Abstract: Apparatus and methods for alternative coatings applicable to metal are disclosed. According to one embodiment, an apparatus comprises a composition having, an ethylene acrylic acid copolymer; a neutralizing base; and water. The ethylene acrylic acid copolymer is about 15 percent to about 45 percent by weight concentration of the water. The apparatus further comprises metal coated with the composition.
Type:
Grant
Filed:
September 15, 2016
Date of Patent:
April 25, 2023
Assignee:
G3 Enterprises, Inc.
Inventors:
John Cunningham, Kenneth Metzger, Timmy Sath Ka
Abstract: The present disclosure provides an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which also has favorable combustion and self-heating properties. Also provided is a method of preparing an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which has favorable combustion and self-heating properties. Further provided is a method of improving the hydrophobicity, the liquid water uptake, the heat of combustion, or the onset of thermal decomposition temperature of an aerogel composition.
Type:
Grant
Filed:
November 19, 2021
Date of Patent:
March 7, 2023
Inventors:
Owen R Evans, Kathryn E deKrafft, Nicholas A Zafiropoulos, Wenting Dong, David J Mihalcik, George L Gould, Irene Melnikova
Abstract: A substantially biobased prepolymer mixture including 31.80 to 67.95 percent biogenic carbon content by weight, wherein the mixture is a combination of: an isocyanate; and a cleaned biobased polyoxyalkylene glycol polyol, wherein the cleaned biobased polyoxyalkylene glycol polyol is completely primary hydroxyl-tipped or primary hydroxyl end-grouped, further wherein said cleaned biobased polyoxyalkylene glycol polyol is polymerized from 100% biobased ethylene oxide, further wherein the cleaned biobased polyoxyalkylene glycol polyol comprises less than 15 ppm sodium and potassium metals, and further wherein the cleaned biobased polyoxyalkylene glycol polyol comprises less than 0.5% water by weight.
Abstract: There is disclosed a polymer-based foam composition comprising a polymer and up to 20 M.-% particles of one or more inorganic particulate materials, based on the total weight of the composition, wherein the one or more inorganic particulate materials comprise less than 20 wt.-% Al, calculated as Al2O3-content. According to one aspect, the one or more inorganic particulate materials comprise phyllosilicates. Also part of the present invention is the use of such polymer-based foam compositions and their method of production.
Type:
Grant
Filed:
April 17, 2015
Date of Patent:
February 28, 2023
Assignee:
IMERTECH SAS
Inventors:
Caroline Abler, Michael Schmidt, Gilles Meli
Abstract: Polyurethane-polyisocyanurate foams are prepared using a polyether polyol made from an alkylene oxide mixture that contains a specified proportion of ethylene oxide. The selection of proper polyol equivalent weight and ethylene oxide content leads to the production of foams having a useful combination of properties.
Type:
Grant
Filed:
June 3, 2019
Date of Patent:
February 21, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Adebola O. Ogunniyi, Aiping Hu, Kaoru Aou, Robert S. York, Melissa M. Rose, Arne Anderson, David K. Mulkey
Abstract: The disclosure relates to methods of making foams comprising aromatic polyester polyether polyol materials derived from the transesterification of polyethylene terephthalate with either glycerin or trimethylolpropane, wherein each of these triols, independently, has a degree of ethoxylation of from 1 to 9. Uses of the foams are further disclosed. The disclosure further relates to selection of blowing agents suitable to generate a selected end use case. Yet further, the disclosure relates to selection of end uses, properties, and environmental profiles of the foams generated according to the methods herein, and selecting formulation variables suitable to obtain the foams.
Abstract: This invention relates to an in-situ formed polyol blend having an overall functionality of 2 to 3 and an overall hydroxyl number of 50 to 150. A process for preparing these polyol blends is also disclosed. These in-situ formed polyol blends are suitable for preparing viscoelastic flexible polyurethane foams. A process for preparing these foams is also disclosed.
Type:
Grant
Filed:
March 12, 2021
Date of Patent:
February 7, 2023
Assignee:
Covestro LLC
Inventors:
Sharlene A. Lewis, Jack R. Reese, Nigel Barksby, Brian L. Neal
Abstract: The invention is related to a method for reducing the emission of acetaldehyde and/or propionaldehyde from a polyurethane or polyurea foam, by using a reaction mixture comprising at least one isocyanate reactive component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamine and a polyester polyamine; an isocyanate component; and cyanoacetamide.
Type:
Grant
Filed:
February 6, 2017
Date of Patent:
January 10, 2023
Assignee:
Huntsman International LLC
Inventors:
Ingrid Welvaet, Geert Lodewijk Dries, Joris Karel Peter Bosman
Abstract: A closed loop recycling process of manufacturing a foam part includes dispersing a filler material recycled from an additive manufacturing (AM) process in at least one foam reactant and pouring or injecting the at least one foam reactant with the filler material into a mold and forming the foam part. The foam part has a foam matrix with between 2.5 wt. % and 30 wt. % of the filler material. The filler material can be a recycled powder from a selective laser sintering process that is not graded (i.e., sized) before being dispersed in the at least one foam reactant. For example, the recycled powder can be a recycled polyamide 12 (rPA12) powder with an average particle diameter of less than 100 micrometers. Also, the least one foam reactant can be a polyol reactant and an isocyanate reactant such that a polyurethane foam matrix with recycled rPA12 filler material is formed.
Type:
Grant
Filed:
September 28, 2018
Date of Patent:
January 3, 2023
Assignee:
Ford Global Technologies, LLC
Inventors:
Alper Kiziltas, Zachary Dowling, Matthew Linden Bedell, Deborah Mielewski
Abstract: A polyHIPE-based substance-releasing system capable of releasably encapsulating a highly concentrated solution and/or a room temperature solid while minimizing or avoiding burst release from the closed-cell microstructure of an elastic polyHIPE.
