Patents Examined by Keling Zhang
  • Patent number: 11814290
    Abstract: A method for the synthesis of carbon nanotubes from natural rubber, including providing a first material, the first material may include natural rubber or derivatives thereof, thermally decomposing the first material at a first temperature into an intermediate material, contacting the intermediate material with a catalyst, treating the intermediate material in contact with the catalyst at a second temperature, for forming carbon nanotubes. Adjusting an average characteristic of resulting nanotubes, including carrying out the synthesis method as a reference method and for decreasing the average diameter of the nanotube: decreasing the second temperature and/or decreasing the reaction time and/or increasing the concentration of H2 in the forming gas in relation to the reference method. Or, for increasing the average diameter of the nanotube: increasing the second temperature and/or increasing the reaction time and/or decreasing the concentration of H2 in the forming gas in relation to the reference method.
    Type: Grant
    Filed: September 27, 2018
    Date of Patent: November 14, 2023
    Assignee: Agency for Science, Technology and Research
    Inventors: Ming Lin, Yuanting Karen Tang, Hui Teng Casandra Chai, Ziyi Zhong, Ji Zhong Luo
  • Patent number: 11814285
    Abstract: The reaction rate of hydrocarbon pyrolysis can be increased to produce solid carbon and hydrogen by the use of molten materials which have catalytic functionality to increase the rate of reaction and physical properties that facilitate the formation and contamination-free separation of the solid carbon. Processes, materials, reactor configurations, and conditions are disclosed whereby methane and other hydrocarbons can be decomposed at high reaction rates into hydrogen gas and carbon products without any carbon oxides in a single reaction step. The process also makes use of specific properties of selected materials with unique solubilities and/or wettability of products into (and/or by) the molten phase to facilitate generation of purified products and increased conversion in more general reactions.
    Type: Grant
    Filed: November 16, 2018
    Date of Patent: November 14, 2023
    Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    Inventors: Eric W. McFarland, Ches Upham, Jiren Zeng, Clarke Palmer, Shizhao Su, Davide Mannini, Dohyung Kang, Nazanin Rahimi, Horia Metiu, Michael Gordon
  • Patent number: 11801496
    Abstract: The present disclosure relates to a catalyst for preparing 1,2-pentanediol from furfural and/or furfuryl alcohol, and more particularly to a catalyst, which is configured such that a catalytically active metal containing both at least one transition metal and tin (Sn) is supported on a basic support and is capable of increasing reaction selectivity for 1,2-pentanediol, and a method of preparing 1,2-pentanediol using the same.
    Type: Grant
    Filed: July 4, 2019
    Date of Patent: October 31, 2023
    Assignee: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
    Inventors: Young Kyu Hwang, Do Young Hong, Jaesung Kwak, Pandharinath Pravin Upare, Dong Won Hwang, Jung Ho Lee, Jong-San Chang, Joung-mo Cho, U Hwang Lee, Kyung Ho Cho, Su Kyung Lee
  • Patent number: 11801493
    Abstract: Methods for conditioning an ethylene epoxidation catalyst are provided. The conditioning methods comprise contacting an ethylene epoxidation catalyst comprising a carrier, having silver and a rhenium promoter deposited thereon, with a conditioning feed gas comprising oxygen for a period of time of at least 2 hours at a temperature that is above 180° C. and at most 250° C., wherein the contacting of the ethylene epoxidation catalyst with the conditioning feed gas occurs in an epoxidation reactor and in the absence of ethylene. Associated methods for the epoxidation of ethylene are also provided.
    Type: Grant
    Filed: November 29, 2017
    Date of Patent: October 31, 2023
    Assignee: SHELL USA, INC.
    Inventors: Marek Matusz, Robert Lewis Paddock, Randall Clayton Yeates, John Robert Lockemeyer
  • Patent number: 11773028
    Abstract: A method of removing fluoride ion from waste liquid is provided, which includes providing a calcium source and a plurality of ceramic particles to a waste liquid containing fluoride ion for forming a plurality of calcium fluoride layers wrapping the ceramic particles. The calcium fluoride layers are connected to form a calcium fluoride bulk. The ceramic particles are embedded in the calcium fluoride bulk. The ceramic particles and the calcium fluoride bulk have a weight ratio of 1:4 to 1:20.
