Patents Examined by Jun Li
  • Patent number: 11260374
    Abstract: The present invention relates to a Cu-based catalyst, a preparation process thereof and its use as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst contains copper, at least one auxiliary metal selected from metal of Group IIA, non-noble metal of Group VIII, metal of Group VIB, metal of Group VIIB, metal of Group IIB and lanthanide metal of periodic table of elements, and an alkali metal, and further contains at least one ketone additive selected from a ketone represented by formula (II) and a ketone represented by formula (II?). Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin. R1-C(?O)—CH(OH)—R2??(II) R1-C(?O)—CH(?O)—R2??(II?) In formulae (II) and (II?), each group is defined as in the description.
    Type: Grant
    Filed: November 14, 2018
    Date of Patent: March 1, 2022
    Assignees: China Petroleum & Chemical Corporation, Dalian Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.
    Inventors: Kai Qiao, Feng Zhou, Jie Su, Huixia Ma, Qingtong Zhai, Shumei Zhang
  • Patent number: 11241672
    Abstract: A nanomaterial catalyst comprising a partially crystalline porous magnesium silicate support and gold nanoparticles, the catalyst being useful for oxidative cracking of hydrocarbons, specifically the production of light olefins from propane. Methods of producing the nanomaterial catalyst as well as a method of oxidative cracking of a hydrocarbon to produce light olefins are provided.
    Type: Grant
    Filed: October 20, 2021
    Date of Patent: February 8, 2022
    Assignee: King Abdulaziz University
    Inventors: Katabathini Narasimharao, Sulaiman Nasir Basahel, Abdulmohsen Al Shehri, Fawaz Saleh Al-Sultan
  • Patent number: 11241678
    Abstract: A method for making organo-metal material involves providing a metal ion source in a medium that removes metal ions from the source and forms 1D metal-containing coordination polymers that self-assemble and precipitate as at least one of a 2D and 3D coordination polymer material that can be thermally treated to produce a porous metal oxide material.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: February 8, 2022
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Martin M. Thuo, Boyce S. Chang, Jiahao Chen, Aaron J. Rossini
  • Patent number: 11213804
    Abstract: Disclosed herein are methods of preparing dehydrogenation catalysts using non-halogen containing metal sources. The methods generally comprise the steps of providing a first solution comprising anions of a first metal selected from Group 14 of the Periodic Table of Elements, and impregnating an inorganic support with the first solution to obtain a first impregnated inorganic support, wherein the first solution has a pH value of less than the isoelectric point of the inorganic support. The dehydrogenation catalysts prepared in accordance with the methods of the present disclosure are typically free or substantially free of halogen species. Such catalysts may be particularly useful in the dehydrogenation of a feed comprising cyclohexane and/or methylcyclopentane.
    Type: Grant
    Filed: February 7, 2019
    Date of Patent: January 4, 2022
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Doron Levin
  • Patent number: 11207661
    Abstract: A process for preparing a peptized alumina having increased solids and acid contents and a decreased water content. The process comprising mixing a boehmite or pseudoboehmite alumina and acid with a high intensity, high energy mixer at a ratio of 0.16 to 0.65 moles acid/moles alumina for a time period sufficient to form a substantially free-flowing solid particulate having a solids content of 45 to 65 wt %. When used in catalyst manufacture, peptized alumina produced by the process provides an increased rate in catalyst production and decreased costs due to high solids concentration and the presence of less water to be evaporated.
    Type: Grant
    Filed: July 25, 2017
    Date of Patent: December 28, 2021
    Assignee: W.R. Grace & Co.—CONN.
    Inventors: Udayshankar Singh, Sundaram Krishnamoorthy, Michael Scott Ziebarth, Wu-Cheng Cheng
  • Patent number: 11203008
    Abstract: A nanomaterial catalyst comprising a partially crystalline porous magnesium silicate support and gold nanoparticles, the catalyst being useful for oxidative cracking of hydrocarbons, specifically the production of light olefins from propane. Methods of producing the nanomaterial catalyst as well as a method of oxidative cracking of a hydrocarbon to produce light olefins are provided.
