Abstract: The present invention provides a polyrotaxane for obtaining a material combining a higher degree of elongation with a higher breaking strength and/or a polyrotaxane having properties not possessed by conventional polyrotaxanes, such as compatibility with compounds to be used in a material, solubility in solvents, and functionality. The polyrotaxanes of the present invention each comprise: a pseudo-polyrotaxane comprising cyclic molecules and a linear molecule which passes through the cavities of the cyclic molecules to form a clathrate; and blocking groups disposed at both ends of the pseudo-polyrotaxane so that the cyclic molecules are not released. The cyclic molecules each include a hydroxyl-inactivation group and a hydroxyl group bonded by a spacer group. The polyrotaxanes have a hydroxyl value of 10-65 mg-KOH/g.
Abstract: A modified polyolefin resin may be capable of obtaining an intended adhesion strength regardless of a kind of a base resin thereof even when graft modification is carried out by using an ?,?-unsaturated carboxylic acid derivative having a cyclic structure. Such a modified polyolefin resin may be a modified product of a polyolefin resin and satisfying (A) and (B): (A): a modifying component includes an ?,?-unsaturated carboxylic acid derivative having a cyclic structure; and (B): a ring-opening degree expressed by formula (1) is 40 or more: ring-opening degree=modification degree K×ring-opening rate R??(1), wherein, in formula (1), the modification degree K is a grafting weight (% by weight) of the ?,?-unsaturated carboxylic acid derivative, and the ring-opening rate R is a ring-opening rate (%) of the cyclic structure in the ?,?-unsaturated carboxylic acid derivative.
Abstract: Water-soluble films including a polyvinyl alcohol polymer (PVOH) and one or more eutectic solvent pairs (eutectic solvent) in predefined ratios.
Type:
Grant
Filed:
February 3, 2022
Date of Patent:
June 4, 2024
Assignee:
The Procter & Gamble Company
Inventors:
Freddy Arthur Barnabas, Michaela Monika Czupik, Lori Ann Bacca, Daniel Brannum
Abstract: A polyethylene composition for preparing filaments and fibers, made from or containing: A) from 65% to 97% by weight of a copolymer of ethylene having: 1) a density of 0.925 g/cm3 or higher; and 2) a MI2 value of 0.5 g/10 min. or greater; and B) from 3% to 35% by weight of a polyolefin composition made from or containing: BI) from 5% to 35% by weight of a propylene homopolymer; BII) from 20% to 50% by weight of an ethylene homopolymer or a copolymer of ethylene with up to 5% by weight of alpha-olefin comonomers, containing 5% by weight or less of a fraction soluble in xylene at 25° C.; and BIII) from 30% to 60% by weight of a terpolymer of ethylene, propylene, and 1-butene containing from 30% to 85% by weight of a fraction soluble in xylene at 25° C.
Abstract: Provided are tread rubber compositions and pneumatic tires which are excellent in abrasion resistance. Included is a tread rubber composition containing, based on 100% by mass of a rubber component therein, 10% by mass or more of styrene-butadiene rubber and 10% by mass or more of polybutadiene rubber, and having an absolute value of change in hardness before and after heat aging, |?Hs|, satisfying the following relationship (1) and an absolute value of change in Swell before and after heat aging, |?Swell|, satisfying the following relationship (2) |?Hs|?3.0??(1); |?Swell|?20%??(2).
Abstract: A polyolefin composition made from or containing: A) 5-35% by weight of a propylene homopolymer; B) 20-50% by weight of an ethylene homopolymer; and C) 30-60% by weight of a terpolymer of ethylene, propylene and 1-butene derived units.
Type:
Grant
Filed:
January 7, 2020
Date of Patent:
May 14, 2024
Assignee:
Basell Poliolefine Italia S.r.l.
Inventors:
Monica Galvan, Michele Grazzi, Marco Ciarafoni, Claudio Cavalieri
Abstract: The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-?-olefin plastomer having—a density of from 850 kg/m3 to 900 kg/m3; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-?-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt. % with respect to the grafted ethylene-?-olefin plastomer; (c) contacting said grafted ethylene-?-olefin plastomer with 2 to 8 wt. % of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-?-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.
