Patents Examined by Michael J. DiVerdi
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Patent number: 6171993Abstract: The present invention provides an ethylene copolymer resin that has unique melt elastic properties not observed in ethylene copolymers heretofore known. Specifically, the ethylene copolymer resin of the present invention when in pelletized form has a reduction in melt elasticity (ER) of 10% or more to a final value of 1.0 or less upon rheometric low shear modification or solution dissolution. Moreover, the resin of the present invention when in reactor-made form exhibits at least a partially reversible increase of 10% or more in ER when pelletizing the same. An ethylene polymerization catalyst, a process of preparing the ethylene copolymer resin and a high-impact film are also provided herein.Type: GrantFiled: December 4, 1998Date of Patent: January 9, 2001Assignee: Equistar Chemicals, LPInventors: Harilaos Mavridis, Mark K. Reinking, Ramesh N. Shroff, Joel A. Mutchler, Charles S. Holland, Keta M. Lindstrom, Kiran M. Gupte, Michael H. Treptau, Francis M. Mirabella
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Patent number: 6156115Abstract: Multilayer interference pigment consisting of a central layer of a transparent or semitransparent material of low refractive index and alternating layers of a metal or of a material of high refractive index and of a material of low refractive index either side of the central layer, the material of low refractive index preferably being magnesium fluoride or acrylate and the metal preferably being aluminium or chromium.Type: GrantFiled: October 26, 1998Date of Patent: December 5, 2000Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Gerhard Pfaff, Gerd Bauer, Martin Friz, Matthias Kuntz, Christina Schank
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Patent number: 6156690Abstract: The present invention provides a solid catalyst component for polymerization of olefins obtained by allowing a solid component and an alcohol to come in contact with each other, wherein the solid component is prepared by allowing a magnesium compound, a titanium compound and an electron donor compound to come in contact with each other, and also provides a catalyst for polymerization of olefins made of the solid catalyst component, an organic aluminum compound represented by the general formula R.sup.1.sub.p AlQ.sub.3-p and an organic silicon compound represented by the general formula R.sup.2.sub.q Si(OR.sup.3).sub.4-q. By using the catalysts in a polymerization of olefins, polyolefins excellent in stereoregularity can be obtained in high yield.Type: GrantFiled: February 25, 1999Date of Patent: December 5, 2000Assignee: Toho Titanium Co., Ltd.Inventor: Motoki Hosaka
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Patent number: 6156117Abstract: A method of preparing a polymer structured pigment slurry which comprises providing an anionic, aqueous slurry including a plurality of solid mineral particles, adding a low molecular weight, cationic polymer in an amount of less than about 0.20% by weight to the slurry and then adding a small amount of an inorganic dispersant to the polymer treated pigment slurry. The Malvern median particle size of the mineral particles treated with the polycationic polymer is less than about 20% larger than the Malvern median particle size of the untreated mineral particles.Type: GrantFiled: September 1, 1998Date of Patent: December 5, 2000Assignee: J. M. Huber CorporationInventors: Gary M. Freeman, Sung-Tsuen Liu
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Patent number: 6150295Abstract: Novel catalyst systems which comprise pyridine-2-carboxaldimine nickel complexes can be used with methylaluminoxane in slurry polymerization processes to polymerize mono-1-olefins and, optionally a higher alpha-olefin comonomer, to produce low molecular weight polymers.Type: GrantFiled: March 30, 1998Date of Patent: November 21, 2000Assignee: Phillips Petroleum CompanyInventor: Nancy W. Eilerts
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Patent number: 6146455Abstract: The invention relates to a novel crystal modification (.delta.-modification) of C.I. Pigment Red 53:2 of the formula (1) ##STR1## having the following characteristic reflections in the X-ray powder diffraction pattern:______________________________________ 2.THETA. d relative intensity (in %) ______________________________________ 3.3 26.6 32 4.7 18.7 100 7.5 11.9 14 9.4 9.3 19 10.5 8.4 13 13.8 6.4 10 14.2 6.2 9 14.9 5.9 10 16.7 5.3 11 17.6 5.0 9 18.1 4.9 16 18.9 4.7 10 20.4 4.3 7 21.1 4.2 9 22.1 4.0 9 22.7 3.9 12 23.1 3.8 9 23.6 3.8 13 24.1 3.7 9 24.9 3.6 10 25.5 3.5 23 26.3 3.4 9 27.7 3.2 9 28.1 3.2 6 28.9 3.1 6 30.4 2.Type: GrantFiled: June 21, 1999Date of Patent: November 14, 2000Assignee: Clariant GmbHInventors: Martin Ulrich Schmidt, Hans Joachim Metz
