Patents Examined by Marks S Kaucher
  • Patent number: 11746221
    Abstract: Provided is a thermoplastic elastomer composition obtained by melt-kneading (A) an ethylene/?-olefin/non-conjugated polyene copolymer rubber that is a copolymer of ethylene, an ?-olefin having 3 to 20 carbon atoms and a non-conjugated polyene, (B) a polyolefin resin and (C) a mineral oil-based softening agent in the presence of (D) a crosslinking agent, at least part of the ethylene/?-olefin/non-conjugated polyene copolymer rubber (A) being crosslinked, the thermoplastic elastomer composition having a sea-island structure in which the ethylene/?-olefin/non-conjugated polyene copolymer rubber (A) is dispersed as a dispersed phase (island phase) in a continuous phase (sea phase) of the polyolefin resin (B), and when a cross-section of the composition is observed with an atomic force microscope (AFM), a ratio of (b) a local elastic modulus of the continuous phase to (a) a local elastic modulus of the dispersed phase being from 10 to 30.
    Type: Grant
    Filed: July 15, 2022
    Date of Patent: September 5, 2023
    Assignee: ENEOS Materials Corporation
    Inventors: Masato Kobayashi, Ryoji Usui, Yuki Sato, Osamu Kose
  • Patent number: 11746219
    Abstract: A recycled resin composition with significantly improved stress crack resistance and impact properties with minimal loss of stiffness. The recycled resin composition is a blend of at least one recycled resin (PCR and/or PIR), at least one virgin high density polyethylene and at least one virgin metallocene catalyzed linear low density polyethylene. The recycled resin composition can have a flex modulus @0.05 in/min of 110,000 psi to 180,000 psi, as measured by ASTM D790, Proc. A 1% Secant Modulus; and/or an ESCR, as measured by 100% Igepal Cond B, ASTM D1693, of about 10 hr to about 75 hr.
    Type: Grant
    Filed: May 4, 2022
    Date of Patent: September 5, 2023
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Robert M. Canright, James A. Stern, Kelsey L. Terrill
  • Patent number: 11738322
    Abstract: The present invention relates to a microfluidic flow process for making polymers, polymers made by such processes, and methods of using such polymers. In such process, a novel reagent delivery setup is used in conjunction with microfluidic reaction technology to synthesize anionic polymerization reaction products from superheated monomer orders of magnitude faster than is possible in batch and continuous syntheses. The aforementioned process does not require the cryogenic temperatures which are required for such syntheses in batch or bulk continuous. Thus the aforementioned process is more economically efficient and reduces the environmental impact of linear polymer production.
    Type: Grant
    Filed: March 31, 2021
    Date of Patent: August 29, 2023
    Assignee: United States of America as represented by the Secretary of the Air Force
    Inventors: Kamran B. Ghiassi, Neil D. Redeker
  • Patent number: 11725100
    Abstract: Heterophasic polypropylene copolymer compositions and methods of making the same include a matrix phase of a random polypropylene-based copolymer; and an elastomeric rubber phase dispersed in the matrix phase, wherein the elastomeric rubber phase includes propylene and one or more comonomers and has a viscosity index ratio, relative to a viscosity index of the random polypropylene-based copolymer, that ranges from 0.3 to 1.1; and wherein an average particle size of the dispersed elastomeric rubber phase is less than 300 nm. Methods include dispersing an elastomeric rubber phase that includes propylene and one or more comonomers into a matrix phase of a random polypropylene-based copolymer, wherein the elastomeric rubber phase has a viscosity index ratio, relative to a viscosity index of the random polypropylene-based copolymer that ranges from 0.3 to 1.1.
    Type: Grant
    Filed: May 13, 2020
    Date of Patent: August 15, 2023
    Assignee: Braskem S.A.
    Inventors: Tadeu Mezacasa Forest, Gustavo Gori Lusa
  • Patent number: 11713389
    Abstract: An object of the present invention is to provide a propylene polymer composition capable of forming a heat seal layer that can be heat-sealed at a relatively low temperature and suppressing blocking in a film including the heat seal layer. A propylene polymer composition contains the following propylene polymer (1) and the following propylene-?-olefin copolymer (2), in which a content of the propylene polymer (1) is 2% by mass to 25% by mass with respect to 100% by mass of a total content of the propylene polymer (1) and the propylene-?-olefin copolymer (2), and the propylene polymer composition satisfies the following requirement (3): Propylene polymer (1): a polymer containing 94% by mass or more of a monomer unit derived from propylene. Propylene-?-olefin copolymer (2): a copolymer containing 60% by mass or more and less than 94% by mass of a monomer unit derived from propylene and more than 6% by mass and 40% by mass or less of a monomer unit derived from an ?-olefin having 4 to 12 carbon atoms.
