Abstract: A process to prepare a polypropylene, and the polypropylene and films therefrom, comprising combining a high melt strength polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?vis) of at least 0.95, and a melt strength of at least 20 cN determined using an extensional rheometer at 190° C., and within the range from 20 to 1000 ppm of a long half-life organic peroxide, and isolating the polypropylene, wherein the polypropylene thus formed has a molecular weight distribution (Mw/Mn) within a range of from 7 to 22, a z-average molecular weight of less than 1,600,000 g/mole, a branching index (g?vis) of at least 0.95; and a melt strength less than 20 cN.

Abstract: The present invention relates to an energy curable aqueous composition (X) comprising (a) Water; (b) At least a water-insoluble ethylenically unsaturated compound (A); (c) At least one (meth)acrylic polymer (B1) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C) and/or at least one (meth)acrylic hybrid (B2) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C); and (d) At least one nonionic emulsifier (D) comprising alternating polyalkylene oxide segments, said nonionic emulsifier (D) having an HLB value of at least 4.5. Materials of the invention are suitable for the preparation of inks, overprint varnishes or coating compositions.

Abstract: The present invention relates to a novel PVC-free plastisol composition that cures at a temperature much lower than conventional plastisols. The plastisol composition includes an acrylate polymer; and a plasticizer mixture comprising at least three plasticizers selected from the group consisting of 2,2,4-trimethyl-1,3 pentanediol diisobutyrate, dioctyl terephthalate, dibutyl terephthalate, and benzyl butyl 1,2-cyclohexyldicarboxylate. Also disclosed is a method of applying the composition.

Abstract: Disclosed are processes for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula: A-S-P, wherein A is a chemical group containing at least one aliphatic double bond, S is a sulfur atom, and P is a protecting group.

Abstract: Provided is a multi-component copolymer capable of improving the rollability of a rubber composition while having excellent low heat generating property. The multi-component copolymer comprises conjugated diene units, non-conjugated olefin units and aromatic vinyl units, wherein: a ratio among all of the aromatic vinyl units of at least one aromatic vinyl unit existing in amorphous parts inclusive of the conjugated diene units is less than 50%.

Abstract: A polyester resin composition comprising a crystalline wholly aromatic polyester which is a polycondensate of an aromatic dicarboxylic acid and an aromatic diol, and a filler, wherein a structural unit derived from the aromatic dicarboxylic acid comprises a structural unit represented by chemical formula (1): and a structural unit derived from the aromatic diol comprises chemical formula (4): wherein content of a residue of 4,4?-dicarboxy diphenyl ether (corresponding to the structural units represented by chemical formula (1)) and a residue of 4,4?-dihydroxy benzophenone (corresponding to the structural units represented by chemical formula (4)) is at least 80 mol % in the entire structural units of the crystalline wholly aromatic polyester.

Abstract: Presented are fiber-reinforced polymer (FRP) sandwich structures, methods for making/using such FRP sandwich structures, and motor vehicles with a vehicle component fabricated from a compression molded thermoset or thermoplastic FRP sandwich structure. A multidimensional composite sandwich structure includes first and second (skin) layers formed from a thermoset of thermoplastic polymer matrix, such as resin or nylon, filled with a fiber reinforcing material, such as chopped carbon fibers. A third (core) layer, which is encased between the first and second skin layers, is formed from a thermoset/thermoplastic polymer matrix filled with a fiber reinforcing material and a filler material, such as hollow glass microspheres. The first, second and third layers have respective rheological flow properties that are substantially similar such that all three layers flow in unison at a predetermined compression molding pressure.

Abstract: A package with a coating composition deposited on at least a portion thereof is disclosed. The coating composition comprises: (a) a latex polymer comprising the emulsion polymerization product of (i) an emulsion monomer component comprising at least one ethylenically unsaturated monomer polymerized in the presence of (ii) a surfactant that is polymerizable with the at least one ethylenically unsaturated monomer. Also disclosed is a method for applying the coating composition to the package.

Abstract: A liquid composition for imparting alcohol-repellency to a semiconductor substrate material and a method for treating a semiconductor substrate surface using the liquid composition, are disclosed. The liquid composition contains: a surfactant (A) having a substituent of formula (1) (where n is an integer of 3 to 20), and an anionic hydrophilic group; and a compound (B) being selected from the group consisting of compounds having a polyethylenimine and a substituent of formula (2) or formula (3) (where R1, R2, R3 and R4 are each independently hydrogen or a C1-6 alkyl, alkenyl, alkynyl, or aryl, and X? is a fluoride ion, a chloride ion, a bromide ion, an iodide ion, a fluoroborate ion, a phosphate ion, an acetate ion, a trifluoroacetate ion, a sulfate ion, a hydrogen sulfate ion, a methane sulfate ion, a hydroxide ion, a perchlorate ion, or a nitrate ion).

Abstract: Systems and methods of providing a self-healing UV-protective polymer coating include a polymer matrix formed by initiating polymerization of a UV-absorbing-matrix precursor and a UV initiator and a self-healing portion disposed within the polymer matrix. The polymer matrix includes a plurality of active sites therein. The self-healing portion includes a self-healing precursor that is flowable and a self-healing initiator. The self-healing initiator is configured to polymerize the self-healing precursor using a cationic ring opening process.

