Patents Examined by Kumar R Bhushan
  • Patent number: 11739246
    Abstract: A method of recycling a direct emulsion wellbore fluid may include disrupting a direct emulsion comprising an aqueous external phase and an oleaginous internal phase, wherein the direct emulsion is stabilized by a surfactant composition; and separating the aqueous phase and the oleaginous phase.
    Type: Grant
    Filed: July 1, 2019
    Date of Patent: August 29, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Hui Zhang, Jeremy Smith, Xia Wei, Weiqing Huang, Steven Philip Young
  • Patent number: 11732184
    Abstract: A sintered rod-shaped proppant and anti-flowback agent possesses high strength and high conductivity. The sintered rods comprise between about 0.2% by weight and about 4% by weight aluminum titanate. In some embodiments, the sintered rods are made by mixing bauxitic and non-bauxitic sources of alumina that may also contain several so-called impurities (such as TiO2), extruding the mixture, and sintering it. The starting material may optionally be milled to achieve better compacity and crush resistance in the final sintered rod. A fracturing fluid may comprise the sintered rods alone or in combination with a proppant, preferably a proppant of a different shape.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: August 22, 2023
    Assignee: U.S. Ceramics LLC
    Inventors: Jean Andre Alary, Thomas Parias
  • Patent number: 11725102
    Abstract: Process of providing polyacrylamides to a site-of-use comprising at least the steps of mixing a polyacrylamide powder at a manufacturing site with an aqueous liquid, thereby obtaining a homogeneous aqueous polyacrylamide concentrate, transporting said concentrate in a transport unit from the manufacturing site to the site-of-use, and removing the homogeneous aqueous concentrate from the transport unit at the site-of-use. Process of treating subterranean, oil and/or gas bearing formations by injecting an aqueous treatment fluid into at least one wellbore, wherein the aqueous treatment fluid is manufactured by mixing at least an aqueous base fluid with said homogeneous aqueous polyacrylamide concentrate at the site-of-use.
    Type: Grant
    Filed: October 17, 2019
    Date of Patent: August 15, 2023
    Assignee: BASF SE
    Inventors: Faissal-Ali El-Toufaili, Dennis Loesch, Anna-Corina Schmidt, Tobias Joachim Zimmermann, Markus Ostermayr, Jack F. Tinsley, Brent Busby, Daniel Barrera-Medrano
  • Patent number: 11725135
    Abstract: An inhibited mud acid composition, said composition comprising: hydrofluoric acid in solution; an alkanolamine; and a mineral acid selected from a group consisting of: HCl; MEA-HCl and other modified acids, wherein said alkanolamine and hydrofluoric acid are present in a molar ratio of at least 1:1.
    Type: Grant
    Filed: December 1, 2021
    Date of Patent: August 15, 2023
    Assignee: Dorf Ketal Chemicals FZE
    Inventors: Clay Purdy, Markus Weissenberger, Karl W. Dawson, Kyle G. Wynnyk
  • Patent number: 11718696
    Abstract: A process for making down a powder is provided. The process comprises making down a powder comprising one or more acrylamide-based polymer(s) to form a made down powder solution, comprising blending a mixture of the powder and a solvent for no more than about 15 minutes to yield the made down powder solution, wherein the powder comprises particles having been dry-cut to a median particle size of from about 200 microns to about 10,000 microns.
    Type: Grant
    Filed: July 31, 2018
    Date of Patent: August 8, 2023
    Assignee: ECOLAB USA INC.
    Inventors: Heqing Huang, Cheng Sung Huang, Weiguo Cheng
  • Patent number: 11713414
    Abstract: Polyacrylamide (PAM) compositions and methods of using the compositions as drag reducers in well treatment fluids are disclosed. The compositions use PAM particles with log-asymmetric particle size distributions. For example, about 10% or more of the PAM particles may have particle sizes above 76 ?m, but the particle size distribution tails toward lower particles sizes. Dry PAM formulations and premixed concentrate compositions are disclosed. Well treating fluids prepared using the disclosed compositions reach maximum drag reduction very quickly and also exhibit high sustained drag reduction.
