Abstract: Methods described herein manage wafer entry into an electrolyte so that air entrapment due to initial impact of the wafer and/or wafer holder with the electrolyte is reduced and the wafer is moved in such a way that an electrolyte wetting wave front is maintained throughout immersion of the wafer also minimizing air entrapment.

Abstract: A method of additive manufacturing that deposits material onto a cathode by transmitting current from an anode array through an electrolyte to the cathode; the method uses feedback to control the manufacturing of successive layers of a part. For example, feedback signals may be a map of current across the anode array; this current map may be processed using morphological analysis or Boolean operations to determine the extent of deposition across the layer. Feedback data may be used to determine when a layer is complete, and to adjust process parameters such as currents and voltages during layer construction. Layer descriptions may be preprocessed to generate maps of desired anode current, to manipulate material density, and to manage features such as overhangs. Feedback signals may also trigger execution of maintenance actions during the build, such as replenishment of anodes or removal of films or bubbles.

Abstract: Disclosed is a method for producing an electrocast belt which method ensures long-term use of an electrocasting bath and which method enables provision of an electrocast belt having a required product quality even when an electrocasting bath that has been used in electrolysis with a large cumulative amount of electricity. The method includes a first step of producing an electrocast belt having a required product quality in an electrocasting bath of a specific composition until a predetermined period of time has elapsed; a second step of subsequently producing an electrocast belt in the same electrocasting bath; and a third step of polishing a surface of the electrocast belt produced from the second step so that the electrocast belt produced from the third step has a product quality equivalent to that of the electrocast belt produced from the first step.

Abstract: A method for electrodepositing aluminum and nickel using a single electrolyte solution includes forming a mixture comprising nickel chloride and an organic halide, adding aluminum chloride to the electrolyte solution in an amount at which the mixture becomes an acidic electrolyte solution, providing a working electrode and a counter electrode in the acidic electrolyte solution, and applying a waveform to the counter electrode using cyclic voltammetry to cause aluminum and nickel ions to be deposited on the working electrode.

Abstract: A water treatment device in which a treatment target water introduction portion is provided in an upper portion of a receptacle, and the water treatment device has a space in which conductive porous members are not disposed between the conductive porous members and the treatment target water introduction portion in the receptacle. When a backwashing fluid is introduced from a lower portion of the receptacle in a desorption, the conductive porous members flow and are agitated owing to the backwashing fluid, because of which a desorption of ions adsorbed to the conductive porous members is promoted. Grains of the agitated conductive porous members collide with other grains of the conductive porous members or with electrodes or a separator, whereby scale and a biofilm appearing on surfaces of the grains of the conductive porous members, the electrodes, or the separator can be removed, and desalination efficiency can be maintained.

Abstract: Embodiments disclosed herein relate to methods and systems for producing and using hypochlorite from brine.

Abstract: An apparatus for fabricating an electrode structure includes a high voltage unit, a plating material part facing the high voltage unit, and a transfer roll to which a negative voltage is applied. The high voltage unit includes a high voltage roll, and an insulating sheath configured to cover a surface of the high voltage roll. The high voltage roll is applied with a voltage of about 1 kV to about 100 kV, the plating material part is applied with a positive voltage, and the high voltage unit and the transfer roll rotate.

Abstract: A method of forming a micro-structure involves forming a multi-layered structure including i) an oxidizable material layer on a substrate and ii) another oxidizable material layer on the oxidizable material layer. The oxidizable material layer is formed of an oxidizable material having an expansion coefficient, during oxidation, that is more than 1. The method further involves forming a template, including a plurality of pores, from the other oxidizable material layer, and growing a nano-pillar inside each pore. The nano-pillar has a predefined length that terminates at an end. A portion of the template is selectively removed to form a substantially even plane that is oriented in a position opposed to the substrate. A material is deposited on at least a portion of the plane to form a film layer thereon, and the remaining portion of the template is selectively removed to expose the nano-pillars.

Abstract: Disclosed herein is a bottom-up electrolytic via plating method wherein a first carrier substrate and a second substrate having at least one through-via are temporarily bonded together. The method includes applying a seed layer on a surface of the first substrate, forming a surface modification layer on the seed layer or the second substrate, bonding the second substrate to the first substrate with the surface modification layer to create an assembly wherein the seed layer and the surface modification layer are disposed between the first and second substrates, applying conductive material to the through-via, removing the second substrate having the through-via containing conductive material from the assembly.

Abstract: Devices, apparatus and methods for sequencing macromolecules are disclosed. The devices and apparatus include independently controllable fluid channels bi-directionally coupled to a measurement module.

Abstract: The present invention relates to applying at least one ultra/mega sonic device and its reflection plate for forming standing wave in a metallization apparatus to achieve highly uniform metallic film deposition at a rate far greater than conventional film growth rate in electrolyte. In the present invention, the substrate is dynamically controlled so that the position of the substrate passing through the entire acoustic field with different power intensity in each motion cycle. This method guarantees each location of the substrate to receive the same amount of total sonic energy dose over the interval of the process time, and to accumulatively grow a uniform deposition thickness at a rapid rate.

