Abstract: Used catalyst containing carbon and sulfur deposits is continuously regenerated by staged burnoff of the carbon and sulfur using a multiple zone treatment vessel containing thin beds of catalyst. The catalyst is exposed to successively increased temperatures and oxygen concentrations to effectively remove substantially all the carbon and sulfur deposits. The used catalyst can be that removed from hydroconversion processes, such as from H-Oil, H-Coal and fluid catalystic cracking processes, and processed in a multizone treatment vessel in combination with proper auxiliary heating equipment for continuous step-wise regeneration of the catalyst. Operating conditions of catalyst temperature, oxygen concentration of gas, and catalyst residence time in each stage of the catalyst regeneration process are carefully controlled to provide staged burnoff of carbon and sulfur deposits for superior regenerated catalyst results.
Abstract: A regeneration process for tellurium-containing metal oxide catalysts used in the process for oxidation, ammoxidation or oxidative dehydrogenation of organic compounds at a temperature of about 300.degree. C. to about 600.degree. C. The process can be effectively applied to such catalysts which have become partially deactivated during the reaction.
Abstract: The disclosed catalyst for polyurethane comprises an organic carboxylic acid salt of a tertiary amine compound and 1-methyl-4-(2-dimethylaminoethyl)piperazine. The tertiary amine compound is selected from the group of triethylenediamine, bis(2-dimethylaminoethyl)ether and N,N,N',N",N"-pentamethyldiethylenetriamine and the organic carboxylic acid is selected from the organic carboxylic acids having 1-20 carbon atoms.
Abstract: Ruthenium carbonyl-cobalt carbonyl catalyst mixtures effectively catalyze the dealkoxyhydroxymethylation of aldehyde acetals, wherein said acetal may be prepared separately or in situ from an aldehyde and an alcohol. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of this ruthenium carbonyl-cobalt carbonyl catalyst to form the monomethyl ether of ethylene glycol.The invention also is directed to the ruthenium carbonyl-promoted cobalt carbonyl catalysts per se, including novel precipitated forms of these ruthenium-cobalt carbonyl catalyst mixtures.
Abstract: The present invention is directed to an activated carbon made from macadamia nuts. The macadamia nuts each comprise an outer husk, a shell and a kernel. The shell is used as a material of the activated carbon. The shell is separated from the husk and the kernel and subjected to carbonization and activation processes to obtain the activated carbon.
Abstract: A method for recovering a denitrating catalyst which is characterized by washing, with an aqueous oxalic acid solution, the used tungsten-titania or the tungsten-titania-vanadium denitrating catalyst which dust components have adhered to or have accumulated on and in which an SO.sub.2 -oxidizing power has thus risen; impregnating the catalyst with a tungsten compound; and drying and calcining the thus treated catalyst.
Abstract: The present invention provides for a process and associated apparatus for limiting the vertical mixing of catalyst in a fluidized catalyst regenerator so that spent catalyst entering the regenerator will remain at the top of the fluidized bed for a longer period of time. This is accomplished by employing a generally horizontally placed baffle device located between 2 ft.-4 ft. below the catalyst bed level in the regenerator.
Abstract: In a process apparatus for the regeneration of fluid cracking catalyst, the catalyst is cooled in an exchanger mounted to the lower side of the regenerator and cool catalyst is returned to the regenerator by means of gas lift.
Type:
Grant
Filed:
June 21, 1985
Date of Patent:
September 30, 1986
Assignee:
Ashland Oil, Inc.
Inventors:
Paul W. Walters, H. Anthony Raiche, Ronald L. Harness, Genaro M. Quodala
Abstract: An ureteral stent comprises an elongated, flexible tubular member which has proximal and distal ends in the form of hooks. Both of the ends of the member are open but the opening at the proximal end is smaller than the lumen or the opening at the distal end. Methods of inserting the stent, maneuvering the stent past difficult obstructions in the ureter, replacing an indwelling stent are described, as well as kits for performing those methods.
Abstract: A catalytic conversion system having sulfur-contaminated vessels and/or conduits upstream from the fixed catalytic bed is regenerated in situ by first flowing regenerating oxygen-containing gas having not more than 0.1 mol percent oxygen and at a temperature of above 850.degree. F., through the normal flow path of the vessels and/or conduits and then the fixed catalyst beds, wherein the sulfur contaminants are oxidized to sulfur dioxide which pass through the catalyst bed in the absence of sufficient oxygen to permit substantial conversion to harmful sulfur trioxide in the presence of catalyst containing a platinum group component on a porous inorganic oxide base, prior to removal of carbonaceous material from the catalyst.
