Abstract: Polyester molding compositions, which have improved crystallization and processing, a cycloaliphatic polyester component, and a nucleating agent comprising a fluoropolymer containing a thermoplastic resin.
Type:
Grant
Filed:
March 20, 2001
Date of Patent:
July 1, 2003
Assignee:
General Electric Company
Inventors:
Peter Hendrikus Theodurus Vollenberg, Gerardus Bernardus Wilhelmus Hieltjes, Franciscus Petrus Maria Mercx, Aagje Petronella den Breejen
Abstract: A compounded unsaturated polyester resin composition having 10-90 wt % of at least one high viscosity, high molecular weight unsaturated polyester, 10-80 wt % of at least one low viscosity, low molecular weight unsaturated polyester, and 9-30 wt % of at least one monomer. The cone and plate viscosity of the high molecular weight unsaturated polyester is 1 Pas/100° C. to 10 Pas/150° C. and the weight average molecular weight Mw is 1,200 to 10,000. The cone and plate viscosity of the low molecular weight unsaturated polyester is 1 Pas/25° C. to 4 Pas/100° C., and the weight average molecular weight Mw is 400 to 3,000.
Type:
Grant
Filed:
June 12, 2001
Date of Patent:
June 24, 2003
Assignee:
Ashland, Inc.
Inventors:
Karri Airola, Paul Mahbub, Eija Valtonen
Abstract: According to the present invention, a polyester resin composition superior in the impact resistance, especially low-temperature impact resistance, and in the stiffness as well as in the fracture toughness can be obtained. The polyester resin composition according to the present invention is a composition which comprises, per 100 parts by weight of a polyester resin (A), 5-200 parts by weight of a graft-modified ethylene/&agr;-olefin random copolymer (B) obtained by grafting onto an ethylene/&agr;-olefin random copolymer (B-1) composed of ethylene unit and of an &agr;-olefin unit of 6-20 carbon atoms an unsaturated carboxylic acid or its derivative (B-2), wherein the grafting amount of the unsaturated carboxylic acid or its derivative (B-2) is 0.01-10% by weight and wherein the said ethylene/&agr;-olefin random copolymer (B-1) before being graft-modified has (a) a content of the &agr;-olefin unit of 6-20 carbon atoms of 6-25 mole % and (b) a melt flow rate (ASTM D 1238, 190° C., 2.16 kg load) of 0.
Abstract: The invention concerns a terephthalic polyester composition (CPT), comprising in mixture: an ethyleneterephthalate homooligomer (PET 1) essentially containing recurrent terephthalate oxyethylene (TE) units; and a block terephthalate copolymer (PET 2/TE-POE) containing at least a polyethyleneterephthalate (PET 2) sequence; and at least a terephthalate polyoxyethylene (TE-POE) sequence whereof the POE unit has a molecular mass of 1500 to 4000 in number; said composition (CPT) being characterised in that: the quantity of (TE) units of (PET 1) represents not more than 10% of the total number of (TE) units present in said composition (CPT); the weight quantity of (TE) units present in the composition (CPT) represents at least 10% of (TE) units present in the composition (CPT); the quantity by weight of mono(oxyethyleneoxy) radicals (OEO) represents at least 1.
Abstract: A method of producing modified polyester moulded articles which is characterized in that, when producing moulded articles from a modified polyester composition comprising a polyester composed of an acid component chiefly consisting of aromatic dicarboxylic acid and glycol component chiefly consisting of aliphatic diol, and a modified polyolefin, there is incorporated an ethylene-acrylate copolymer; together with the moulded articles produced thereby.
Abstract: Melt fabricable compositions of at least 50 wt % polytetrafluoroethylene are provided, wherein the composition contains polyaryletherketone and optionally part of the polytetrafluoroethylene is PTFE micropowder.
Abstract: A thermoplastic resin composition comprising an aromatic polysulfone resin and at least one resin selected from aromatic polyester resins, wherein the amount of alkali metal which exists in the aromatic polysulfone resin as a terminal phenolate is 50 ppm or less, and molded article thereof. This composition is excellent in heat resistance and melt-mold processability.
