Abstract: A method for manufacturing a zinc ferrite film includes forming a zinc ferrite film on a base material by having a reaction liquid, which contains metal ions including only bivalent iron ions and bivalent zinc ions, contact an oxidation liquid, which contains an oxidant that oxidizes the metal ions, in the presence of a pH adjuster. The pH adjuster includes a carbonate of ammonium and an alkali metal salt of mono-carboxylic acid.
Type:
Grant
Filed:
June 14, 2017
Date of Patent:
May 21, 2019
Assignees:
Shinko Electric Industries Co., LTD., Tokyo Institute of Technology
Abstract: One purpose of the present invention is to provide a water-absorbent resin having excellent water absorption characteristics and being capable of improving the shape-retaining characteristics of a water-absorbent material when used in the water-absorbent material. A water-absorbent resin obtained by performing reversed phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a hydrocarbon dispersion medium, using a radical polymerization initiator, said resin being capable of having both excellent absorption performance and shape retention in a water-absorbent material using the water-absorbent resin, as a result of fulfilling the conditions of: (1) having a water-retention capacity of physiological saline of at least 38 g/g; (2) having a water-absorption capacity of physiological saline under a load of 4.14 kPa of at least 15 ml/g; and (3) having a tan ? of a 50-fold swollen gel of at least 2.10×10?2.
Abstract: A method of preparing an antimicrobial coating comprises coating a surface with an aqueous mixture of 3-(trihydroxysilyl)propyl dimethyloctadecyl ammonium chloride, 3-chloropropyltrimethoxysilane, and triethanolamine and then coating the surface with an aqueous titanyl sol-gel solution comprising an aqueous mixture of peroxotitanium acid and peroxo-modified anatase sol overtop of the silane to form the antimicrobial coating. The antimicrobial coating exhibits residual antimicrobial efficacy against E. coli and S. epidermidis after water rinsing or after abrasion. The use of 3-chloropropyltrimethoxysilane was found to improve storage stability of the quaternary silane composition and the durability of the antimicrobial coating.
Type:
Grant
Filed:
May 2, 2018
Date of Patent:
April 16, 2019
Assignee:
ALLIED BIOSCIENCE, INC.
Inventors:
Craig Grossman, Gavri Grossman, Daniel Moros, Jie Fang
Abstract: A superhydrophobic ceramic coating that is transparent and durable includes a dispersion of a multiplicity of silica nanoparticles stacked to form a topography that is rough that is infused with and conformally coated with a sol-gel glass matrix that has a fluoroalkyl silane or an alkyl silane monolayer on the surface of the coating. The silica nanoparticles do not scatter light to a large extent as they are sufficiently small and free of aggregation. The sol-gel glass is formed from a trialkoxysilane precursor and applied to the stacked silica nanoparticles to retain the rough topography of the deposited nanoparticles.
Type:
Grant
Filed:
August 1, 2016
Date of Patent:
April 9, 2019
Assignee:
University of Florida Research Foundation, Inc.
Abstract: A self-healing composite material includes a polymer matrix, microcapsules filled with a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives such as ethylidene norbornene, or cyclooctadiene), and polymeric particles comprised of a polymer that is soluble in the monomer with which the microcapsules are filled and having catalytic endgroups derived from an olefin metathesis catalyst, such as a Grubbs'-type catalyst. In some embodiments, the polymer having catalytic endgroups is synthesized via solution polymerization of a ring-opening metathesis-active monomer (e.g., norbornene, norbornene derivatives, or cyclooctadiene) in the presence of an olefin metathesis catalyst (e.g., Grubbs' 1st generation catalyst). The polymer having catalytic endgroups may then be processed via a grinding operation, for example, to prepare the small polymeric particles. In other embodiments, the polymeric particles are synthesized directly as microparticles (e.g., microspheres, granules, beads, etc.