    Type: Grant
    Filed: September 29, 2020
    Date of Patent: October 3, 2023
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Sheng-Min Yu, Sheng-Yi Chiu, Chien-Chung Hsu
  • Patent number: 11673123
    Abstract: Pyrochlore-based solid mixed oxide materials suitable for use in catalysing a hydrocarbon reforming reaction are disclosed, as well as methods of preparing the materials, and their uses in hydrocarbon reforming processes. The materials contain a catalytic quantity of inexpensive nickel and exhibit catalytic properties in dry reforming reactions that are comparable—if not better—than those observed using expensive noble metal-containing catalysts. Moreover, the Pyrochlore-based solid mixed oxide materials can be used in low temperature dry reforming reactions, where other catalysts would become deactivated due to coking. Accordingly, the catalytic materials represent a sizeable development in the industrial-scale reforming of hydrocarbons.
    Type: Grant
    Filed: March 12, 2018
    Date of Patent: June 13, 2023
    Assignees: University of Surrey, University of Alicante
    Inventors: Tomas Ramirez Reina, Estelle Le Saché, Sai Gu, David Watson, Laura Pastor Pérez, Antonio Sepúlveda Escribano
  • Patent number: 11661348
    Abstract: The invention discloses a sound-absorbing material particle and a preparation method thereof. The method for preparing the sound-absorbing material particle comprises: mixing a sound-absorbing raw material with a solvent to form a sound-absorbing slurry; filling the sound-absorbing slurry into a mechanical compression die, and performing compression molding on the sound-absorbing slurry to form a particle; performing a hydrothermal crystallization reaction on the particle to crystallize the sound-absorbing raw material in the particle; and drying the particle to produce the sound-absorbing material particle.
    Type: Grant
    Filed: May 18, 2016
    Date of Patent: May 30, 2023
    Assignee: GOERTEK INC.
    Inventor: Xiaodong Cao
  • Patent number: 11648536
    Abstract: The present invention relates to a catalyst for oxidative dehydrogenation of butene and a method for producing the same. The catalyst for oxidative dehydrogenation of butene has a large amount of Mo—Bi phase acting as a reaction active phase on the surface, and therefore, can exhibit high catalytic activity, high conversion rate and high butadiene selectivity in the oxidative dehydrogenation of butene.
    Type: Grant
    Filed: November 27, 2018
    Date of Patent: May 16, 2023
    Assignee: LG CHEM, LTD.
    Inventors: Ara Cho, Young Chang Byun, Gyo Hyun Hwang, Jungup Bang, Cheolock Song
  • Patent number: 11635009
    Abstract: A method of making an oxygen storage material (OSM) with developed mesoporosity having a small fraction of pores <10 nm (fresh or aged), and resistance to thermal sintering is provided. This OSM is suitable for use as a catalyst and catalyst support. The method of making this oxygen storage material (OSM) includes the preparation of a solution containing pre-polymerized zirconium oligomers, cerium, rare earth and transition metal salts; the interaction of this solution with a complexing agent that has an affinity towards zirconium; the formation of a zirconium-based precursor; and the co-precipitation of all constituent metal hydroxide with abase.
    Type: Grant
    Filed: January 7, 2019
    Date of Patent: April 25, 2023
    Assignee: Pacific Industrial Development Corporation
    Inventors: Anatoly Bortun, Mila Bortun, David Shepard, Yunkui Li, Jin Cho, Wei Wu, Jeffery Lachapelle
  • Patent number: 11628425
    Abstract: An object of the present invention is to provide a catalyst ensuring that when a gas-phase catalytic oxidation reaction of a material substance is conducted using a catalyst to produce a target substance, the pressure loss and coking are suppressed and the target substance can be produced in high yield. The present invention is related to a ring-shaped catalyst having a straight body part and a hollow body part, which is used when a gas-phase catalytic oxidation reaction of a material substance is conducted to produce a target substance, wherein a length of the straight body part is shorter than a length of the hollow body part and at least at one end part, a region from an end part of the straight body part to an end part of the hollow body part is concavely curved.
