Patents Examined by Michael L Leonard
  • Patent number: 11247388
    Abstract: A method of applying a material comprising a fusible polymer comprises the step of: applying a filament of the at least partly molten material comprising a fusible polymer from a discharge opening of a discharge element to a first substrate. The fusible polymer has the following properties: a melting point (DSC, differential scanning calorimetry; 2nd heating at heating rate 5° C./min) within a range from ?35° C. to ?150° C.; a glass transition temperature (DMA, dynamic-mechanical analysis to DIN EN ISO 6721-1:2011) within a range from ??70° C. to ?110° C.; wherein the filament, during the application process, has an application temperature of ?100° C. above the melting point of the fusible polymer for ?20 minutes. There are still free NCO groups in the material including the fusible polymer.
    Type: Grant
    Filed: July 12, 2019
    Date of Patent: February 15, 2022
    Assignee: Covestro Intellectual Property GmbH & Co. KG
    Inventors: Dirk Achten, Thomas Buesgen, Joerg Tillack, Fabian Schuster, Ralf Rott, Nicolas Degiorgio, Jonas Kuenzel, Joerg Buechner, Wolfgang Arndt, Martin Melchiors, Harald Kraus
  • Patent number: 11242429
    Abstract: A composition for an automotive interior skin, a method for manufacturing the same, and an automotive interior skin manufactured using the same. The composition for an automotive interior skin includes: 30 wt % to 70 wt % of a polyol compound; 5 wt % to 40 wt % of dicyclohexylmethane-4,4?-diisocyanate; and 5 wt % to 30 wt % of an aromatic glycol-based chain extender.
    Type: Grant
    Filed: January 7, 2020
    Date of Patent: February 8, 2022
    Assignees: Hyundai Mobis Co., Ltd., DONGSUNG CORPORATION, HANWHA Q CELLS & ADVANCED MATERIALS CORPORATION
    Inventors: Chang Wan Son, Dae Young Kwon, Jae Chan Lee, Hoon Jeong Kim, Gyu Min Lee
  • Patent number: 11242428
    Abstract: Hydroxyaldimines of formula (I), their reaction products, in particular products of their reaction with polyisocyanates, and compositions including isocyanate groups and containing such reaction products. The hydroxyaldimine permits compositions which have good storage stability, a long open time, low odour, rapid, bubble-free curing and good mechanical properties, and which are not susceptible to plasticizer migration and have a particularly low content of monomeric diisocyanates. In particular, it permits reactive hot-melt adhesives with a particularly good workability.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: February 8, 2022
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Urs Burckhardt, Andreas Kramer, Martin Schmider
  • Patent number: 11230522
    Abstract: The present invention relates to polyaspartic acid ester compositions which contain polyaspartic acid esters with primary amino groups and small amounts of fumaric acid dialkyl esters, to a method for preparing same and the use thereof as a reactive component for polyisocyanates in two-component polyurethane systems.
    Type: Grant
    Filed: September 14, 2018
    Date of Patent: January 25, 2022
    Assignee: COVESTRO DEUTSCHLAND AG
    Inventors: Dorota Greszta-Franz, Jan Weikard, Matthias Wintermantel, Robert Maleika, Thomas Klimmasch, Thomas Schuettler
  • Patent number: 11225545
    Abstract: The present invention relates to specific translucent, preferably lightfast, polyurethane foams which have a high light transmission and are therefore suitable e.g. for producing translucent polyurethane foams or multilayer composite elements, for example for producing structural components, more particularly as roof elements such as strip lights and light domes, as wall elements such as a panel, in vehicles, in lamps, as furniture, as partitions and in sanitary facilities.
