Patents Examined by Margery S. Phipps
  • Patent number: 5679181
    Abstract: According to the present invention, there is provided a method of forming a corrosion-resistant nickel plated steel sheet or strip comprising a base sheet made of a cold rolled steel sheet or strip. A nickel layer is electroplated on at least one side thereof. A part or all of the nickel plated layer forms Fe-Ni diffusion layer. Moreover, the exposure rate of iron on the surface of the nickel plated layer is 4-30%.
    Type: Grant
    Filed: January 25, 1996
    Date of Patent: October 21, 1997
    Assignee: Toyo Kohan Co., Ltd.
    Inventors: Hitoshi Ohmura, Yasuhiro Koyakumaru, Satoshi Iketaka
  • Patent number: 5674330
    Abstract: A process for the fabrication of zirconium alloy sheet specifically intended for the manufacture of structural elements for boiling water reactors, which includes the following steps:a) producing in a vacuum an ingot having the composition of the desired alloy;b) forging and hot rolling the ingot;c) quenching of the blank thus obtained after reheating in the beta range;d) hot rolling after heating;e) heat treatment in the alpha range;f) at least one cycle of cold rolling followed by a heat treating in the alpha range; andg) final cold rolling followed by subcritical annealing in the alpha range;where the hot rolling of the sheet after quenching from the beta range is carried out in an initial direction, then in a direction perpendicular to the initial direction.
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: October 7, 1997
    Assignee: Compagnie Europeene du Zirconium Cezus
    Inventors: Daniel Charquet, Pierre Barberis, Gerard Bunel
  • Patent number: 5673556
    Abstract: Metal hydrides for absorbing hydrogen which are capable of undergoing repeated charge/discharge cycles of absorbing and desorbing hydrogen at high temperatures and cycles through a high temperature followed by a low temperature. These alloys are intended for use in devices such as heat pumps, heat exchangers, energy storage devices, thermal actuators, temperature sensors and electrochemical cells. The alloys generally comprise the chemical formulaA.sub.1-x B.sub.xwhereA is selected from the group of elements consisting of Ti, Hf, Y,B is selected from the group of elements consisting of Nb, Ni, Co, and Fe,and x is in a range from 0.05 to approximately 0.80, and specific alloys comprise hafnium-nickel (HfNi), hafnium cobalt (HfCo), hafnium-iron (Hf.sub.2 Fe), yttrium-nickel (YNi) and titanium-niobium Ti.sub.1-x Nb.sub.x, where x is in a range of from 0.05<.times.<0.60.
    Type: Grant
    Filed: January 6, 1995
    Date of Patent: October 7, 1997
    Assignee: Ergenics, Inc.
    Inventors: P. Mark Goldben, Gary D. Sandrock
  • Patent number: 5662745
    Abstract: Bars of titanium alloys suited for the manufacture of at least the stems (2), (3) of engine valves are mass-producible while maintaining good configurational and dimensional accuracies throughout the valve fabricating process and the wear-resistance imparting processes to at least the stems (2), (3), by surface oxidizing and nitriding. The alloys are of the .alpha.+.beta. type whose microstructure consists of any of an acicular .alpha.-phase consisting of acicular .alpha. crystals having a width of not smaller than 1 .mu.m, an acicular .alpha.-phase consisting of acicular .alpha. crystals having a width of not smaller than 1 .mu.m and dispersed with equiaxed .alpha. crystals, and an equiaxed .alpha.-phase consisting of .alpha. crystals whose diameter is not smaller than 6 .mu.m. Their microstructure may also include one in which the diameter of the pre-.beta. crystals in the acicular .alpha.-phase is not larger than 300 .mu.m and the width of the acicular .alpha. crystals is not smaller than 1 .mu.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: September 2, 1997
    Assignee: Nippon Steel Corporation
    Inventors: Isamu Takayama, Satoshi Yamamoto, Masanori Kizaki
  • Patent number: 5649282
    Abstract: An element for thermally protecting a substrate is deposited on the substrate and comprises a quasicrystalline aluminium alloy having a thermal diffusivity lower than 2.5.times.10.sup.-6 m.sup.2 /s at room temperature and a thermal diffusivity, within the temperature range 650.degree.-750.degree. C., which does not exceed its thermal diffusivity at room temperature by a factor greater than 3. The element may be used to provide heat barriers or bonding layers for substrates. The heat protection element, used in the form of a heat barrier or in the form of a bond coat for heat barriers, exhibits good thermal insulation properties, good mechanical properties, a low specific mass, good resistance to corrosion, and great ease of processing. Further, the invention is useful in limiting heat transfer towards or from parts and components of fittings in many household and industrial devices, for example, heating or cooking devices, smoothing irons, automobile components, and in aeronautic components.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: July 15, 1997
    Assignee: Centre National de la Recherche Scientifique
    Inventors: Jean-Marie Dubois, Pierre Archambault, Bernard Colleret
  • Patent number: 5637274
    Abstract: The present invention provides a Pd alloy thin wire for wire bonding semiconductor elements comprising Ca, Al, Cr and Si each in an amount of up to 0.0003% by weight, from 0.001 to 0.01% by weight of In, optionally one or both of Au and Ag each having a purity of at least 99.99% in respective amounts of 0.001 to 2.0% by weight and 0.001 to 5.0% by weight, and the balance Pd having a purity of at least 99.99% by weight and unavoidable impurities. The Pd alloy thin wire exhibits an excellent loop shape compared with that of an Au alloy thin wire, ensures bonding reliability, and can replace an Au bonding wire.
