Abstract: Disclosed herein is a catalyst composite containing a perovskite-oxide and an oxide support, methods of preparing a catalyst composite containing a perovskite-oxide and an oxide support, and the use thereof for CO2 conversion by a reverse water gas shift chemical looping (RWGS-CL) process.
Abstract: Process for preparing a catalyst or a trapping mass comprising the following steps: bringing a porous oxide support into contact with a metal salt comprising at least one metal belonging to groups VIB, VIIB, VIIIB, IB or IIB, of which the melting point of said metal salt is between 20° C. and 150° C., for a period of between 5 minutes and 5 hours in order to form a solid mixture, the weight ratio of said metal salt to said porous oxide support being between 0.1 and 1; heating the solid mixture with stirring at a temperature between the melting point of said metal salt and 200° C. and for 5 minutes to 12 hours; calcining the solid obtained in the preceding step at a temperature above 200° C. and below or equal to 1100° C. under an inert atmosphere or under an oxygen-containing atmosphere.
Type:
Grant
Filed:
September 3, 2019
Date of Patent:
May 30, 2023
Assignee:
IFP Energies Nouvelles
Inventors:
Elodie Tellier, Dominique Decottignies, Antoine Fecant
Abstract: An oxidation catalyst for treating an exhaust gas produced by a diesel engine comprises a catalytic region and a substrate, wherein the catalytic region comprises a catalytic material comprising: bismuth (Bi) or an oxide thereof; a Group 8 metal or an oxide thereof; a platinum group metal (PGM) selected from the group consisting of (i) platinum (Pt), (ii) palladium (Pd) and (iii) platinum (Pt) and palladium (Pd); and a support material, which comprises alumina, silica, a mixed oxide of alumina and a refractory oxide, a mixed oxide of silica and a refractory oxide, a composite oxide of alumina and a refractory oxide, a composite oxide of silica and a refractory oxide, alumina doped with a refractory oxide or silica doped with a refractory oxide.
Abstract: Porous particles comprising an active ingredient and a coating exhibiting greater dissolution rate in aqueous media than in alcoholic media are disclosed. A process for the manufacture of the particles is also disclosed, as well as tamper-proof particles and solid dosage forms comprising the coated particles. The differential solubility characteristics of the particle coating allow the particles to be incorporated into abuse-deterrent medicaments.
Abstract: Oxidative dehydrogenation catalysts comprising MoVNbTeO having improved consistency of composition and a 25% conversion of ethylene at less than 420° C. and a selectivity to ethylene above 95% are prepared by treating the catalyst precursor with H2O2 in an amount equivalent to 0.30-2.8 mL H2O2 of a 30% solution per gram of catalyst precursor prior to calcining and treating the resulting catalyst with the equivalent amount of peroxide after calcining.
Type:
Grant
Filed:
July 31, 2019
Date of Patent:
May 2, 2023
Assignee:
NOVA Chemicals (International) S.A.
Inventors:
Vasily Simanzhenkov, Xiaoliang Gao, David Jeffrey Sullivan, Hanna Drag, Marie Barnes
Abstract: The present disclosure provides a method of synthesizing an aluminosilicate molecular sieve by a crystal seed-assisted method, a natural aluminosilicate clay mineral treated and activated by an alkali is used as a crystal seed for synthesis of the aluminosilicate molecular sieve, and the target molecular sieve product is synthesized by hydrothermal crystallization, wherein the synthesis process does not require addition of conventional crystal seeds of a molecular sieve or use of any organic template agent, thus the synthesized product does not require a calcination process to remove the template agent. The method of synthesizing an aluminosilicate molecular sieve by a crystal seed-assisted method can meet the requirements of both crystallinity and nucleation time, and greatly reduce costs of synthesizing the aluminosilicate molecular sieve, and reduce the environmental pollution caused by removal of the template agent by calcinating.
Abstract: An aluminum-rich molecular sieve material of MFS framework type, designated SSZ-123, is provided. SSZ-123 can be synthesized using 1-ethyl-1-[5-(triethylammonio)pentyl]piperidinium cations as a structure directing agent. SSZ-123 may be used in organic compound conversion and/or sorptive processes.