Type:
Grant
Filed:
August 16, 2017
Date of Patent:
December 20, 2022
Assignee:
Technion Research & Development Foundation Limited
Inventors:
Michael S. Silverstein, Katya Kapilov-Buchman, Reinhard Effenberger, Dorit Canfi
Abstract: A crosslinked biobased hydrophilic foam comprising a reaction product of: a cleaned biobased polyoxyalkylene glycol polyol with an ethylene oxide content of at least 40 mole percent, constituting 31.80 to 67.95 percent biogenic carbon content by weight, constituting less than 15 ppm combined sodium and potassium metals, and comprising less than 0.5% water by weight; an isocyanate, wherein the isocyanate and the cleaned biobased polyoxyalkylene glycol polyol are premixed to create a prepolymer mixture with the cleaned biobased polyoxyalkylene glycol polyol of the prepolymer mixture; and water, wherein the water is admixed with the prepolymer mixture to yield the crosslinked biobased hydrophilic foam.
Abstract: Recovery times and/or airflow of flexible polyurethane foam is increased by including certain tackifiers in the foam formulation. The tackifiers are formed into an emulsion that includes a polyether containing oxyethylene groups, a nonionic surfactant and certain fumed silica, carbon black or talc particles.
Type:
Grant
Filed:
March 8, 2019
Date of Patent:
December 6, 2022
Assignee:
Dow Global Technologies LLC
Inventors:
Kaoru Aou, Qinghao Meng, Daniel L. Dermody, Hari Katepalli, William J. Harris, An Kaga, Kathleen Barnes, Colin Li Pi Shan
Abstract: The present invention provides a polyol composition that can secure the stability over time even when a large amount of water is blended in the polyol composition; a flexible polyurethane foam that uses the polyol composition, is low in density and is excellent in durability; and a method for producing the same. The above objects are solved by a polyol composition for molding a flexible polyurethane foam, comprising a polyol component; a catalyst; a foam stabilizer; a foaming agent; and a compatibilizing agent, wherein the compatibilizing agent is an anionic surfactant which has a hydrophilic portion having an alkali metal salt, and which has a hydrophobic portion having an aromatic ring or alternatively a hydrophobic portion not having an aromatic ring but containing 8 or more carbon atoms in total.
Abstract: A graft macromer, comprising the reaction product of at least one macromer being at least one molecule which comprises in its structure one or more hydroxyl-terminated polyether and/or polyester chains, with at least one grafting compound which comprises in its structure at least one at least monoalkoxylated or at least monohalogenated silyl group and at least one alkyl, cycloalkyl or aryl containing group which is reactive towards the hydroxyl group of the macromer, is used for dispersing e.g. SiO2 in a polyol.
Type:
Grant
Filed:
January 25, 2018
Date of Patent:
October 25, 2022
Assignee:
BASF SE
Inventors:
Frank Thielbeer, Christian Koenig, Amir Doroodian, Heinz-Dieter Lutter, Sebastian Richter, Udo Hadick
Abstract: A (super)hydrophobic isocyanate based organic aerogel/xerogel/cryogel having a water contact angle of at least 90° comprising: a cross-linked porous network structure made of polyurethane and/or polyisocyanurate and/or polyurea, and hydrophobic compounds having before the gelling step at least one isocyanate-reactive group and no isocyanate groups Characterized in that said hydrophobic compounds are covalently bonded within the porous network of the aerogel/xerogel/cryogel and wherein said bondings are created during the gelling step of the formation of the isocyanate based organic aerogel/xerogel/cryogel cross-linked porous network structure.
Type:
Grant
Filed:
October 12, 2016
Date of Patent:
September 6, 2022
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Thomas Julien Joncheray, Jan Vandenbroeck, Gilles Jean Geumez
Abstract: Polyisocyanurate (PIR) and/or polyurethane (PUR) comprising insulation foams having significantly improved long term insulation values are disclosed as well as a processing method to fabricate said improved insulation foams and use of the improved insulation foams for thermal insulation.
Type:
Grant
Filed:
April 30, 2019
Date of Patent:
September 6, 2022
Assignee:
HUNTSMAN INTERNATIONAL LLC
Inventors:
Thomas Julien Joncheray, Jan Vandenbroeck, Linda Carillo, Kristof Dedecker, Gilles Jean Geumez
Abstract: A cleaned biobased polyoxyalkylene glycol polyol, wherein the cleaned biobased polyoxyalkylene glycol polyol is completely primary hydroxyl-tipped or end-grouped, further wherein the cleaned biobased polyoxyalkylene glycol polyol comprises less than 15 ppm sodium and potassium metals, and further wherein the cleaned biobased polyoxyalkylene glycol polyol comprises less than 0.5% water by weight.
Abstract: This invention relates to novel preformed stabilizers in which a portion of the polymer control agent is recovered and comprises from 10 to 1500 ppm of an inhibitor. This invention also relates to a process for preparing these preformed stabilizers, and to polymer polyols comprising these novel preformed stabilizers macromers and to a process for preparing polymer polyols comprising these novel preformed stabilizers. The present invention also relates to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.
Abstract: Formation of low-crystallinity phytosterol nanoparticles via cooling-controlled supercritical carbon dioxide (SC—CO2) impregnation of phytosterols into biodegradable nanoporous starch aerogels and methods of preparing these aerogels are disclosed. The nanoporous starch aerogels increase water dissolution and bioaccessibility of the phytosterols, thereby making them available for preparation of high nutraceutical value foods.