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Patent number: 6147024Abstract: The present invention provides a catalyst for the polymerization of olefin that exhibits improved selectivity and broader molecular weight distribution in the polymer product. The catalyst is a conventional supported Ziegler-Natta catalyst in combination with a mixture of at least two electron donors, both having the general formula SiR.sub.m (OR').sub.4-m where R is selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a vinyl group; R' is an alkyl group; and m is 0-3, wherein when R is an alkyl group, R may be identical with R'; when m is 0, 1 or 2, the R' groups may be identical or different; and when m is 1, 2 or 3, the R groups may be identical or different. This catalyst produces polypropylene having xylene solubles of 1-7 to 5.1 wt % and a molecular weight distribution of about 10.Type: GrantFiled: July 12, 1999Date of Patent: November 14, 2000Assignee: Fina Technology, IncInventors: Edwar S. Shamshoum, David John Rauscher, Douglas Alan Burmaster
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Patent number: 6139618Abstract: A fine yellow composite iron oxide hydroxide pigment of the present invention has an average major axial diameter of not less than 0.005 .mu.m and less than 0.1 .mu.m, which comprises:fine goethite particles as core particles, containing aluminum inside thereof in an amount of 0.05 to 50% by weight, calculated as Al, based on the weight of said core particles; anda composite oxide hydroxide of Fe and Al, coated on the surface of each core particle. Such fine yellow composite iron oxide hydroxide pigment are excellent in transparency and heat resistance.Type: GrantFiled: August 26, 1999Date of Patent: October 31, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Mineko Ohsugi, Hiroshi Sumita, Hiroko Morii
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Patent number: 6140264Abstract: The present invention provides a novel process for preparing a catalyst, preferably free of electron donor, useful in gas phase polymerization of olefins having a broad polydispersity.Type: GrantFiled: May 12, 1998Date of Patent: October 31, 2000Assignee: Nova Chemicals Ltd.Inventors: Mark Kelly, Dusan Jeremic, Victoria Ker, Charles Russell
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Patent number: 6136748Abstract: A catalyst composition for the polymerization of olefins is provided, which comprises a) a catalyst comprising a metal atom complexed with a non-cycloalkadienyl anionic ligand, wherein the chemical hardness, .eta., and chemical potential, .mu., of said non-cycloalkadienyl anionic ligand calculated using the MOPAC (PM3) computer program satisfy the relationship: .eta.=3.0+0.75.mu..+-.0.2 eV; and b) an activating cocatalyst.Type: GrantFiled: June 12, 1998Date of Patent: October 24, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Jack Allen Smith
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Patent number: 6113682Abstract: Disclosed herein is a method for preparation of composite pigments for make-up cosmetics having improved skin-adhesion and spreadability, and excellent skin color-expression, and improved water resistance by silicon polymer coated on the surface of the complex particle of flaky silica and titanium dioxide coated thereon.Type: GrantFiled: November 6, 1998Date of Patent: September 5, 2000Assignees: Pacific Corporation, Bokwang Chemical Co. Ltd.Inventors: Dal Sik Shin, Dong Myong Kim, Sung Ho Lee, Ok Sob Lee, Kwang Soo Kim, Ju Hong Min
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Patent number: 6106922Abstract: A web of material has a plurality of stems extending from at least one side of the web. The web includes a first layer of material having a first side and a second side and a second layer of material. The second layer of material has a first side which faces the first side of the first layer and a second side from which the plurality of stems extend. The first and second layers of material are joined together while they are both molten, before either layer has cooled. The first and second layers of material can be formed of thermoplastic material or melt processable polymeric material. A method of making a web of material includes selecting a first material for a first layer of material and selecting a second material for a second layer of material. The first and second layers of material are melt formed. Then, the first and second layers of material are joined while the layers are in the molten state to form a multiple layer sheet.Type: GrantFiled: October 3, 1997Date of Patent: August 22, 2000Assignee: 3M Innovative CompanyInventors: John E. Cejka, Mark R. Dupre, Jeffrey O. Emslander, William H. Hartt, Robert D. Kampfer, Francis V. Loncar, Jr., Louis S. Moren, Diane L. Regnier, Jayshree Seth, Robert W. G. Shipman, Alan J. Sipinen, William C. Unruh, Dennis G. Welygan, Leigh E. Wood