    Type: Grant
    Filed: March 28, 2018
    Date of Patent: January 18, 2022
    Assignee: Covestro Deutschland AG
    Inventors: Lutz Böhnke, Dirk Achten, Robert Maleika
  • Patent number: 11225543
    Abstract: In one or more embodiments, the present invention provides a novel approach to the addition of plasticizers for softening TPUs, i.e., lowering the durometer and the melt viscosity. This approach involves incorporating bonded sulfonate groups with quaternary ammonium counterions into the TPU. In one or more embodiments of the present invention, the softening of TPU is achieved by incorporating an ionic diol, such as N,N-bis (2-hydroxyethyl)-2-aminoethane-sulfonic acid (BES), coupled with various bulky alkyl ammonium cations, during the chain extension step of the TPU synthesis. It is believed that that steric hindrance of the bulky quaternary ammonium groups weakens the dipole-dipole interactions of the sulfonate groups and/or lowers the crystallinity of the hard block, thereby creating additional free volume that softens the polymer and lowers the melt viscosity.
    Type: Grant
    Filed: February 26, 2019
    Date of Patent: January 18, 2022
    Assignee: The University of Akron
    Inventors: Matthew Becker, Robert A. Weiss, Zachary Kurtiss Zander, Don S. Wardius, Karl W. Haider, Bruce D. Lawrey
  • Patent number: 11225458
    Abstract: A pinene-derived diisocyanate compound, a process for forming a pinene-derived polyurethane, and an article of manufacture that includes the polyurethane are disclosed. The process for forming the polyurethane includes forming a pinene-derived diisocyanate compound, and reacting the pinene-derived diisocyanate compound with a polyol in a polymerization compound.
    Type: Grant
    Filed: November 5, 2019
    Date of Patent: January 18, 2022
    Assignee: International Business Machines Corporation
    Inventors: Brandon M. Kobilka, Joseph Kuczynski, Jacob T. Porter, Jason T. Wertz
  • Patent number: 11220617
    Abstract: A two-component adhesive composition is disclosed. The adhesive composition comprises an isocyanate component comprising an isocyanate-terminated prepolymer that is the reaction product of a polyisocyanate and an isocyanate reactive component having an average molecular weight less than 1,500. The NCO content of the isocyanate component without solvent is between 9 and 18%. The composition further comprises a polyol component comprising a polyester polyol having a molecular weight greater than 1,500 that is the reaction product of a polyhydric alcohol and a polybasic acid. The composition still further comprises an adhesion promoter. The average functionality of the adhesive composition is from 2 to 2.4. The adhesive composition provides for improved performance and processability at a solid content greater than 45 wt %. A methods of forming the adhesive composition is also disclosed. A laminate formed by this method is also disclosed.
    Type: Grant
    Filed: May 22, 2017
    Date of Patent: January 11, 2022
    Assignee: Dow Global Technologies LLC
    Inventors: Rui Xie, Mikhail Y. Gelfer, Jonathan Barrus
  • Patent number: 11214649
    Abstract: A method for producing a shaped body, containing: producing the shaped body from a composition by a powder-based layer construction process, wherein the composition contains a thermoplastic polyurethane, obtained by reacting a polyisocyanate composition and a polyol composition, the thermoplastic polyurethane is solid at least in a temperature region below 50° C. and has end groups selected from the group consisting of first end groups and second end groups, wherein the first end groups are optionally eliminated at a first temperature, and the second end groups are optionally eliminated at a second temperature, to form reactive groups on the thermoplastic polyurethane that optionally enter into a reaction with functional groups of the thermoplastic polyurethane or functional groups of a further component of the composition, and wherein the first temperature and the second temperature are each greater than or equal to 60° C.
    Type: Grant
    Filed: February 16, 2018
    Date of Patent: January 4, 2022
    Assignee: BASF SE
    Inventors: Rajan Hollmann, Sebastian Richter, Martin Hufnagel, Hendrik Wagner
  • Patent number: 11214539
    Abstract: Biobased diisocyanates are bio-derived derived from biomass natural sources that include rosin acids. The biobased diisocyanates are of the formula 1, 2 or 3: where: R is an alkylene of from about 2 to about 12 carbon atoms, and R? is an alkyl group of from about 1 to about 12 carbon atoms.
