Abstract: The invention relates to novel specially substituted urethane acrylates based on tris(p-isocyanatophenyl)thiophosphate having a high refractive index and reduced double bond density, and to a method for the production and use thereof.
Type:
Grant
Filed:
November 2, 2010
Date of Patent:
August 19, 2014
Assignee:
Bayer MaterialScience AG
Inventors:
Thomas Rölle, Friedrich-Karl Bruder, Thomas Fäcke, Marc-Stephan Weiser, Dennis Hönel
Abstract: Provided are an organic-inorganic composite resin composition and an organic-inorganic composite resin material made of a cured product thereof, containing at least an organic compound having a polymerizable functional group, metal oxide fine particles, and a polymerization initiator. The cured product obtained by curing the organic-inorganic composite resin composition through application of an active energy has a refractive index nd of 1.61 or more and 1.65 or less, Abbe's number ?d of 13 or more and 20 or less, and an anomalous dispersion characteristic ?g,F of 0.42 or more and 0.54 or less. Further provided is an optical element comprising a transparent substrate and the organic-inorganic composite resin material formed on the transparent substrate.
Abstract: An optical data storage medium is provided. The optical data storage medium includes a polymer matrix; a reactant capable of undergoing a change upon triplet excitation, thereby causing a refractive index change; and a non-linear sensitizer capable of absorbing actinic radiation to cause upper triplet energy transfer to said reactant. The refractive index change capacity of the medium is at least about 0.005. The non-linear sensitizer comprises a triarylmethane dye.
Type:
Grant
Filed:
December 14, 2010
Date of Patent:
July 15, 2014
Assignee:
General Electric Company
Inventors:
Arunkumar Natarajan, Patrick Joseph McCloskey, Eugene Pauling Boden, Kwok Pong Chan, Matthew Jeremiah Misner, Evgenia Mikhailovna Kim
Abstract: The invention relates to a method for producing holographic media, wherein a photopolymer formulation comprising matrix polymers, writing monomers, a photoinitiator system, and optionally auxiliary materials and additives as components is provided, the photopolymer formulation is applied as a coating on the surface of a carrier film and the photopolymer formulation is dried on the carrier film at a temperature XX<T>YY DEG C, wherein only those compounds having TGA 95 values >100 DEG C. and at least 30 DEG C. above the temperature T are selected as components for the photopolymer formulation. The invention further relates to a holographic medium that can be obtained by means of the method according to the invention.
Type:
Grant
Filed:
November 2, 2010
Date of Patent:
July 8, 2014
Assignee:
Bayer MaterialScience AG
Inventors:
Marc-Stephan Weiser, Thomas Rölle, Dennis Hönel, Friedrich-Karl Bruder, Thomas Fäcke
Abstract: The invention relates to a method for producing holographic films, in which a photopolymer formulation is provided which comprises as constituents matrix polymers, writing monomers, a photoinitiatior system, optionally a non-photopolymerizable component and optionally catalysts, radical stabilizers, solvents, additives and other auxiliaries and/or additives. The photopolymer formulation is applied in a planar manner and in the form of a film on a support film and the photopolymer formulation is dried on the support film at a temperature 60<T<120 DEG C, wherein only compounds are selected as components for the photopolymer formulation, the TGA 95 values of which are >100 DEG C and are above the temperature T by at least 30 DEG C, and a photopolymer formulation having a plateau module of =0.030 MPa is used.
Type:
Grant
Filed:
November 2, 2010
Date of Patent:
July 8, 2014
Assignee:
Bayer MaterialScience AG
Inventors:
Dennis Hönel, Marc-Stephan Weiser, Friedrich-Karl Bruder, Thomas Rölle, Thomas Fäcke
Abstract: An optical information recording medium 1 is constructed by sequentially layering a reflective layer 11, a protective layer 12, a recording layer 13, a protective layer 14, and a light transmissive protective layer 15 on a substrate 10. As the recording layer 13, a recording layer containing ZnS, SiO2, and Sb as principal components, or preferably, a recording layer expressed by a compositional formula [(ZnS)x(SiO2)1-x]y(SbzX1-z)1-y (where 0<x?1.0, 0.3?y?0.7, and 0.8<z?1.0 are met and X denotes at least one element selected from a group of Ga, Te, V, Si, Zn, Ta, and Tb) is adopted.
Abstract: A novel polymerizable high-refractive index compound which is useful as an optical material, and a holographic recording medium using the same, which has high diffraction efficiency, high light transmittance and small rate of shrinkage, are provided. A composition for forming a holographic recording layer containing a reactive compound represented by the following formula 1, a holograph recording material, and a holographic recording medium provided with a recording layer containing the same, are disclosed.
