Abstract: A glass fiber filter element for visible light photocatalysis and air purification and a method for preparing the same. The glass fiber filter element includes 4 to 7 wt % of nanoparticles including at least one selected from zinc oxide, graphene oxide, titanium oxide, and reduced graphene oxide, 2 to 7 wt % of silver nanowires, 3 to 12 wt % of an adhesive system, and 78 to 91 wt % of a glass fiber mat, based on the total weight of the glass fiber filter element. The glass fiber mat is made of at least two glass fibers with different diameters, and the diameters are in a range of 0.15 to 3.5 ?m. The nanoparticles have a particle size from 1 to 200 nm, and the silver nanowires have a diameter of 15 to 50 nm.
Type:
Grant
Filed:
November 17, 2021
Date of Patent:
April 2, 2024
Assignees:
CHONGQING INSTITUTE OF EAST CHINA NORMAL UNIVERSITY, ROI OPTOELECTRONICS TECHNOLOGY CO, LTD., EAST CHINA NORMAL UNIVERSITY
Abstract: The present invention concerns a catalyst and pre-treatment process for acidic charges consisting of sulfated zirconia and cerium for the production of biofuels, characterized in that the catalyst has greater activity and resistance to deactivation with acidic charges.
Abstract: Described is a method of preparing transition metal nanoparticles on a graphene support, in which a tertiary graphite intercalation compound is provided with intercalated metal ions such that the tertiary graphite intercalation compound comprises a graphene sheet having a negative charge. The graphene sheet is contacted with a transition metal salt to cause reduction of the transition metal salt by the graphene sheet, and to form transition metal nanoparticles. Also described are products arising from the method, and uses of those products.
Type:
Grant
Filed:
February 13, 2019
Date of Patent:
March 26, 2024
Assignee:
UCL BUSINESS LTD
Inventors:
Chris Howard, Rhodri Jervis, Daniel Brett, Gyen Angel, Patrick Cullen, Chris Gibbs
Abstract: A piezoelectric polymer used as a piezocatalyst, and methods of manufacture and use therefor. A preferred piezoelectric polymer is poly(vinylidene difluoride) (PVDF) due to its piezoelectric response and good flexibility. The polymer can be doped with a metal, metal salt, metal carbonyl, metal oxide such as ZnO, Co2O3, or TiO2, or ion such as Cr3+, Co2+, or Zn2+. The dopant can be chosen so that when the polymer is PVDF the dopant increases the amount of ?-phase PVDF and/or ?-phase PVDF relative to ?-phase PVDF, thereby increasing the piezocatalytic response of the polymer. The compound to be decomposed can be adsorbed on the surface of the piezoelectric polymer. Applications include wastewater treatment, CO2 capture and reduction, hydroformylation, water splitting, and ammonia synthesis.
Type:
Grant
Filed:
March 2, 2021
Date of Patent:
March 19, 2024
Assignee:
University of Rhode Island Board of Trustees
Inventors:
William B. Euler, Angela Thach, Lasanthi Sumathirathne, Benjamin B. Cromwell, Mara Dubnicka
Abstract: Disclosed is a catalyst, a method for producing the catalyst, an electrode comprising the catalyst, a membrane-electrode assembly comprising the electrode, and a fuel cell comprising the membrane-electrode assembly, the catalyst being highly efficient and having a long service life due to improved interfacial properties with ionomer from having fluoride (F) groups on the surface thereof. The catalyst according to the present invention comprises: a support; metal particles supported in the support; and fluoride (F) groups on the surface of the support and metal particles.
Abstract: A method is provided that allows the sulfur component concentration in gasoline to be estimated to high precision. The measuring method of the disclosure is a method of measuring the concentration of sulfur components in gasoline that contains sulfur components and aromatic components. The measuring method of the disclosure comprises: (A1) removing a portion of the gasoline by gasification to lower the proportion of the aromatic component concentration with respect to the sulfur component concentration in the gasoline, (A2) measuring values related to the refractive index of the gasoline, and (A3) measuring the sulfur component concentration in the gasoline based on the values related to the refractive index.
Type:
Grant
Filed:
November 9, 2020
Date of Patent:
March 19, 2024
Assignees:
Toyota Jidosha Kabushiki Kaisha, National University Corporation Okayama University
Abstract: A Ziegler-Natta catalyst component precursor made from or containing a mechanical mixture of (a) distinct particles of adducts of formula MgCl2(R1OH)n where R is a C1-C8 alkyl group and n is from 0.2 to 6 having average particle size (P50a) ranging from 5 to 100 ?m; and (b) from 0.2 to 5.0% by weight of distinct particles of a solid compound containing more than 50% by weight of Sift units and having average particle size (P50b), wherein the ratio P50b/P50a ranges from 0.4 to 1.5.
