Abstract: A coating composition includes a blocked urethane elastomer (A) containing a terminal isocyanate group blocked with an oxime compound and having a number average molecular weight of 800 to 5,000, an aromatic diamine compound (B) containing an electron-donating group, and an amide compound (C). An equivalent ratio (amino group/isocyanate group) of the amino group of the aromatic diamine compound (B) to the isocyanate group of the blocked urethane elastomer (A) is within a range of 1.0 to 2.0. A solid content of the amide compound (C) is within a range of 0.5 mass % to 5 mass % based on a total solid content of the blocked urethane elastomer (A) and the aromatic diamine compound (B).
Abstract: The disclosure provides a cross-linkable polymer composition, a core layer for an information carrying card comprising such cross-linked composition, resulting information carrying card, and methods of making the same. A crosslinkable polymer composition comprises a curable base polymer resin in a liquid or paste form, and a particulate thermoplastic filler. The base polymer resin is selected from the group consisting of urethane acrylate, silicone acrylate, epoxy acrylate, urethane, acrylate, silicone and epoxy. The particulate thermoplastic filler may be polyolefin, polyvinyl chloride (PVC), a copolymer of vinyl chloride and at least another monomer, or a polyester such as polyethylene terephthalate (PET), a compound or blend thereof.
Abstract: The invention relates to a continuous method for producing an isocyanurate-containing isocyanate mixture, in which in a step a) a mixture of a first and a second isocyanate component and an isocyanate group trimerization catalyst is provided; in a step b) the mixture obtained in step a) is reacted in a first residence time zone at an elevated temperature; in a step c), the reaction mixture obtained in step b) is further heated in a second residence time zone, optionally after adding a stopper; and in a step d), the reaction mixture obtained in step c) is cooled down in a third residence time zone by way of lowering the temperature, thus obtaining the desired isocyanurate-containing isocyanate mixture.
Type:
Grant
Filed:
December 14, 2018
Date of Patent:
June 14, 2022
Assignee:
Covestro Deutschland AG
Inventors:
Christian Hahn, Hans-Detlef Arntz, Stephan Schubert, Ernst Felske, Claudia Houben, Frank Behrendt
Abstract: Disclosed is a carboxy group-containing aqueous resin composition containing a carboxy group-containing aqueous resin and a polycarbodiimide compound (X) represented by the following general formula (1): wherein R1 represents a residue obtained by removing a functional group capable of reacting with an isocyanate from a hydrophilic compound having the functional group capable of reacting with an isocyanate; R2 represents a divalent residue obtained by removing isocyanate groups from a diisocyanate compound; R3 represents a divalent residue obtained by removing hydroxy groups from a glycol compound; X represents a group to be formed through a reaction between the hydrophilic compound and the diisocyanate compound; n1 represents a number of 1 to 10; n2 represents a number of 1 to 10; m represents a number of 1 to 5; and plural R1's may be the same or different and plural R2's may be the same or different.
Abstract: A photocurable composition is provided. The photocurable composition includes: a urethane acrylamide oligomer derived from a first urethane prepolymer having an isocyanate end group and a polar group-containing acrylamide; a urethane acrylate oligomer derived from a second urethane prepolymer having an isocyanate end group and a polar group-containing (meth)acrylate; and an amide group-containing acrylic polymer derived from acrylamide and a polar group-containing (meth)acrylate.
