Abstract: Catalytic materials useful, e.g., in water oxidation performing at low overpotential and/or stable for applications such as solar-to-fuel conversion systems may include nanoscale, nanoporous Pd-containing materials. Thin-film Pd electrocatalysts may be obtained via Aerosol-Assisted Chemical Vapor Deposition (AACVD) on conducting surfaces. XRD and XPS analyses show a phase pure crystalline metallic Pd deposit. Surface morphology study reveals a nanoparticulate highly porous nanostructure. Under electrochemical conditions, such Pd electrocatalysts may conduct water oxidation at onset potentials starting around 1.43 V against a reversible hydrogen electrode (? of 200 mV, Tafel slope of 40 mV/dec), and/or may achieve around 100 mA/cm2 current density at 1.63 V against a reversible hydrogen electrode, and may exhibits long-term stability in oxygen evolution. Method of making such electrocatalysts and their uses are also provided.

Abstract: An electrode, which includes at least one tetragonally crystallized compound containing at least one element selected from the group of Cu and Ag, the crystal lattice of the compound being of the space group I41/amd type. An electrolysis cell includes the electrode.

Abstract: The present invention generally provides a system for metal corrosion protection, including a metallic object to be protected, connectable to an electron source as cathode, an electrically isolating coating disposed on at least a portion of the metallic object, an electrically conductive blanket anode applied on at least a portion of the electrically isolating coating; an electrode electrically connected to the blanket anode and connectable to the electron source. The present invention further proposes a kit for providing corrosion protection to a substrate and method thereof.

Abstract: In a method for producing high-purity electrolytic copper, a first additive (A) containing an aromatic ring of a hydrophobic group and a polyoxyalkylene group of a hydrophilic group, a second additive (B) formed of polyvinyl alcohols, and a third additive (C) formed of tetrazoles are added to a copper electrolyte, copper electrolysis is performed by controlling each concentration of the first additive (A), the second additive (B), and the third additive (C), a current density and a bath temperature, and accordingly, electrolytic copper in which a concentration of Ag is less than 0.2 mass ppm, a concentration of S is less than 0.07 mass ppm, a concentration of all impurities is less than 0.2 mass ppm, and an area ratio of crystal grains having an average crystal grain misorientation (referred to as a GOS value) exceeding 2.5° is 10% or less is obtained.

Abstract: An electrode including a metal coil and a metal wire is provided. The metal coil includes a metal selected from copper, silver, gold, nickel and aluminium. The turns of the metal coil are separated by a gap. At least part of the metal wire is arranged inside the metal coil. The metal wire and the metal coil are in electrical contact. The metal wire includes a metal selected from copper, silver, gold, nickel and aluminum. The metal wire and the metal coil are made of a same metal. The metal coil has a plurality of turns forming an elongated coil body with a central channel along a central axis of the metal coil. The metal wire extends longitudinally inside the central channel from one end of the metal coil to an other end of the metal coil along the central axis of the metal coil.

Abstract: The present disclosure provides a method and apparatus to perform an electrochemical process by manipulating the charge on an electrode involved in the primary circuit of the electrochemical reaction. The amount of charge on the electrode can be manipulated independent of the bias voltage of the primary circuit and is accomplished by coupling the electrode with various different configurations.

Abstract: An array of anode assemblies for insertion at a plurality of locations in a gap between a section of a reinforced concrete structure and another solid structure is provided. Each anode assembly comprises an expandable member, an anode attached to the expandable member for protecting a steel reinforcement in the reinforced concrete structure, and an anode connector for interconnecting the array of anode assemblies. During use, each anode assembly of the array of anode assemblies is inserted into the gap, between the section of the reinforced concrete structure and the solid structure, at the plurality of locations. The expandable member of each anode assembly is configured to expand so as to press the anode into contact with a surface of the reinforced concrete structure.

Abstract: The present disclosure relates to a bismuth vanadate electrode including vanadium-functionalized graphene quantum dots and a method for preparing the same. More particularly, it relates to a technology which is capable of, by adding graphene quantum dots (GQDs) in the process of immersing a bismuth vanadate (BiVO4) electrode in an alkaline solution to remove vanadium oxide (V2O5) excessively formed on the surface of the electrode during its preparation, protecting the electrode from the alkaline solution as the graphene quantum dots are adsorbed onto the surface of BiVO4 while V2O5 is removed, and improving the efficiency of oxygen evolution reaction (OER) when applied to a photoanode due to vanadium (V)-functionalized graphene quantum dots formed as the etched vanadium ions ((VO)43?) are adsorbed onto the graphene quantum dots.

Abstract: A system consisting of a pencil-type sacrificial anode rod and a companion plug for use in, e.g., marine engines, generators, and other machinery or fluid-containing components requiring the presence of sacrificial anodes to prevent galvanic and electrolytic corrosion. The anode rod is securely held in the plug via a push-to-connect mechanism that allows the anode rod to rotate when acted on by a torsional force. This mechanism allows for extraction of the plug through pure tensile forces on the anode rod, thus preventing the breaking of stuck anode rods through torsional forces or stuck anode rods being left behind in engine components due to unthreading of the anode rod from the plug. Electrical continuity between the anode rod and plug is continuously maintained via metal-to-metal contact.

