Abstract: Siloxanes are prepared by reacting: a compound A with a compound B or a compound A with a compound C or a compound B with a compound C or a compound C alone, in the presence of a compound D at ?40° C., wherein compound A is a silane or a siloxane having at least one silicon-bonded hydrogen atom, compound B is a silane or a siloxane having at least one silicon-bonded alkoxy moiety, compound C is a silane or a siloxane having at least one silicon-bonded hydrogen atom and at least one silicon-bonded alkoxy moiety, and compound D is a cationic Si(II) compound.

Abstract: Reversibly crosslinkable compositions are provided for forming removable crosslinked films. A reversibly crosslinkable composition may comprise entangled chains of a polysiloxane comprising pendant functional groups having formula —NH—(C?O)—X—COOH, wherein X is an alkyl group, an alkenyl group, or an aryl group; a plurality of inorganic oxide nanoparticles; and a solvent; wherein non-covalent bonds between the pendant functional groups and the inorganic oxide nanoparticles crosslink the entangled chains to form a polymeric matrix in the absence of the solvent, wherein the non-covalent bonds dissociate and the polymeric matrix collapses in the presence of water and heat.

Abstract: This organopolysiloxane composition, when cured at room temperature by moisture in the atmosphere, provides a silicone rubber cured product having good self-adhesiveness to a magnesium alloy. The organopolysiloxane composition contains (A) an organopolysiloxane having a hydroxy group and/or a hydrolysable silyl group at both ends of the molecular chain, (B) an organic silicon compound other than (A) and (C), having at least three hydrolysable groups bonded to a silicon atom per molecule, and/or a partial hydrolysis-condensation product thereof, and (C) a silane coupling agent having a specific molecular structure having a carboxylic acid silyl ester bond. Furthermore, a novel compound, having an alkoxysilyl group and a carboxylic acid silyl ester group per molecule, can have improved adhesiveness/bonding properties with respect to a base material due to the effect of carboxylic acid after hydrolysis thereof.

Abstract: Provided is a silicone polymer of the Formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj.

Abstract: Provided is an organopolysiloxane composition, comprising: (A) an organopolysiloxane having at least two silicon atom-bonded alkenyl groups in each molecule, (B) an organohydrogenpolysiloxane having at least two silicon atom-bonded hydrogen atoms in each molecule, (C) a platinum catalyst, and (D) a specific isocyanide compound.

Abstract: Tiles are adhesively bonded to substrates such as kitchen or bathroom walls by a process in which a tile adhesive is used, the tile adhesive being a one component RTV-1 moisture-curable tile adhesives having properties superior to conventional cementitious and RTU tile adhesives, which contain at least one low viscosity alkoxysilyl-functional polymer, a silicone resin, an aminoalkyl-functional alkoxysilane or partial hydrolysate thereof, and in excess of 60 weight percent mineral filler, of which at least 50 weight percent is a non-reinforcing filler.

Abstract: A silane-modified polyphenylene ether resin and a preparation method thereof are provided. A polyphenylene ether resin having hydroxyl groups at both ends is reacted with a silane having at least one alkoxy group and at least one vinyl group at the end, so as to obtain the silane-modified polyphenylene ether resin with a vinyl group at the end.

Abstract: Silicone resins are reproducibly prepared in a four step process in which alcohol recovered in a second step is recycled to the first step, and an aqueous phase recovered in the fourth step contains very little HCl, alcohol, or organopolysiloxane, and can be directed to waste treatment without any prior processing.

Abstract: An aqueous composition contains N-benzyl-substituted N-(2-aminoethyl)-3-aminopropylsiloxane hydrochlorides, wherein the composition after storage for 6 weeks at 60° C. has a color number of ?1 Gardner, a content of methanol of ?0.5% by weight, an active substance content of ?60% by weight, and a content of water of ?40% to ?60% by weight, and wherein the components in the composition sum to 100% by weight.

Abstract: Branched SiOC-linked polyethersiloxanes have the following formula (I) where R1 is an alkyl radical having 1 to 4 carbon atoms or a phenyl radical, but preferably 90% of the radicals R1 are methyl radicals; b has a value of from 1 to 10; a has a value of from 1 to 200, preferably 10 to 100, a value of from 3 to 70 when b is ?1 and ?4, or a value of from 3 to 30 when b is >4; and R2 denotes identical or different polyether radicals, but at least one radical R2 is a structural element radical of formula (II): where p=at least 2, preferably p=2-6, particularly preferably p=3.