Type:
Grant
Filed:
September 26, 2019
Date of Patent:
May 14, 2024
Assignee:
Borealis AG
Inventors:
Oscar Prieto, Jeroen Oderkerk, Jari-Jussi Ruskeeniemi, Stefan Hellström, Tanja Piel, Daniela Mileva
Abstract: The invention provides a composition comprising a first composition, comprising a first ethylene/alpha-olefin/non-conjugated polyene and a second ethylene ethylene/alpha-olefin/non-conjugated polyene, and wherein the first composition comprises the following property: Mw>1389.6 [g/mole] MV+115,000 g/mole, wherein MV is the Mooney Viscosity (ML 1+4, 125 C), and Mw N is the weight average molecular weight, as determined by conventional GPC.
Type:
Grant
Filed:
June 29, 2017
Date of Patent:
May 14, 2024
Assignee:
Dow Global Technologies LLC
Inventors:
Colin LiPiShan, Juan C. Tuberquia, Guang Ming Li, Timothy E. Clayfield, Lena T. Nguyen, Edward O. Madenjian, Cory M. Thomas West, Alexandra E. Frankel
Abstract: A polyolefin composition made from or containing: T1) 50-90 wt % of a recycled polyolefin mixture and T2) 10-50 wt % of a polyolefin component, containing A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 20-50% by weight of an ethylene homopolymer; and C) 30-60% by weight of a terpolymer of ethylene, propylene, and 1-butene made from or containing 45 to 65 percent by weight of ethylene units and from 15 to 38 percent by weight of 1-butene units.
Abstract: Creping adhesives and processes for making and using same. In some embodiments, the creping adhesive can include a solvent, a modified polyvinyl alcohol, and a crosslinked resin. The crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties and propanediyl moieties, where the primary crosslinking moieties can be derived from a functionally symmetric crosslinker. In other embodiments, the crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties and secondary crosslinking moieties, where the primary crosslinking moieties can be derived from a first functionally symmetric crosslinker and the secondary crosslinking moieties can be derived from a second functionally symmetric crosslinker. In other embodiments, the crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties, where the primary crosslinking moieties can be derived from a functionally symmetric crosslinker.
Type:
Grant
Filed:
November 6, 2020
Date of Patent:
May 14, 2024
Assignee:
ECOLABS USA INC.
Inventors:
Ashish Dhawan, David J. Castro, Gary S. Furman, Christopher Kaley
Abstract: A process for producing a low density polyethylene with modified melt flow index, comprising subjecting to thermal visbreaking a precursor polyethylene (I) comprising 35% by weight or more of LDPE.
Type:
Grant
Filed:
December 19, 2022
Date of Patent:
May 7, 2024
Assignee:
Basell Polyolefine GmbH
Inventors:
Timo Hees, Andreas Maus, Pascal Rebmann, Diana Doetsch, Katharina Elsas, Harilaos Mavridis, Gerhardus Meier
Abstract: The invention provides a flame retardant polyolefin composition comprising a) an ethylene based plastomer with a density in the range of 0.850 to 0.915 g/cm3 and an MFR2 in the range 0.5-30 g/10 min; b) a propylene based plastomer with a density in the range of 0.860 to 0.910 g/cm3 and an MFR2 in the range 0.01-30 g/10 min; and c) a flame retardant.
Abstract: A process for producing a low density polyethylene with modified melt flow index, comprising subjecting to thermal visbreaking a precursor polyethylene (I) comprising 35% by weight or more of LDPE and blending the so obtained intermediate polyethylene product (II) with an additional polyethylene (III).