    Type: Grant
    Filed: September 24, 2019
    Date of Patent: April 18, 2023
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kazuharu Tazawa, Takanori Taniguchi, Takuya Nakamura
  • Patent number: 11603319
    Abstract: A synthesis method for producing a refractory oxide-ceramic material of CaZrO3, in particular in the form of a refractory granular material that is preferably mechanically comminuted, in particular crushed and/or ground, as well as to a batch and a coarse ceramic, shaped or unshaped, refractory product containing at least one pre-synthesized refractory calcium zirconate-containing granular material.
    Type: Grant
    Filed: November 28, 2018
    Date of Patent: March 14, 2023
    Assignee: Refratechnik Holding GmbH
    Inventors: Helge Jansen, Constantin Jahn, Christos Georgios Aneziris
  • Patent number: 11583835
    Abstract: A nickel-iron alloy hydrogenation catalyst and a fabricating method thereof are provided. The nickel-iron alloy hydrogenation catalyst has 65 to 95 atomic percent nickel; and 5 to 35 atomic percent of iron, wherein the nickel-iron alloy hydrogenation catalyst is spherical and has an average particle diameter of 180 to 300 nm. The nickel-iron alloy hydrogenation catalyst is present in a non-carrier form. The nickel-iron alloy hydrogenation catalyst can generate a hydrogenation reaction at a low temperature (about 130˜140° C.) and has a high conversion rate (compared to pure nickel catalyst).
    Type: Grant
    Filed: September 23, 2020
    Date of Patent: February 21, 2023
    Assignee: National Cheng Kung University
    Inventors: Chuh-Yung Chen, Cheng-Chien Wang, Po-Wei Lan, Ying-Ji Lin
  • Patent number: 11583845
    Abstract: Provided is a method of preparing a pure M1 phase MoVTeNb-oxide catalyst with a high specific surface area, including S1) mixing and dissolving a molybdenum-containing compound, a vanadium-containing compound, a tellurium-containing compound, a niobium-containing compound and a protective agent to obtain a precursor-protective agent mixed solution, in which the protective agent is a surfactant or a small molecule organic acid and a salt thereof; S2) subjecting the precursor-protective agent mixed solution to a hydrothermal reaction to separate out a solid; S3) calcining the solid in an air atmosphere, followed by calcining the same in an inert gas, and then performing a hydrogen peroxide purification treatment to obtain a pure M1 phase MoVTeNb-oxide catalyst. This catalyst exhibits an excellent conversion rate, selectivity, space time yield and stability in the oxidative dehydrogenation reaction of ethane for preparing ethylene.
    Type: Grant
    Filed: July 17, 2018
    Date of Patent: February 21, 2023
    Assignee: University of Science and Technology of China
    Inventors: Weixin Huang, Xuanyu Zhang, Zeyue Wei, Rui You
  • Patent number: 11583839
    Abstract: Disclosed are a catalyst for preparing hydrocarbons from carbon dioxide by one-step hydrogenation and a method for preparing same. The catalyst includes nano-metal oxides and hierarchical zeolites, where the mass fraction of the nano-metal oxides in the catalyst is 10%-90%, and the mass fraction of the hierarchical zeolites in the catalyst is 10%-90%. The catalyst has excellent catalytic performance, good reaction stability and high selectivity for desired products, and in the hydrocarbons, C2=-C4= reach up to 80%, C5+ reach up to 80%, and aromatics reach up to 65%.
    Type: Grant
    Filed: May 10, 2017
    Date of Patent: February 21, 2023
    Assignee: SHANGHAI ADVANCED RESEARCH INSTITUTE, CHINESE ACADEMY OF SCIENCES
    Inventors: Yuhan Sun, Shanshan Dang, Peng Gao, Xianni Bu, Ziyu Liu, Hui Wang, Liangshu Zhong, Minghuang Qiu, Zhibiao Shi
  • Patent number: 11577965
    Abstract: Provided herein are methods and systems to form calcium carbonate comprising vaterite, comprising dissolving lime in an aqueous base solution under one or more precipitation conditions to produce a precipitation material comprising calcium carbonate and a supernatant solution, wherein the calcium carbonate comprises vaterite.
    Type: Grant
    Filed: February 25, 2021
    Date of Patent: February 14, 2023
    Assignee: Arelac, Inc.
