Patents Examined by M. J. Welsh
  • Patent number: 3986994
    Abstract: Stable emulsions of terpolymer particles are formed by polymerizing ethylene, an acrylic monomer such as acrylic acid, and an alkyl vinyl monomer having from about 3 up to about 24 carbon atoms in an aqueous medium in the presence of a water soluble persulfate initiator, and a nonionic and/or anionic emulsifier. The resulting novel stable emulsions contain particles of ethylene-acrylic-alkyl vinyl terpolymer which will provide film coatings of increased flexibility and toughness. Furthermore, the emulsions have excellent compatibility when blended within conventional polish formulations.
    Type: Grant
    Filed: January 16, 1975
    Date of Patent: October 19, 1976
    Assignee: Cosden Technology, Inc.
    Inventors: Glenn E. Teer, Jerry G. Higgins, George D. Warren
  • Patent number: 3985698
    Abstract: A method for improving emulsion paint which is characterized in that 1 to 40 parts by weight as solids of aqueous acrylic resin solution is added to 100 parts by weight as resin solids of emulsion paint, said aqueous acrylic resin solution being produced from ethylenically unsaturated monomer having tertiary amine group, ethylenically unsaturated monomer having carboxyl group(s) and other ethylenically unsaturated monomer. The improved emulsion paint thereby formed has a low thixotropic property and an excellent coating property, and forms excellent coating film with good water resistance, moisture resistance and chemical resistance.
    Type: Grant
    Filed: February 24, 1975
    Date of Patent: October 12, 1976
    Assignee: Kansai Paint Company, Ltd.
    Inventors: Tadashi Matsudaira, Tadashi Watanabe, Yashuhiko Haruta, Teiitsu Takagi
  • Patent number: 3985713
    Abstract: Cyclic nitrile adducts are used as crosslinking agents for acrylic interpolymers to produce thermosetting resins having exceedingly high impact resistance. Adipodinitrile carbonate is a preferred cyclic nitrile.
    Type: Grant
    Filed: November 15, 1972
    Date of Patent: October 12, 1976
    Assignee: Atlantic Richfield Company
    Inventors: Kurt C. Frisch, Sidney L. Reegen, Harry L. Bauer
  • Patent number: 3985694
    Abstract: Asphaltic compositions, having improved elastic properties, durability and resistance to deterioration by oil and grease and improved adhesion to aggregate particles, are provided comprising a major amount of asphalt, a minor amount of a synthetic terpenic resin and an interpolymer of ethylene, vinyl acetate and an organic acid.
    Type: Grant
    Filed: August 29, 1974
    Date of Patent: October 12, 1976
    Assignee: Mobil Oil Corporation
    Inventors: Richard J. Petrucco, Charles A. Pagen
  • Patent number: 3985701
    Abstract: A novel oil-containing rubber composition is prepared by admixing a rubber from the group consisting of natural rubber, homopolymers of conjugated diolefins, and copolymers of conjugated diolefins with ethylenically unsaturated monomers, with mineral oil having at least 10 weight percent aromatic compounds which has been obtained byA. mixing a mineral oil starting material with an acidic reagent comprising anhydrous hydrogen fluoride in amount from 10 to 40 percent by weight of said starting material; thereby to form an acid phase insoluble in said mineral oil and containing components extracted from said starting material, and an oil phase comprising unextracted components of said starting material and containing dissolved acidic material,B. separating said acid phase from said oil phase,C. mixing said oil phase with an alkaline reagent to neutralize said dissolved acidic material and form neutralization products, andD. separating said neutralization products from said oil phase.
    Type: Grant
    Filed: May 29, 1967
    Date of Patent: October 12, 1976
    Assignee: Sun Oil Company of Pennsylvania
    Inventors: Abraham Schneider, Archibald P. Stuart
  • Patent number: 3984368
    Abstract: Stable emulsions of terpolymer particles are formed by polymerizing ethylene, a difunctional olefin such as maleic anhydride and an alkyl vinyl monomer having from about 3 to about 18 carbon atoms in an aqueous medium in the presence of a water soluble persulfate initiator, and a nonionic and/or anionic emulsifier. The resulting novel stable emulsions contain particles of terpolymer of the three monomers which will provide film coatings of increased flexibility and toughness. Furthermore, the emulsions have excellent compatibility when blended with conventional polish formulations.
    Type: Grant
    Filed: January 23, 1975
    Date of Patent: October 5, 1976
    Assignee: Cosden Technology, Inc.
    Inventors: Glenn E. Teer, Jerry G. Higgins, George D. Warren
  • Patent number: 3983308
    Abstract: A novel process for making polymers degradable by the direct action of sunlight is disclosed. The process is based on the addition to the polymer of a compound having the formula: ##EQU1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and are selected from the group consisting of aromatic radicals with the proviso that one or two of them may be selected from the group consisting of hydrogen, alkyl, cycloalkyl and arylalkyl.