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: June 10, 1997
    Assignee: Nippon Steel Corporation
    Inventor: Osamu Kitamura
  • Patent number: 5637159
    Abstract: This invention relates to nickel-cobalt based alloys comprising the following elements in percent by weight: from about 0.002 to about 0.07 percent carbon, from about 0 to about 0.04 percent boron, from about 0 to about 2.5 percent columbium, from about 12 to about 19 percent chromium, from about 0 to about 6 percent molybdenum, from about 20 to about 35 percent cobalt, from about 0 to about 5 percent aluminum, from about 0 to about 5 percent titanium, from about 0 to about 6 percent tantalum, from about 0 to about 6 percent tungsten, from about 0 to about 2.5 percent vanadium, from about 0 to about 0.06 percent zirconium, and the balance nickel plus incidental impurities, the alloys having a phasial stability number N.sub.v3B less than about 2.60. Furthermore, the alloys have at least one element selected from the group consisting of aluminum, titanium, columbium, tantalum and vanadium. Also, the alloys have at least one element selected from the group consisting of tantalum and tungsten.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: June 10, 1997
    Assignee: SPS Technologies, Inc.
    Inventor: Gary L. Erickson
  • Patent number: 5635131
    Abstract: A ring setting is made from a nickel-free palladium white gold alloy that contains 7-12% by weight palladium; 50-65% by weight gold; 25-32% by weight silver; and 1-5% by weight zinc. Such ring settings are resistant to chemical or stress corrosion cracking.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: June 3, 1997
    Assignee: Hoover & Strong, Inc.
    Inventors: Frederick W. Klotz, Torrance D. Hoover
  • Patent number: 5634989
    Abstract: A corrosion-resistant amorphous alloy containing Ta in an amount of from 10 to 40 atomic % and Mo, Cr, W, P, B and/or Si is disclosed.This alloy can be prepared by rapidly cooling and solidifying molten alloy, shows a satisfactory corrosion resistance in high-temperature concentrated phosphoric acid, and is adapted to be used as a plant structural material or a separator for a fuel cell.
    Type: Grant
    Filed: July 15, 1992
    Date of Patent: June 3, 1997
    Assignees: Mitsubishi Materials Corporation, Koji Hashimoto
    Inventors: Koji Hashimoto, Akira Mitsuhashi, Katsuhiko Asami, Asahi Kawashima, Yoshio Takizawa
  • Patent number: 5628835
    Abstract: Object of the present invention is to obtain a Nb.sub.3 Al group superconductor having a high critical current density under a whole range of magnetic field from low to high such as 20 T level, manufacturing methods thereof, a Nb.sub.3 Al group superconducting precursory composition, and a magnet for high magnetic field. In a process for manufacturing Nb.sub.3 Al phase by a diffusion reaction of Nb.sub.2 Al phase and Nb phase, a part of the Nb.sub.2 Al phase is remained and dispersed in the Nb.sub.3 Al phase homogeneously as for magnetic flux pinning centers for a high magnetic field. As for a method for dispersing the Nb.sub.2 Al phase homogeneously, a Nb.sub.3 Al group superconducting precursory composition obtained by dispersing Nb particles and Nb.sub.2 Al ultrafine particles by a mechanical alloying method is used, and further, by a conventional method for generating Nb.sub.3 Al phase by a diffusion reaction of Nb and an aluminum alloy, the object of the present invention can be achieved.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: May 13, 1997
    Assignee: Hitachi, Ltd.