Abstract: A method for producing a polyorganosiloxane resin composition including: (a) mixing a thermally-conductive filler having a particle size distribution having a single peak, with a surface treatment agent containing a siloxane to form a mixture, and (b) mixing the mixture from step (a) with a polysiloxane resin.

Abstract: A production method comprising: (a) a step of melt-mixing a base resin containing a chlorinated polyethylene; an organic peroxide, an inorganic filler, and a silane coupling agent, in specific ratios, at a temperature equal to or higher than a decomposition temperature of the organic peroxide, to prepare a silane master batch; (b) a step of mixing the silane master batch obtained in the step (a) with a silanol condensation catalyst, and then forming the resultant mixture; and conducting at least one of the melt-mixing in the step (a) and the mixing in the step (b) is performed in the coexistence of a chloroprene rubber or a polyvinyl chloride; a heat-resistant chlorine-containing crosslinked resin formed body produced by the method, a silane master batch, a mixture and formed body thereof, and a heat-resistant product.

Abstract: A method for the production of a sol-gel based matrix resulting in a sol-gel based matrix with high stability and high porosity. The sol-gel based material may be used for the production of a composite or sensor suitable for monitoring analytes.

Abstract: An essentially solvent free emulsion is described comprising about 10 parts to about 80 parts of a silicone gum; about 1 part to about 20 parts of an amino-functionalized organopolysiloxane; about 1 part to about 20 parts of a nonionic surfactant; about 0.01 to about 5 parts acid; optionally, a silicone polyether; and optionally, an aqueous solution to equal 100 parts.

Abstract: Provided is a thermally conductive composite silicone rubber sheet formed by laminating an acrylic pressure-sensitive adhesive layer on one side of a non-pressure-sensitive adhesive/high-hardness thermally conductive silicone rubber sheet, wherein the acrylic pressure-sensitive adhesive layer is a cured product of an acrylic pressure-sensitive adhesive composition containing: an acrylic pressure-sensitive adhesive made of a polymer of a monomer mixture in which 5-50 mol % of hydroxyl group-containing monomers are contained in all of the constituent monomers; and 0.05-5 parts by mass of a chelate-based curing agent with respect to 100 parts by mass of the acrylic pressure-sensitive adhesive, and the thermally conductive silicone rubber sheet has a thermally conductive silicone rubber layer which, as a cured product of a thermally conductive silicone composition containing a thermally conductive filler, has a durometer A hardness of 60-96.

Abstract: A curable organopolysiloxane composition is provided. The curable organopolysiloxane composition comprises: (A) a diorganopolysiloxane having at least two silicon-bonded alkenyl groups per molecule; (B) an organopolysiloxane resin; (C) a mixture of (C1) a diorganopolysiloxane endblocked with silicon-atom bonded hydrogen atoms at both molecular terminals and (C2) an organohydrogenpolysiloxane having at least three silicon-bonded hydrogen atoms per molecule; (D) a polyether having at least one aliphatic unsaturated group per molecule; and (E) a hydrosilylation catalyst.

Abstract: Branched organopolysiloxanes and organopolysiloxanes with low alkoxy content are produced in a first reaction unit by continuous feed of organohalosilanes and alcohol to a reaction vessel surmounted by a distillation column, the vessel containing an excess of water relative to the halogen content of the organohalosilanes. A second reaction unit for removing volatiles from the product from the first reaction unit is also preferably employed.

Abstract: The present invention provides a water-soluble silicone macromer. The water-soluble silicone macromer has a general formula: E?(M1)x?(M2)y, wherein M1 is a repeating unit which is derived from a silicone containing monomer, M2 is a repeating unit which is derived from a first hydrophilic monomer, and E is an ethylenically unsaturated group. The amount of M1 is in a range of 30-60 wt % based on the total weight of the water-soluble silicone macromer, and the amount of M2 is in a range of 40-70 wt % based on the total weight of the water-soluble silicone macromer. A silicone hydrogel composition containing the water-soluble silicone macromer and a silicone hydrogel lens made of the silicone hydrogel composition are also provided herein.

Abstract: The present disclosure provides a hybrid coating composition including a siloxane-based polymer and an organic polymer. The composition can be applied to a wide variety of substrates include metals, ceramic materials, plastics, composites, minerals and the like. A process for making articles is also provided.

Abstract: The present invention relates to an elastomeric composition comprising a silicone rubber, glycerol, at least one crosslinking agent, and optionally one or more excipients, wherein said glycerol is present as discrete droplets in the silicone rubber, obtainable through the application of high shear forces.