly effective introduction of small amounts of certain toner compounds or combinations that exhibit specific measurable appearance characteristics. Such toners exhibit at least one absorption peak within a specific range of wavelengths (e.g., from about 560 to 610 nm) and specific ranges of half-height bandwidths (from 40 to 130 nm). Furthermore, such a compound or combination of compounds, is preferably liquid in nature (at room temperature) or in dispersion form and may thus be easily incorporated within target polyurethane precursor compositions for admixture with either black pigments (or dispersions thereof), black polymeric (liquid) colorants, or both.
    Type: Grant
    Filed: March 27, 2003
    Date of Patent: April 3, 2007
    Assignee: Milliken & Company
    Inventors: Jusong Xia, Rajnish Batlaw
  • Patent number: 7192990
    Abstract: The present invention relates to a method for preparing a polyurethane foam, which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, and an acid-blocked tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein and wherein the tertiary amino alkyl amide catalyst of formula I is acid-blocked.
    Type: Grant
    Filed: December 2, 2003
    Date of Patent: March 20, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Juan Jesus Burdeniuc
  • Patent number: 7189765
    Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, a gelling catalyst, and a tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein and wherein the tertiary amino alkyl amide catalyst of formula I is acid-blocked.
    Type: Grant
    Filed: December 2, 2003
    Date of Patent: March 13, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Juan Jesus Burdeniuc, Mark Leo Listemann
  • Patent number: 7183330
    Abstract: A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing a blowing agent comprising a C4 or C5 hydrocarbon, or mixtures thereof, with an average molecular weight of ?72 g/mole and a boiling point in the range of 27.8 to 50° C., and a silicone surfactant comprising a polyether-polysiloxane copolymer represented by the following formula: (CH3)3—Si—O—(Si(CH3)2—O)x—(Si(CH3)(R)O)y—Si(CH3)3 where R=(CH2)3—O—(—CH2—CH2—O)a—(CH2—CH(CH3)—O)b—R?, and where R? is H, (CH2)zCH3, or C(O)CH3; x+y+2 is 60–130; x/y is 5–14; z is 0–4; the total surfactant molecular weight, based on the formula, is 7000–30,000 g/mole, the wt % siloxane in the surfactant is 32–70 wt %, the blend average molecular weight (BAMW) of the polyether portion is 450–1000 g/mole, and the mole % of ethylene oxide in the polyether portion is 70–100 mole %.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: February 27, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Wayne Robert Furlan, Mark Leo Listemann, Joan Sudbury-Holtschlag, Thomas John Markley, Gary Dale Andrew
  • Patent number: 7183331
    Abstract: A method for producing a rigid polyurethane foam, which comprises reacting a polyol with a polyisocyanate in the presence of an amine catalyst and a blowing agent, wherein as the amine catalyst, at least one amine compound having at least one type of substituent selected from the group consisting of a hydroxyl group, a primary amino group and a secondary amino group in its molecule, or N-(2-dimethylaminoethyl)-N?-methylpiperazine, is used, and as the blowing agent, 1,1,1,3,3-pentafluoropropane (HFC-245fa) and/or 1,1,1,3,3-pentafluorobutane (HFC-365mfc) is used.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: February 27, 2007
    Assignee: Tosoh Corporation
    Inventors: Hiroyuki Kiso, Katsumi Tokumoto, Yutaka Tamano
  • Patent number: 7179846
    Abstract: A structural element of closed-cell polyurethane rigid foam, with good thermal insulation and improved sound absorption is achieved by means of surface depressions satisfying specified criteria.
    Type: Grant
    Filed: March 9, 2004
    Date of Patent: February 20, 2007
    Assignee: Bayer MaterialScience AG
    Inventor: Thorsten Dreier
  • Patent number: 7179845
    Abstract: The invention relates generally to a stable flexible latex foam. The latex foam will contain at least one polymer having a plurality of hard domains and a plurality of soft domains, a micelle forming agent, a hydrocarbon propellant substantially free of dimethyl ether, and an agent which is a solvent for said micelle forming agent and an emulsifier for said hydrocarbon propellant.
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: February 20, 2007
    Assignee: Fomo Products, Inc.
    Inventor: Anthony Taylor
  • Patent number: 7169823
    Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, and a tertiary amine amide catalyst composition represented by formula (I): wherein A, R1–R6, and n are defined herein and wherein the tertiary amino amide catalyst of formula I is acid-blocked.
    Type: Grant
    Filed: December 2, 2003
    Date of Patent: January 30, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Juan Jesus Burdeniuc
  • Patent number: 7169824
    Abstract: Process for preparing flexible polyurethane foam by reacting an MDI-based polyisocyanate and a polyether polyol with a high oxyethylene content in a mold.
    Type: Grant
    Filed: July 24, 2002
    Date of Patent: January 30, 2007
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Eric Huygens, Jan-Willem Leenslag, Herman Eugene Germain Moureau
  • Patent number: 7144926
    Abstract: Foam blowing agent blends containing trans-1,2-dichloroethylene and one or more hydrofluorocarbons are provided, as are foam compositions containing such blends. The resulting foams exhibit dramatic improvement in fire performance.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: December 5, 2006
    Assignee: Arkema Inc.
