Abstract: Anti-atherosclerotic agents of the formula: ##STR1## wherein R.sup.1 is (a) alkyl having from 1 to 22 carbon atoms; or(b) of the formula ##STR2## in which m is 0, 1 or 2, and each of R' and R" is, independently, hydrogen, halo or lower alkyl or alkoxy; R.sup.2 and R.sup.3 are joined to form with the silicon atom a heterocyclic ring having from 3 to 20 ring members; and R is an aralkyl-, phenyl- tryptophanyl- or benzocycloalkyl-type radical, eg 1-butyl-N-[(2-(4'-methyl-phenyl)-1-phenylethyl]-1-silacyclohexane propanamide, are obtained by reducing corresponding .alpha.,.beta.-unsaturated analogs.
Abstract: Cationic dyestuffs of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another represent a lower alkyl, alkenyl or hydroxyalkyl radical,R.sub.3 represents H or halogen,R.sub.4 represents H, halogen, or a lower alkyl, alkenyl or alkoxy radical,R.sub.5 represents H or a lower alkyl radical,R.sub.6 represents a lower alkyl, alkenyl, halogenoalkyl, alkoxyalkyl, hydroxyalkyl or cyanoalkyl radical andX.sup.- represents an anion,at least one of the substituents R.sub.3 and R.sub.4 being other than H, are used for dyeing and printing natural and synthetic materials, in particular polyacrylonitrile.
Abstract: Homopolymers and copolymers of compounds according to the formula: ##STR1## wherein R is an alkyl having 1 to 3 carbons, a+b+c+d=e, b=O to e, c=O to e, b+c>1, d=0 to 5, e=1 to 100, and Y is an organic group containing at least one>C.dbd.C<are hydrophilic as well as exhibiting properties similar to silicone compounds. The polymers are particularly useful in contact lenses having enhanced oxygen permeability.
Abstract: The invention provides a novel class of organosilicon compounds which are hydrogenalkenyloxysilanes represented by the general formula ##STR1## in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or a monovalent hydrocarbon group having from 1 to 8 carbon atoms and n is a number of zero, 1 or 2. The silane compounds are readily obtained by the dehydrochlorination reaction between a corresponding hydrogen-containing chlorosilane compound and an .alpha., .beta.-unsaturated aldehyde compound or a ketone compound in the presence of an acid acceptor. The compounds are useful as a modifying agent in the silicone technology and also serve as a curing agent.
Type:
Grant
Filed:
May 20, 1980
Date of Patent:
October 13, 1981
Assignee:
Shin-Etsu Chemical Co. Ltd.
Inventors:
Toshio Takago, Masatoshi Arai, Koji Futatsumori
Abstract: New biscyclohexylamine derivatives represented by the following formula ##STR1## wherein R.sup.1 to R.sup.4 represent identical or different alkyl groups having 1 to 6 carbon atoms;X is a single bond,a divalent aliphatic straight-chain or branched-chain group having from 2 to 10 carbon atoms,a methylene group, when at least one of the substituents R.sup.1 to R.sup.4 has more than 1 carbon atom,a divalent cycloaliphatic group having from 6 to 12 carbon atoms,a divalent aliphatic straight-chain or branched-chain group with cycloaliphatic substituents having from 6 to 8 carbon atoms,a divalent straight-chain or branched-chain dialkyl cyclohexane group having from 8 to 12 carbon atoms and a divalent straight-chain or branched-chain dialkyl benzene group having from 8 to 12 carbon atoms.
Type:
Grant
Filed:
May 5, 1980
Date of Patent:
October 6, 1981
Assignee:
Bayer Aktiengesellschaft
Inventors:
Oskar Weissel, Volker Serini, Hans-Josef Buysch
Abstract: This invention relates to novel 4-oxy-2-substituted-cyclopent-2-en-1-ones of the following general formula: ##STR1## and the optical antipodes, racemic mixtures, and diastereomeric mixtures thereof wherein p is an integer from 2 to 6, inclusive, and J is hydrogen or an appropriate and compatible blocking group such as tetrahydropyranyl or tri(lower alkyl)silyl. Suitable lower alkyl groups contemplated by the present invention are those having up to four carbon atoms such as methyl, ethyl, isopropyl, tert-butyl, etc.
Type:
Grant
Filed:
January 28, 1980
Date of Patent:
October 6, 1981
Assignee:
American Cyanamid Company
Inventors:
Karel F. Bernady, Middleton B. Floyd, Jr., John F. Poletto, Robert E. Schaub, Martin J. Weiss
Abstract: A condensation product from aliphatic or cycloaliphatic polyols, aliphatic saturated or once unsaturated hydroxycarboxylic acids and aliphatic or cycloaliphatic saturated or unsaturated monocarboxylic acids is an effective lubricant for the working of metals, optionally in admixture with other lubricating oils and conventional additives.
Type:
Grant
Filed:
March 6, 1980
Date of Patent:
September 29, 1981
Assignee:
Bayer Aktiengesellschaft
Inventors:
Karl-Heinz Hentschel, Rolf Dhein, Wolfgang Schule
Abstract: In the method of producing 3-chloropropyltrichlorosilane by the addition reaction of trichlorosilane to allyl chloride, [Pt(PPh.sub.3).sub.2 Cl.sub.2 ] is used as the catalyst for the reaction.Side reactions are suppressed to give a high yield of the product.