    Type: Grant
    Filed: June 22, 2021
    Date of Patent: December 21, 2021
    Assignee: King Abdulaziz University
    Inventors: Katabathini Narasimharao, Sulaiman Nasir Basahel, Abdulmohsen Al Shehri, Fawaz Saleh Al-Sultan
  • Patent number: 11183695
    Abstract: A heat treatment method performed to form a particle structure of a carbon-supported metal catalyst includes preparing the carbon-supported metal catalyst by supporting metals on a support including carbon. The heat treatment method also includes applying heat shock to the carbon-supported metal catalyst. The applying heat shock to the carbon-supported metal catalyst includes raising a temperature of the carbon-supported metal catalyst to a first temperature and lowering the temperature of the carbon-supported metal catalyst to a second temperature. A difference between the first temperature and the second temperature is 500° C. to 1,100° C. The applying heat shock to the carbon-supported metal catalyst is repeated at least once. A carbon-supported metal catalyst is prepared by the heat treatment method.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: November 23, 2021
    Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION
    Inventor: Ju Hee Lee
  • Patent number: 11179713
    Abstract: A process for the preparation of a catalyst from a catalytic precursor comprising a support based on alumina and/or silica-alumina and/or zeolite and comprising at least one element of group VIB and optionally at least one element of group VIII, by impregnation of said precursor with a solution of a C1-C4 dialkyl succinate. An impregnation step for impregnation of said precursor which is dried, calcined or regenerated, with at least one solution containing at least one carboxylic acid other than acetic acid, then maturing and drying at a temperature less than or equal to 200° C., optionally a heat treatment at a temperature lower than 350° C., followed by an impregnation step with a solution containing at least one C1-C4 dialkyl succinate followed by maturing and drying at a temperature less than 200° C. without subsequent calcination step. The catalyst is used in hydrotreatment and/or hydroconversion.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: November 23, 2021
    Assignees: IFP ENERGIES NOUVELLES, TOTAL RAFFINAGE MARKETING
    Inventors: Bertrand Guichard, Laurent Simon, Sylvie Lopez, Valentina De Grandi, Delphine Minoux, Jean-Pierre Dath
  • Patent number: 11173481
    Abstract: Disclosed are a metal single-atom catalyst and a method for preparing the same. The method uses a minimal amount of chemicals and is thus environmentally friendly compared to conventional chemical and/or physical methods. In addition, the method enables the preparation of a single-atom catalyst in a simple and economical manner without the need for further treatment such as acid treatment or heat treatment. Furthermore, the method is universally applicable to the preparation of single-atom catalysts irrespective of the kinds of metals and supports, unlike conventional methods that suffer from very limited choices of metal materials and supports. Therefore, the method can be widely utilized to prepare various types of metal single-atom catalysts. All metal atoms in the metal single-atom catalyst can participate in catalytic reactions. This optimal atom utilization achieves maximum reactivity per unit mass and can minimize the amount of the metal used, which is very economical.
    Type: Grant
    Filed: August 7, 2019
    Date of Patent: November 16, 2021
    Assignees: Korea Institute of Science and Technology, Global Frontier Center for Multiscale Energy Systems
    Inventors: Sung Jong Yoo, Injoon Jang, Hee-Young Park, So Young Lee, Hyun Seo Park, Jin Young Kim, Jong Hyun Jang, Hyoung-Juhn Kim
  • Patent number: 11161093
    Abstract: A nanomaterial catalyst comprising a partially crystalline porous magnesium silicate support and gold nanoparticles, the catalyst being useful for oxidative cracking of hydrocarbons, specifically the production of light olefins from propane. Methods of producing the nanomaterial catalyst as well as a method of oxidative cracking of a hydrocarbon to produce light olefins are provided.
