Abstract: The present invention relates to a method for manufacturing fluoroelastomers having iodinated/brominated chain ends, notably vinylidene fluoride (VDF)-based fluoroelastomers, in emulsion polymerization whereas no addition of fluorosurfactants or hydrogenated surfactants is required, and to a fluoroelastomers which can be obtained from said method.

Abstract: A composition comprising (A) 40 to 80 wt.-% of a first heterophasic composition (HECO1); (B) 7 to 30 wt.-% of a second heterophasic composition (HECO2); (C) 0 to 12 wt.-% of an HDPE; (D) 2 to 12 wt.-% of a plastomer; and (E) 7 to 25 wt.-%, of talc; wherein HECO1 has a Tm of 150 to 159° C., an MFR2 of 20.0 to 120 g/10 min, a CRYSTEX crystalline fraction of 79.0 to 91.0 wt.-%, a CRYSTEX soluble fraction of 9.0 to 21.0 wt.-%, and an ethylene content of 1.5 to 6.5 mol.-%; HECO2 has an MFR2 of 2.0 to 10.0 g/10 min, a CRYSTEX crystalline fraction of 70.0 to 82.0 wt.-%, a CRYSTEX soluble fraction of 18.0 to 30.0 wt.-% and an ethylene content of 9.0 to 20.0 mol.-%; the plastomer being a C2/C8 or a C2/C4 copolymer having a density of 850 to 900 kg/m3.

Abstract: The present invention relates to a curable resin composition capable of forming a cured product having excellent adhesive strength and easy dismantlability by an oxidizing agent, and capable of imparting excellent dismantlability when used as a primer to pretreat an adherend even when various adhesives, sealants, and coating agents are used. The curable resin composition includes the following components (A) and (B) but free of epoxy resin: Component (A): A compound having one or more (meth)acryloyl groups per molecule. Component (B): A hydrazide compound.

Abstract: The present disclosure relates to a thermoplastic resin composition which includes: a graft polymer including a rubber polymer having a gel content of 0 to 10 wt % and including an aromatic vinyl-based monomer unit and a diene-based monomer unit; and a shell including a (meth)acrylate-based monomer unit and an aromatic vinyl-based monomer unit which are grafted to the rubber polymer; and a non-grafted polymer including a (meth)acrylate-based monomer unit and an aromatic vinyl-based monomer unit, wherein the refractive indices of the graft polymer and the non-grafted polymer differ by 0.0100 or less.

Abstract: A resin composition, including: a resin component containing propylene units, and a resistance-imparting agent, wherein the resistance-imparting agent is a monomer having a phenol skeleton with hydrogen or an alkyl group having 1 to 3 carbon atoms, bonded to at least one of ortho positions to the hydroxyl group of the phenol skeleton, and has a melting point of 215° C. or less and a molecular weight of 200 or more and 500 or less, a content of the resistance-imparting agent is 0.4 parts by mass or more and 10 parts by mass or less with respect to 100 parts by mass of the resin component, and a content ratio of metal impurities is 0.02% by volume or less.

Abstract: The present invention relates to a maleimide resin composition containing (A) one or more selected from the group consisting of a maleimide compound having one or more N-substituted maleimide groups and a derivative thereof, and (B) a polymer having a hydrocarbon chain or a polyether chain in a main chain thereof, wherein the component (A) dissolves in an alcohol-based solvent, a ketone-based solvent, an aromatic hydrocarbon-based solvent, an ester-based solvent, or a nitrogen atom-containing solvent in an amount of 30% by mass or more at 25° C. The present invention also relates to a prepreg, a laminate, a resin film, a printed wiring board, and a semiconductor package that are obtained by using the maleimide resin composition.

Abstract: A PTFE aqueous dispersion having low viscosity at high temperature. The PTFE aqueous dispersion contains PTFE and a nonionic surfactant, has a PTFE solid concentration of 50 to 70% by mass, is substantially free from a fluorine-containing surfactant, and has a viscosity at 55° C. of 50 mPa·s or lower. Also disclosed is a method for producing the PTFE aqueous dispersion, a coating film obtained by applying the PTFE aqueous dispersion, an impregnated film obtained by impregnating the PTFE aqueous dispersion, and a coated article containing a coating film obtained by applying the PTFE aqueous dispersion.

Abstract: A multilayer sheet including a transparent film with a total light transmittance of 85% or more in accordance with ISO 13468, a coating layer disposed on a first surface of the transparent film, and an elastic film disposed below a second surface of the transparent film is disclosed. The Martens hardness HM measured on a surface of the coating layer is 180 N/mm2 or more.