    Type: Grant
    Filed: November 18, 2021
    Date of Patent: August 1, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Yasuhito Niwa
  • Patent number: 11713390
    Abstract: A thermoplastic elastomer composition for overmolding a predominantly polyamide substrate, a method for the preparation of an overmolded article, and an overmolded article having a layer of thermoplastic elastomer is provided. The thermoplastic elastomer composition comprises a thermoplastic vulcanizate, an olefinic block copolymer, and a maleated functionalized polyolefin copolymer. The method for the preparation of the overmolded article comprises heating the thermoplastic elastomer composition followed by applying the heated composition to at least a portion of the predominantly polyamide substrate.
    Type: Grant
    Filed: December 23, 2020
    Date of Patent: August 1, 2023
    Assignee: Star Thermoplastic Alloys & Rubbers, Inc.
    Inventors: Prakash Sanjeevaiah, Krishna Venkataswamy, Pei-Zhen Jian
  • Patent number: 11708484
    Abstract: A polyolefin composition made from or containing: T1) 70-95 wt %, a polyolefin component containing: a1) from 30 wt % to 70 wt % of a propylene based polymer; and a2) from 30 wt % to 70 wt % of an ethylene based polymer; the sum of a1) and a2), being referred to the total weight of a1) and a2), being 100; and T2) 5-30 wt % of a propylene ethylene copolymer containing from 2.0 wt % to 10.0 wt %; of ethylene derived units and having a melt flow rate (230° C./2.16 kg) ranging from 0.5 to 20.0 g/10 min, and having a fraction soluble in xylene at 25° C. lower than 20 wt %. the sum of the amount of T1) and T2), being referred to the total weight of T1) and T2), being 100.
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: July 25, 2023
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Roberto De Palo, Claudio Cavalieri
  • Patent number: 11708443
    Abstract: Provided is a method of preparing a graft copolymer, which includes: preparing a liquid maleimide-based monomer; preparing a reaction solution including a diene-based rubber polymer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer; and adding the liquid maleimide-based monomer and the reaction solution to a reactor and carrying out polymerization. According to the preparation method of the present invention, the amount of the maleimide-based monomer involved in the polymerization can be increased, and the color characteristics, glass transition temperature, and softening temperature of the graft copolymer are improved.
    Type: Grant
    Filed: November 8, 2019
    Date of Patent: July 25, 2023
    Assignee: LG CHEM, LTD.
    Inventors: Ji Uk Jang, Dae Woo Lee, Jae Bum Seo, Jung Tae Park, Gyu Sun Kim
  • Patent number: 11692095
    Abstract: Provided is a hydrogenated block copolymer, which is a hydrogenation product of a block copolymer including a polymer block (A) containing more than 70 mol % of a structural unit derived from an aromatic vinyl compound and a polymer block (B) containing 30 mol % or more of a structural unit derived from at least one selected from the group consisting of a conjugated diene compound and isobutylene, the hydrogenated block copolymer being satisfied with the following requirements (1) and (2): Requirement (1): the content of the polymer block (A) in the block copolymer is 1 to 30% by mass; and Requirement (2): when the polymer block (B) is regarded as having a structure with a hydrogenation rate of 100 mol %, an average value of a methylene chain length of a main chain of the structural unit derived from at least one selected from the group consisting of a conjugated diene compound and isobutylene is 1.0 to 6.0.
    Type: Grant
    Filed: May 14, 2021
    Date of Patent: July 4, 2023
    Assignee: KURARAY CO., LTD.
    Inventors: Yasushi Senda, Shinya Oshita
  • Patent number: 11680117
    Abstract: The present disclosure provides processes for producing polyethylene resins. In at least one embodiment, a polyethylene has: a density of from about 0.91 g/cm3 to about 0.94 g/cm3; a value of Mz of about 1,500,000 g/mol or greater; and a ratio of Mz to Mw of about 7 or greater. A process includes introducing a first feed stream having ethylene monomer and a first free radical initiator to a first inlet of a first reaction zone, where the first reaction zone has a first inlet temperature. The process further includes introducing a second feed stream having ethylene monomer and a second free radical initiator to a second inlet of a second reaction zone, where the second reaction zone has a second inlet temperature that is the same or different than the first inlet temperature.
