Abstract: A composition of matter includes a polymerizable mixture comprising 1 to 99 weight percent of a first monomer and an initiator therefor, the first monomer being one of 1) at least one free-radically polymerizable monomer or 2) at least one cyanate ester monomer, and 99 to 1 weight percent of a second monomer and an initiator therefor, the second monomer being the member of 1) or 2) that is not selected as the first monomer, wherein the curative for the cyanate ester is a transition metal-containing organometallic compound curing agent and the curative for the free-radically polymerizable monomer is a free-radical generating curing agent or a transition metal-containing organometallic compound.
Type:
Grant
Filed:
July 17, 1996
Date of Patent:
January 26, 1999
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Fred B. McCormick, David J. Drath, Ilya Gorodisher, Michael A. Kropp, Michael C. Palazzotto, Melville R. V. Sahyun
Abstract: The preent invention relates to a sustained-release oral ointment which comprises a hydrophobic ointment base, an adhesive substance, an aluminum compound and a drug. The ointment is useful as a sustained-release oral ointment which has applicability to an oral mucosa, particularly to a peridontal pocket, sustained-release properties to supply a drug to affected part over a long period of time while maintaining the concentration thereof at a sufficiently high level, and enhanced ratio of utilization of drug (the ratio of the total amount of drug released to affected part to the total amount of drug in the ointment applied).
Abstract: Resins for use in chemically amplified resists are represented by the general formula (I): ##STR1## wherein R.sub.1 is t-butyl or tetrahydropyranyl; R.sub.2 is hydrogen or methyl; n and m are integers; and the ratio n/((m+n) ranges from 0.1 to 0.9. Methods for manufacturing the resins comprise reacting a monomer represented by the formula (II): ##STR2## with a monomer represented by the formula (III): ##STR3## to form a copolymer represented by the formula (IV): ##STR4## wherein R.sub.1 and R.sub.2 are defined as above; and hydrolyzing acetoxy groups contained in the copolymer represented by the formula (IV) to form the resin compositions.
Abstract: The invention is directed to compositions containing at least one olefinic monomer, at least one polymer prepared form an olefinic monomer, an indicator dye to the basic structure of which an olefinic polymerisable group is covalently bonded directly or via a bridge group, at least one diolefinic cross-linking agent, and an effective amount of a polymerisation initiator; to polymerisates of the compositions, the polymerisates being in the form of interpenetrating networks; to membranes and unsupported films prepared from the polymerisates; to carrier materials coated with the compositions and polymerisates; to optical sensors prepared from the polymerisates; and to methods of determining ions and/or gases in solutions and/or blood.
Abstract: A system of the present invention for applying a substance to an applied area includes a patch (11), as well as apparatus (12, 14, 16, 18 and 21) and methods for making the same. The patch includes backing material (52) and a tri-laminate (54), with a dose of medication sealed therebetween in reservoir (62). To facilitate and increase transdermal and/or topical application of the medication to the applied area, such as the skin of a user, the tri-laminate includes a layer material (68) having at least one opening therein (64), which permits the medication to flow through each opening without tearing or ripping the layer of material covering the reservoir.
Abstract: Solid organic polymers, for example, rubber and plastic particles, which may include coated papers, to especially include as recovered from recycle streams, can be made to have a sulfonated outer layer by treatment with a reactant gas containing sulfur trioxide. A silo apparatus can be employed to make these sulfonated particles, wherein untreated particles fall through the silo which is provided with a reactant gas supply. The sulfonated particles may optionally be neutralized, for example, with moist ammonia. These sulfonated particles can be used in articles of manufacture such as aggregates in cements, organic resins, cellulosics, and so forth, with beneficial properties being imparted to the composite. When used in a Portland cement, for example, increased performance concrete can result. Also, sulfonated sheets may be correspondingly employed for the sulfonated particles.
Abstract: This invention concerns polymers, having fluoroalkoxy side chains, which are made by a novel process comprising reacting a polymer containing hydroxyl groups, especially poly(vinyl alcohol), with a fluorinated olefin in the presence of a base. The resulting polymers are useful in coatings, as in optical wave guides, and antireflective coatings and in other optical devices.
Abstract: The process for the manufacture of (co)polymer powders by aqueous suspension polymerization of at least one monomer which is polymerizable in suspension is conducted in the presence of at least one free-radical generator as catalyst, of at least one dispersing agent and, in addition, of at least one inhibitor scavenging free radicals of at least one complexing agent.
Abstract: A method for conformance control of a reservoir comprising injecting into a zone of the reservoir an aqueous solution of a co-polymer comprising at least one ethylenically unsaturated polar monomer and at least one copolymerizable ethylenically unsaturated ester formed from a hydroxy compound of the formula ROH wherein R is a selected alkyl group, alkenyl group, cycloalkyl group, aryl group or such groups substituted with from 1 to 3 hydroxyl, ether or thio ether groups or a heterocyclic or selected heterocyclic alkylene group and at least one hetereatom selected from oxygen, nitrogen and sulfur and a selected alkenoic or aralkenoic carboxylic acid or sulfonic or phosphoric acid together with a crosslinking agent comprising a multi-valent metal ion capable of crosslinking an acrylic acid polymer to form a viscous gel.