    Type: Grant
    Filed: August 26, 2021
    Date of Patent: August 1, 2023
    Assignee: TUCC Technology, LLC
    Inventors: James W. Dobson, Jr., Rickey L. Warmack
  • Patent number: 11708523
    Abstract: Clay stabilization compositions include one or a plurality of triamino compounds and/or derivatives thereof, fluids containing an effective amount of the clay stabilization compositions and methods for making and using same.
    Type: Grant
    Filed: November 11, 2021
    Date of Patent: July 25, 2023
    Assignee: PfP Industries LLC
    Inventors: Aziz Hikem, Madhukar Chetty, Derek Vaughn, Prasad Taranekar, Jeffery W. Balko
  • Patent number: 11702585
    Abstract: A tight oil reservoir CO2 flooding multi-scale channeling control system and a preparation method, including nanoscale CO2 responsive worm-like micellar systems and micron-scale CO2 responsive dispersion gel, are provided. The nanoscale CO2 responsive worm-like micelle system is prepared by CO2 reactive monomers and organic anti-ion monomers stirred in water. The micron-scale CO2 responsive dispersion gel is made of acrylamide, a responsive monomer, a silane coupling agent modified hydroxylated multi-walled carbon nanotubes as raw materials, cross-linked in water.
    Type: Grant
    Filed: August 31, 2022
    Date of Patent: July 18, 2023
    Assignee: Southwest Petroleum University
    Inventors: Daijun Du, Huancai Fan, Wanfen Pu, Rui Liu, Fayang Jin, Lin Sun, Binyang Zou, Bowen Chen
  • Patent number: 11702582
    Abstract: A biochemical viscosity reducer for heavy oil and a preparation method thereof. The viscosity reducer includes: Brevibacillus borstelensis-fermented mixed lipopeptide solution: 30 to 60 parts; compound biological enzyme: 15 to 30 parts; plant-based nonionic surfactant: 10 to 20 parts; antibacterial agent: 1 to 5 parts; stabilizer: 1 to 5 parts; and alcohol solvent: 10 to 20 parts; where, the above components are measured by mass. The preparation method includes: step 1: adding 30 to 60 parts of a Brevibacillus borstelensis-fermented mixed lipopeptide solution, 15 to 30 parts of a compound biological enzyme, 10 to 20 parts of a plant-based nonionic surfactant, and 1 to 5 parts of a stabilizer to a reactor; and step 2: adding 1 to 5 parts of an antibacterial agent and an alcohol solvent to the reactor, and stirring a resulting mixture for 60 min to 120 min.
    Type: Grant
    Filed: April 9, 2021
    Date of Patent: July 18, 2023
    Assignee: Yangtze University
    Inventors: Yuehui She, Fan Zhang, Zhi Zhang, Puyong Yao, Fei Li, Hao Dong, Shanshan Sun, Gaoming Yu, Shaojin Yi, Wenda Zhang, Linqi Hu, Yangyang Feng, Anying Zheng, Yang Li
  • Patent number: 11697756
    Abstract: Disclosed are molybdenum-containing complexes used in compositions and methods for inhibiting or reducing the deposition of foulant on equipment.
    Type: Grant
    Filed: July 29, 2020
    Date of Patent: July 11, 2023
    Assignee: ECOLAB USA INC.
    Inventors: Omer Gul, Oussama Zenasni, Janelle Pennington
  • Patent number: 11692121
    Abstract: Disclosed are a high-temperature-resistant tertiary amine-grafted silica nano-plugging agent and water-based drilling fluids, relating to oil-gas field drilling. The nano-plugging agent is prepared from a hydrazine compound, a diallyl compound, an enamine compound, silica particle, and an amino-containing silane coupling agent by stepwise reaction. The nano-plugging agent has a grain size of 58-280 nm.
