Abstract: A reactor includes a vessel, a gas inlet, a solid outlet, a catalyst support configured to at least partially retain a catalyst material and allow a tail gas to pass therethrough, and a tail gas outlet. The gas inlet is in fluid communication with the solid outlet. A system for producing a solid product includes a reactor, a compressor, a heater, a make-up reactive gas inlet, and a solids discharge means for removing the solid product from the solid outlet of the reactor. Methods of forming solid products include providing a catalyst material in a vessel having a porous catalyst support, delivering a reactive gas to the vessel, reacting the reactive gas to form a solid product and a tail gas in the vessel, passing the tail gas through a portion of the catalyst material to separate the solid product from the tail gas, and removing the solid product.

Abstract: An automated radiosynthesizer device includes a plurality of reactor assemblies, each reactor assembly being operatively connected to a horizontal actuator for moving the reactor assembly in the horizontal direction and a vertical actuator for moving the reactor assembly in the vertical direction. A plurality of disposable cassettes are disposed above each of the plurality of reactor assemblies, each cassette comprising a lower surface comprising a plurality of sealed and un-sealed gaskets, wherein the un-sealed gaskets are connected to internal fluid paths within the cassette. The device includes a three-axis reagent and gas handling robot disposed above the plurality of cassettes and terminates in a vial gripper and a gas manifold having an inert gas port and a vacuum port. The device includes a control system configured to control the horizontal actuator and vertical actuator of each reactor assembly and the three-axis reagent and gas handling robot.

Abstract: The present invention discloses aromatization reactor vessels with hydrogen membrane tubes, and associated aromatization reactor vessel systems. Also disclosed are processes for conducting aromatization reactions utilizing these reactor vessels and systems.

Abstract: An apparatus for producing butadiene by way of oxidative dehydrogenation of a butene-rich feed stream includes: (a) a reactor adapted for receiving said butene-rich feed stream and converting butenes to butadiene, thereby providing a butadiene enriched product effluent stream; (b) a superheater coupled to the reactor to receive the butadiene enriched product effluent stream from the reactor as well as being configured to receive reactor feed, said superheater transferring sensible heat from the butadiene enriched product effluent stream to reactor feed and (c) a first feed-vaporizer coupled to the superheater to receive the butadiene enriched product effluent stream as it exits the superheater and to transfer sensible heat from the butadiene enriched product effluent stream to reactor feed. Also provided are (d) a second feed vaporizer; (e) a purification train; and (f) a thermal oxidizer.

Abstract: This disclosure relates to a fluidized bed reaction system and method for continuous production of titanium tetrachloride from titanium-bearing materials containing high concentrations of alkaline earth metal impurities. Agglomerated heavy particles in a reaction are taken out continuously from a chlorination reactor without clogging and stopping. The reactors and related methods disclosed apply to the chlorination of titanium slag containing high content of alkaline earth metal oxides of up to 15% by weight.

Abstract: The invention relates to equalizing and distributing reactants more evenly across the interior space of a reactor vessel utilizing a combination equalizer and distributor at the inlet end that initially impedes with uneven flow rates of vapor and then directs the flow of vapor through a series of circumferential nozzles. The nozzles are physical spaced such that the first nozzle provides the reactants into the vessel to spread radially and broadly outwardly into the vessel and each successive circumferential nozzle to deliver reactants in a less broadly distribution or dispersion where the interior space is filled with reactants without broadly diverse velocities that may create hot spots within the catalyst bed.

Abstract: The invention provides a solid phase hydrogen-generating system utilizing a solid chemical hydride fuel selected from the group consisting of sodium borohydride, lithium borohydride, magnesium hydride and calcium hydride, wherein the fuel is encapsulated in a plurality of removable capsules, the capsules being pumpable and having a major axis of up to 40 mm.

Abstract: A subsurface thermally autogenous reactor and method has downgoing and upgoing flow passages connected at the bottom to form a U-tube and in heat exchange relation to each other. The downgoing and upgoing flow passages each have an upper heat exchange section and a lower reaction section. An air injection system injects air into the downgoing flow passage between the heat exchange and reaction sections. The cross sectional area of the upgoing heat exchange section is greater than the cross sectional area of the downgoing heat exchange section to balance the downgoing and upgoing flow velocities. The downgoing heat exchange section has multiple tubes to increase the heat transfer area.

Abstract: In a fuel reforming system (32) of a fuel cell system (1), which includes a reformer (7) generating hydrogen-containing gas to be an electromotive fuel and a combustor (6) generating combustion gas, the combustor (6) has two combustion parts including a main combustion part (20) and a sub-combustion part (18), a fuel pre-vaporization part (19) between the two combustion parts and a main fuel injection valve (16) and a sub-fuel injection valve (15) which supply the fuel to the respective combustion parts.

Abstract: The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

Abstract: A carbon monoxide oxidizer comprises an oxidant supply unit (4) that supplies an oxidant gas to a reformate gas, a mixing unit (5) that mixes the reformate gas with the oxidant gas, and a preferential oxidation catalyst unit (6) that removes carbon monoxide from a mixed gas using catalytic action. The mixing unit (5) comprises a stacked body (9) of plates (100A-100F). A rotating passage (101) that is formed in the stacked body (9) to rotate the flow of the mixed gas, thereby promoting mixing of the reformate gas with the oxidant gas by a rotating flow formed by the rotating passage (101).