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Patent number: 6103658Abstract: Methods for preparing olefin polymers, and catalysts for preparing olefin polymers are disclosed. The polymers can be prepared by contacting the corresponding monomers with a Group 8-10 transition metal catalyst. The polymers are suitable for processing in conventional extrusion processes, and can be formed into high barrier sheets or films, or low molecular weight resins for use in synthetic waxes in wax coatings or as emulsions.Type: GrantFiled: October 22, 1998Date of Patent: August 15, 2000Assignee: Eastman Chemical CompanyInventors: Peter Borden Mackenzie, Leslie Shane Moody, Christopher Moore Killian, James Allen Ponasik, Jr., Jason Patrick McDevitt, Gino Georges Lavoie
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Patent number: 6099634Abstract: A titanyl sulfate solution or a titanium tetrachloride solution is neutralized with an alkali to form orthotitanic acid, to which hydrochloric acid is added such as to adjust the TiO.sub.2 concentration to 80-140 g/L and the HCl concentration to 90-150 g/L and a synthesis reaction is performed at a temperature of 25-60.degree. C. to produce titanium oxide particles in which needles aggregate and/or bind together to yield fan-shaped particles.Type: GrantFiled: February 27, 1998Date of Patent: August 8, 2000Assignee: Titan Kogyo Kabushiki KaishaInventors: Toshiaki Uenishi, Takanori Yamasaki
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Patent number: 6093673Abstract: The invention relates to olefin polymerization using an organosilicon compound from the pyrazolyl family as an external adjuvant.Type: GrantFiled: September 27, 1999Date of Patent: July 25, 2000Assignee: Equistar Chemicals, LPInventors: Douglas D. Klendworth, Gregory G. Hlatky
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Patent number: 6086667Abstract: The invention relates, in particular, to pigments in the form of fine particles having enhanced stability with respect to ultraviolet solar radiation and particle radiation (electrons, protons), characterized in that the pigment are coated with a UV filter.Application in the production of paints for spacecrafts.Type: GrantFiled: February 5, 1999Date of Patent: July 11, 2000Assignee: Centre National d'Etudes SpatialesInventors: Jean-Claude Guillaumon, Pascale Veronique Nabarra
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Patent number: 6086669Abstract: Describes a free flowing particulate composition comprising, in combination, particulate amorphous precipitated silica, e.g., in the form of granules, hydrocarbon process oil, e.g., an aromatic process oil, and organic carboxylic acid having from 2 to 30 carbon atoms, e.g., stearic acid. The hydrocarbon process oil and organic carboxylic acid are sorbed on the silica and are present in amounts sufficient to measurably improve the dispersibility of the particulate amorphous precipitated silica into an elastomer as measured by percent white area. Optionally, an organosilane coupling agent may also be present in said composition. The free flowing particulate composition of the present invention is useful in reinforcing elastomers, e.g., rubbers used in vehicle tires and the soles of athletic foot wear.Type: GrantFiled: April 9, 1998Date of Patent: July 11, 2000Assignee: PPG Industries Ohio, Inc.Inventors: Shailesh D. Patkar, Harold E. Swift, William B. Scott
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Patent number: 6077341Abstract: A silica-metal oxide particulate composite comprising silica agglomerates having voids formed by random stacking of scaly silica primary particles, and metal oxide particulates supported on the surfaces, and the inner surfaces in the voids, of the silica agglomerates.Type: GrantFiled: September 28, 1998Date of Patent: June 20, 2000Assignees: Asahi Glass Company, Ltd., Dohkai Chemical Industry Co., Ltd.Inventors: Kunihiko Terase, Masaharu Tanaka, Masaki Inoue, Eiichi Ono, Takayoshi Sasaki