Abstract: A self-healing composite material includes a polymer matrix, microcapsules filled with a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives such as ethylidene norbornene, or cyclooctadiene), and polymeric particles comprised of a polymer that is soluble in the monomer with which the microcapsules are filled and having catalytic endgroups derived from an olefin metathesis catalyst, such as a Grubbs'-type catalyst. In some embodiments, the polymer having catalytic endgroups is synthesized via solution polymerization of a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives, or cyclooctadiene) in the presence of an olefin metathesis catalyst (e.g., Grubbs' 1st generation catalyst). The polymer having catalytic endgroups may then be processed via a grinding operation, for example, to prepare the small polymeric particles. In other embodiments, the polymeric particles are synthesized directly as microparticles (e.g., microspheres, granules, beads, etc.

Abstract: A composition comprises a first siloxane compound comprising at least one cyclic siloxane moiety and a first salt, the first salt comprising a conjugate base of a volatile organic acid. A method for producing a cross-linked siloxane network comprises the steps of providing a first siloxane compound comprising at least one cyclic siloxane moiety, providing a first salt comprising a conjugate base of a volatile organic acid, combining the first siloxane compound and the first salt to produce a reaction mixture, heating the reaction mixture to a temperature sufficient for the first salt to open the ring of the cyclic siloxane moiety, and maintaining the reaction mixture at an elevated temperature so that at least a portion of the opened cyclic siloxane moieties react with each other to produce a cross-linked siloxane network.

Abstract: A method of production of conjugated diene rubber including a first step of polymerizing a compound represented by a following formula (1) by using a polymerization initiator to obtain a polymer block of the compound represented by the formula (1) having an active end, and a second step of polymerizing a monomer containing at least a conjugated diene compound by using the active end of the polymer block, wherein, in the formula (1), R1 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, R2 is a hydrocarbon group having 3 to 20 carbon atoms and containing a ring structure, each of R3 and R4 independently is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which is substituted or unsubstituted, and X is arbitrary monovalent group.

Abstract: An anti-microbial coating formulation consisting essentially of triethanolamine and a silane.

Abstract: The present invention relates to a method for the production of a sol-gel based matrix. The method comprises the steps of: a) providing a first alkoxysilane of the general formula: R1—Si(OR2)3 and a second alkoxysilane of the general formula (I): b) preparing a first sol-gel component by polymerization of the first alkoxysilane in the presence of an acid catalyst, c) preparing a second sol-gel component by polymerization of the second alkoxysilane in the presence of an Lewis acid catalyst, d) Mixing the first sol-gel component and the second sol-gel component for the preparation of a sol-gel based matrix. The above method results in a sol-gel based matrix with high stability and high porosity. The sol-gel based material may be used for the production of a composite or sensor suitable for monitoring analytes. Methods for preparing these composites or sensors are provided as well.

Abstract: A polymer with alternating phenylene silicon and siloxane structure and a method of producing a precursor of the same are introduced to develop an autonomous synthesis process for para-phenylene disilanol monomer compounds and design a technique of purifying the polymer with alternating phenylene silicon and siloxane structure easily, so as to enable mass production of the polymer with alternating phenylene silicon and siloxane structure.

Abstract: The present disclosure relates, in exemplary embodiments, to compositions of matter comprising synthetic blends of at least two feedstocks that produce a distribution of fluorinated polyhedral oligomeric silsesquioxane molecule structures. The present disclosure also relates, in exemplary embodiments, to methods of making such synthetic blends.

Abstract: The present disclosure relates to an FPOSS prepolymer which may be reacted with a reactive coating or a polyisocyanate and/or one or more of a polysiloxane, a polyol, a polyamine and a reactive coating; an FPOSS polyisocyanate prepolymer which may be reacted with one or more of a polysiloxane, a polyol, a polyamine or a reactive coating; and an FPOSS siloxane prepolymer which may be reacted with a polyisocyanate and/or one or more of a polyol, a polyamine or a reactive coating to form cross-linked polymers capable of reducing the ability of ice to adhere to the surface of an object, in particular aircraft or other vehicles, methods of producing the prepolymers and polymers and their use in coating surfaces.

Abstract: A silicone composition that contains an organopolysiloxane having at least two aliphatic unsaturated hydrocarbon groups per molecule, a filler containing an aluminum powder and a zinc oxide powder, an organohydrogenpolysiloxane having two or more SiH groups per molecule, and a platinum group metal catalyst, in which when a storage and loss elastic modulus G? of the silicone composition is measured by means a viscoelasticity measurement apparatus capable of measuring shear modulus, the silicone composition can provide a cured product wherein G? after 3,000 seconds from the start of holding is 10,000 Pa or less, G? after 7,200 seconds from the start of holding is 100,000 Pa or less, and G? exceeds G? after 800 seconds or more from the start of holding. As a result, there is provided a silicone composition excellent in crushability, spreadability, and heat conductivity.