Type:
Grant
Filed:
December 19, 2022
Date of Patent:
May 7, 2024
Assignee:
Basell Polyolefine GmbH
Inventors:
Andreas Maus, Timo Hees, Pascal Rebmann, Diana Doetsch, Katharina Elsas, Harilaos Mavridis, Gerhardus Meier
Abstract: Disclosed is a process for producing a polymer polyol, comprising: (a) reacting a first mixture comprising an initiator, a polyol, a diluent, a stabilizer, a styrene-based monomer and a nitrile-based monomer; and (b) continuously adding, to the first mixture, a second mixture comprising an initiator, a polyol, a stabilizer, a styrene-based monomer and a nitrile-based monomer to react, wherein the first mixture and second mixture comprise the stabilizer in a weight ratio of 1:1 to 3, respectively, and a polymer polyol produced according to the process.
Abstract: A first composition comprising a first ethylene/?-olefin/diene interpolymer and a second ethylene/?-olefin interpolymer, and wherein the first composition comprises from 0.1 to 1.0 wt % diene, based on the weight of the first composition, and wherein the first composition comprises from 40 to 70 wt % ethylene, based on the weight of the first composition.
Type:
Grant
Filed:
February 14, 2018
Date of Patent:
April 30, 2024
Assignee:
Dow Global Technologies LLC
Inventors:
Xiaosong Wu, Guang Ming Li, Bo Lv, Tao Han, Colin LiPiShan
Abstract: A styrene-isoprene-styrene triblock copolymer, a method for manufacturing the same, a composition, and an adhesive composition using the same are provided. The styrene-isoprene-styrene triblock copolymer includes a first polystyrene block, a polyisoprene block, and a second polystyrene block. Based on 100 wt % of the styrene-isoprene-styrene triblock copolymer, the content of the first polystyrene block and the second polystyrene block is 30-50 wt %, and the content of the polyisoprene block is 70-50 wt %. The weight average molecular weight (Mw) of the styrene-isoprene-styrene triblock copolymer is 40,000-75,000.
Abstract: A modified polyolefin resin having an intended adhesion strength to various substrates even when graft modification may be carried out by using an ?,?-unsaturated carboxylic acid derivative having a cyclic structure. The modified polyolefin resin may be a modified product of a polyolefin resin and satisfies conditions (A) to (C): condition (A)—a modifying component includes an ?,?-unsaturated carboxylic acid derivative having a cyclic structure; condition (B)—a ring-opening degree expressed by formula (1) is 40 or more; and condition (C)—the polyolefin resin includes an ethylene structural unit, ring-opening degree=modification degree K×ring-opening rate R??(1) wherein, in the formula (1), the modification degree K is a grafting weight (wt. %) of the ?,?-unsaturated carboxylic acid derivative, and the ring-opening rate R is a ring-opening rate (%) of the cyclic structure in the ?,?-unsaturated carboxylic acid derivative.
Abstract: The present disclosure provides method of making a nanoparticle complex wherein the nanoparticle complex comprises a ligand and a metal cation. The disclosure also provides nanoparticle complexes, methods of treating a disease in a patient utilizing the nanoparticle complexes, methods of identifying a disease in a patient utilizing the nanoparticle complexes, and kits involving the nanoparticle complexes.
Abstract: An electrical responsive graphene-PVDF material and the manufacturing method thereof is disclosed in the present invention. The method includes three steps. Firstly, prepare a mother solution of PVDF. Then, add graphene powders into the mother solution of PVDF to prepare a graphene-PVDF slurry. At last, remove the solvent from the graphene-PVDF slurry to directly form an electrical responsive graphene-PVDF material. Due to the ability of transforming the non-electrical energy into the electrical energy, the electrical responsive graphene-PVDF material can be formed for many different applications in the form of individual film or of film with a substrate via various film formation methods.
Type:
Grant
Filed:
May 12, 2021
Date of Patent:
April 9, 2024
Assignee:
NATIONAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGY
Abstract: The invention is related to fast setting, bio-based hot melt adhesive compositions and use thereof. The bio-based hot melt adhesive compositions are based on renewable-based feedstock, making them environmentally friendly, and particularly suitable for sealing cardboard case, carton, and cardboards.
Type:
Grant
Filed:
June 10, 2021
Date of Patent:
April 2, 2024
Assignees:
Henkel AG & CO. KGaA, Ingevity UK LTD., PURAC Biochem B.V.
Inventors:
Patrick Hayes, Michael Harwell, Jennifer Plummer