    Type: Grant
    Filed: October 24, 1974
    Date of Patent: September 28, 1976
    Assignee: Snam Progetti S.p.A.
    Inventors: Nicola Palladino, Marcello Mazzei, Walter Marconi
  • Patent number: 3981680
    Abstract: Savings in reductant are realized and effluent is reduced in the continuous process of steam fixing of vat dyes on textile web by expressing reductant-comprising liquor containing excess reductant from the web following the steam fixing step and applying expressed liquor, together with fresh reductant liquor, to web entering the fixing step.
    Type: Grant
    Filed: January 17, 1975
    Date of Patent: September 21, 1976
    Inventor: John Milford Fletcher
  • Patent number: 3980594
    Abstract: Quaternary ammonium salts or inorganic and organic oxygen acids having pK values (where pK is the negative log of the dissociation constant) for at least one of the dissociable hydrogen atoms equal to or greater than 2.0 in aqueous solution are employed as extremely efficient catalysts for trimerization of organic isocyanates, particularly aromatic isocyanates, to isocyanurates and for urethane formation.
    Type: Grant
    Filed: April 23, 1975
    Date of Patent: September 14, 1976
    Assignee: The General Tire & Rubber Company
    Inventors: Hubert J. Fabris, Edwin M. Maxey, Heinz Uelzmann
  • Patent number: 3979349
    Abstract: Polymer dispersions in which an aqueous phase comprising a water-soluble polymer is dispersed in an organic liquid in the presence of a polymeric water-in-oil type dispersing agent containing salt-forming basic nitrogen atoms. When the dispersion is mixed with water in the presence of an acid, which acid may be present in the aqueous or organic phase of the dispersion or added separately, the dispersing agent transforms into an oil-in-water type, the previously dispersed polymer dissolves in the water, and the previously continuous organic phase is dispersed in the water.Methods of making such polymer dispersions.Methods of forming aqueous solutions of water-soluble polymers by combining such dispersions with water in the presence of an acid.
    Type: Grant
    Filed: May 1, 1974
    Date of Patent: September 7, 1976
    Assignee: Rohm GmbH
    Inventors: Herbert Fink, Horst Pennewiss, Hermann Plainer, Hans Trabitzsch, Josef Frieser, Juergen Masanek
  • Patent number: 3979344
    Abstract: Room-temperature-curable silicon-terminated organic sealant compositions having improved cure speeds, and metal and glass primer compositions for use therewith. These sealant compositions comprise a blend of a small amount of N-beta-aminoethyl, gamma - aminopropyl trimethoxy silane with an organosilicon-capped, isocyanate-terminated polyurethane polymer. The composition preferably further comprises a moisture-curing catalyst such as dibutyl tin diacetate.
    Type: Grant
    Filed: November 19, 1974
    Date of Patent: September 7, 1976
    Assignee: Inmont Corporation
    Inventors: Earle Ruskin Bryant, Joseph August Weis
  • Patent number: 3979364
    Abstract: The use of small amounts of an amine-terminated polyether in the B-component of a two-component polyurethane composition results in the immediate thickening of the A and B-components upon mixing to provide an elastomer precursor with improved sag resistance without substantially affecting the workability of the mixed components or the properties of the cured elastomer. These elastomers are useful as sealants, caulks and surface coatings.
    Type: Grant
    Filed: September 23, 1974
    Date of Patent: September 7, 1976
    Assignee: Jefferson Chemical Company, Inc.
    Inventor: Richard Lee Rowton
  • Patent number: 3977828
    Abstract: New aqueous, stable, highly concentrated, finely dispersed, flowable dyestuff preparations having a low content of dispersing agents and a high content of dyestuff insoluble to difficultly soluble in water are described, which dyestuffs have a particle size smaller than 10 .mu., particularly smaller than 2 .mu., the said preparations being characterised in that they contain at least 10 percent by weight of water, at least 30 percent by weight of a finely dispersed dyestuff, especially a disperse or vat dyestuff, and a mixture consisting of at most 10 percent by weight of an anionactive dispersing agent, at most 5 percent by weight of a nonionic dispersing agent and at most 35 percent by weight of a hydrotropic agent as well as, optionally, further additives.
    Type: Grant
    Filed: September 17, 1974
    Date of Patent: August 31, 1976
    Assignee: Ciba-Geigy AG
    Inventors: Carl Becker, Jacques Wegmann, Andres Schaub
  • Patent number: 3978017
    Abstract: Stable polyethylene emulsions are produced having a solids content of at least about 30% by weight in a polymerization process without the necessity of a concentration step by contacting ethylene with an aqueous reaction medium containing from about 0.5 to about 1.5 weight percent of a water soluble persulfate initiator and from about 5.5 to about 10.0 weight percent of an alkyl benzene sulfonate emulsifier and allowing the reaction to proceed until at least about 30 weight percent solids level is obtained. The resulting polymeric emulsions are stable and surprisingly have superior properties to polyethylene emulsions which are conventionally produced at lower solids levels and then concentrated to the higher solids level.