Abstract: A process for synthesis of PtNi high surface area core/shell particles. The processing including formation of PtNi nanoparticles, exposure of the PtNi nanoparticles to oxygen to form a nickel oxide coating on the nanoparticles at the same time the segregation of Ni to surface induces a Pt-skin with PtNi core structure, removal of the nickel oxide coating to form PtNi core/Pt shell (or Pt-skin) structure.
Type:
Grant
Filed:
January 28, 2021
Date of Patent:
April 18, 2023
Assignee:
UChicago Argonne, LLC
Inventors:
Rongyue Wang, Vojislav Stamenkovic, Gregory K. Krumdick, Krzysztof Pupek
Abstract: A catalyst for use in chemical looping combustion is provided. The catalyst includes a mixture of metal oxides dispersed on a ceramic support. The mixture of metal oxides forms a nickel tungsten oxide (NiWO4) interaction complex which functions as an oxygen carrier in the chemical looping combustion reaction.
Type:
Grant
Filed:
April 22, 2021
Date of Patent:
April 18, 2023
Assignee:
UTI LIMITED PARTNERSHIP
Inventors:
Nader Mahinpey, Amr Abdalla Ibrahim Abdalla, Mansour Mohammedramadan Tijani
Abstract: The present disclosure belongs to the field of single-atom catalytic degradation of refractory organic pollutants, and provides a single-atom catalyst for activation of persulfate to generate pure singlet oxygen (1O2) as well as a preparation method and an application thereof. The single-atom catalyst of the present disclosure includes supports and single iron atoms loaded on the support; the supports are graphitic carbon nitride nanosheets; the single iron atoms are bound to the supports in the form of a Fe—N4 coordination structure. The present disclosure employs graphitic carbon nitride nanosheets as the supports, so that the single iron atoms have a uniform surrounding environment and the persulfate is only converted into 1O2 when being activated; 1O2 has good selectivity and anti-interference ability, so the single-atom catalyst provided in the present disclosure may have excellent selectivity and anti-interference performance in the degradation of organic pollutants.
Abstract: The invention relates to a lead-free piezoceramic material based on bismuth sodium titanate (BST) having the following parent composition: x(Bi0.5Na0.5)TiO3-yBaTiO3-zSrTiO3 where x+y+z=1 and 0<x<1, 0<y<1, 0?z?0.07 or x(Bi0.5Na0.5)TiO3-yBaTiO3-zCaTiO3 where x+y+z=1 and 0<x<1, 0<y<1, 0<z?0.05 or x(Bi0.5Na0.5)TiO3-y(Bi0.5K0.5)TiO3-zBaTiO3 where x+y+z=1 and 0<x<1, 0<y<1, 0?z<1, characterized by addition of a phosphorus-containing material in a quantity that gives a phosphorus concentration of from 100 to 2000 ppm in the piezoceramic material.
Type:
Grant
Filed:
January 14, 2019
Date of Patent:
April 4, 2023
Assignee:
PI CERAMIC GMBH
Inventors:
Eberhard Hennig, Antje Kynast, Michael Töpfer, Michael Hofmann
Abstract: The invention relates to a V-Ni2P/g-C3N4 photocatalyst, a preparation method, and application thereof. The V-Ni2P/g-C3N4 photocatalyst is a composite material of V-Ni2P and g-C3N4, wherein V-Ni2P has the spherical structure formed by nanosheets; the mass ratio of the V-Ni2P and g-C3N4 is (0.01 to 0.2):1.
Type:
Grant
Filed:
August 25, 2021
Date of Patent:
April 4, 2023
Assignee:
SHAANXI UNIVERSITY OF SCIENCE & TECHNOLOGY
Abstract: A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P. or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.