    Type: Grant
    Filed: July 30, 2021
    Date of Patent: January 4, 2022
    Assignee: Evoco Limited
    Inventors: Jason James Robinson, Juri Helmut Moebus, Tristan Calayan, Guerino G. Sacripante
  • Patent number: 11203659
    Abstract: A method for producing a polyurethane according to the present invention including: a first step wherein an epoxy carboxylate compound (X) is obtained by reacting (a) an epoxy compound that includes a halogen atom content of 10 ppm by mass or less, while having only two epoxy groups and no hydroxyl group in each molecule, (b) an unsaturated aliphatic monocarboxylic acid that has an ethylenic unsaturated group in each molecule, while having no aromatic ring, and (c) an aromatic monocarboxylic acid that has no ethylenic unsaturated group in each molecule; and a second step wherein the epoxy carboxylate compound (X) obtained in the first step is reacted with a diisocyanate compound (Y).
    Type: Grant
    Filed: May 19, 2017
    Date of Patent: December 21, 2021
    Assignee: SHOWA DENKO K. K.
    Inventors: Jun Dou, Masahiko Toba, Hiroshi Uchida
  • Patent number: 11203678
    Abstract: Thermoplastic polyurethane (TPU) compositions, methods for producing TPU compositions, methods of using TPU compositions, and apparatuses produced therefrom are disclosed. Disclosed TPU compositions include a thermoplastic polyurethane polymer, a heat stabilizer, a flow agent, and a filler material. The filler may be a glass fiber. Disclosed TPU compositions have improved thermal stability and improved flow properties suitable for injection molding of articles of manufacture having a large plurality of fine openings or pores. Articles produced from the composition have superior thermal stability, abrasion resistance, and chemical resistance. Example articles include screening members for vibratory screening machines.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: December 21, 2021
    Assignee: DERRICK CORPORATION
    Inventors: James R. Colgrove, Keith Wojciechowski
  • Patent number: 11192976
    Abstract: The present invention provides: a copolymer (A) which is a copolymer obtained by copolymerizing one or plural cycloolefin monomers and one or plural acyclic olefin monomers, or a copolymer obtained by copolymerizing two or more cycloolefin monomers, wherein the glass transition temperature (Tg) of the copolymer is 100° C. or higher, the refractive index of the copolymer is 1.545 or higher, and the Abbe's number of the copolymer is 50 or larger, and at least one of the cycloolefin monomers is a deltacyclene.
    Type: Grant
    Filed: April 2, 2020
    Date of Patent: December 7, 2021
    Assignee: ZEON CORPORATION
    Inventors: Kensaku Fujii, Takashi Houkawa, Takuya Komatsubara, Yasuhiro Shimizu
  • Patent number: 11186673
    Abstract: The purpose of the present invention is to appropriately control the rate of polymerization of a composition in which a thiol compound and an isocyanate compound are added to an episulfide compound and thereby provide an optical material which has high transparency. This composition for use as optical material comprises (a) an episulfide compound, (b) an isocyanate compound, (c) a thiol compound, and (d) a benzyl halide compound represented by formula (1): wherein: X is a halogen; L is selected from the group consisting of a hydrogen atom, a methyl group, a halogen, a mercaptomethyl group, and an isocyanate methyl group; and n is 1 or 2.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: November 30, 2021
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Kazuki Kariyazono, Takashi Aoki, Kouhei Takemura, Kikuo Furukawa
  • Patent number: 11186746
    Abstract: Provided are a method of preparing a polyurethane prepolymer with high functionality and the polyurethane prepolymer with high functionality prepared therefrom and a curing agent comprising the same. The method includes the steps of: Step (A): providing an alcohol composition comprising a first polyol having 2 or 3 OH groups and a second polyol having 4 or more OH groups; Step (B): reacting the alcohol composition with a polyisocyanate to undergo a first polymerization, so as to obtain an intermediate; wherein a molar ratio of a total number of the OH groups of the alcohol composition to a total number of NCO groups of the polyisocyanate is from 1:2 to 1:6; and Step (C): adding a catalyst to carry out a second polymerization of the intermediate to obtain the polyurethane prepolymer with high functionality, which has four or more NCO groups.