Abstract: Provided are a preparation method for a propylene epoxidation catalyst, and a use thereof. During the preparation, an alkoxide solution of a prepared active component and a silica gel support are mixed, then a rotary evaporation treatment is performed on the mixture to remove a low-carbon alcohol to obtain a catalyst precursor, and then the obtained catalyst precursor is subjected to calcination and silylation treatments to obtain the propylene epoxidation catalyst. The catalyst is prepared in a simple process, can be applied to the chemical process of preparing propylene oxide by propylene epoxidation, has high average selectivity to propylene oxide, and has industrial application prospect.
Type:
Grant
Filed:
January 14, 2020
Date of Patent:
March 5, 2024
Assignee:
Wanhua Chemical Group Co., Ltd.
Inventors:
Lei Wang, Tongji Wang, Fei Ye, Kang Sun, Naibo Chu, Qiankun Jiao, Yuan Li
Abstract: A catalyst for continuous production of 1,1,1,3-tetrachloropropane through gas-solid reaction as well as a preparation method and use thereof are provided. The catalyst includes a zero-valent iron and phosphorus co-modified carbon material which includes a carbon material as a carrier, a zero-valent iron supported onto the carrier and serving as an active component, and a phosphate functional group formed on the surface of the carbon material. The preparation method includes: co-modifying a carbon material using a ferric salt and organic phosphorus to obtain the catalyst for continuous production of 1,1,1,3-tetrachloropropane through gas-solid reaction. The present application further provides a method for continuous production of 1,1,1,3-tetrachloropropane through gas-solid reaction.
Type:
Grant
Filed:
December 24, 2021
Date of Patent:
March 5, 2024
Assignees:
NINGBO INSTITUTE OF MATERIALS TECHNOLOGY & ENGINEERING, CHINESE ACADEMY OF SCIENCES, NINGBO JUHUA CHEMICAL & SCIENCE CO., LTD.
Inventors:
Yexin Zhang, Qiang Zhou, Jian Zhang, Junliang Zhong, Xiuxiu Wang, Jili Du, Hui Chen, Chengjun Mu, Jie Yang, Linbing Xia, Yong Yang, Gang Wu
Abstract: The present invention relates to the redox buffer electro-catalyst for bi-functional air electrode of metal-air batteries and fuel cells, wherein an electro-catalyst comprising of redox buffer oxides facilitates bi-functional activity of air electrode towards oxygen reduction and oxygen evolution reactions at the air electrode-electrolyte interface. The bi-functional activity of electro-catalyst comprising of redox buffer oxides is superior, due to improved electron transfer ability in comparison to electro-catalyst without redox buffer oxides.
Abstract: The present invention relates to a hydrogenolysis process wherein a hydrocarbon-based feedstock comprising aromatic compounds having at least 8 carbon atoms is treated by means of a hydrogen feed and in the presence of a catalyst, in order to convert C2+ alkyl chains of said aromatic compounds into methyl groups and to produce a hydrogenolysis effluent enriched in methyl-substituted aromatic compounds, wherein the catalyst comprises a support, comprising at least one refractory oxide, and an active phase comprising nickel and molybdenum, wherein: the nickel content being between 0.1 and 25% by weight relative to the total weight of the catalyst; the molybdenum content being between 0.1 and 20% by weight relative to the total weight of the catalyst; and the catalyst comprising a molar ratio of molybdenum to nickel of between 0.2 and 0.9. The present invention also relates to said catalyst and to the process for preparing said catalyst.
Type:
Grant
Filed:
December 13, 2019
Date of Patent:
February 20, 2024
Assignee:
IFP ENERGIES NOUVELLES
Inventors:
Vincent Coupard, Anne-Claire Dubreuil, Alexandre Jouve, Denis Uzio
Abstract: A method of chlorinating a antimony fluorohalide catalyst is disclosed. In one embodiment the method comprises contacting an antimony fluorohalide catalyst that contains one or more fluorines with a regenerating agent chosen from 2-chloro-3,3,3-trifluoropropene (1233xf), 1,1,1,3-tetrachloropropane (250fb), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) and combinations of 1233xf, 250fb, and 244bb, under conditions effective to exchange at least one fluorine in the antimony fluorohalide catalyst with chlorine. The method can be used to regenerate spent antimony fluorohalide catalyst, for example regenerating SbCl5 from SbF5.
Type:
Grant
Filed:
September 6, 2019
Date of Patent:
February 20, 2024
Assignee:
THE CHEMOURS COMPANY FC, LLC
Inventors:
Xuehui Sun, Mario Joseph Nappa, Karl Krause
Abstract: A fuel cell electrode catalyst includes: catalyst metal particles containing at least one of platinum or a platinum alloy; and support particles supporting the catalyst metal particles. The crystallite size 2r obtained from an X-ray diffraction image of the catalyst metal particles is 3.8 nm or less, where r represents a crystallite radius of the catalyst metal particles obtained from the X-ray diffraction image. The amount of CO adsorption Y (mL/g-Pt) on the fuel cell electrode catalyst satisfies Y?40.386/r+1.7586.