Type:
Grant
Filed:
November 6, 2018
Date of Patent:
May 24, 2022
Inventors:
Sang Hwan Kim, Sle Lee, Jang Soon Kim, Kwang Su Seo
Abstract: A method for the production of polyoxazolidinone compounds, comprising the step of reacting an isocyanate compound (A) with an epoxide compound (B) in the presence of a catalyst (C), wherein the isocyanate compound (A) comprises a isocyanate compound (A1) wherein the a isocyanate compound (A1) comprising at least two isocyanate groups (I1?2), preferred two isocyanate groups (I1=2), wherein the epoxide compound (B) comprises a epoxide compound (B1) and an epoxide compound (B2), wherein the epoxide compound (B2) is different from the epoxide compound (B1) wherein the epoxide compound (B1) comprising at least two terminal epoxide groups (F1?2), preferred two terminal epoxide groups (F1=2), linked together by a linking group (L1) and the epoxide compound (B2) comprising at least two terminal epoxide groups (F2?2)), preferred two terminal epoxide groups (F2=2), linked together by a linking group (L2), wherein the linking group (L2) comprises acyclic and covalent bonds to each other free of conjugated multiple bond
Type:
Grant
Filed:
August 16, 2017
Date of Patent:
May 10, 2022
Assignee:
Covestro Deutschland AG
Inventors:
Anna Weber, Claudine Rangheard, Michael Kessler, Walter Leitner, Christoph Gürtler, Carsten Koopmans, Thomas Ernst Müller
Abstract: The invention relates to a thermoplastic polyurethane matrix resin composition, comprising at least one C3-8 alkane diol, at least one alkoxylated aromatic diol and at least one polyisocyanate. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermoplastic polyurethane polymer matrix according to the present invention and a fiber material. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
Type:
Grant
Filed:
June 3, 2019
Date of Patent:
April 26, 2022
Assignee:
Henkel AG & Co. KGaA
Inventors:
Andreas Niegemeier, Andreas Ferencz, Tamara Schmidt, Wolfgang Lupp
Abstract: In various embodiments, coated infill includes a plurality of infill granules and a preformed coating on the infill granules including a cured polyurethane product of at least one polyurethane prepolymer component and a curative component. The polyurethane prepolymer component includes a reaction product of an isocyanate component including diphenylmethane diisocyanate (MDI) and a polyol component, and has a free isocyanate content (% NCO) from 2 wt % to 12 wt %. The curative component includes water. Methods for making an artificial turf surface using the coated infill are also provided.
Type:
Grant
Filed:
February 22, 2018
Date of Patent:
April 26, 2022
Assignee:
Dow Global Technologies LLC
Inventors:
Virginie Assemat, Andrea Benvenuti, Amber Marie Stephenson
Abstract: An alternative polyurethane composition is provided which comprises a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer reacted at a temperature of from 20° C. to 120° C., wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of an alkynol of the formula (I), HC?C—R1R2—OH??(I), and wherein R1 is an electron-withdrawing group selected from the group consisting of carbonyl, ester, amide, and urethane and R2 is a linear or branched alkyl chain having from 1 to 15 carbon atoms. The inventive alternative polyurethane composition position may be used to provide adhesives, sealants, films, elastomers, castings, foams, and composites.
Type:
Grant
Filed:
November 25, 2019
Date of Patent:
April 26, 2022
Assignees:
Covestro LLC, The University Of Southern Mississippi
Inventors:
Robson F. Storey, Alan Ekin, R. Hunter Cooke, III, Jie Wu
Abstract: The present invention relates to a polymer composition comprising a polymeric matrix and particles of an impact modifier within the polymeric matrix, wherein the impact modifier comprises at least one urethane group and the impact modifier is obtainable by reacting in situ within the polymeric matrix a) a polyol comprising a dimer fatty residue; and b) a polyisocyanate. The invention also relates to a method of making the polymer composition.
Type:
Grant
Filed:
November 3, 2016
Date of Patent:
April 19, 2022
Assignee:
Croda International PLC
Inventors:
Angela Leonarda Maria Smits, Johannes Rutger Idsard Knoop
Abstract: A self-restoring polyurethane-based polymer obtained by polymerization of a composition containing an aromatic disulfide diol represented by Chemical Formula, HO—Ar1—S—S—Ar2—OH, an alicyclic polyisocyanate, and a polyol. Ar1 and Ar2 each are independently a substituted or unsubstituted C6-C30 arylene group. The composition satisfies Equation, 0.1?M[disulfide]/M[OH]. M[disulfide] is a total mole number of the aromatic disulfide diol in the composition, and M[OH] is a total mole number of the aromatic disulfide diol and the polyol in the composition.
Type:
Grant
Filed:
July 11, 2018
Date of Patent:
April 12, 2022
Assignee:
Korea Research Institute of Chemical Technology
Inventors:
Sung Yeon Hwang, Jeyoung Park, Dong Yeop Oh, Jong Geon Jegal, Seon Mi Kim, Hyeon Yeol Jeon
Abstract: A polyurethane foam material having the following properties: Compression hardness at 10% (according to ISO 3386/1) higher than 60 kPa and lower than 120 kPa; Free rise density in the range 40-80 kg/m3 (according to ISO 845); Flexural modulus (according to ISO 1209-2) in range 0.95-2 MPa.
Abstract: The present invention relates to a method for producing a biopolyether polyol, which is a copolymerization reaction of tetrahydrofuran and 2-methyltetrahydrofuran in a monomer ratio (by mass) of 85/15 to 50/50, and the resulting polyether polyol of 100% plant origin having a number-average molecular weight of 500-5000. In addition, a polyurethane resin, which is the product of a synthetic reaction having as the main reactants the above polyether polyol of 100% plant origin, a polyisocyanate compound, and a chain extender that reacts with isocyanate groups, has a change in storage modulus (E?) in the low temperature range (0° C.) with respect to normal temperature (20° C.) of within 0-15%.