Abstract: Disclosed is 2 and a process for its preparation: ##STR1## It is useful in the synthesis of N-formimidoyl thienamycin; R.sup.2 is hydrogen or a protecting group.
Type:
Grant
Filed:
June 25, 1980
Date of Patent:
September 29, 1981
Assignee:
Merck & Co., Inc.
Inventors:
Thomas M. H. Liu, Robert A. Reamer, Ichiro Shinkai, Meyer Sletzinger
Abstract: A process for the addition of Si-bonded hydrogen to an aliphatic multiple bond in the presence of a platinum catalyst which is obtained by dissolving a platinum halide in at least 20 parts by weight of olefin for each part by weight of the platinum halide, and subsequently heating and mixing the solution obtained with from 0.5 to 1 mole of a primary and/or secondary amine for each gram atom of platinum.
Type:
Grant
Filed:
November 10, 1980
Date of Patent:
September 29, 1981
Assignee:
Wacker-Chemie GmbH
Inventors:
Tassilo Lindner, Georg Engelsberger, Norbert Zeller, Rudolf Riedle
Abstract: A process of producing tetramethyldisilane by reacting tetramethyldichlorodisilane with a reducing mixture of NaH and NaBH.sub.4 in the presence of a complexing ether such as the diethyl ether of tetraethylene glycol.
Abstract: Indanyloxy compounds having 2-alkynyl substituents which exhibit diuretic, saluretic, and uricosuric activity are described. The compounds are obtained according to a process involving selective etherification of a 5-hydroxyindanone followed by alkynylation with a silylated alkynyl bromide to provide novel silylated intermediates which are hydrolyzed to indanyloxy compounds such as (6,7-dichloro-1-oxo-2-phenyl-2-propargyl-5-indanyloxy)acetic acid.
Abstract: 1,2 Dichloro-1,1,2,2-tetramethyldisilane is synthesized in high yield and good purity starting from a crude mixture of chloromethyldisilanes formed as by-products in the manufacture of silicones. The new method uses less than half as much Grignard reagent as previous methods required. The synthesis can also be used to produce other haloalkyldisilanes such as chloropentamethyldisilane or 1,1,2 trichloro-1,2,2-trimethyldisilane.
Abstract: The present invention relates to a variety of silicone diffusion pump fluids which are inexpensive to produce. An example of a preferred diffusion pump fluid of the present case is one of the formula, ##STR1## where .phi. is phenyl and such that the fluid boils at 245.degree. C. at 1.5 mm. of Hg pressure. The present invention also has within its scope a process for producing such silicone diffusion pump fluids by hydrolyzing the appropriate chlorosilanes by a reverse hydrolysis procedure, that is, adding the appropriate amount of water to the mixture of chlorosilanes.
Abstract: Molybdenum-containing compositions prepared by reacting an olefinically unsaturated compound capable of reacting with active sulfur with a composition prepared by reacting:(a) a phosphorus-containing acid represented by the formula: ##STR1## wherein each X and X' is independently oxygen or sulfur, each n is zero or one and each R is independently the same or a different hydrocarbon-based radical; and(b) at least one hexavalent molybdenum oxide compound, and(c) hydrogen sulfide,in the presence of (d) a polar solvent are useful as additives for lubricants. Internal combustion engines, especially gasoline engines, when lubricated by said additive-containing lubricants exhibit improved fuel economy.
Abstract: Process for the preparation of tetraalkylorthosilicates which comprises contacting alkanol and dimethylamine with copper-activated silicon, followed by adding alkanol to the resultant silane mixture.
Type:
Grant
Filed:
June 30, 1980
Date of Patent:
September 15, 1981
Assignee:
Union Carbide Corporation
Inventors:
William B. Herdle, Bernard Kanner, Donald L. Bailey
Abstract: The invention provides a novel class of organosilane compounds having a glycidyloxy group and one or more of alkenyloxy groups bonded to the silicon atom as represented by the general formula ##STR1## in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or a monovalent hydrocarbon group having from 1 to 8 carbon atoms, m is an integer of 3, 4 or 5 and n is a number of zero, 1 or 2. The organosilane compound, e.g. 3-glycidyloxypropyl-containing alkenyloxysilanes can be readily prepared by the addition reaction of glycidyl allyl ether and a corresponding alkenyloxysilane having a hydrogen atom directly bonded to the silicon atom in the presence of a platinum catalyst. The organosilane compounds are useful as a coupling agent to increase adhesive bonding strength between inorganic and organic materials.
Abstract: Tetraalkyl silicates are produced by the reaction of silicon metal with an alkanol in the presence of an alkali metal salt of an alkoxyalkoxy alcohol or a polyalkylene glycol in either an alkoxyalkoxy alcohol or a polyalkylene glycol or mixtures thereof and recovery of the product. Tetramethyl silicate and tetraethyl silicate are the preferred products. The preferred alkoxyalkoxy alcohol is 2-(2-butoxyethoxy)ethanol. The preferred glycol is diethylene glycol. An indifferent solvent and/or a hydroxide-scavenger may be employed in the reaction mixture.
Abstract: A method for producing silanol chain-stopped fluoroalkyl polysiloxane fluids is disclosed. Fluoroalkyl substituted cyclic trisiloxanes are reacted with water, a catalyst and a polyethyleneglycol ether promoter to produce a fluorosilicone polymer of the desired molecular weight and viscosity.