Abstract: The present invention has for its object to provide an ester elastomer having a high block of the hard and soft segment components, high flexibility, and good mechanical properties at high temperature, particularly high temperature creep resistance and a process for producing said ester elastomer.
Abstract: Thermoplastic compositions comprising a bulk polymer, an additive, and a compatibilizer/emulsifier/surfactant (CES) are described. The bulk polymer comprises an alkylene terephthalate or naphthalate polyester such as polyethylene terephthalate. The additive comprises an amorphous or substantially amorphous co-polymer of ethylene and a co-monomer that forms polar portions, such as methacrylate, butylacrylate, ethyl acrylate, or ethylhexyl methacrylate. The CES comprises a co-polymer or ter-polymer of ethylene and a glycidyl acrylate or maleic anhydride, and optionally an acrylate such as methacrylate, ethylacrylate, propylacrylate, butylacrylate, ethylhexylacrylate, or mixtures thereof. The thermoplastic compositions of the present invention exhibit improved molding properties, high dimensional stability, high temperature resistance, and are particularly useful in food-grade applications such as dual-ovenable containers.
Abstract: A high flow polyphenylene ether resin composition with improved HDT values and flame retardance comprising a blend of at least two polyphenylene ether resins, a first resin having an intrinsic viscosity of at least 0.3 dl/g, and a second resin having an intrinsic viscosity of less than 0.25 dl/g and preferably having a particle size of at least about 100 &mgr;m. The composition preferably contains less than 30 wt % of the low viscosity polyphenylene ether based on the weight of the total composition. Fiber reinforced and flame retarded compositions also exhibit high HDT values.
Abstract: A hyperbranched polyester polyol macromolecule, having a plurality of both embedded and exterior hydroxyl groups thereon, may be synthesized in a polymerization reaction having several steps. The hyperbranched polyol includes a central nucleus, a first chain extension, an intermediate substituent and a second chain extension. The central nucleus is a hydrocarbon structure with a plurality of oxygen atoms. The first chain extender is attached to the central nucleus and includes a carboxylic ester group and a plurality of hydroxyl groups. The intermediate substituent is attached to the first chain extender, and is a polyfunctional carboxylic acid or anhydride thereof. The preferred intermediate substituent is a cyclic compound. The second chain extension is attached to the intermediate substituent. The preferred second chain extension includes a glycidyl ester or epoxy. Methods of making a hyperbranched polyester polyol are also disclosed.
Abstract: There is described a novel blend composition comprising specified amounts of any polycarbonate and specified amounts of a specific copolyester comprising terephthalic acid, naphthalenedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, or mixtures thereof; isophthalic acid; and 1,4-cyclohexanedimethanol. Also described are films and sheets produced from the novel blend compositions that are thermoformable without having to pre-dry the films and sheets. Further, articles of manufacture produced from the novel blend compositions are described.
Type:
Grant
Filed:
September 5, 2001
Date of Patent:
May 27, 2003
Assignee:
Eastman Chemical Company
Inventors:
James Carl Williams, John Guthrie Thompson, Roy Lee Conn
Abstract: A flowable nondigestible oil composition having a Consistency in a temperature range of 20° C. to 40° C. of less than about 600 P.sec(n−1), preferably less than about 400 P.sec(n−1). The flowable nondigestible oil contains a liquid polyol polyester having a complete melt point less than 37° C., and a solid polyol polyester having a complete melt point of at least about 37° C. The solid polyol polyester can be a solid saturated polyol polyester, a solid diversely esterified polyol polyester, a polyol polyester polymer, or a combination thereof, which are crystallized, or co-crystallized, into unaggregated crystal particles of typically less than 10 microns in maximum dimension. The flowable nondigestible oil is made by a process which includes the steps of melting completely the nondigestible oil, crystallizing the solid polyol polyester while applying shear to avoid formation of clusters of crystallized aggregates which can prevent the composition from being flowable.