Abstract: A coating material system including components (A) to (C) and also, optionally, further components, with, in a first option, all components (A) to (C) and also, where present, the further optional components being present separately from one another, in other words the individual components not being mixed with one another. In a second option of the coating material system, conversely, the aforementioned components may also be mixed wholly or at least partly with one another. Where the components are at least partly mixed with one another, for example, component (C) is mixed with component (A), while component (B) is present separately from this mixture of (A) and (C). Optionally, component (B) may also be mixed with a portion of component (C). Furthermore, the mixtures of (A) and (C) and of (B) and (C) may additionally include at least one optional component such as a solvent, for example.
Type:
Grant
Filed:
September 21, 2017
Date of Patent:
March 15, 2022
Assignee:
BASF Coatings GmbH
Inventors:
Peter Hoffmann, Benedikt Schnier, Emre Levent
Abstract: The present invention relates to an aqueous, solids-containing dipping bath composition for treating reinforcing inserts for rubber products comprising the following components or consisting of these components, (A) at least one blocked MDI mixture, the MDI mixture comprising MDI oligomers of formula (I), n being a whole number from 1 to 8, and MDI monomers; (B) at least one latex; (C) at least one compound selected from the group consisting of polyacrylates, lignin derivatives and mixtures hereof; and (D) possibly at least one additive; the dipping bath composition being essentially free of epoxides, and the dipping bath composition being essentially free of resorcinol, formaldehyde and the reaction products thereof.
Abstract: A leather finishing composition includes water, a polymeric component, and a non-ionic surfactant component covalently bonded to the polymeric component. Advantageously, the leather finishing composition is substantially free of ionic groups. A method for applying the leather finishing composition to a leather substrate is provided.
Abstract: A method for deblocking a blocked isocyanate is described herein. The method includes contacting a blocked isocyanate and a halide ion source under conditions effective to provide a deblocked isocyanate. A method of making a polyurethane is also disclosed. The method of making a polyurethane includes combining a blocked isocyanate, a polyol, and a halide ion source in the presence of solvent and under conditions effective to provide the polyurethane.
Type:
Grant
Filed:
August 31, 2018
Date of Patent:
February 22, 2022
Assignees:
THE UNIVERSITY OF MASSACHUSETTS, BASF SE
Abstract: Some variations provide a reworkable ionomer composition comprising: a polymer containing a plurality of ionic monomers disposed in a chain backbone of the polymer, wherein the ionic monomers have a monomer charge polarity that is either positive or negative; and a plurality of ionic species disposed within the chain backbone of the polymer, wherein the ionic species have opposite charge polarity compared to the monomer charge polarity, wherein the ionic species and the ionic monomers are ionically bonded, and wherein the ionic species are capable of undergoing a reversible oxidation-state transition of at least +1 or ?1 when in the presence of a redox reagent. The polymer may be selected from the group consisting of polyurethanes, polyacrylates, polyamides, polyesters, polyureas, polyurethane-ureas, polysiloxanes, polycarbonates, and combinations thereof. Many options for ionic monomers and ionic species are disclosed.
Type:
Grant
Filed:
May 22, 2019
Date of Patent:
February 22, 2022
Assignee:
HRL Laboratories, LLC
Inventors:
Ashley M. Dustin, April R. Rodriguez, Shanying Cui, Andrew P. Nowak, Adam F. Gross
Abstract: Some variations provide a method of forming a transparent icephobic coating, comprising: obtaining a hardenable precursor comprising a first component and a plurality of inclusions containing a second component, wherein one of the first component or the second component is a low-surface-energy polymer, and the other is a hygroscopic material; applying mechanical shear and/or sonication to the hardenable precursor; disposing the hardenable precursor onto a substrate; and curing the hardenable precursor to form a transparent icephobic coating. The coating contains a hardened continuous matrix containing regions of the first component separated from regions of the second component on an average length scale of phase inhomogeneity from 10 nanometers to 10 microns, such as less than 1 micron, or less than 100 nanometers. The transparent icephobic coating may be characterized by a light transmittance of at least 50% at wavelengths from 400 nm to 800 nm, through a 100-micron coating.
Type:
Grant
Filed:
October 29, 2018
Date of Patent:
February 15, 2022
Assignee:
HRL Laboratories, LLC
Inventors:
April R. Rodriguez, Andrew P. Nowak, Adam F. Gross