Abstract: A method of manufacturing a plurality of diffractive optical elements includes providing a partially transmissive slide, providing a first piece of PTR glass, and directing first UV radiation through the partially transmissive slide to impinge on the first piece of PTR glass. The method also includes exposing predetermined portions of the first piece of PTR glass to the first UV radiation and thermally treating the exposed first piece of PTR glass. The method further includes providing a second piece of PTR glass and directing second UV radiation through the thermally treated first piece of PTR glass to impinge on the second piece of PTR glass. The method additionally includes exposing predetermined portions of the second piece of PTR glass to the second UV radiation, thermally treating the exposed second piece of PTR glass, and repeating providing and processing of the second piece of PTR glass using additional pieces of PTR glass.
Type:
Grant
Filed:
August 19, 2009
Date of Patent:
May 20, 2014
Assignee:
Lawrence Livermore National Security, LLC
Inventors:
Andy J. Bayramian, Christopher A. Ebbers, Diana C. Chen
Abstract: Articles for recording a holographic image are described. The articles include a holographic recording medium having a plurality of surfaces, having a transparent polymeric binder and a photochemically active dye, the holographic recording medium having a holographic image recorded therein formed by exposed areas of the photochemically active dye and unexposed areas of the photochemically active dye; and a first light-blocking layer or material over a first surface of the holographic recording medium from which surface the holographic image is viewed, the light blocking layer or material absorbing light in the wavelength range to which the photochemically active dye is sensitive and allowing transmission of light in a different wavelength range for viewing the holographic image.
Type:
Grant
Filed:
February 16, 2011
Date of Patent:
May 20, 2014
Assignee:
Sabic Innovative Plastics IP B.V.
Inventors:
Andrew A. Burns, Sumeet Jain, Pradeep Jeevaji Nadkarni, Shantaram Narayan Naik, Arunkumar Natarajan, Kiran ArunKumar Puthamane, Michael T. Takemori, Vinodkumar Vasudevan
Abstract: An optical disc of the present invention includes at least a light reflection layer and a light transmission layer formed on a substrate, wherein recording and reading are performed by a laser beam through the light transmission layer, the light transmission layer is formed from a cured film of a ultraviolet-curable composition containing an epoxy acrylate resin obtained by reacting a half ester compound (A), which is obtained from a lactone-adduct of a hydroxyalkyl (meth)acrylate (a1) and a dibasic acid anhydride (a2), and an epoxy resin (B), and the film thickness of the light transmission layer is from 50 to 150 ?m.
Abstract: The present invention concerns a process for realization of polymeric materials with second order nonlinear electro-optical properties comprising the following steps: mixing of a chromophore with nonlinear optical properties with two or three hydroxy groups; isolation of said pure bi- or tri-isocyanate NLO chromophores obtained according to the above step; dissolution of said bi- or tri-isocyanate NLO chromophores obtained according to the above step in one or more isocyanate group not reactive solvents containing reactive substances; coating of a thin layer of said prepolymer mixture on a substrate and evaporation of said not reactive solvents; cross-linking and poling of said thin layer on substrate, by means of heating and application of an electric field; cooling of said thin cross-linked and poled layer at ambient temperature maintaining the applied poling electric field; switching off the poling electric field.
Type:
Grant
Filed:
December 21, 2011
Date of Patent:
May 13, 2014
Assignee:
Selex Sistemi Integrati S.p.A
Inventors:
Fabio Borbone, Antonio Roviello, Roberto Centore, Antonio Carella, Fabio De Matteis, Mauro Casalboni, Glauco Stracci, Massimiliano Dispenza
Abstract: A method of making a hologram includes recording a first hologram in a holographic recording medium at a first deformation ratio; changing the first deformation ratio to a second deformation ratio that is different from the first deformation ratio; and recording a second hologram in the holographic recording medium at the second deformation ratio to form a recorded holographic medium.
Type:
Grant
Filed:
July 30, 2010
Date of Patent:
May 6, 2014
Assignee:
Sabic Innovative Plastics IP B.V.
Inventors:
Michael Teruki Takemori, Amitabh Bansal, Andrew A. Burns, Mark Cheverton, Sumeet Jain
Abstract: The invention relates to applying novel photo polymers based on special urethane acrylates as writing monomers in printing methods which are suitable for producing holographic media, in particular for the visual display of images.