Abstract: Provided is a hydrogenated copolymer (X) comprising: a hydrogenated copolymer (A); and a hydrogenated copolymer (B), wherein the hydrogenated copolymer (X) satisfies: (1): the hydrogenated copolymer (A) has a random copolymer structure comprising a conjugated diene monomer unit and a vinyl aromatic monomer unit, and content of the vinyl aromatic monomer unit in (A) is 10 to 80 mass %; (2): the hydrogenated copolymer (B) has a random copolymer structure comprising a conjugated diene monomer unit and a vinyl aromatic monomer unit, and content of the vinyl aromatic monomer unit in (B) is 10 to 80 mass %; (3): a ratio (Mn1/Mn2) of (Mn1) of the hydrogenated copolymer (A) to (Mn2) of the hydrogenated copolymer (B) is less than 0.25, and 1000?Mn1?40000; and (4): a mass ratio (A)/(B) of a content of the hydrogenated copolymer (A) to a content of the hydrogenated copolymer (B) is 5/95 to 50/50.

Abstract: A composition is disclosed comprising a sulfonated styrenic block copolymer (SSBC) having an ion exchange capacity (IEC) of at least 0.5 meq/g; and at least one compound which reacts with the SSBC forming a cross-linked SSBC. The compound is selected from: (i) a cross-linking agent, (ii) a metal cation, and (iii) a non-sulfonated polymer. A film prepared from the composition containing the cross-linked SSBC has a toughness in wet state measured after 1 week of 1.2 to 8 MJ/m3; and a tensile stress in wet state measured after 1 week of 3.2 to 8 MPa, according to ASTM D412. The film can be used as a water purification membrane or an antimicrobial protection layer.

Abstract: A resin composition contains a maleimide compound (A) and a phosphorus-containing compound (B). The maleimide compound (A) includes a first maleimide compound (A1) having an alkyl group, of which a carbon number is equal to or greater than six, and/or an alkylene group, of which a carbon number is equal to or greater than six. The phosphorus-containing compound (B) includes a phosphorus-containing compound (B1) having a structure expressed by the following formula (b1), where s indicates an integer falling within a range from 1 to 10, Z indicates either an arylene group or an ester bond expressed by the following formula (b1.1), R1 to R3 each independently indicate either a hydrogen atom or a monovalent organic group, and * indicates a bond.

Abstract: A block copolymer (A) including a vinyl alcohol-based polymer block (b) and an ionic polymer block (c) containing a monomer unit with an ionic group forming a salt and a vinyl alcohol-based monomer unit. The ionic group is a carboxylic acid group, a sulfonic acid group, or an ammonium group. The vinyl alcohol-based polymer block (b) has a number-average molecular weight (Mnb) from 15,000 to 220,000. The ionic polymer block (c) has a content of the vinyl alcohol-based monomer unit from 5 to 95 mol % based on the total monomer units. The block copolymer (A) has a number-average molecular weight (MnA) from 20,000 to 440,000. A ratio (Mnb/MnA) of the number-average molecular weight (Mnb) to the number-average molecular weight (MnA) is from 0.1 to 0.9.

Abstract: Multiphase polymers comprising crosslinking monomers and polyfunctional amine are disclosed. The multiphase polymer comprises a first phase polymer having a Tg from 60° C. to 240° C., a second phase polymer having a Tg from 40° C. to 240° C., and a soft phase polymer having a Tg from ?25° C. to 30° C. The crosslinking monomers include a triacrylate such as trimethylol propane triacrylate, an unsaturated alkoxysilane, and an unsaturated keto monomer reactive with the polyfunctional amine. In contrast to conventional knowledge, incorporation of trimethylolpropane triacrylate reduces the minimum film forming temperature of multiphase polymers. This unusual reduction in MFFT helps to reduce the VOC requirement to form a good film at low VOC. The other crosslinking monomers including unsaturated alkoxy silane and unsaturated keto monomer which react with the polyfunctional amine improve print resistance, block resistance and lower the tackiness of paint films.

Abstract: A catalytic system based on at least one rare-earth metallocene and as co-catalyst an organomagnesium reagent of formula X—Mg—RA—Mg—X is provided. In the formula, RA is a divalent aliphatic hydrocarbon-based chain, optionally interrupted with an oxygen atom, a sulfur atom or with an arylene group, and X is a halogen atom. The catalytic system allows the synthesis of dienic and/or ethylenic telechelic polymers.