    Inventors: Steve M. Galaton, Christopher Bertelo
  • Patent number: 7141613
    Abstract: The invention relates to flame resistant rigid foams and formulations useful for the production thereof. The polyol formulation must include at least one substance which is inert with respect to isocyanates, does not deplete the ozone layer and has a boiling point below 55° C. and a reaction product of at least one compound with an aromatic ring, at least one aldehyde or ketone and at least one primary or secondary amine. This polyol formulation is reacted with an isocyanate, optionally with other commonly used additives, to produce rigid flame resistant foams.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: November 28, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Albach, Michael Brockelt, Juan Cirujeda-Ranzenberger
  • Patent number: 7098255
    Abstract: A process for producing a finely cellular polyurethane foam by mixing a first ingredient comprising an isocyanate compound and a second ingredient comprising a compound containing an active hydrogen group, characterized by comprising adding a nonionic silicone surfactant containing no hydroxyl group to at least one of the first ingredient and the second ingredient in an amount of 0.1 to 5 wt %, excluding 5 wt %, based on the total amount of the first ingredient and the second ingredient, subsequently agitating the surfactant containing ingredient together with an unreactive gas, which has no reactivity to isocyanate group or active hydrogen group, to disperse the unreactive gas as fine bubbles to prepare a bubble dispersion and then mixing the bubble dispersion with the remaining ingredient to cure the resultant mixture and forming finely cellular structure into the resultant polyurethane foam by the fine bubbles of the bubble dispersion.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: August 29, 2006
    Assignee: Toyo Tire & Rubber Co., Ltd.
    Inventors: Hiroshi Seyanagi, Kaoru Inoue, Kazuyuki Ogawa, Takashi Masui, Koichi Ono
  • Patent number: 7094811
    Abstract: Energy absorbing flexible foams can be produced by reacting an isocyanate with a first polyol, prepared at least in part by an active double metal cyanide catalyst and a second polyether polyol is prepared at least in part by a basic or acidic catalyst.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: August 22, 2006
    Assignee: Bayer Corporation
    Inventors: Neil H. Nodelman, David A. Radovich, Albert Magnotta, Carl E. Holsinger
  • Patent number: 7087657
    Abstract: The present invention relates to polyol dispersions with long-term stability, to cellular polyurethane moldings produced therewith, to processes for their preparation and to their use.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: August 8, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Haas, Alfred Neuhaus
  • Patent number: 7078443
    Abstract: A viscoelastic foam is provided having an amine-based polyol system to impart strength, recoverability and endurance to the foam, and an appropriately selected trifunctional non-amine-based polyol system to provide flexibility to the foam. The combination of amine-based and non amine-based polyols provides a viscoelastic semi-rigid foam with excellent impact and recovery properties, recovering to substantially 100% of its initial volume and shape following an impact, yet with high rigidity and stiffness so that it is effective at absorbing high as well as low-energy impacts. A method of making the above viscoelastic foam is also provided. In a preferred embodiment, the foam is made using an allophanate-modified MDI prepolymer in order to provide the isocyanate in liquid form at standard temperature and pressure in order to simplify the production of the invented viscoelastic foams.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: July 18, 2006
    Assignee: Intellectual Property Holdings, LLC
    Inventor: Charles M. Milliren
  • Patent number: 7078442
    Abstract: A composition and method for consolidating aggregate material is disclosed. The method includes introducing a reaction composition into the aggregate material and allowing it to reach on form a polymer which binds the aggregate together. The composition includes polyol, isocyanate, and ester.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: July 18, 2006
    Assignee: Baysystems North America LLC
    Inventor: Scott A Brown
  • Patent number: 7049265
    Abstract: Disclosed herein are compositions useful for introducing metal carboxylate salts as catalysts into systems useful for producing polyurethane and polyisocyanurate foams. The methods permit the introduction of such catalysts in the absence of substantial amounts of water which otherwise cause inferior foams to be produced. A method for producing foam employing the catalysts are also described.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: May 23, 2006
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Robert A. Grigsby, Jr., Robert L. Zimmerman, Ernest L. Rister, Jr.
  • Patent number: 7008974
    Abstract: Disclosed is a composition for preparing a rigid polyurethane foam having a good demolding property by defining polyol component and catalyst component. The polyol component comprises 40˜60 wt. % of polyol obtained by polymerization with an organic oxide using sorbitol as an initiator, 5˜10 wt. % of polyol obtained by polymerization with an organic oxide using ethylene diamine as an initiator, 20˜30 wt. % of polyol obtained by polymerization with an organic oxide using toluene diamine or toluene diamine and triethanol amine as a single or a complex initiator, and, optionally, 5˜20 wt. % of multivalent polyol of an ester structure, and the catalyst component is chosen in a group comprising a foaming catalyst, a gelling catalyst, a trimerization catalyst, a mixed form of the foaming catalyst and the gelling catalyst, and compound thereof.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: March 7, 2006
    Assignee: LG Electronics Inc.
    Inventors: Hyun-Keun Cho, Ju-Hyun Kim
  • Patent number: 7008973
    Abstract: A flexible, flame-retarded, polyurethane foam comprising brominated and/or phosphorous flame retardants and an acid scavenger.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: March 7, 2006
    Assignee: PABU Services, Inc.
    Inventors: Stephen B. Falloon, Richard S. Rose, Mathew D. Phillips