Abstract: Superconformally filling a recessed feature includes: contacting the recessed feature with superconformal filling composition that includes: Au(SO3)23? anions; SO32? anions; and Bi3+ cations; convectively transporting Au(SO3)23? and Bi3+ to the bottom member of the recessed feature; subjecting the recessed feature to an electrical current to superconformally deposit gold from the Au(SO3)23? on the bottom member relative to the sidewall and the field, the electrical current providing a cathodic voltage; and increasing the electrical current subjected to the field and the recessed feature to maintain the cathodic voltage between ?0.85 V and ?1.00 V relative to the SSE during superconformally depositing gold on the substrate to superconformally fill the recessed feature of the article with gold as a superconformal filling of gold, the superconformal filling being void-free and seam-free.

Abstract: A gas sensor includes a sensing element having an electrode pad a metal terminal, and a separator that has insertion holes in which the metal terminal is held. The metal terminal includes a main body and an elastic portion that is integrally connected to the main body and is elastically connected to the electrode pad at a predetermined contact point. The main body includes a front-end-side restricting portion and a rear-end-side restricting portion that restrict the movement of the main body by contacting wall surfaces of the insertion hole when the main body moves in a direction intersecting the direction of an axial line. The contact point is located between the front-end-side restricting portion and the rear-end-side restricting portion in the direction of the axial line. The front-end-side restricting portion and the rear-end-side restricting portion are connected to each other so that a flat board portion is interposed therebetween.

Abstract: An electrochemical reaction device, comprises: an anode to oxidize a first substance; a first flow path facing on the anode and through which a liquid containing the first substance flows; a cathode to reduce a second substance; a second flow path facing on the cathode and through which a gas containing the second substance flows; a porous separator provided between the anode and the cathode; and a power supply connected to the anode and the cathode. A thickness of the porous separator is 1 ?m or more and 500 ?m or less. An average fine pore size of the porous separator is larger than 0.008 ?m and smaller than 0.45 ?m. A porosity of the porous separator is higher than 0.5.

Abstract: Apparatus includes treatment chamber including at least one outlet for exit of electrochemically treated liquid, and a liquid disperser having a plurality of liquid passageways, wherein each said liquid passageway includes at least one inlet to the treatment chamber for entry of a liquid to be treated; and a plurality of electrodes positioned within the treatment chamber for electrochemical treatment of the liquid.

Abstract: Methods and systems for electrochemically producing at least one product are disclosed. In some embodiments, the systems include a membraneless electrochemical flow-through reactor. A pair of porous electrodes configured at an angle to each other is disposed within the reactor in a channel of flowing electrolyte including a target reactant. As the electrolyte stream flows through the porous electrodes, a voltage is applied across the electrodes, resulting in the generation of a catholyte effluent stream and an anolyte effluent stream Gaseous and/or liquid products may then be separated from these streams. The membraneless electrochemical flow-through reactor is an easy to design and assemble apparatus for a variety of electrochemical processes.

Abstract: Disclosed herein are methods and systems that relate to electrochemically oxidizing metal halide with a metal ion in a lower oxidation state to a higher oxidation state; halogenating an unsaturated hydrocarbon or a saturated hydrocarbon with the metal halide with the metal ion in the higher oxidation state; and oxyhalogenating the metal halide with the metal ion from a lower oxidation state to a higher oxidation state in presence of an oxidant. In some embodiments, the oxyhalogenation is in series with the electrochemical oxidation, the electrochemical oxidation is in series with the oxyhalogenation, the oxyhalogenation is parallel to the electrochemical oxidation, and/or the oxyhalogenation is simultaneous with the halogenation.

Abstract: In a method for manufacturing an interconnect structure, a dielectric layer is removed to form a first recess and a second recess. The first recess is below the second recess. A first metal layer is deposited to fill the first recess and a first portion of the second recess. A carbon-containing layer is deposited over the first metal layer to fill a second portion of the second recess, which is over the first portion. A second metal layer is deposited over the carbon-containing layer to fill a third portion of the second recess, which is over the second portion. A carbon concentration of the carbon-containing layer is greater than a carbon concentration of the first metal layer and a carbon concentration of the second metal layer, and the carbon concentration of the first metal layer is substantially the same as the carbon concentration of the second metal layer.

Abstract: The invention concerns an electrolytic reactor, in particular for separating phosphate from phosphate-containing liquids and recovering phosphate salts, comprising a housing, an inlet and an outlet for the liquid and two electrodes of different polarity, which enclose a reactor chamber between them, whereby at least one of the two electrodes is a sacrificial electrode and consists of a magnesium-containing material, whereby the sacrificial electrode is constructed of trapezoid bars which have a first and a second upper surface, whereby the first upper surface is smaller than the second upper surface, and whereby four lateral surfaces connect the first upper surface with the second upper surface.

Abstract: The invention relates to an electrode arrangement (10) for electrochemically treating a liquid. The electrode arrangement (10) has two electrodes (2), each of which has at least one electrode surface (4) and at least one through-flow chamber (34) with at least one inlet (22) and at least one outlet (24). The at least one through-flow chamber (34) is delimited on at least one first face by at least one electrode (2) which has a structure (8) on its electrode surface (4) such that a distance between the electrode surface (4) and a second through-flow chamber (34) face lying opposite the first face is varied.