Abstract: A polymeric substrate is disclosed. The polymeric substrate comprises a barrier layer including a polymeric material comprising about 50 wt. % or more of at least one polyolefin polymer and 50 wt. % or less of a hydrocarbon resin. The polymeric material exhibits a DTUL of 30° C. or more and a tensile modulus of 500 MPa or more and/or a flexural secant modulus of 500 MPa or more. The barrier layer has a thickness of greater than 200 ?m to 6,500 ?m. A shaped polymeric article comprising the polymeric substrate is also disclosed.

Abstract: The invention relates to thermoplastic molding compositions (T) comprising 10 to 99% by weight, based on the total weight of the molding composition (T), of at least one type of recycled polymer material (A), containing 20 to 100% by weight, based on recycled material (A), of recycled acrylonitrile-butadiene-styrene copolymer (A1); up to 80% by weight of at least one recycled styrene-acrylonitrile copolymer (A2); up to 10% by weight of recycled polymeric impurities (A3), different from (A1) and (A2); 0.1 to 30% by weight, based on the total weight of the molding composition (T), of at least one graft copolymer (B), different from (A); 0.1 to 18% by weight, based on the molding composition (T), of block copolymer (C); and optionally up to 89.8% by weight of further polymer component (D), different from (A), (B) and (C); optionally up to 30% by weight of filler and/or reinforcing agent (E); and optionally up to 30% by weight of further additive (F).

Abstract: The present disclosure generally relates to catalyst systems, polyethylene compositions, and uses of such compositions in, e.g., films. In an embodiment is provided a film that includes a polyethylene composition, comprising: ethylene and a C3-C40 olefin comonomer, the polyethylene composition having at least 75 wt % ethylene content and from 0 wt % to 25 wt % of a C3-C40 olefin comonomer content based upon the total weight of the composition as determined by GPC-IR5-LS-VIS, the film having: an average of MD and TD 1% secant modulus of 42,000 psi or greater as determined by ASTM D-882, and a Dart Drop Impact of greater than 400 g/mil, as determined by ASTM D1709.

Abstract: A process for preparing a multiblock polymer by statistical copolymerization of a mixture containing ethylene and a 1,3-diene and subsequent polymerization of ethylene in the presence of a rare-earth metallocene and an organomagnesium reagent RB—(Mg—RA)m—Mg—RB or X—Mg—RA—Mg—X is provided. According to the formula, RA is a divalent aliphatic hydrocarbon-based chain optionally interrupted with one or more oxygen or sulfur atoms or arylene groups, RB comprises a benzene nucleus substituted with the Mg atom, one of the carbon atoms of the benzene nucleus ortho to the Mg is substituted with a methyl, an ethyl or an isopropyl or forms a ring with the carbon atom which is its closest neighbour and which is meta to the Mg. The other carbon atom of the benzene nucleus ortho to the Mg is substituted with a methyl, ethyl or isopropyl, X being a halogen atom, m being greater than or equal to 1.

Abstract: A catalytic system based on at least one rare-earth metallocene and an organomagnesium reagent as co-catalyst of formula RB—(Mg—RA)m—Mg—RB is provided. According to the formula, RB comprises a benzene nucleus substituted with the magnesium atom. One of the carbon atoms of the benzene nucleus ortho to the magnesium is substituted with a methyl, an ethyl or an isopropyl or forms a ring with the carbon atom which is its closest neighbour and which is meta to the magnesium. The other carbon atom of the benzene nucleus ortho to the magnesium is substituted with a methyl, an ethyl or an isopropyl. RA is a divalent aliphatic hydrocarbon-based chain, optionally interrupted with one or more oxygen or sulfur atoms or with one or more arylene groups. The m is a number greater than or equal to 1, preferably 1. The catalytic system allows the synthesis of dienic and/or ethylenic telechelic polymers.

Abstract: Provided is a block polymer (X) containing, as structural units, a polyolefin structure derived from a polyolefin (A) below and a polyolefin structure derived from a polyolefin (B) below. The polyolefin (A) contains a C3-C8 ?-olefin as a structural monomer with ?-olefin portions having an isotacticity of 70 to 100%, has a number average molecular weight of 1000 to 200000, and has a carbon-carbon double bond number of 0.01 to 8.0 per 1000 carbon atoms. The polyolefin (B) contains a C3-C8 ?-olefin as a structural monomer with ?-olefin portions having an isotacticity of 1 to 65%, and has a number average molecular weight of 1000 to 200000.