Type:
Grant
Filed:
March 9, 2022
Date of Patent:
February 13, 2024
Assignees:
TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
Abstract: The present invention combines the advantages of fabrication of semiconductor heterostructure (Ag3PO4—WO3) with plasmonic metals (Pt and Ag) with optical interference to optimize the visible light photo response of plasmonic metals deposited semiconductor (Pt—Ag/Ag3PO4—WO3) for visible light assisted H2 generation utilizing the aqueous bio-alcohols. Crystalline Ag3PO4 and WO3 nanofibers were synthesized by microwave and electrospinning methods. Three different WO3 nanofibers composition (5, 10 and 15 wt. %) were used to obtain Ag3PO4/WO3 nanocomposite heterostructures, which are effective visible light active photo catalysts. Further, a simple, enviro-friendly, and cost-effective biogenic synthesis method have been achieved using Salvia officinalis extract to decorate Pt and Ag metal nanoparticles on the surface of Ag3PO4—WO3 composites. Presence of bioactive agents in the extract are responsible for the Pt and Ag3PO4 reduction and for prevention of the Pt nanoparticles from aggregation in aqueous medium.
Type:
Grant
Filed:
October 5, 2023
Date of Patent:
February 13, 2024
Assignee:
Jazan University
Inventors:
Ahmed Hussain Jawhari, Ibrahim Ali Radini, Nazim Hasan, Maqsood Ahmad Malik, Katabathini Narasimharao
Abstract: A bifunctional oxygen electrocatalyst, a preparation method and use thereof are disclosed. The bifunctional oxygen electrocatalyst is represented by A1-x-yBxCyO2, wherein element A is one selected from the group consisting of Pt, Ir, Ru, and Pd, and each of element B and element C is selected from the group consisting of Mo, Mn, Fe, Co, Ni, Cu and Zn; the bifunctional oxygen electrocatalyst is a three-dimensional porous foam sheet catalyst; optionally, the element B is the same as the element.
Type:
Grant
Filed:
October 8, 2021
Date of Patent:
February 13, 2024
Assignee:
Tsinghua University
Inventors:
Rufan Zhang, Chenhui Zhou, Haibing Meng, Ying Han
Abstract: A powder material for an air electrode in a solid oxide fuel cell, the powder material being a powder of a metal composite oxide having a perovskite crystal structure represented by: A11-xA2xBO3-?, where the element A1 is at least one selected from the group consisting of La and Sm, the element A2 is at least one selected from the group consisting of Ca, Sr, and Ba, the element B is at least one selected from the group consisting of Mn, Fe, Co, and Ni, x satisfies 0<x<1, and ? is an oxygen deficiency amount. The powder has a specific surface area of 20 m2/g or more, satisfies (Crystallite diameter/Specific surface area-based particle diameter)?0.3, and contains elements M in an amount of 300 ppm or less in terms of atoms, the elements M being other than the elements A1, A2 and B, and oxygen.
Abstract: The present disclosure provides an active material comprising a mixed metal oxide in a hydrotalcite derived rocksalt structure, a processes to convert paraffins to corresponding olefins and or heavier hydrocarbons using the active material, and a method of preparing the active material.
Type:
Grant
Filed:
October 18, 2021
Date of Patent:
February 6, 2024
Assignee:
EXXONMOBIL TECHNOLOGY AND
ENGINEERING COMPANY
Inventors:
Kun Wang, Yi Du, Bradley D. Wooler, Jonathan E. Mitchell, Christine E. Kliewer
Abstract: The present invention is directed to supported catalyst having utility in the polymerization and co-polymerization of epoxide monomers, said supported catalyst having the general Formula (I): [DMCC]*b Supp??(I) wherein: [DMCC] denotes a double metal cyanide complex which comprises a double metal cyanide (DMC) compound, at least one organic complexing agent and a metal salt; Supp denotes a hydrophobic support material; and, b represents the average proportion by weight of said support material, based on the total weight of [DMCC] and Supp, and is preferably in the range 1 wt. %?b?99 wt. %.
Type:
Grant
Filed:
December 16, 2020
Date of Patent:
January 30, 2024
Assignee:
Henkel AG & Co. KGaA
Inventors:
Jan-Erik Damke, Johann Klein, Marion Marquardt, Esteban Mejia, Udo Kragl
Abstract: A steam reforming catalyst that promotes production of hydrogen from a gas containing a hydrocarbon in the presence of steam includes a carrier and two or more catalyst metals supported on the carrier and including a first metal and a second metal. The first metal includes Ni, the second metal includes at least one of Co and Ru, and the carrier is represented by LaNbO4 or La1-xSrxNbO4 where x is in a range of 0<x?0.12.