    Type: Grant
    Filed: April 6, 2021
    Date of Patent: June 20, 2023
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Haiqing Peng, Henri A. Lammens, Timothy S. McCracken, Arthur G. Voepel
  • Patent number: 11680158
    Abstract: A polymer composition suitable for manufacturing of isotropic three-dimensional printed articles, the composition including: a matrix phase including a propylene-based polymer or copolymer; and a dispersed phase in the matrix phase, the dispersed phase including an ethylene-based copolymer having a C3-C12 comonomer, wherein the dispersed phase has a different composition than the matrix phase, wherein the matrix phase has a crystallization half-time of less than 60 minutes.
    Type: Grant
    Filed: November 13, 2018
    Date of Patent: June 20, 2023
    Assignee: Braskem S.A.
    Inventors: Jason Clark, Leonardo Ito, Alexandre da Luz
  • Patent number: 11680138
    Abstract: A polymer dispersion is disclosed. The polymer dispersion includes a liquid crystal polymer powder, a polyamide acid, and a solvent. A solid content of the polymer dispersion includes the liquid crystal polymer powder and the polyamide acid. The liquid crystal polymer powder has a mass ratio of 20% to 30% in the solid content. The polyamide acid has a mass ratio of 70% to 80% in the solid content. The polyamide acid is obtained by mixing two kinds of diamines and two kinds of dianhydrides together, causing the diamines and the dianhydrides to be polymerized with each other. Both two kinds of diamines and two kinds of dianhydrides comprise a liquid crystal structure and a flexible structure respectively. A method of preparing the polymer dispersion, and a method for preparing a polymer composite film using the polymer dispersion are also disclosed.
    Type: Grant
    Filed: December 8, 2020
    Date of Patent: June 20, 2023
    Assignee: Zhen Ding Technology Co., Ltd.
    Inventors: Kuan-Wei Lee, Szu-Hsiang Su, Shou-Jui Hsiang, Pei-Jung Wu, Wei-Hsin Huang
  • Patent number: 11680126
    Abstract: A thermoplastic elastomer composition includes about 80 parts by weight of an ethylene propylene diene monomer (EPDM) including 5-ethylidene-2-norbornene (ENB) and polyethylene, about 30 parts by weight to about 70 parts by weight of polypropylene, about 20 parts by weight to about 40 parts by weight of a filler, and about 60 parts by weight to about 90 parts by weight of a plasticizer.
    Type: Grant
    Filed: November 22, 2021
    Date of Patent: June 20, 2023
    Assignees: HYUNDAI MOTOR COMPANY, KIA CORPORATION, HAWSEUNG Material Co., Ltd., Research & Business Foundation SUNGKYUNKWAN UNIVERSITY
    Inventors: Sang Hyun Lee, JeeHoon Seong, Ho Dong Kim, Jonghwan Suhr, Bumyong Yoon, Seunghyun Cho, Kyoung-Min Hong, Sang Hyun Lee
  • Patent number: 11674023
    Abstract: A bimodal polymer composition comprising a lower molecular weight homopolymer and a higher molecular weight copolymer wherein the bimodal polymer composition has a density of from about 0.930 gram per cubic centimeter (g/cc) to about 0.970 g/cc, a ratio of high load melt index:melt index of from about 10 to about 150 and an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561. A chromium-catalyzed polymer composition comprising (i) a lower molecular weight homopolymer and (ii) a higher molecular weight copolymer, wherein the bimodal polymer composition has an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561.
    Type: Grant
    Filed: October 15, 2020
    Date of Patent: June 13, 2023
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Youlu Yu, Eric D. Schwerdtfeger, Jeffrey S. Fodor, David A. Soules
  • Patent number: 11673988
    Abstract: Disclosed are multi-block polymers and blends thereof having high electrical conductivity and adhesion. Also disclosed herein are methods of making the same.
    Type: Grant
    Filed: January 7, 2021
    Date of Patent: June 13, 2023
    Assignee: The Florida State University Research Foundation, Inc.
    Inventor: Hoyong Chung
  • Patent number: 11667744
    Abstract: A block copolymer having the general formula as formula (1): mediator-P2-P1-X, formula (1), and the chemical structural formula is formula (2), in which the mediator in formula (1) and formula (2) is a regulator, which is a conjugated seven-membered ring structure, P1 is a first polymer which may be a conjugated or non-conjugated olefin monomer, R1 is the functional group of P1, n is the number of the monomer of P1, which is a positive integer and the range is 10˜1,500. P2 is a second polymer, m is the number of the monomer of P2, which is a positive integer and the range is 10˜1,500, and X is the end-functional group of the block copolymer.