    Type: Grant
    Filed: April 16, 2021
    Date of Patent: November 2, 2021
    Assignee: King Abdulaziz University
    Inventors: Katabathini Narasimharao, Sulaiman Nasir Basahel, Abdulmohsen Al Shehri, Fawaz Saleh Al-Sultan
  • Patent number: 11155473
    Abstract: A method of forming a metal oxide material having a rod shape or polyhedral nanostructure includes preparing a first reverse micro-emulsion system comprising an aqueous precipitating agent dispersion and a second reverse micro-emulsion system containing an aqueous metal salt dispersion; combining the micro-emulsions together to initiate a reaction; allowing the reaction to continue to form a product mixture comprising a metal oxide gel and aqueous media; separating the metal oxide gel from the aqueous media; collecting the metal oxide gel; and calcining the metal oxide gel to form the metal oxide material. The metal oxide material corresponds to the chemical formula of La2MxNi1-xO4, Pr2-yAyNiO4, or La2-zDzNiO4, wherein M is copper, cobalt, iron, manganese, chromium, aluminum, or platinum; A is lanthanum or neodymium; D is calcium, barium or strontium; x ranges from 0 to 1; y ranges from 0 to 2; and z ranges from 0 to 0.25.
    Type: Grant
    Filed: December 4, 2018
    Date of Patent: October 26, 2021
    Assignee: Wayne State University
    Inventors: Eranda Nikolla, Bingwen Wang, Ayad Nacy
  • Patent number: 11117120
    Abstract: A catalyst for synthesizing a carbon nanotube includes a support containing a metal, and an active metal impregnated on the support. The active metal includes cobalt and manganese. A surface molar ratio of the active metal relative to the metal of the support is 40% or less of a bulk molar ratio of the active metal relative to the metal of the support. A carbon nanotube having high purity and low resistance is obtained from the catalyst.
    Type: Grant
    Filed: October 30, 2018
    Date of Patent: September 14, 2021
    Assignees: SK Innovation Co., Ltd., SK Global Chemical Co., Ltd.
    Inventors: Hye Ryun Seo, Yong Tak Kwon
  • Patent number: 11110433
    Abstract: The present invention relates to a metal-doped tin oxide which has a BET surface area of at least 30 m 2/g, and comprises at least one metal dopant which is Sb, Nb, Ta, Bi, W, or In, or any mixture thereof, wherein the metal dopant is present in an amount of from 2.5 at % to 25 at %, based on the total amount of tin and metal dopant atoms, and is in a mixed valence state containing atoms of oxidation state OS1 and atoms of oxidation state OS2, wherein the oxidation state OS1 is >0 and the oxidation state OS2 is >OS1 and the atomic ratio of the atoms of OS2 to the atoms of OS1 is from 1.5 to 12.0.
    Type: Grant
    Filed: March 17, 2017
    Date of Patent: September 7, 2021
    Assignee: BASF SE
    Inventors: Xu Yuan Peng, Rosalba Adriana Ricon-Ovalles, Shyam Sundar Venkataraman, Domnik Bayer, Andreas Haas
  • Patent number: 11110440
    Abstract: A composite catalyst for coal depolymerization, the catalyst includes an agent A and an agent B. The agent A includes an iron salt-based catalyst, and the agent B includes a metal salt-based catalyst different from the iron salt-based catalyst. The agent A and the agent B are alternately added during use.
    Type: Grant
    Filed: August 2, 2018
    Date of Patent: September 7, 2021
    Assignee: TAIYUAN UNIVERSITY OF TECHNOLOGY
    Inventors: Wei Huang, Litong Liang, Qian Zhang, Jianwei Liu, Juntian Huai, Xiaogang Hao, Zhonglin Zhang
  • Patent number: 11104575
    Abstract: The catalyst in this present application includes a support and an active component dispersed on/in the support; wherein the support is at least one selected from inorganic oxides and the support contains macropores and mesopores; and the active component includes an active element, and the active element contains an iron group element. As a high temperature stable catalyst for methane reforming with carbon dioxide, the catalyst can be used to produce syngas, realizing the emission reduction and recycling utilization of carbon dioxide. Under atmospheric pressure and at 800° C., the supported metal catalyst with hierarchical pores shows excellent catalytic performance. In addition to high activity and good selectivity, the catalyst has high stability, high resistance to sintering and carbon deposition.
