Abstract: A glass-ceramic article comprises: a center-volume composition comprising (on an oxide basis): 55-75 mol % SiO2; 0.2-10 mol % Al2O3; 0-5 mol % B2O3; 15-30 mol % Li2O; 0-2 mol % Na2O; 0-2 mol % K2O; 0-5 mol % MgO; 0-2 mol % ZnO; 0.2-3.0 mol % P2O5; 0.1-10 mol % ZrO2; 0-4 mol % TiO2; and 0-1.0 mol % SnO2. Lithium disilicate and either ?-spodumene or ?-quartz are the two predominant crystalline phases (by weight) of the glass-ceramic article. The glass-ceramic article further comprises tetragonal ZrO2 as a crystalline phase. The composition of the glass-ceramic article from a primary surface into a thickness of the glass-ceramic article can comprise over 10 mol % Na2O (on an oxide basis), with the mole percentage of Na2O decreasing from the primary surface towards the center-volume. The glass-ceramic article exhibits a ring-on-ring load-to-failure of at least 120 kgf, when the thickness of the glass-ceramic article is 0.3 mm to 2.0 mm.
Type:
Grant
Filed:
June 25, 2021
Date of Patent:
August 15, 2023
Assignee:
CORNING INCORPORATED
Inventors:
Carol Ann Click, Qiang Fu, Mathieu Gerard Jacques Hubert, Charlene Marie Smith, Alana Marie Whittier
Abstract: A temperature-stable modified NiO—Ta2O5-based microwave dielectric ceramic material and a preparation method thereof are provided. Using ion doping modification to form solid solution structure is an important measure to adjust microwave dielectric properties, especially the temperature stability. Based on formation rules of the solid solution, ion replacement methods are designed including Ni2+ ions are replaced by Cu2+ ions, and (Ni1/3Ta2/3)4+ composite ions are replaced by [(Al1/2Nb1/2)ySn1-y]4+ composite ions, which considers that cations with similar ionic radii to Ni2+ and Ta5+ ions can be introduced into the NiTa2O6 ceramic for doping under the same coordination environment (coordination number=6), and therefore a ceramic material with the NiTa2O6 solid solution structure can be obtained. The microwave dielectric ceramic material with excellent temperature stability and low loss is finally prepared by adjusting molar contents of each of doped ions, and its microwave dielectric properties are excellent.
Type:
Grant
Filed:
November 2, 2022
Date of Patent:
August 15, 2023
Assignee:
UNIVERSITY OF ELECTRONIC SCI. AND TECH. OF CHINA
Inventors:
MengJiang Xing, MingShan Qu, HongYu Yang
Abstract: The present disclosure relates to a glass composition as well as a glass powder. The disclosure also relates to the use in the dental field, e.g. as dental material such as dental filling or dental restauration material, in particular as or for the production of a glass ionomer cement, for example for the treatment and/or for the filling of cavities in human and/or animal teeth and/or for tooth restoration.
Abstract: A transparent colored glass ceramic, in particular an LAS glass ceramic, suitable for use as a cooking surface is provided. The transparent colored glass ceramic includes high-quartz solid solution (HQ s.s.) as a main crystal phase and exhibits thermal expansion of ?1 to +1 ppm/Kin the range from 20° C. to 700° C. The glass ceramic has from 3.0 to 3.6 percent by weight of lithium oxide (Li2O) as constituents and either is colored with 0.003 to 0.05 percent by weight of vanadium oxide (V2O5) or is colored with 0.003 to 0.25 percent by weight of molybdenum oxide (MoO3).
Type:
Grant
Filed:
June 22, 2021
Date of Patent:
August 15, 2023
Assignee:
SCHOTT AG
Inventors:
Evelin Weiss, Meike Schneider, Oliver Hochrein, Friedrich Siebers, Roland Dudek, Martin Mueller, Matthias Bockmeyer, Birgit Doerk
Abstract: Provided are a powder for laser manufacturing which can be stably manufactured and from which a three-dimensional manufactured object ensuring a manufacturing accuracy can be obtained and a using method thereof. A powder for ceramic manufacturing for obtaining a manufactured object by repeatedly sintering or fusing and solidifying in sequence a powder in an irradiation portion with laser light, in which the powder includes a plurality of compositions, at least one composition of the compositions is an absorber that relatively strongly absorbs the laser light compared to other compositions, and at least a part of the absorber changes to a different composition that relatively weakly absorbs the laser light by irradiation with the laser light and a using method of a powder in which the powder is used.
Abstract: A method for producing a refractory lining in a combustion chamber operating in a reducing atmosphere. The lining includes at least one or more Zirconia (Zr)-based refractory lining members comprising one or more Zr-based parts. The Zr-based parts comprise at least 90 wt. %, preferably at least 95 wt. %, of monoclinic ZrO2 and/or partially stabilized ZrO2 and/or fully stabilized ZrO2, wherein the total content of tetragonal and cubic ZrO2 amounts to at least 20 wt. %, preferably more than 35 wt. %, as well as Zr based refractory lining members and methods for manufacturing the Zr based refractory lining members.