    Type: Grant
    Filed: November 8, 2022
    Date of Patent: July 4, 2023
    Assignee: SOUTHWEST PETROLEUM UNIVERSITY
    Inventors: Gang Xie, Ruolan Wang, Jinjun Huang, Yang Bai
  • Patent number: 11692119
    Abstract: Implementations described herein generally relate to a drag reducing agent (DRA) for improving flow of crude oils having high asphaltene content through pipelines. The DRA is a terpolymer having a glass transition temperature (Tg) of 6 degrees Celsius or below. The terpolymer is formed by a first monomer, a second monomer, and a third monomer. The first and second monomers are chosen based on the glass transition temperatures of corresponding homopolymers. The glass transition temperature of the homopolymer formed with the first monomer is at least 120 degrees Celsius higher than the glass transition temperature of the homopolymer formed with the second monomer. The DRA comprised of the terpolymer formed with the second monomer produces softer solids and fewer solids due to the low glass transition temperature of the terpolymer. The softer solids are more easily handled by the pump to keep the injection system clear.
    Type: Grant
    Filed: July 6, 2021
    Date of Patent: July 4, 2023
    Assignee: LIQUIDPOWER SPECIALTY PRODUCTS INC.
    Inventor: Stuart N. Milligan
  • Patent number: 11685852
    Abstract: A wellbore fluid may include a base fluid and at least one cationic heterocyclic polymer in an amount effective to increase a viscosity of the base fluid, the cationic heterocyclic polymer includes at least two distinct cyclic monomers, at least one of which has at least two heteroatoms in the cyclic structure. A method of drilling a wellbore may introduce such wellbore fluid into the wellbore. A method of producing a cationic heterocyclic polymer may include reacting, in a solvent selected from the group that includes tetrahydrofuran, dioxane, dichloromethane, alcoholic solvents, chlorinated solvents, aromatic hydrocarbon solvents, or mixture thereof, at least two distinct cyclic monomers, at least one of which has at least two heteroatoms in the cyclic structure.
    Type: Grant
    Filed: September 3, 2020
    Date of Patent: June 27, 2023
    Assignee: ARAMCO SERVICES COMPANY
    Inventors: Hasmukh A. Patel, Carl Thaemlitz
  • Patent number: 11680198
    Abstract: A method of sealing propagating cracks in a sensor-laden cement sheath comprising the steps of monitoring an electrical resistivity of the sensor-laden cement sheath to produce a measured value, wherein the sensor-laden cement sheath comprises a conductive sensor, an on-demand expanding agent, and a cement, activating a heat source when the measured value of the electrical resistivity is greater than an activation threshold, increasing a temperature of the sensor-laden cement sheath with the heat source to an activation temperature, wherein the activation temperature is operable to initiate a reaction between the on-demand expanding agent and water, wherein the activation temperature is greater than a formation temperature, reacting the on-demand expanding agent with water to produce a swelled agent, wherein the swelled agent occupies a greater volume than the on-demand expanding agent, and sealing the propagating cracks in the sensor-laden cement sheath with the swelled agent.
    Type: Grant
    Filed: September 13, 2019
    Date of Patent: June 20, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Simone Musso, Ashok Santra
  • Patent number: 11667760
    Abstract: A polymer gel may comprise a polymer gel base material and superparamagnetic nanoparticles. At least 25 wt. % of the superparamagnetic nanoparticles may have diameters in a first size range between a first diameter and a second diameter. At least 25 wt. % of the superparamagnetic nanoparticles may have diameters in a second size range between a third diameter and a fourth diameter. The Brownian relaxation time of the portion of the superparamagnetic nanoparticles in the first size range may be at least 5 times the Neel relaxation time of the portion of the superparamagnetic nanoparticles in the first size range. The Neel relaxation time of the portion of the superparamagnetic nanoparticles in the second size range may be at least 5 times the Brownian relaxation time of the portion of the superparamagnetic nanoparticles in the second size range. Methods for monitoring gel integrity in a wellbore are further included.
    Type: Grant
    Filed: July 20, 2020
    Date of Patent: June 6, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Jesus Manuel Felix Servin, Amr I. Abdel-Fattah
  • Patent number: 11649390
    Abstract: The present invention relates to the use of sequential copolymers (P), comprising at least one chain (C) capable of being obtained by micellar polymerization, for keeping solid particles (p) in suspension in a fluid (F) where said chain (C) is soluble.