Abstract: A method for making an electrocatalyst containing manganese oxide nanoparticles present on carbon obtained from Albizia procera (MnOxNPs-C) for electrochemical water oxidation. The method includes a thermal decomposition and forms a product with specific morphological variations, including crystalline structure, elemental composition, and chemical compatibility. The manganese oxide nanoparticles are well dispersed over the carbon. The amount of manganese oxide nanoparticles increases by increasing the amount of precursor. Single-phase formation of the Mn3O4, and Mn3O4 along with MnO phase occurs at low and high amount of the precursor materials, respectively. The electrocatalyst can be used for the purpose electrolytic water splitting.

Abstract: One object of this application is to provide an advanced substrate holder including a clamper. A substrate holder holds a substrate by interposing the substrate between frames. The substrate holder includes a front frame, a rear frame, and one or a plurality of clampers. Each of the clampers includes a hook portion including a hook base and a hook main body, and a plate including at least one claw. At least one of the clampers includes the plate including a first claw for a lock and a second claw for a semi-lock.

Abstract: In an aspect, a method of making a composite core-shell nanoparticle comprises forming a nanoparticle core comprising nickel oxide or iron oxide via thermal decomposition of a nickel complex or an iron complex; and forming an oxide shell over the core, the oxide shell comprising nickel, iron or a mixture thereof. In another aspect, a method of making composite nanoparticles comprises providing a mixture comprising nickel complex and iron complex; and thermally decomposing the nickel and iron complexes to provide the composite nanoparticles comprising (Ni,Fe)Ox alloy. In yet another aspect, a composition comprises composite nanoparticles, the composite nanoparticles including a nickel oxide core and oxide shell, the oxide shell comprising a mixture of nickel and iron.

Abstract: This disclosed technology includes a cathodic protection system for protection of metal components. The cathodic protection system can include a non-solid anodic composition, such as an anodic paste. The non-solid anodic composition can include zinc and/or magnesium. The cathodic protection system can include a barrier protection system that can include one or more layers. The barrier protection system can include an outer moisture barrier.

Abstract: An article is provided that includes a substrate, a silicon containing layer on the substrate, and a layer including metallic Pt on the silicon containing layer. The silicon containing layer is a diamond-like glass layer. Optionally, the substrate is a porous membrane. In some cases, the silicon containing layer is a continuous layer.

Abstract: An oxygen evolution reaction catalyst electrode may include: a glass electrode; a first coating, directly upon the glass electrode, comprising a layer of fluorine-doped tin oxide (FTO); and a second coating, directly upon the first coating, comprising a layer comprising at least 95 wt. % palladium, relative to a total weight of the second coating, wherein the palladium in the second coating is in the form of porous, spongy-textured clusters comprising palladium spheroid nanoparticles in cubic crystalline phase. The second coating may have a thickness in a range of from 0.5 to 10 ?m, and the clusters may have an average largest dimension in a range of from 500 to nm.

Abstract: An electrochemical substrate holder assembly, including: a first housing and a second housing; wherein the first housing and the second housing collectively define an interior space; a first gasket coupled to the first housing and adapted to contact a first side of a substrate; and a second gasket coupled to the second housing and adapted to contact a second side of the substrate; wherein the first gasket and the second gasket are collectively adapted to hold the substrate within the interior space. The first housing defines a first port adapted to receive a first electrical lead to electrically contact the first side of the substrate. The second housing defines a second port adapted to allow a fluid to pass there through to fluidly contact at least the second side of the substrate. The second housing is adapted to receive one or more of a second and third electrical lead.

Abstract: There is provided the substrate holder for holding a substrate comprising a first holding member, a second holding member, a sealing member, a pin, a ring, and a moving mechanism. The sealing member forms a sealed space inside the substrate holder. The pin is fixed to one of the first holding member and the second holding member. The ring is disposed on another of the first holding member and the second holding member. The ring engages with the pin. The moving mechanism circumferentially moves the ring. The pin and the ring are engaged with one another to fix the first holding member and the second holding member to one another. The pin and the ring are disposed inside the sealed space.

Abstract: A method of synthesizing a disulfide compound is provided. The method may include providing an electrochemical cell that has a compartment, an anode, and a cathode. The compartment may contain a solution of one or more thiol compounds, a catalyst, and a solvent. The method may also include providing an electrical current to the electrochemical cell and converting the one or more thiol compounds into the disulfide compound.

Abstract: It is configured that a frame body is locked to a back panel by: inserting a number of first pins of the frame body into a number of first holes of the back panel; moving a fastening body outward by a moving mechanism of a lock mechanism; and fitting a notch into a concave portion at the tip of the first pin.

Abstract: A substrate holder prevents a substrate to be bent or damaged owing to inward declining of a seal lip. The substrate holder with an opening includes a seal, and a seal support which has a seal support surface, and is formed on an outer circumference of the opening. The seal includes a seal body and a seal lip. At least a part of the seal support surface has an inclination angle that allows an inner end of the seal support surface to approach the plane on which the substrate is to be positioned. The inner end of the seal support surface is positioned on an inner side than the seal lip.