Abstract: The present invention relates to glyoxylic compound comprising one or more active ingredient. By the present invention, a delayed release of the active ingredient is provided upon contact of the compound with an aqueous medium.
Type:
Grant
Filed:
February 8, 2001
Date of Patent:
May 6, 2003
Assignee:
The Procter & Gamble Company
Inventors:
Stephen Wayne Heinzman, Simon Timothy Farrington Sawyer, Robert J. Strife, Arnaud Pierre Struillou
Abstract: Carboxy-functionalized polyphenylene ethers containing structural units with a carboxyalkyl group in the 2-position are prepared by redistribution of a polyphenylene ether with a 2-carboxyalkylphenol such as 2-(3-carboxypropyl)phenol (melilotic acid), or by oxidative coupling of a suitable phenol with such a 2-carboxyalkylphenol. The products form compatibilizing copolymers with polymers containing carboxylic acid-reactive functional groups, such as polyesters, polyamides and epoxy resins.
Abstract: Solid extrusion coating compositions for metal substrates, a method of extrusion coating a metal substrate, and a metal article are disclosed. The extrusion coating composition is a thermoplastic material and comprises: (a) a polyester having a weight average molecular weight of about 10,000 to about 50,000, and optionally, (b) a modifying resin, such as an epoxy resin having an epoxy equivalent weight of about 500 to about 15,000. The extrusion coating composition is applied to a metal substrate in an extrusion process to provide a composition film having a thickness of about 1 to about 40 microns.
Type:
Grant
Filed:
August 8, 2000
Date of Patent:
April 22, 2003
Assignee:
The Valspar Corporation
Inventors:
Christina Schmid, Rolf Jung, Hans Widmer, Martin Lu, Artemia Jimenez, Louis Sharp, Stephen Postle
Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150° C.
Abstract: A method for making a biodegradable thermoplastic composition. The thermoplastic composition may be used in methods to produce multi-component fibers and non-woven materials that demonstrate a higher contact angle hysteresis, quicker intake times, and improved skin dryness as compared to prior art materials. In addition, biodisintegratable nonwoven materials made according to the present invention also exhibit high wetting rates, which is unexpected based upon the higher hysteresis values. The nonwoven material may be produced using thermoplastic compositions which comprise an unreacted mixture of an aliphatic polyester polymer as a continuous phase, polyolefin microfibers as a discontinuous phase encased within the aliphatic polyester polymer continuous phase, and a compatibilizer for the aliphatic polyester polymer and the polyolefin microfibers. The multicomponent fiber exhibits substantial biodisintegratable properties and good wettability yet is easily processed.
Abstract: The present invention improves the effectiveness of the oxygen scavenging composition and maintains an excellent balance in the color properties of the polymer. The present invention relates to an improved oxygen scavenging PET based copolymer comprising from about 10 to about 120 ppm cobalt based on the PET polymer, and from about 15 to about 150 ppm zinc based on the PET polymer. The present invention also comprises a process for preparing a PET based oxygen scavenging copolymer, comprising the steps of:
a) polymerizing a PET based polymer;
b) adding Zn, Co, and an oxygen scavenging compound during said polymerizing step;
c) copolymerizing said oxygen scavenging compound with said PET based polymer to form a copolymer; and
d) extruding said copolymer.
Type:
Grant
Filed:
August 1, 2001
Date of Patent:
April 8, 2003
Assignee:
Arteva North America S.A.R.L.
Inventors:
David Anthony Schiraldi, Douglas John Sekelik, Brad Lee Smith
Abstract: An adhesive prepared by blending a hardening resin serving as the main component with an urethane resin having a polycarbonate structure. The addition of the urethane resin with the polycarbonate structure makes it possible to give an adhesive which has a high solvent resistance and a good low temperature impact resistance and achieves good adhesion between vinyl chloride and a steel plate. This urethane resin can be obtained by reacting a polyol with an isocyanate compound. It is advantageous to use the urethane resin in an amount of 5 to 35% by weight.