Abstract: The invention relates to a method of making an aqueous coating composition comprising a blend of at least a first aqueous polymer dispersion and a second aqueous polymer dispersion comprising a film-forming second polymer wherein the first aqueous polymer dispersion comprises a first polymer having a number average molecular weight, Mn, of from 2000 to 120000, an acid value of 30 to 150 mg KOH/g, a glass transition temperature Tg of at least 20° C. as calculated with the Fox formula, and an ethylene-oxide content of from 1 to 20 wt %, the method comprising blending an aqueous dispersion of the first polymer having a solids content of 25 to 50 wt % and a pH of 4.5 to 8.0 with an aqueous dispersion of the second polymer having a solids content of 25 to 55 wt % and a pH of 4.5 to 8.0.

Abstract: Copolymerization of elemental sulfur with functional comonomers afford sulfur copolymers having a high molecular weight and high sulfur content. Nucleophilic activators initiate sulfur polymerizations at relative lower temperatures and in solutions, which enable the use of a wider range of comonomers, such as vinylics, styrenics, and non-homopolymerizing comonomers. Nucleophilic activators promote ring-opening reactions to generate linear polysulfide intermediates that copolymerize with comonomers. Dynamic sulfur-sulfur bonds enable re-processing or melt processing of the sulfur polymer. Chalcogenide-based copolymers have a refractive index of about 1.7-2.6 at a wavelength in a range of about 5000 nm-8????. The sulfur copolymer can be a thermoplastic or a thermoset for use in elastomers, resins, lubricants, coatings, antioxidants, cathode materials for electrochemical cells, dental adhesives/restorations, and polymeric articles such as polymeric films and free-standing substrates.

Abstract: A sorbent composition for enhanced baghouse function is described. The composition may include a sorbent such as powder activated carbon as well as an additive that is a heat moderator or a permeability agent. The heat moderator may act as a heat sink or barrier. Heat moderators may include in non-limiting examples phyllosilicates, cyclosilicates, or nesosilicates that may include, montmorillonite, bentonite, halloysite, aluminum silicates, muscovite, illite, kaolin, andalusite, kyanite, sillimanite, metakaolin, mullite, polymers, such as chitosan, and/or clays, either natural or synthetic (e.g., montmorillonite), or polyethylenimine. Permeability may be affected by mixing sorbents of lower D50 with sorbents of higher D50 in various ratios, or addition of a permeability agent such as a phyllosilicate, perlite, silica, diatomaceous earth. Further, a permeability agent such as a fluoropolymer may be coated onto or admixed with the sorbent.

Abstract: A process of forming a resveratrol-based flame retardant small molecule with a phosphonate/phosphinate molecule that includes a chloride group and a terminal functional group.

Abstract: The invention relates to copolymers of vinyl lactams with derivatized maleates. In particular, it relates to copolymers that are suitably used in the area of personal care and pharmaceuticals, to compositions comprising the copolymers and to methods for preparing the copolymers.

Abstract: An environmentally friendly, formaldehyde-free, aqueous binder composition that includes a carbohydrate, a crosslinking agent, and a pre-reacted product of an alcohol or polyol and monomeric or polymeric polycarboxylic acid or polyglycerol is provided. The pre-reacted product may include glycerol and esters of citric acid such a monoglyceryl citrate, diglyceryl citrate, and triglyceryl citrate as well as other higher molecular weight citric acid-based esters. The inclusion of the pre-reacted product in the binder composition helps to speed the crosslinking reaction, induces faster water evaporation, decreases the viscosity of the binder, helps to reduce the amount of water needed for application of the binder, decreases tackiness, and helps to achieve a maximum vertical expansion of the insulation pack in the transfer zone. The binder composition may be used in the formation of insulation materials and non-woven chopped strand mats.

Abstract: An ethylene alpha-olefin copolymer having (a) a density of from about 0.910 g/cc to about 0.940 g/cc; (b) a weight average molecular weight of from about 150,000 g/mol to about 300,000 g/mol; and (c) a melt index at a load of 2.16 kg of from about 0.01 dg/10 min. to about 0.5 dg/min.; wherein a 1 mil blown film formed from the polymer composition is characterized by (i) a Dart Impact strength greater than about 175 g/mil; (ii) an Elmendorf machine direction tear strength greater than about 20 g/mil; and (iii) an Elmendorf transverse direction tear strength greater than about 475 g/mil.

Abstract: The present disclosure refers to an aqueous stain resistant coating composition, comprising, one or more aqueous dispersions of self-crosslinkable polymeric particles; and one or more particulate solids, wherein the polymeric particles have a Tg of 10° C. or less; and wherein the particulate solids comprise a combination of sheet-like particulate solids and sphere-like particulate solids in a weight ratio of 1:1 or more; and wherein the coating composition has a pigment volume concentration of 45% or more; and the coating composition is substantially free of volatile organic compounds.

Abstract: A fire insulation precursor material formed of cement, in an amount of between 10-30% w/w; and an aluminium or magnesium hydroxide, huntite or hydromagnesite in an amount of between 60-90% w/w. A fire insulation material is provided including the previously mentioned precursor material. Further described are methods of forming a fire insulation material and applications for such material in sheaths, duct coatings, cable trays and other elongate components.

Abstract: Provided is a multi-component copolymer comprising conjugated diene units, non-conjugated olefin units and aromatic vinyl units, wherein: a weight-average molecular weight of chain parts, divided by the conjugated diene units and each containing one or more of the non-conjugated olefin units and/or one or more of the aromatic vinyl units, is 50,000 or more. A rubber composition comprising the multi-component copolymer, a crosslinked rubber composition, and a rubber article comprising the crosslinked rubber composition are also provided.