    Inventors: Naofumi Tada, Fumio Iida, Ryukichi Takahashi, Takaaki Suzuki
  • Patent number: 5620536
    Abstract: A method of manufacturing nuclear fuel elements which include fuel rods whose cladding tubes are provided with an internal liner layer to obtain PCT resistance in the nuclear fuel element involves carefully choosing parameters for heat treatment of the inner component even from the machining of an ingot of the inner component. The internal layer of zirconium or a zirconium alloy, suitable as inner layer in a PCI-resistant cladding, from the fabrication of an ingot of the inner component up to the completion of a cladding tube, including forging, rolling, extrusion, heat treatment and final heat treatment, is manufactured in such a way that the temperature in the inner component never exceeds the temperature when an incipient phase transformation to beta phase takes place.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: April 15, 1997
    Assignee: ABB Atom AB
    Inventor: Mats Dahlb ack
  • Patent number: 5620532
    Abstract: In a method for manufacturing Nb.sub.3 Al phase by a diffusion reaction of Nb.sub.2 Al phase and Nb phase, a part of the Nb.sub.2 Al phase is remained and dispersed in the Nb.sub.3 Al phase homogeneously as for magnetic flux pinning centers for a high magnetic field. As for a method for dispersing the Nb.sub.2 Al phase homogeneously, a Nb.sub.3 Al group superconducting precursory composition obtained by dispersing Nb particles and Nb.sub.2 Al ultrafine particles by a mechanical alloying method is used, and further, by a conventional method for generating Nb.sub.3 Al phase by a diffusion reaction of Nb and an aluminum alloy, A Nb.sub.3 Al group superconductor can be achieved.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 15, 1997
    Assignee: Hitachi, Ltd.
    Inventors: Naofumi Tada, Fumio Iida, Ryukichi Takahashi, Takaaki Suzuki
  • Patent number: 5616191
    Abstract: The aluminum conductor having increase of its electric resistivity kept small at ultra low temperature of 30.degree. K. or lower even after cyclic strain is given at ultra low temperature, by controlling the crystal structure of the high purity aluminum conductor with purity of 99.9-99.9999 wt % so as to consist of (i) a veritable single or a substantially single crystal consisting of a bundle of sub-grains which have their crystal axes in the same direction or in the directions within a couple of degrees of deviation as a whole which has a specific crystal axis of <111> or <100> or the crystal axes close thereto in the longitudinal direction of the aluminum conductor, or (ii) a polycrystal most of which grains have respective specific crystal axes of <111> and/or <100>, or the crystal axes close thereto with respect to each grain in the longitudinal direction of the aluminum conductor, and have specific grain size of 0.01 mm to 3.0 mm.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 1, 1997
    Assignees: Sumitomo Chemical Co., Ltd., The Texas A & M University Systems
    Inventors: Akihiko Takahashi, Hitoshi Yasuda, Karl T. Hartwig, Lacy C. McDonald, Hong Zou
  • Patent number: 5607522
    Abstract: An electrical contact material having metal oxide particles dispersed in a silver metal matrix and having an easily brazeable backing layer is made free of internal oxide depletion zones by bonding a conventional internally oxidizable silver alloy to a thin backing layer of a second silver alloy to form a composite metal. The first silver alloy is selected to be internally oxidizable under selected oxidizing conditions. The second alloy is selected so that under the selected oxidizing conditions an oxygen-impenetrable barrier is quickly established on the surfaces of the composite formed by the second alloy. In that way, the first alloy layer is forced to be internally oxidized unidirectionally from the opposite surface of the composite to form the desired metal oxide dispersal extending substantially throughout the first alloy layer free of any internal oxide depletion zone in the first layer.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: March 4, 1997
    Assignee: Texas Instruments Incorporated
    Inventor: Donald G. McDonnell
  • Patent number: 5605584
    Abstract: Columnar grain and single crystal nickel base superalloys are heat treated to provide a damage tolerant microstructure. The microstructure contains large, irregularly shaped "barrier" .gamma.' particles interspersed in an ordered array of smaller cuboidal .gamma.' particles in a .gamma. phase matrix. The barrier particles interrupt the progression of cracks through the microstructure. The invention process includes solutioning the .gamma.' phase, cooling slowly to a temperature about 50.degree. F. to 150.degree. F. (28.degree. C. to 83.degree. C.) below the .gamma.' solvus temperature, further cooling at a rate of at least about 100.degree. F. (56.degree. C.) per minute to less than 1000.degree. F. (538.degree. C.), reheating to 1975.degree. F. to 2000.degree. F. (1079.degree. C. to 1093.degree. C.) and holding for about four to six hours, cooling at 100.degree. F. (56.degree. C.) per minute to less than 1000.degree. F. (538.degree. C.), and heating to 1600.degree. F. .+-.25.degree. F. (871.degree. C. .+-.14.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: February 25, 1997