    Type: Grant
    Filed: June 3, 2016
    Date of Patent: May 16, 2023
    Assignee: Energy Solutions (US) LLC
    Inventors: Arnaud Cadix, David James Wilson, Lingjuan Shen
  • Patent number: 11649392
    Abstract: A variety of fluid loss control compositions and methods are provided for controlling fluid loss in a cementing operation. As described herein, polyelectrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles can be effective for fluid loss control in a variety of cementing operations. Methods of making and methods of using the electrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles are also provided. The polyelectrolyte complex nanoparticles can include a polycation polymer such as a branched chain polyethylenimine, and a polyanion polymer such as polyacrylic acid or poly(vinylsulfonic) acid. The polyelectrolyte complex nanoparticles can contain additional additives such as metal ions or fluid loss additives such as a cellulose polymer.
    Type: Grant
    Filed: November 3, 2018
    Date of Patent: May 16, 2023
    Assignee: The Texas A&M University System
    Inventors: Ying-Ying Lin, Jenn-Tai Liang, Corbin D. Andersen
  • Patent number: 11634621
    Abstract: The organophilic clay comprises a smectite-type clay ion exchanged with quaternary ammonium ions, where at least 75 mol-% of said quaternary ammonium ions are bis-(2-hydroxypropyl)-dimethylammonium fatty acid esters and at least 90% of the fatty acid moieties of the bis-(2-hydroxypropyl)-dimethylammonium fatty acid esters have a structure RC(O) with group R being a linear alkyl or alkenyl group containing from 9 to 21 carbon atoms. The organophilic clay is useful for thickening oil based compositions, in particular drilling fluids for drilling oil or gas wells, comprising an oil phase.
    Type: Grant
    Filed: November 3, 2020
    Date of Patent: April 25, 2023
    Assignee: Evonik Corporation
    Inventors: Sarah Smith, Gary Davis, Dennis Parrish, Miyako Hisamoto
  • Patent number: 11634625
    Abstract: A well treatment additive includes a siloxane surfactant, a solvent and an aqueous phase. The solvent is preferably a terpene hydrocarbon. Also disclosed is a method for using the well treatment additive to form and enhance the properties of terpene solvent based additives useful for the treatment of oil and gas wells. Methods of using the novel well treatment additives include using the additives in a variety of well treatment processes including, but not limited to, acidizing operations, hydraulic fracturing operations, well remediation operations and water removal operations.
    Type: Grant
    Filed: March 13, 2020
    Date of Patent: April 25, 2023
    Assignee: Flotek Chemistry, LLC
    Inventors: Glenn S. Penny, Keith Ingram Dismuke, Richard Nelson Fox, Andrei Zelenev, Randal M. Hill
  • Patent number: 11634624
    Abstract: The anionic cocogem surfactant of formula (I) for an oil production process of increased efficiency wherein each R1 and R2 is independently selected from hydrogen or C1-C18 straight or branched alkyl optionally substituted by OH; each R3 is independently selected from hydrogen; C1-C25 straight or branched alkyl or alkenyl optionally comprising inter-chain amido-group; aromatic group optionally substituted by C1-C25, preferably C5-C20, more preferably C5-C15 straight or branched alkyl, preferably selected from phenyl and diphenylether; or C10-C20 straight or branched alkenyl, alkadienyl or alkatrienyl; Z is C1-C18 straight or branched alkylene optionally substituted by one or two C1-C6 alkyl or preferably C3-C6 cycloalkyl, optionally comprising (EO)n and/or (PO)m groups, wherein EO is ethylene-oxide i.e. —CH2CH2O—, and PO is propylene-oxide, i.e.
    Type: Grant
    Filed: March 28, 2019
    Date of Patent: April 25, 2023
    Assignee: MOL MAGYAR OLAJ- ÉS GÁZIPARI NYILVÁNOSAN MŰKÖDŐ RÉSZVÉNYTÁRSASÁG
    Inventors: József Dudás, Sándor Puskás, Árpád Vágó, László Bartha, Roland Nagy, Mária Törö, István Lakatos