Type:
Grant
Filed:
February 11, 2021
Date of Patent:
August 1, 2023
Assignees:
Topsoe A/S, P-D Refractories GmbH
Inventors:
Johannes Ruben Larsen, Fred Brunk, Thomas Sandahl Christensen, Søren Gyde Thomsen
Abstract: A glass material with a low dielectric constant and a low fiberizing temperature includes silicon dioxide, boron trioxide, aluminum oxide, calcium oxide, phosphorus pentoxide and zinc oxide. The silicon dioxide makes up 45%-52% by weight of the glass material. The boron trioxide makes up 25%-30% by weight of the glass material. The aluminum oxide makes up 10%-14% by weight of the glass material. The calcium oxide makes up 1%-4% by weight of the glass material. The phosphorus pentoxide makes up 0-3% by weight of the glass material. The zinc oxide makes up 1%-5% by weight of the glass material. The reduced silicon dioxide content and calcium oxide content and addition of phosphorus pentoxide and zinc oxide in the glass material lower the dielectric constant and fiberizing temperature of the glass material.
Abstract: A transparent glass-ceramic composition including: of the formula Ta2-xAlxO5-x where x is less than 1; of the formula AlTaO4; of the formula AlPO4; a mixture of AlTaO4 and AlPO4; or a mixture of the formula Ta2-xAlxO5-x, AlTaO4, and AlPO4. Also disclosed are transparent glass-ceramic compositions including, for example, a dopant as defined herein, or a supplemental metal oxide or metalloid oxide of MxOy, MxM?xOy, or a mixture thereof such as oxides of Nb, Ti, W, B, or Ga, as defined herein. Also disclosed are methods of making the disclosed transparent glass-ceramic compositions, and optical articles, optical components, and optical apparatus thereof.
Type:
Grant
Filed:
October 6, 2021
Date of Patent:
July 25, 2023
Assignee:
CORNING INCORPORATED
Inventors:
Bruce Gardiner Aitken, Randall Eugene Youngman
Abstract: A transparent ?-quartz glass ceramic is provided. The glass ceramic includes a primary crystal phase including a ?-quartz solid solution, a secondary crystal phase including tetragonal ZrO2, and a lithium aluminosilicate amorphous phase. The glass ceramic may be ion exchanged utilizing molten nitrate salt baths. Methods for producing the glass ceramic are also provided.
Abstract: The disclosure relates to glass compositions with high coefficients of thermal expansion and low fracture toughness designed for thermal tempering. These glasses are ideally suited to produce a “dicing” pattern when thermally tempered, even when thin (<3 mm). Disclosed glasses have high thermal expansions at low and high temperatures to produce increased temper stresses once quenched, coupled with low fracture toughness which promotes crack bifurcation and enhanced frangibility. Methods of making such glasses are also provided.
Type:
Grant
Filed:
November 30, 2018
Date of Patent:
July 25, 2023
Assignee:
Corning Incorporated
Inventors:
Timothy Michael Gross, Peter Joseph Lezzi
Abstract: The present invention relates to a particle mixture comprising particles of glass frit and particles of a crystalline oxide material, wherein the glass frit comprises silicon oxide (SiO2), zinc oxide (ZnO) and sulfur (S) and wherein the D90 particle size of the particle mixture is less than 5 microns. The particle mixture may be used to apply an enamel to a substrate. The present invention further relates to the use of the particle mixture to form an enamel on a substrate, to a glass sheet and to an automotive window pane.
Type:
Grant
Filed:
July 16, 2018
Date of Patent:
July 25, 2023
Assignee:
Fenzi AGT Netherlands B.V.
Inventors:
Miria Medeiros Pacheco De Andrade, Edwin Peter Kennedy Currie, Syarif Riyadi, Patricia Ann Sutton
Abstract: A composition comprises at least one form of attapulgite present in a solid weight fraction amount ranging from 0.25% to 5%; kaolin present in a solid weight fraction amount ranging from 17% to 50%; and optionally Ball Clay in a solid weight fraction amount ranging from 0% to 25%. Although makeable by other processes, in some embodiments, the composition is makeable by mixing component ingredients. Although usable for other purposes, in some embodiments, the composition is used to make ceramic pieces, e.g., via casting, pressing, jiggering or jollying, especially when the slip has solids, chemistry and viscosity suitable for shaping before drying, sintering, and optionally finishing.
Type:
Grant
Filed:
March 29, 2021
Date of Patent:
July 25, 2023
Assignee:
Active Minerals International, LLC
Inventors:
Dennis Clay Parker, Robert J. Purcell, Jr., Matthew J. Lyman, Donald Keith Mills, John W. Kitchens, Charles Pettit, James Cutright
Abstract: Disclosed herein are embodiments of low temperature co-fireable dielectric materials which can be used in conjunction with high dielectric materials to form composite structures, in particular for isolators and circulators for radiofrequency components. Embodiments of the low temperature co-fireable dielectric materials can be scheelite or garnet structures, for example, bismuth vanadate. Adhesives and/or glue is not necessary for the formation of the isolators and circulators.