    Type: Grant
    Filed: March 15, 2017
    Date of Patent: August 31, 2021
    Assignee: FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER, CHINESE ACADEMY OF SCIENCE
    Inventors: Yumin Chen, Guocong Guo, Zhongning Xu, Zhiqiao Wang, Qingsong Chen, Hongzi Tan
  • Patent number: 11078124
    Abstract: Systems and methods for making ceramic powders configured with consistent, tailored characteristics and/or properties are provided herein. In some embodiments a system for making ceramic powders, includes: a reactor body having a reaction chamber and configured with a heat source to provide a hot zone along the reaction chamber; a sweep gas inlet configured to direct a sweep gas into the reaction chamber and a sweep gas outlet configured to direct an exhaust gas from the reaction chamber; a plurality of containers, within the reactor body, configured to retain at least one preform, wherein each container is configured to permit the sweep gas to flow therethrough, wherein the preform is configured to permit the sweep gas to flow there through, such that the precursor mixture is reacted in the hot zone to form a ceramic powder product having uniform properties.
    Type: Grant
    Filed: January 7, 2019
    Date of Patent: August 3, 2021
    Assignee: ALCOA USA CORP.
    Inventors: James C. McMillen, Lance M. Sworts, Benjamin D. Mosser, Charles Robert Shanta, III
  • Patent number: 11081702
    Abstract: A synthesis method of a metal catalyst having carbon shell, includes: a) forming a metal-ligand complex without further chemical additives by mixing a ligand with a metal precursor; b) separating the metal-ligand complex and collecting the separated metal-ligand complex; c) supporting the collected metal-ligand complex to a support by mixing the collected metal-ligand complex with the support in a solvent; and d) treating a composite consisting of the metal-ligand complex and the support by heating.
    Type: Grant
    Filed: August 21, 2018
    Date of Patent: August 3, 2021
    Assignee: INCHEON UNIVERSITY INDUSTRY ACADEMIC COOPERATION FOUNDATION
    Inventors: Oh Joong Kwon, Mohanraju Karuppannan
  • Patent number: 11033882
    Abstract: Nickel-based catalysts comprising silicon modified nickel (nickel silicate) are provided, as are methods for using the catalysts to i) convert methane to CO and H2 (e.g. for use in synthetic chemical compound production); or to ii) convert methane to oxygenated hydrocarbons e.g. one or more of methanol, acetone, formaldehyde, and dimethyl ether. The catalysts are bifunctional and comprise both Ni metallic catalytic sites and acidic nickel-silicon catalytic sites, and the conversions are performed under moderate reaction conditions.
    Type: Grant
    Filed: March 11, 2019
    Date of Patent: June 15, 2021
    Assignee: WASHINGTON STATE UNIVERSITY
    Inventors: Su Yun Ha, M. Grant Norton, Oscar Gerardo Marin Flores
  • Patent number: 11014864
    Abstract: The invention relates to a process for producing copper-containing catalysts, in particular shaped catalyst bodies having increased mechanical strength and a low volume shrinkage, and also the shaped catalyst bodies produced by the process of the invention and the use thereof as catalysts or as precursors and components for catalysts. The catalysts of the invention are particularly suitable for the synthesis of methanol and for the low-temperature conversion of CO into CO2.
    Type: Grant
    Filed: March 19, 2015
    Date of Patent: May 25, 2021
    Assignee: Clariant International Ltd.
    Inventors: Patrick Kurr, Benjamin Kniep, Andrea Blindhuber, Verena Pritscher
  • Patent number: 11001729
    Abstract: A coating material of the present invention includes an insulating resin, and dispersion particles dispersed in the insulating resin. The dispersion particle includes a core particle containing zinc oxide as a main component and having nonlinear resistance, and a resin layer covering the surface of the core particle and having an average thickness being less than or equal to 5.0 ?m. The coating material of the present invention is a coating material for coating an inner surface of a ground tank of a gas insulated switchgear.
    Type: Grant
    Filed: April 6, 2017
    Date of Patent: May 11, 2021
    Assignee: MITSUBISHI ELECTRIC CORPORATION
    Inventors: Satoru Sato, Naoki Yasuda, Nobuo Yokomura, Ryoko Kawano, Manabu Yoshimura, Shinichiro Nakauchi