Abstract: Polyacrylates based on alkyl acrylates or alkyl alkylacrylates or mixtures thereof as monomers are prepared in the presence of an initiator composition containing an alkali metal ester enolate and an organic aluminum compound or a mixture thereof, by a process in which an ester which differs from the monomers is present in the initiator composition, the carbon atom .alpha. to the ester group having no acidic proton.
Type:
Grant
Filed:
July 21, 1997
Date of Patent:
November 3, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Stephan Jungling, Christof Mehler, Helmut Schlaad, Bardo Schmitt, Axel Mueller, Horst Weiss, Susanne Steiger
Abstract: It concerns a monomer, a polymer obtained from the monomer and a process for obtaining the said polymer. The monomer consists of a polyether containing at least 3 ether units and pyrrole or thiophene units bonded to the ends of the chains of this polyether via, for each of these heterocycic compounds, either their carbon atoms in the 3,3'-positions of their heterocycles or, as regards more particularly the pyrrole groups, via their respective nitrogen atoms, the 2- and 2'-positions of these heterocycles being, however, free of all substitutions or, at the very most, substituted by easily removable groups (protective groups, for example).Application to the purification and recovery of metal ions such as radioactive silver.
Type:
Grant
Filed:
August 20, 1996
Date of Patent:
November 3, 1998
Assignee:
Electricite de France -- Service National
Abstract: The present invention is directed to a porous polymer micro-particle, in the form of broken spheres, open to a porous oleophilic interior surface area, having a high oil and water absorbency and an apparent bulk density of about 0.02 to about 0.1 grams/cc.
Abstract: (1) A perfluoroalkyl diester of maleic acid or fumaric acid,(2) a copolymer obtained by polymerizing the perfluoroalkyl ester, a lower alkyl (meth)acrylate and, if necessary, styrene, and(3) a stainproofing agent comprising the copolymergive excellent water repellency, oil repellency and stainproof properties which have never been heretofore obtained.
Abstract: A process for producing a microporous oil sorbent polymer comprising the steps of:dissolving a polyunsaturated monomer in a silicone organic solvent to provide a monomer mixture containing more than 90% by weight polyunsaturated monomer;polymerizing said monomers by precipitation polymerization, under an inert atmosphere to precipitate microporous, micro-particles in the form of micro-particles, agglomerates and aggregates having a bulk density of about 0.02 gm/cm.sup.3 to about 0.01 gm/cm.sup.3 and capable of adsorbing at least about 20% by weight organic materials based on the total weight of polymer plus adsorbed organic material.
Abstract: The invention relates to an active ingredient patch in the form of a laminate, the patch comprising a carrier and a matrix of a single polymer and if appropriate another polymer and vitamin E.
Abstract: This invention provides a coating composition which utilizes a free radical initiator and an organic tintability additive which remains substantially unpolymerized even after the remainder of the coating composition is cured. Superior tintability and adhesion to polycarbonate makes this coating particularly suitable for making tinted opthalmic lenses.
Type:
Grant
Filed:
January 10, 1997
Date of Patent:
October 27, 1998
Assignee:
General Electric Company
Inventors:
George F. Medford, Gregory R. Gillette, Norio Sato
Abstract: Invented are controlled release formulations of medicaments for oral administration comprising a hydrophobic waxy material and prepared by thermal infusion.
Type:
Grant
Filed:
May 25, 1995
Date of Patent:
October 20, 1998
Assignee:
SmithKline Beecham Corporation
Inventors:
Nageswara R. Palepu, Gopadi M. Venkatesh
Abstract: The present invention provides a multi-phase polymerization process for making a water insoluble polymer. The process includes (1) providing a mixture comprising carbon dioxide and an aqueous phase, and containing a monomer and a polymerization initiator, and (2) polymerizing the monomer in the reaction mixture. The monomer may be a hydrocarbon or a fluorinated monomer. The polymerization initiator may be soluble in the aqueous phase, soluble in carbon dioxide, or insoluble in both the aqueous phase and carbon dioxide, such that the initiator forms a separate phase. The present invention also provides multi-phase polymerization reaction mixtures useful in the process of making water insoluble polymers.
Type:
Grant
Filed:
September 26, 1997
Date of Patent:
October 20, 1998
Assignee:
University of North Carolina--Chapel Hill
Abstract: Described are preferred processes for producing linear polyvinylpyridines. The processes involve the use of hydrogen peroxide to initiate polymerization of vinylpyridine monomers in an aqueous solvent. Processes of the invention provide good reaction rates and conversions, and are particularly advantageous in achieving control of the M.sub.w 's of the final product polymers.
Type:
Grant
Filed:
August 2, 1996
Date of Patent:
October 20, 1998
Assignee:
Reilly Industries, Inc.
Inventors:
Eric F. V. Scriven, James R. Stout, Ramiah Murugan, James G. Keay
Abstract: Fluoroelastomers having copolymerized units of vinylidene fluoride and at least one other fluorinated monomer are prepared in aqueous suspension using an initiator comprising a solution of an oil soluble peroxide in a water-soluble hydrocarbon solvent.