    Type: Grant
    Filed: December 5, 2019
    Date of Patent: November 30, 2021
    Assignee: NOVAMAT APPLIED MATERIAL CO., LTD.
    Inventor: Hua Wang
  • Patent number: 11180604
    Abstract: Polyurethane prepolymers having non-linear short chain diols and/or soft diisocyanates incorporated into the backbone are used to provide cured polyurethane coatings having a high hard segment content and low haze. The polyurethane prepolymers can also be used to improve the dispersion of filler in cured polyurethane compositions having a high filler loading. Cured coatings prepared from the two-part polyurethane systems meet the requirements for aerospace applications.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: November 23, 2021
    Assignee: PRC-DeSoto International, Inc.
    Inventors: Razmik Boghossian, James Smith
  • Patent number: 11180603
    Abstract: The present patent application relates to a thermoplastic polymer produced at least from diisocyanate and diepoxide using a catalyst, wherein the catalyst is an ionic liquid, to an associated production method and use.
    Type: Grant
    Filed: February 14, 2018
    Date of Patent: November 23, 2021
    Assignee: BASF SE
    Inventors: Hans-Josef Thomas, Markus Schuette, Berend Eling, Patrick Matt
  • Patent number: 11168175
    Abstract: The present invention relates to a thermoplastic polyurethane obtainable or obtained by the conversion of at least a polyisocyanate composition, ethane-1,2-diol as chain extender and a polyol composition, wherein no further chain extender is used aside from ethane-1,2-diol, to a process for preparing such a thermoplastic polyurethane, and to the use of such a polyurethane for production of injection molded products, extrusion products, films and shaped bodies.
    Type: Grant
    Filed: September 20, 2016
    Date of Patent: November 9, 2021
    Assignee: BASF SE
    Inventors: Elmar Poeselt, Dirk Kempfert
  • Patent number: 11168171
    Abstract: Disclosed is a segmented thermoplastic elastomer that can be a polyurethane, polyurea, or polyurethane-urea comprising soft segments and hard segments, wherein the soft segments are made of polyolefin diols or polyolefin diamine that may have 0 to 1000 carbon atoms in the main chain, wherein each carbon atom in the main chain may have 0 to 2 side chains and each side chain may have 0 to 30 carbon atoms, the hard segment is made of a diisocyante and a chain extender, the hard segments make up 10-60% of the elastomer and the soft segments make up the rest, the number-average molecular weight of the elastomer is 5×103-1000×103 g/mol, the ultimate elongation of the elastomer is 100-1000%, the Young's modulus is 1 to 3,000 MPa, and the ultimate tensile strength is 10-100 MPa. Also disclosed are a method for preparing the segmented thermoplastic elastomer and use of segmented thermoplastic elastomer.
    Type: Grant
    Filed: March 2, 2017
    Date of Patent: November 9, 2021
    Assignee: Medtronic, Inc.
    Inventors: Jing Chen, Haining Na, Jin Zhu, Suping Lyu, XiangJi Chen
  • Patent number: 11161929
    Abstract: A thermoplastic polyurethane film including a cured product of a polyurethane resin composition is provided. The polyurethane resin composition includes a polyurethane resin, a first isocyanate-based curing agent, and an organic solvent. The thermoplastic polyurethane film has a tensile strength of 0.2 MPa to 1.5 MPa at an initial elongation of 5% to 10%. A method for preparing the thermoplastic polyurethane film is also provided.
    Type: Grant
    Filed: March 16, 2018
    Date of Patent: November 2, 2021
    Inventors: Sang Yool Lee, Joo Hee Hong, Se Jung Park, Sang Hwan Kim, Jang Soon Kim