Type:
Grant
Filed:
February 13, 2017
Date of Patent:
April 9, 2019
Assignee:
International Business Machines Corporation
Abstract: A composition comprises a first siloxane compound comprising at least one cyclic siloxane moiety and a first salt, the first salt comprising a conjugate base of a volatile organic acid. A method for producing a cross-linked siloxane network comprises the steps of providing a first siloxane compound comprising at least one cyclic siloxane moiety, providing a first salt comprising a conjugate base of a volatile organic acid, combining the first siloxane compound and the first salt to produce a reaction mixture, heating the reaction mixture to a temperature sufficient for the first salt to open the ring of the cyclic siloxane moiety, and maintaining the reaction mixture at an elevated temperature so that at least a portion of the opened cyclic siloxane moieties react with each other to produce a cross-linked siloxane network.
Type:
Grant
Filed:
May 16, 2017
Date of Patent:
April 2, 2019
Assignee:
Milliken & Company
Inventors:
Sudhanshu Srivastava, Sasha Stankovich, Michael E. Wilson, Robbie W. J. Hanssen, Eduardo Torres, Cliferson Thivierge, Russell A. Stapleton, Eric B. Monroe
Abstract: A method of production of conjugated diene rubber including a first step of polymerizing a compound represented by a following formula (1) by using a polymerization initiator to obtain a polymer block of the compound represented by the formula (1) having an active end, and a second step of polymerizing a monomer containing at least a conjugated diene compound by using the active end of the polymer block, wherein, in the formula (1), R1 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, R2 is a hydrocarbon group having 3 to 20 carbon atoms and containing a ring structure, each of R3 and R4 independently is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which is substituted or unsubstituted, and X is arbitrary monovalent group.
Abstract: The present invention relates to a method for the production of a sol-gel based matrix. The method comprises the steps of: a) providing a first alkoxysilane of the general formula: R1—Si(OR2)3 and a second alkoxysilane of the general formula (I): b) preparing a first sol-gel component by polymerization of the first alkoxysilane in the presence of an acid catalyst, c) preparing a second sol-gel component by polymerization of the second alkoxysilane in the presence of an Lewis acid catalyst, d) Mixing the first sol-gel component and the second sol-gel component for the preparation of a sol-gel based matrix. The above method results in a sol-gel based matrix with high stability and high porosity. The sol-gel based material may be used for the production of a composite or sensor suitable for monitoring analytes. Methods for preparing these composites or sensors are provided as well.
Type:
Grant
Filed:
October 24, 2014
Date of Patent:
March 19, 2019
Assignee:
Kobenhavns Universitet
Inventors:
Thomas Just Sorensen, Martin Rosenberg, Bo W. Laursen
Abstract: A polymer with alternating phenylene silicon and siloxane structure and a method of producing a precursor of the same are introduced to develop an autonomous synthesis process for para-phenylene disilanol monomer compounds and design a technique of purifying the polymer with alternating phenylene silicon and siloxane structure easily, so as to enable mass production of the polymer with alternating phenylene silicon and siloxane structure.
Type:
Grant
Filed:
January 17, 2017
Date of Patent:
March 12, 2019
Assignee:
NATIONAL CHUNG SHAN INSTITUTE OF SCIENCE AND TECHNOLOGY
Inventors:
Chao-Fan Liang, Chih-Min Hsieh, Jui-Chang Tseng, Qi-Qian Tan
Abstract: The present disclosure relates, in exemplary embodiments, to compositions of matter comprising synthetic blends of at least two feedstocks that produce a distribution of fluorinated polyhedral oligomeric silsesquioxane molecule structures. The present disclosure also relates, in exemplary embodiments, to methods of making such synthetic blends.
Abstract: The present disclosure relates to an FPOSS prepolymer which may be reacted with a reactive coating or a polyisocyanate and/or one or more of a polysiloxane, a polyol, a polyamine and a reactive coating; an FPOSS polyisocyanate prepolymer which may be reacted with one or more of a polysiloxane, a polyol, a polyamine or a reactive coating; and an FPOSS siloxane prepolymer which may be reacted with a polyisocyanate and/or one or more of a polyol, a polyamine or a reactive coating to form cross-linked polymers capable of reducing the ability of ice to adhere to the surface of an object, in particular aircraft or other vehicles, methods of producing the prepolymers and polymers and their use in coating surfaces.