    Type: Grant
    Filed: February 7, 1975
    Date of Patent: August 31, 1976
    Assignee: Cosden Technology, Inc.
    Inventors: Glenn E. Teer, Jerry G. Higgins, George D. Warren
  • Patent number: 3976425
    Abstract: A process for printing acrylic fiber substantially free of acid dye sites with a printing paste containing a monosulfonic acid dye having an inorganicity/organicity ratio of less than about 4 and thereafter steaming the printed fiber to fix the dye is disclosed.
    Type: Grant
    Filed: December 13, 1973
    Date of Patent: August 24, 1976
    Assignee: American Cyanamid Company
    Inventors: Eichiro Ueno, Hideo Kawasaki, Syozo Shigita
  • Patent number: 3975349
    Abstract: A process for preparing a diallyl phthalate latex which comprises using in proportions of a total of 30 - 100 weight parts of monomer and a total of 0.3 - 10.0 weight parts of an anionic surfactant to a total of 100 weight parts of water, andI. carrying out the emulsion polymerization of the following emulsion polymerization system, i.e., an emulsion polymerization system comprisingA. water in an amount of 50 - 70 weight % of the total amount thereof,B. monomer in an amount of 10 - 20 weight % of the total amount thereof, said monomer being selected from the group consisting of a diallyl phthalate monomer and a diallyl phthalate-containing monomeric mixtureC. said surfactant in an amount of 10 - 20 weight % of total amount thereof, andD. a radical catalyst in toto; and, thenIi.
    Type: Grant
    Filed: January 13, 1975
    Date of Patent: August 17, 1976
    Assignee: Osaka Soda Co., Ltd.
    Inventors: Akio Suzui, Hiroshi Yoshimoto, Takeshi Kuri
  • Patent number: 3972677
    Abstract: Process for the preparation of discharge effects under or on dyeings or prints with disperse dyes on flat-surface textile structures made of synthetic fibers, which process comprises applying to the textile material a dyeing by padding, slop-padding or printing dischargeable disperse dyes and drying at mild temperatures, printing on the dyeing which has not yet been fixed a discharge paste containing discharge-resistent disperse dyes and fixing that paste after intermediate drying either by a steaming process in saturated steam followed by a treatment with dry heat or a treatment with over-heated steam, or by steaming in pressurized steam.
    Type: Grant
    Filed: March 21, 1974
    Date of Patent: August 3, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erich Feess, Heinz Dethloff
  • Patent number: 3972846
    Abstract: The present invention provides for a curable polyurethane composition comprising a keto compound and a liquid mixture of an organic aliphatic polyfunctional polyisocyanate and a compound having active hydrogen, the keto compound having the general formula: ##EQU1## wherein R.sub.1 and R.sub.2 are each an alkyl group, an aromatic group, and a heterocyclic group, which may be the same or different, and R.sub.2 is a lower alkylene or alkenyl group having 1 to 2 carbon atoms. The curable polyurethane composition is characterized by exhibiting a long pot life due to the existence of the aforementioned keto compound therein.
    Type: Grant
    Filed: October 30, 1974
    Date of Patent: August 3, 1976
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Atsuo Mori, Shuji Kitamura, Kohji Yamatsuta
  • Patent number: 3971761
    Abstract: Plastic compositions containing polyacrylates and bis-phenoxy compounds having the formula: ##SPC1##Wherein Z is bromine or chlorine, m and m' are integers having a value of 1-5, i and i' are integers having a value of 0-2, HBCA is a halo-branched chain alkylene group having from 1 to 6 carbon atoms and A is cyano, nitro, lower alkoxy, lower alkyl, fluorine, dialkylamino, phenyl, halo-phenyl, benzyl or halo-benzyl.
    Type: Grant
    Filed: February 8, 1973
    Date of Patent: July 27, 1976
    Assignee: Michigan Chemical Corporation
    Inventor: Arnold L. Anderson
  • Patent number: 3971746
    Abstract: A synthetic polyisoprene rubber latex produced by emulsifying a solution of polyisoprene rubber in an organic solvent with water and removing the solvent from the resulting oil-in-water emulsion is significantly improved with respect to mechanical stability, wet gel strength and dry film strength by utilizing, as a polyisoprene rubber, a modified polyisoprene rubber prepared by introducing from about 0.03 to 20 carboxyl groups per 100 recurring units of isoprene monomer present in the synthetic cis-1,4-polyisoprene rubber.
    Type: Grant
    Filed: March 28, 1975
    Date of Patent: July 27, 1976
    Assignee: Kuraray Co., Ltd.
    Inventors: Koji Hirai, Takayuki Okamura, Kiyoshi Fujii