Type:
Grant
Filed:
January 4, 2021
Date of Patent:
March 14, 2023
Assignees:
SAUDI ARABIAN OIL COMPANY, BORESKOV INSTITUTE OF CATALYSIS
Abstract: The present disclosure relates to an ionic liquid composition and a process for its preparation. The process of the present disclosure is simple, single pot and efficient process for preparing the ionic liquid composition which is effective in a Friedel Craft reaction like, alkylation reaction, trans-alkylation, and acylation. The present disclosure envisages an ionic liquid composition comprising at least one metal hydroxide; at least one metal halide; and at least one solvent. Also envisaged is a process for preparing an ionic liquid composition. The process comprises mixing in a reaction vessel, at least one metal hydroxide and at least one metal halide in the presence of at least one solvent under a nitrogen atmosphere and continuous stirring followed by cooling under continuous stirring to obtain the ionic liquid composition.
Abstract: A synthesis process for forming nanodendrites. The nanodendrites are utilized in a process to form a heterojunction catalyst. Nanodendrites may include PtRu8 nanodendrites that can be oxidized through annealing to form PtRuO2. One heterojunction catalyst comprises PtRuO2 on a carbon support.
Abstract: The present disclosure relates to a method for producing metal oxide nanoparticles includes a first step of preparing a reaction solution containing a metal complex, an alcohol, and water; a second step of heating the reaction solution for phase-separation under a hermetically sealed atmosphere where the volumetric expansion ratio of the reaction solution reaches 5 to 15%; a third step of holding the reaction solution heated in the second step for 30 minutes or more for dehydrating the metal complex to precipitate the metal oxide nanoparticles; and a fourth step of collecting the metal oxide nanoparticles after the metal oxide nanoparticles are cooled.
Type:
Grant
Filed:
January 23, 2020
Date of Patent:
February 28, 2023
Assignees:
FURUKAWA ELECTRIC CO., LTD., NATIONAL INSTITUTE FOR MATERIALS SCIENCE
Abstract: A hydrotalcite is represented by formula (1): (M2+)1-X(M3+)X(OH)2(An?)X/n·mH2O??(1), wherein M2+ indicates a divalent metal, M3+ indicates a trivalent metal, An? indicates an n-valent anion, n indicates an integer of 1 to 6, 0.17?x?0.36, and 0?m?10. The hydrotalcite has (A) a lattice strain in the <003> direction is 3×10?3 or less as measured using an X-ray diffraction method; (B) primary particles with an average width between 5 nm and 200 nm inclusive per a SEM method; and (C) a degree of monodispersity of 50% or greater (degree of monodispersity (%)=(average width of primary particles as measured using the SEM method/average width of secondary particles as measured using a dynamic light scattering method)×100). A resin containing the hydrotalcite, a suspension containing the hydrotalcite and a method for producing the hydrotalcite are disclosed.
Abstract: Paint and coating compositions including a low molecular weight chitosan composition that may be incorporated in a coating composition at higher loading levels, which exhibits one or more of improved elongation, improved thermocycling characteristics, reduced leaching of coating components, are lesser susceptibility to fungal and mildew defacement than conventional coatings or coatings containing higher molecular weight chitosan compounds, articles coated in the same, and methods for making said coatings and coated articles.
Abstract: The present invention refers to a mineral matter powder preparation by wet process without acrylic additive or other grinding aid additives and to the use of said mineral matter after an optional hydrophobic treatment. Said mineral material having superior dispersing properties.
Type:
Grant
Filed:
May 14, 2019
Date of Patent:
January 17, 2023
Assignee:
Omya International AG
Inventors:
Pierre Blanchard, Jean-Pierre Elgoyhen, Beat Karth, Holger Müller, Jürgen Spehn, Martin Brunner, Pascal Gonnon, Michael Tinkl
Abstract: Methods of producing an isomerization catalyst include preparing a catalyst precursor solution, hydrothermally treating the catalyst precursor solution to produce a magnesium oxide precipitant, and calcining the magnesium oxide precipitant to produce the isomerization catalyst. The catalyst precursor solution includes at least a magnesium precursor, a hydrolyzing agent, and polyethylene glycol. Methods of producing propene from a butene-containing feedstock with the isomerization catalyst and a metathesis catalyst are also disclosed.
Type:
Grant
Filed:
December 3, 2019
Date of Patent:
December 6, 2022
Assignee:
Saudi Arabian Oil Company
Inventors:
Afnan Alghannam, Sohel K. Shaikh, Munir D. Khokhar, Faisal H. Alshafei