    Inventors: Michael Joseph Weiss, Ryan J Gilliam
  • Patent number: 11565241
    Abstract: A method for in-situ generation of nanoflower-like manganese dioxide catalyst on filter material is provided. The method comprises: immersing a filter material in a solution containing sodium lauryl sulfate and nitric acid; first modifying the surface of the filter material by using the sodium lauryl sulfate so that a charge layer is wound around the surface of the filter material and tightly absorbs H+ in an acid solution; and then adding potassium permanganate as an oxidant to react with H30 on the surface of the filter material to generate nano flower-like manganese dioxide in situ on the surface of the filter material, so as to obtain a composite filter material having a denitration function.
    Type: Grant
    Filed: September 12, 2016
    Date of Patent: January 31, 2023
    Assignee: FUZHOU UNIVERSITY
    Inventors: Yuying Zheng, Jian Chen
  • Patent number: 11559787
    Abstract: There is provided a catalyst composition including a hydrogen oxidation catalyst and an oxygen reduction catalyst and a process for applying the catalyst composition to a substrate. Heat exchange reactors including the catalyst composition and methods for heating a heat exchange medium are also provided. Catalytic combustors including a catalytic surface including the catalyst composition are further provided. The catalyst is adapted for low temperature activation of a hydrogen combustion reaction.
    Type: Grant
    Filed: August 22, 2018
    Date of Patent: January 24, 2023
    Assignee: STAR SCIENTIFIC LIMITED
    Inventors: Steven James Heaton, Samuel James Kirk
  • Patent number: 11548790
    Abstract: The present invention aims to provide techniques for efficiently synthesizing inorganic microparticles. According to the present invention, inorganic carbonate microparticles can be synthesized by generating ultrafine bubbles containing carbonic acid gas by injecting a gas containing carbonic acid gas and a liquid into a reaction vessel through a nozzle to deposit an inorganic carbonate having an average primary particle size of 300 nm or less in the presence of the ultrafine bubbles.
    Type: Grant
    Filed: September 4, 2017
    Date of Patent: January 10, 2023
    Assignee: NIPPON PAPER INDUSTRIES CO., LTD.
    Inventors: Masatoshi Oishi, Toru Nakatani, Moe Fukuoka, Shisei Goto
  • Patent number: 11542167
    Abstract: Provided is a production method of a silica particle dispersion liquid which includes, preparing a linked silica particle by adding a liquid A containing alkoxysilane and a liquid B containing an alkali catalyst to a liquid containing water, an organic solvent, and an alkali catalyst in a container. The preparing a linked silica particle includes initially adding an alkali catalyst, the initially adding an alkali catalyst includes decreasing a molar ratio of an alkali catalyst to silica in the liquid in the container to 0.15 to 0.60 by adding the liquid A containing alkoxysilane to the liquid in the container, and increasing the molar ratio by 0.2 or more by adding the liquid B to the liquid having the decreased molar ratio in the container.
    Type: Grant
    Filed: September 23, 2020
    Date of Patent: January 3, 2023
    Assignee: JGC CATALYSTS AND CHEMICALS LTD.
    Inventors: Shogo Hayashi, Miki Egami, Mitsuaki Kumazawa, Ryo Muraguchi, Michio Komatsu
  • Patent number: 11534739
    Abstract: The present disclosure provides a lignite char supported nano-cobalt composite catalyst and a preparation method thereof. In the method, lignite is used as a raw material, and a lignite char supported high dispersion nano-cobalt composite catalyst is obtained by a modified impregnation method followed by a high temperature pyrolysis process. The composite catalyst prepared by the present disclosure has a hierarchical pore structure, a high specific surface area, and uniformly dispersing nano-sized cobalts on the lignite char with controllable particle size, so that the obtained catalyst has an excellent catalytic activity for low-temperature CO2 methanation; moreover, the preparation process is simple and feasible, the raw materials used are cheap and easily available. Therefore, the composite catalyst is very suitable for industrial production and application.
    Type: Grant
    Filed: November 23, 2020
    Date of Patent: December 27, 2022
    Assignee: Wuhan University of Technology
    Inventors: Chunxia Zhao, Feng Li, Wen Chen, Wei Jin, Yanyuan Qi, Shuang Yang