Type:
Grant
Filed:
June 20, 2019
Date of Patent:
July 11, 2023
Assignee:
SKYWORKS SOLUTIONS, INC.
Inventors:
Michael David Hill, David Bowie Cruickshank, Jeffrey Alan Shunkwiler, John Jianzhong Jiang, David Martin Firor, Srinivas Polisetty
Abstract: The present invention relates to a method for preparing a SiC—Si3N4 composite material and a SiC—Si3N4 composite material prepared according to same and comprises the steps of: preparing a mold; and forming a SiC—Si3N4 composite material by introducing, to the mold, a source gas comprising Si, N and C, at 1100 to 1600° C. More particularly, the present invention provides the SiC—Si3N4 composite material of high purity that is applicable to a semiconductor process, and increases the thermal shock strength of a SiC material by causing Si3N4, which is a material with a high thermal shock strength, to grow together via a CVD method.
Abstract: Disclosed are embodiments of high Q modified materials. In some embodiments, complex tungsten oxides and/or hexagonal perovskite crystal structures can be added to provide for advantageous properties. In some embodiments, no tin is used in the formation of the material.
Abstract: A ceramic composite and a method of preparing the same are provided. The method of preparing the ceramic composite includes mixing an aluminum slag and a carbon accelerator to obtain a mixture and reacting the mixture at a temperature equal to or greater than 1600° C. in a nitrogen atmosphere to obtain a ceramic composite. The aluminum slag includes aluminum, oxygen, nitrogen, and magnesium. The weight ratio of the oxygen to the aluminum is 0.6 to 2. The weight ratio of the nitrogen to the aluminum is 0.1 to 1.2. The weight ratio of the magnesium to the aluminum is 0.04 to 0.2. The ceramic composite includes aluminum nitride accounting for at least 90 wt % of the ceramic composite.
Type:
Grant
Filed:
December 9, 2021
Date of Patent:
July 4, 2023
Assignee:
INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
Abstract: Provided are novel high entropy nitrides (HENs) exhibiting excellent physical and chemical properties. Also provided are systems and methods to synthesize bulk HENs by reaction flash sintering. Commercial metal nitride powders can be consolidated into near fully dense single-phase bulk ceramic with a proprietary flash sintering apparatus. A constant DC electrical field of ˜80 V/cm and pressure of ˜15 MPa at room temperature can trigger reaction flash sintering without pre-heating, and the entire process can finish in ˜250 seconds to ˜400 seconds.
Type:
Grant
Filed:
January 12, 2023
Date of Patent:
July 4, 2023
Assignee:
THE FLORIDA INTERNATIONAL UNIVERSITY BOARD OF TRUSTEES
Abstract: Mineral wool fibers having a mineral wool fiber composition are manufactured by introducing batch materials into a melter, melting the mineral batch materials in the melter to provide a melt and fiberizing the melt to form the mineral wool fibers. The batch materials comprise i) fibers having a first batch material composition which is different from the mineral wool fiber composition and consisting of scrap fibers which have broken at a bushing producing continuous fibers; and ii) one of more additional mineral batch materials.
Abstract: An aluminum nitride-based sintered compact includes: aluminum nitride crystal particles containing Mg; composite oxide containing a rare earth element and Al, the composite oxide having a garnet crystal structure; and composite oxynitride containing Mg and Al. Particles of the composite oxide and particles of the composite oxynitride are interspersed between the aluminum nitride crystal particles. The composite oxide may include Y. A content of Mg in the aluminum nitride crystal particles may fall in a range of 0.1 mol % or more and 1.0 mol % or less, based on a total of all metal elements contained in the aluminum nitride crystal particles taken as 100 mol %. A semiconductor holding device includes the aluminum nitride-based sintered compact; and an electrostatic adsorptive electrode.
Abstract: A glass ceramic contains the following components by wt %: 60 to 80% of SiO2; 4 to 20% of Al2O3; 0 to 15% of Li2O; more than 0 but less than or equal to 12% of Na2O; 0 to 5% of K2O; more than 0 but less than or equal to 5% of ZrO2; 0 to 5% of P2O5; and 0 to 10% of TiO2. A crystalline phase contains at least one of R2SiO3, R2Si2O5, R2TiO3, R4Ti5O12, R3PO3, RAlSi2O6, RAlSiO4O10, R2Al2Si2O8, R4Al4Si5O18, quartz and quartz solid solution. With a liquidus temperature below 1,450° C., a thermal conductivity above 2 w/m·k, and a Vickers hardness above 600 kgf/mm2, the glass ceramic is applicable to portable electronic devices and optical devices.