    Assignee: United Technologies Corporation
    Inventors: Daniel P. DeLuca, Howard B. Jones, Bradford A. Cowles
  • Patent number: 5603891
    Abstract: The invention relates to a heat resistant hot formable austenitic nickel alloy consisting of (in % by weight)______________________________________ carbon 0.05 to 0.15 silicon 2.5 to 3.0 manganese 0.2 to 0.5 phosphorus max 0.015 sulphur max 0.005 chromium 25 to 30 iron 20 to 27 aluminium 0.05 to 0.15 calcium 0.001 to 0.005 rare earths 0.05 to 0.15 nitrogen 0.05 to 0.20 ______________________________________residue nickel and the usual impurities due to melting.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 18, 1997
    Assignee: Krupp VDM GmbH
    Inventor: Ulrich Brill
  • Patent number: 5595616
    Abstract: Methods of enhancing oxidation resistance and methods of making molybdenum alloys are provided. In these methods, alloys are prepared by the addition of silicon and boron in amounts defined by the area of a ternary system phase diagram bounded by the points Mo-1.0%Si-0.5%B, Mo-1.0%Si-4.0%B, Mo-4.5%Si-0.5%B, and Mo-4.5%Si-4.0 B. The methods utilize rapid solidification followed by consolidation at below the melting point. The resultant alloys have mechanical properties similar to other high temperature molybdenum alloys while possessing a greatly enhanced resistance to oxidation at high temperature.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 21, 1997
    Assignee: United Technologies Corporation
    Inventor: Douglas M. Berczik
  • Patent number: 5593519
    Abstract: A method of supersolvus forging is described for Ni-base superalloys, particularly those which comprise a mixture of .gamma. and .gamma.' phases, and most particularly those which contain at least about 40 percent by volume of .gamma.'. The method permits the manufacture of large grain size forged articles having a grain size in the range of 50-150 .mu.m. The method comprises the selection of a fine-grained forging preform of a Ni-base superalloy. Supersolvus forging in the range of 0.degree.-100.degree. F. above the alloy solvus temperature then performed at slow strain rates in the range of 0.01-0.001 s.sup.-1. Subsequent supersolvus annealing followed by controlled cooling may be employed to control the distribution of the .gamma.', and hence influence the alloy mechanical and physical properties. The method may also be used to produce location specific grain sizes and phase distributions within the forged article.
    Type: Grant
    Filed: July 7, 1994
    Date of Patent: January 14, 1997
    Assignee: General Electric Company
    Inventors: Charles P. Blankenship, Jr., Michael F. Henry
  • Patent number: 5584947
    Abstract: A method is provided for obtaining uniform grain growth within .gamma.' precipitation strengthened nickel-base superalloys provided in powder metal or cast and wrought form. The method includes alloying the nickel-base superalloy to contain a minimum calculated amount of carbon which, when finely dispersed within the alloy using suitable processing methods, yields a sufficient amount of carbide phase which restricts the grain boundary motion of the alloy during supersolvus heat treatment. When appropriately processed, the grains are not permitted to grow randomly during supersolvus heat treatment, making possible a microstructure whose grain size is uniform, having a grain size range of about 2 to about 3 ASTM units and being substantially free of random grain growth in excess of about 2 ASTM units coarser than the desired grain size range.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: December 17, 1996
    Assignee: General Electric Company
    Inventors: Edward L. Raymond, Robert D. Kissinger, Allen J. Paxson, Eric S. Huron
  • Patent number: 5584948
    Abstract: A method is provided for reducing the tendency for thermally induced porosity within a .gamma.' precipitation strengthened nickel-base superalloy which has been processed to obtain a uniform and coarse grain microstructure. This method is particularly useful for forming components such as gas turbine compressor and turbine disk assemblies in which optimal mechanical properties, such as low cycle fatigue and creep resistance, are necessary for operating at elevated temperatures within a gas turbine engine. The method generally entails alloying a .gamma.' precipitation strengthened nickel-base superalloy to have a boron content of not more than about 0.02 weight percent, and then forming a billet by melting an ingot of the superalloy in an argon gas atmosphere and atomizing the molten superalloy using argon gas. The above atomizing technique encompasses both powder metallurgy and spray forming processes.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: December 17, 1996
    Assignee: General Electric Company
    Inventor: Eric S. Huron