Type:
Grant
Filed:
February 2, 2010
Date of Patent:
May 6, 2014
Assignee:
Bayer MaterialScience AG
Inventors:
Thomas Rölle, Friedrich-Karl Bruder, Thomas Fäcke, Marc-Stephan Weiser, Dennis Hönel, Roland Künzel
Abstract: The invention relates to a method for producing novel photopolymers on the basis of prepolymer-based polyurethane compositions that are suitable for producing holographic media, in particular for the visual display of images.
Type:
Grant
Filed:
January 30, 2010
Date of Patent:
May 6, 2014
Assignee:
Bayer MaterialScience AG
Inventors:
Dennis Hönel, Marc-Stephan Weiser, Friedrich-Karl Bruder, Thomas Rölle, Thomas Fäcke
Abstract: Optical data storage media for bit-wise recording of a microhologram using an incident radiation at a wavelength of about 405 nm are provided. The optical storage medium includes (a) a non-photopolymer polymer matrix; (b) a non-linear sensitizer comprising a phenylethynyl platinum complex, wherein the non-linear sensitizer is capable of triplet-triplet energy transfer from an upper triplet state (Tn) of the non-linear sensitizer to a lower triplet state (T1) of a reactant, wherein “n” is an integer greater than 1; and (c) a reactant capable of undergoing a chemical change upon the triplet-triplet energy transfer from the non-linear sensitizer, thereby causing a refractive index change in the medium to record the microhologram.
Type:
Grant
Filed:
February 27, 2012
Date of Patent:
April 22, 2014
Assignee:
General Electric Company
Inventors:
Arunkumar Natarajan, Riffard Pierre Jean-Gilles, Kwok Pong Chan, Robert James Perry, Victor Petrovich Ostroverkhov, Evgenia Mikhailovna Kim, Julia Lam Lee, Eugene Pauling Boden, Patrick Joseph McCloskey, Brian Lee Lawrence
Abstract: A lithographic apparatus includes a source configured to generate a radiation beam comprising desired radiation and undesired radiation using a plasma, an illumination system configured to condition the radiation beam and to receive hydrogen gas during operation of the lithographic apparatus, and a support structure constructed to hold a patterning device. The patterning device is capable of imparting the radiation beam with a pattern in its cross-section to form a patterned radiation beam. A substrate table is constructed to hold a substrate, and a projection system is configured to project the patterned radiation beam onto a target portion of the substrate. The lithographic apparatus is configured such that the radiation beam on entering the projection system includes at least 50% of the undesired radiation that is generated by the plasma and includes wavelengths of radiation that interact with the hydrogen gas to generate hydrogen radicals.
Type:
Grant
Filed:
July 13, 2009
Date of Patent:
April 1, 2014
Assignee:
ASML Netherlands B.V.
Inventors:
Antonius Theodorus Wilhelmus Kempen, Vadim Yevgenyevich Banine, Vladimir Vitalevich Ivanov, Erik Roelof Loopstra
Abstract: The present invention relates to a novel holographic photopolymer based on prepolymer-based polyurethane compositions, the preparation of said photopolymer and its use for a very wide range of optical applications.
Type:
Grant
Filed:
February 12, 2010
Date of Patent:
April 1, 2014
Assignee:
Bayer MaterialScience AG
Inventors:
Marc-Stephan Weiser, Thomas Rölle, Friedrich-Karl Bruder, Thomas Fäcke, Dennis Hönel
Abstract: An optical data storage disk includes a central substrate and on each side of the substrate a pair of metal/alloy recording layers separated by a transparent layer.
Type:
Grant
Filed:
May 6, 2008
Date of Patent:
April 1, 2014
Assignee:
Enhanced Data Solutions, LLC
Inventors:
Brian Medower, Ian Redmond, David Davies
Abstract: Exemplary embodiments provide methods for patterning large areas, beyond those accessible with the limited single-area exposure techniques, with nanometer scale features. The methods can include forming a grating pattern to make a first interferometric exposure of a first portion of a photosensitive material disposed over a substrate by interfering two or more laser beams, wherein the two or more laser beams comprise an apodized intensity profile having a continuous intensity variation. The method can further include aligning and overlapping the grating pattern to expose a second portion of the photosensitive material such that the first portion and the second portion form a continuous grating pattern.
Type:
Grant
Filed:
April 24, 2007
Date of Patent:
April 1, 2014
Assignee:
STC.UNM
Inventors:
Alexander Raub, Andrew Frauenglass, Steven R. J. Brueck