Abstract: Disclosed is a highly efficient continuous method for the aqueous extraction of water-soluble oxidation catalyst material from a residue such as that generated in the production of dimethyl terephthalate from p-xylene by the molecular oxygen oxidation and methanol esterification process. In the method the desired end product is an aqueous solution of the catalyst material. The residue to be extracted is established in finely dispersed condition in part of the aqueous solution at a weight ratio of aqueous solution to residue of above about 1:1 and maintained in that condition for a length of time sufficient for maximum transfer of catalyst material from the residue to the aqueous solution to take place. The resulting dispersion then is separated in a phase separation zone into an aqueous phase and an extracted residue phase. The separated aqueous phase is withdrawn from the phase separation zone as the aqueous solution.
Abstract: Palladium/rhenium-on-carbon catalyst; a method employing said catalyst to produce tetrahydrofuran, 1,4-butanediol or mixtures thereof in selectable ratios from a number of starting reactants; and a method for making the Pd/Re/C catalyst.
Type:
Grant
Filed:
June 4, 1985
Date of Patent:
September 2, 1986
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Melinda A. Mabry, William W. Prichard, Stanislaw B. Ziemecki
Abstract: Regeneration of an ammoxidation catalyst which is exhausted as a result of prolonged exposure to ammoxidation conditions, containing oxides of Mo, Bi, P, Fe, Co, Ni and possibly an alkali metal, particularly K, on a granular support, particularly silica, by means of a method including:the impregnation of the granules of spent catalyst with an aqueous molybdic acid solution, or with an aqueous solution of partially or totally salified molybdic acid in the form of the ammonium salt, with a volume of impregnation solution less than the total pore volume of the catalyst subjected to regeneration;the drying of the impregnated granules at a temperature of from 100.degree. to 200.degree. C.;the calcining of the dried granules at a temperature of from 250.degree. to 450.degree. C., solely when the impregnation is with an aqueous solution of partially or totally salified molybdic acid.
Abstract: Catalysts comprising iron carbide on a surface modified titania support wherein said support comprises a surface modifying oxide of tantalum, niobium, vanadium and mixtures thereof supported on said titania wherein at least a portion of said surface modifying oxide is in a non-crystalline form. These catalysts are useful for Fischer-Tropsch hydrocarbon synthesis reactions. Preferably, at least about 25 wt. % of said surface modifying oxide will be in a non-crystalline form.
Type:
Grant
Filed:
July 29, 1985
Date of Patent:
August 26, 1986
Assignee:
Exxon Research and Engineering Co.
Inventors:
Israel E. Wachs, Rocco A. Fiato, Claudio C. Chersich
Abstract: Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.
Type:
Grant
Filed:
January 4, 1982
Date of Patent:
August 19, 1986
Assignee:
The Standard Oil Company
Inventors:
David R. Corbin, Louis J. Velenyi, Marc A. Pepera, Serge R. Dolhyj
Abstract: By the process of the present invention the activity of heterogeneous catalysts for reactions at normal and low pressures is restored or maintained. These catalysts can lose their activity as a result of the deposition, physisorption or chemisorption of organic or inorganic deactivating substances which are carried over into the reaction system or are formed as the result of side reactions in a chemical synthesis carried out with the aid of the catalyst. The activity is restored or maintained by using a pressure greater than the critical pressure of the fluid phase and a temperature higher than or equal to the critical temperature of the fluid phase. In this process, the pressure and temperature are applied for a period such that the deactivating substances are either removed from the catalyst or are not initially deposited thereon or absorbed or formed.
Type:
Grant
Filed:
May 6, 1985
Date of Patent:
August 12, 1986
Inventors:
Helmut Tiltscher, Helmut Wolf, Joachim Schelchshorn, Kurt Dialer
Abstract: Candoluminescent material constituted by a mixture of finely divided oxides brought into the form of a net identical to a textile. This mixture has the following molar compositions:75 to 90% zirconia,5 to 20% of yttrium oxide or calcium oxide and yttrium oxide.2 to 15% of magnesia, or magnesia and alumina,0.01 to 1% in all of oxides of iron, chrome, manganese, praseodymium and/or cerium.
Abstract: A process for regenerating a Mo.Bi-based multi-oxide catalyst the catalytic performance of which has deteriorated as a result of its use in vapor-phase catalytic oxidation of propylene or isobutene to prepare acrolein or methacrolein, respectively, which process comprises: heating the deteriorated Mo.Bi-based multi-oxide catalyst in an atmosphere consisting essentially of air at a temperature of 380.degree. C. to 540.degree. C., so as to attain at least partial restoration of the catalytic performance thereof.
Abstract: An improved moving bed continuous catalytic cracking process for cracking hydrocarbon feedstocks, such as gas oil, in the absence of added hydrogen, which includes the use of a minute amount of dispersed platinum supported directly on a cracking catalyst. The trace of platinum induces a substantial increase in the heat efficiency with which coke on catalyst is converted to CO.sub.2 in the regenerator section with minimal or no detriment to the cracking reaction.