Type:
Grant
Filed:
May 29, 2015
Date of Patent:
February 12, 2019
Assignee:
THE BOEING COMPANY
Inventors:
Douglas Henry Berry, Jill Elisabeth Seebergh, Stuart Arthur Bateman, Ranya Simons, Sheng Li, Lee Russell, Alex Bilyk
Abstract: A silicone composition that contains an organopolysiloxane having at least two aliphatic unsaturated hydrocarbon groups per molecule, a filler containing an aluminum powder and a zinc oxide powder, an organohydrogenpolysiloxane having two or more SiH groups per molecule, and a platinum group metal catalyst, in which when a storage and loss elastic modulus G? of the silicone composition is measured by means a viscoelasticity measurement apparatus capable of measuring shear modulus, the silicone composition can provide a cured product wherein G? after 3,000 seconds from the start of holding is 10,000 Pa or less, G? after 7,200 seconds from the start of holding is 100,000 Pa or less, and G? exceeds G? after 800 seconds or more from the start of holding. As a result, there is provided a silicone composition excellent in crushability, spreadability, and heat conductivity.
Abstract: Polysilocarb formulations, cured and pyrolized materials, was well as articles and use for this material. In particular pyrolized polysilocarb ceramic materials and articles contain these materials where, the ceramic has from about 30 weight % to about 60 weight % silicon, from about 5 weight % to about 40 weight % oxygen, and from about 3 weight % to about 35 weight % carbon, and wherein 20 weight % to 80 weight % of the carbon is silicon-bound-carbon and 80 weight % to about 20 weight % of the carbon is free carbon.
Type:
Grant
Filed:
February 28, 2015
Date of Patent:
January 1, 2019
Assignee:
Melior Innovations, Inc.
Inventors:
Andrew R. Hopkins, Mark S. Land, Walter J. Sherwood, Tim C. Moeller, Bruce A. Bricco, Douglas M. Dukes, Brian L. Benac, Michael J. Mueller
Abstract: The present invention provides a polyorganosiloxane compound having a low viscosity, a process for the manufacture of such polyorganosiloxane compounds, polyorganosiloxane compositions comprising said polyorganosiloxane compound and another polyorganosiloxane compound which is different from the polyorganosiloxane compound, aqueous emulsions comprising the polyorganosiloxane compound, and a method of surface treatment using the polyorganosiloxane compound.
Type:
Grant
Filed:
July 13, 2016
Date of Patent:
December 25, 2018
Assignee:
Momentive Performance Materials Inc.
Inventors:
Roland Wagner, Karl-Heinz Stachulla, Katharina Streicher, Christian Wenske
Abstract: An active energy ray-curable resin composition includes 100 parts by weight of (A) a polymer whose main chain is a (meth)acrylic copolymer and which has, at an end of the main chain and/or at a side chain, at least one group having a silicon atom bonded to a hydrolyzable group represented by a formula (I): —SiR2a(OR1)3-a (I), where R1 represents a hydrogen atom or a C1-C10 alkyl group, R2 represents a hydrogen atom or a monovalent hydrocarbon group selected from a C1-C10 alkyl group, a C6-C25 aryl group, and a C7-C12 aralkyl group, and a represents an integer of 0 to 2. The composition further includes 0.1 to 20 parts by weight of (B1) a secondary and/or tertiary amino group-containing silane compound, and 0.05 to 20 parts by weight of (C) a photoacid generator.
Abstract: Disclosed is a coating composition suitable for coating onto a wall or other substrate to yield a dry-erase coating. The composition may be prepared by reacting an excess amount of an aminosilane with a carbonate in aqueous media to yield a silylurethane, introducing an epoxysilane, and allowing the epoxysilane to react with the aminosilane to yield an aminodisilane. This reaction will result in a coating composition that comprises the silylurethane and the aminodisilane. The aqueous mixture of the silylurethane and the aminodisilane together constitute a coating composition that, upon curing, forms a dry-erase coating.
Type:
Grant
Filed:
May 25, 2017
Date of Patent:
November 13, 2018
Assignee:
The Sherwin-Williams Company
Inventors:
Brian Makowski, Frank F. Markovitz, II, Jay A. Reimann, Shailesh S. Shah, Tom Wendland