    Type: Grant
    Filed: March 14, 2022
    Date of Patent: June 6, 2023
    Assignee: NATIONAL TSING HUA UNIVERSITY
    Inventor: Chi-How Peng
  • Patent number: 11655370
    Abstract: Provided is an antistatic agent (Z) containing: a block polymer (A) having a block of a hydrophobic polymer (a) and a block of a hydrophilic polymer (b) as structure units; and a sulfonate (S), the sulfonate (S) being a salt of an alkylbenzenesulfonic acid anion which has a C6-C18 alkyl group, the sulfonate (S) including at least two alkylbenzenesulfonates different in the number of carbon atoms of the alkyl group in the anion, the sulfonate (S) satisfying the following formula: 0.40?W(n)/[W(n?1)+W(n)+W(n+1)]?0.90 wherein n is the number of carbon atoms of the alkyl group in the anion of an alkylbenzenesulfonate accounting for the highest proportion by weight in the sulfonate (S); W(n) is a weight of said alkylbenzenesulfonate; and W(n?1) and W(n+1) are respectively a weight of an alkylbenzenesulfonate containing an anion having an alkyl group with (n?1) carbon atoms and a weight of an alkylbenzenesulfonate containing an anion having an alkyl group with (n+1) carbon atoms.
    Type: Grant
    Filed: January 13, 2022
    Date of Patent: May 23, 2023
    Assignee: SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Yuko Sugimoto, Shinichi Fujita
  • Patent number: 11655378
    Abstract: A composition for forming an electroactive coating includes an acid as a polymerization catalyst, at least one functional component, and at least one compound of formula (1) as a monomer: wherein X is selected from S, O, Se, Te, PR2 and NR2, Y is hydrogen (H) or a precursor of a good leaving group Y? whose conjugate acid (HY) has a pKa of less than 45, Z is hydrogen (H), silyl, or a good leaving group whose conjugate acid (HY) has a pKa of less than 45, b is 0, 1 or 2, each R1 is a substituent, and the at least one compound of formula (1) includes at least one compound of formula (1) with Z?H and Y?H.
    Type: Grant
    Filed: November 3, 2019
    Date of Patent: May 23, 2023
    Assignee: PolyM technology corporation
    Inventors: Chien-Chung Han, Ting-Chia Ku, Jo-Wen Chiang
  • Patent number: 11655326
    Abstract: Provided is a molded body including a polycarbonate-polyorganosiloxane copolymer which contains a polycarbonate block (A-1) formed of a repeating unit having a specific structure and a polyorganosiloxane block (A-2) containing a repeating unit having a specific structure, and in which the content of the polyorganosiloxane block (A-2) is from 20 mass % or more to 70 mass % or less, wherein the molded body has a durometer hardness of from 25 or more to 72 or less measured with a type D durometer in conformity with JIS K 6253-3:2012.
    Type: Grant
    Filed: December 27, 2018
    Date of Patent: May 23, 2023
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventors: Kazushige Ideta, Hirotoshi Ishii, Yasuhiro Ishikawa
  • Patent number: 11649313
    Abstract: A composition containing: modified polyvinyl alcohol; and unsaturated monocarboxylic acid or a salt thereof, wherein the modified polyvinyl alcohol has a viscosity-average degree of polymerization of from 400 to 3500, has a degree of saponification of from 68 mol % to 99.9 mol %, and contains from 0.01 mol % to 1.50 mol % of an acryloyl group or a methacryloyl group in a side chain, the unsaturated monocarboxylic acid or a salt thereof is at least one selected from the group consisting of acrylic acid, methacrylic acid, sodium acrylate, and sodium methacrylate, and in the composition, a mass ratio of the modified polyvinyl alcohol/the unsaturated monocarboxylic acid or a salt thereof is from 82/18 to 99.9/0.1. The composition is thus provided that is excellent in water solubility and storage stability and polymerization stability of a vinyl compound and contains the modified polyvinyl alcohol.
    Type: Grant
    Filed: April 10, 2019
    Date of Patent: May 16, 2023
    Assignee: KURARAY CO., LTD.
    Inventor: Tadahito Fukuhara