Abstract: A gas supplying system for fuel cell includes a reformer generating a reformed gas by reforming a mixed raw material including a fuel and a first water, a piping network distributing the reformed gas to fuel cell systems each of which is installed in different rooms or buildings, a drain recovery unit recovering a water condensed from the reformed gas in the piping network. The piping network has a circulating route. By the circulation route, the reformed gas does not stay in the piping network so that the water condensation in the piping is suppressed. The water in the piping is removed by the drain recovery unit. According to this configuration, the clogging and corrosion of the piping caused by the condensed water is avoided.

Abstract: An exhaust gas-purifying catalyst system is provided with a plurality of catalyst layers including a first and a second catalyst layers, supported on a support structure. The first catalyst layer comes into contact with an exhaust gas stream firstly among the plurality of catalyst layers. The second catalyst layer is provided adjacent to the first catalyst layer. The first catalyst layer contains a first noble metal active component including rhodium, together with a powder of a barely soluble barium compound in an amount of 0.05 mol to 0.2 mol per volume in liter of the support structure. The second catalyst layer contains a second noble metal active component.

Abstract: An exhaust gas cleaning apparatus for cleaning an exhaust gas emitted from a combustion engine has a stack of plural material layers successively arranged on each other in a stacking direction. The material layers are made of a porous material being permeable to the exhaust gas. The stack has an entry side and an exit side. Plural exhaust gas flow channels are defined in the stacking direction between two adjacent material layers in the stack. The exhaust gas flow channels are defined by surfaces of the material layers which have, when viewed in a flow direction of the exhaust gas from the entry side to the exit side, a plurality of concave and convex areas. A first group of exhaust gas flow channels is formed to be open at the entry side of the stack and closed at the exit side thereof.

Abstract: The invention related to a microreactor system for the continuous synthesis, which provides defined reaction chambers and conditions for said synthesis, as well as to the uses of said microreactor in carrying out a chemical reaction. According to said invention, (a) said mircoreactor system (11) is of modular design, (b) a processing unit (10) is made up of processing modules which are connected to each other by frictional engagement and (c) the fluid connections in said processing unit (10) can be obtained by the frictional connection of said processing modules.

Abstract: A fuel reforming system generates burnt gas by burning fuel and air in a burner (6) during system startup, and the temperatures of a reforming reactor (7) and carbon monoxide oxidizer (40) are raised by supplying the burnt gas to the reforming reactor (7) and carbon monoxide oxidizer (40). The temperature of the burnt gas produced by the burner (6) is increased according to the elapsed time from the beginning of the startup processing.

Abstract: This method of upgrading a biomass comprises: an upgrading step for performing upgrading treatment of a cellulose based biomass with an oxygen/carbon atomic ratio of at least 0.5, in presence of water and under a pressure of at least saturated water vapor pressure, and reducing said oxygen/carbon atomic ratio of said biomass to no more than 0.38, and a separation step for separating an upgraded reactant obtained from said upgrading step into a solid component and a liquid component.

Abstract: A tank is fed with mud via a first inlet and the mud is removed via a first outlet. An ultrasonic electroacoustic transducer generates an acoustic energy field in the mud contained in the tank so as to extract the gases from the mud. A carrier gas is injected via a second inlet of the tank and a physico-chemical analysis apparatus of the extracted gases is connected to a second outlet of the tank designed for the carrier gas and the extracted gases. The flow rate of mud fed to the tank is regulated to a constant value and the volume of mud in the tank is constant. The mud can be constituted by oil prospecting drilling mud, the gases to be extracted then being oil revealing gases. The mud feed and injection of carrier gas can be synchronized so as to enable continuous analysis or batch analysis.

Abstract: A liquid column type exhaust gas treatment apparatus comprising a spray header (2) for injecting an absorbing solution upward in an absorption tower (1), wherein exhaust gas introduced from a lower part of the absorption tower (1) and the absorbing solution injected from the spray header (2) are brought into gas-liquid contact with each other, by which desulfurization of exhaust gas is accomplished, characterized in that drift preventing plates (5a and 5b) are provided in a liquid top portion of a liquid column (6) formed by the absorbing solution and/or at the installation position of the spray header (2).

Abstract: Internal combustion engines exhibit improved efficiency of the emissions control system by using a lubricating oil composition of a base oil, an alkali or alkaline earth metal-containing detergent; a metal salt of one or more phosphorus-containing compounds represented by the formula (I), wherein X1 and X2 are independently O or S, and R1 and R2 are independently hydrocarbyl groups, the average total number of carbon atoms in R1 and R2 for the one or more phosphorus-containing compounds being at least 10.4; and an acylated nitrogen-containing compound having at least about 10 alphatic carbon atoms and a TBN of at least about 2; the lubricating oil composition being characterized by a phosphorus concentration of up to about 0.12% by weight and the substantial absence of copper, thereby generating a lean-phosphorus containing exhaust gas.