Abstract: An anti-microbial coating formulation consisting essentially of triethanolamine and a silane.

Abstract: An anti-microbial coating formulation consisting essentially of triethanolamine and a silane.

Abstract: Polysilocarb formulations, cured and pyrolized materials, was well as articles and use for this material. In particular pyrolized polysilocarb ceramic materials and articles contain these materials where, the ceramic has from about 30 weight % to about 60 weight % silicon, from about 5 weight % to about 40 weight % oxygen, and from about 3 weight % to about 35 weight % carbon, and wherein 20 weight % to 80 weight % of the carbon is silicon-bound-carbon and 80 weight % to about 20 weight % of the carbon is free carbon.

Abstract: The present invention provides a polyorganosiloxane compound having a low viscosity, a process for the manufacture of such polyorganosiloxane compounds, polyorganosiloxane compositions comprising said polyorganosiloxane compound and another polyorganosiloxane compound which is different from the polyorganosiloxane compound, aqueous emulsions comprising the polyorganosiloxane compound, and a method of surface treatment using the polyorganosiloxane compound.

Abstract: An active energy ray-curable resin composition includes 100 parts by weight of (A) a polymer whose main chain is a (meth)acrylic copolymer and which has, at an end of the main chain and/or at a side chain, at least one group having a silicon atom bonded to a hydrolyzable group represented by a formula (I): —SiR2a(OR1)3-a (I), where R1 represents a hydrogen atom or a C1-C10 alkyl group, R2 represents a hydrogen atom or a monovalent hydrocarbon group selected from a C1-C10 alkyl group, a C6-C25 aryl group, and a C7-C12 aralkyl group, and a represents an integer of 0 to 2. The composition further includes 0.1 to 20 parts by weight of (B1) a secondary and/or tertiary amino group-containing silane compound, and 0.05 to 20 parts by weight of (C) a photoacid generator.

Abstract: Disclosed is a coating composition suitable for coating onto a wall or other substrate to yield a dry-erase coating. The composition may be prepared by reacting an excess amount of an aminosilane with a carbonate in aqueous media to yield a silylurethane, introducing an epoxysilane, and allowing the epoxysilane to react with the aminosilane to yield an aminodisilane. This reaction will result in a coating composition that comprises the silylurethane and the aminodisilane. The aqueous mixture of the silylurethane and the aminodisilane together constitute a coating composition that, upon curing, forms a dry-erase coating.

Abstract: A composition for forming a silica layer includes a silicon-containing polymer and a mixed solvent including at least two solvents, wherein the mixed solvent has a surface tension of about 5 mN/m to about 35 mN/m at a temperature of about 25° C.

Abstract: Silane-crosslinkable polymeric compositions comprising a polyolefin having hydrolyzable silane groups, an acidic silanol condensation catalyst, and a phenolic antioxidant having at least one ester-containing moiety. Such crosslinkable polymeric compositions can be employed in various articles of manufacture, such as in the wire and cable industry.

Abstract: A moisture-curing two-component composition consisting of a component A containing at least one polyoxyalkylene, polyolefin and/or polyacrylate prepolymer having at least one hydrolysable silane group and at least one solid inert additive selected from hydrocarbons, polyesters or polyamides, a component B containing at least one crosslinking compound for the prepolymers, and auxiliary substances and additives in one or both components, the component A and the two-component composition each having hot-melt adhesive properties.

Abstract: A composition, suitable for use in producing hydrogel polymer films from which biomedical devices such as contact lenses can be made, comprising at least one hydrophilic silicone macromer.

Abstract: This invention relates in one aspect to propylene polymers comprising propylene, said polymers having a melt flow rate (MFR, ASTM 1238, 230° C., 2.16 kg) of 10 dg/min to 25 dg/min; a Dimensionless Stress Ratio/Loss Tangent Index R2 at 190° C. from 1.5 to 28; an average meso run length determined by 13C NMR of at least 70 or higher; and an MFR MFR Ratio of at least 1.0 and optionally, a Loss Tangent, tan ?, at an angular frequency of 0.1 rad/s at 190° C. from 14 to 100. The inventive propylene polymer compositions are useful in in molded articles and non-woven fibers and fabrics.