Abstract: The invention relates to a photolytic interface and its use in series between a High Pressure Liquid Chromatograph (HPLC) and a chemiluminescence detector for the detection of trace (nanogram) amounts of N-nitroso compounds including N-nitrosamides and non-volatile N-nitrosamines in aqueous-based fluid samples. HPLC effluent containing separated N-nitrosoamino acids and N-nitrosoamino amides is introduced into a glass coil with a purge stream of He and irradiated with ultraviolet light. Nitric oxide cleaved by photolysis is rapidly separated from solvent through a series of cold traps and carried by the He into the reaction chamber of a chemiluminescence detector. Biological matrices, such as urine and gastric fluid, can be analyzed directly at high sensitivity without concentration and/or extraction.

Abstract: In a rotary-grate gas producer operated under a pressure from 10 to 100 bars, the fuel constitutes a fixed bed, which slow descends. The mixture of gasifying agents contains water vapor and oxygen is supplied to the fixed bed through a rotary grate and through an ash layer, which is disposed on the rotary grate. In order to ensure that the ash will have a particle size in a desired range, a first pressure (p1) is measured below the rotary grate and a second pressure (p2) is measured approximately at the top of the ash layer. The pressure difference (p1-p2) is compared with a setpoint, which is associated with the current ratio of water vapor to oxygen in the mixture of gasifying agent. Said ratio is increased when the pressure difference is insufficient and the ratio is decreased if the pressure difference is excessive.

Abstract: An apparatus for producing phosphoric acid by the recovery of P.sub.2 O.sub.5 from a phosphate ore is disclosed. A slurry of a phosphate ore in an aqueous phosphoric acid solution is formed in each of a plurality of reaction zones connected in series. Phosphate ore is introduced into the first reaction zone and phosphoric acid into the last reaction zone whereby the reaction of the phosphoric acid with the ore forms a slurry of coarse solids, fine solids and monocalcium phosphate in the phosphoric acid solution. A first process stream comprising coarse solids is removed from the first reaction zone and each of the other reaction zones and is tranferred to the adjacent, successive reaction zone.

Abstract: A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

Abstract: A recycle conduit insulation assembly for use with a helical recycle conduit of a rotary reactor of the type having a rotating, horizontally-oriented, cylindrical chamber for burning materials therein and a quantity of particulate, inorganic material within the chamber for conveying heat energy to material to be burned. The insulation assembly includes a plurality of shell elements, each comprising a cylinder enclosing a portion of the conduit and being arranged in overlapping relation, a plurality of mounting rings, each attached to and extending radially from the conduit and having a T-shape in section for supporting the shell elements at ends thereof, and a pumpable refractory mixture substantially filling the insulating space between the shell elements and conduit.

Abstract: A coal gasification apparatus using coal powder supplies coal powder, along with oxygen or air and steam, into a reaction chamber, supplies the char produced in the reaction chamber or the char and coal, along with oxygen or air and steam into a combustion chamber formed in the lower part of the reaction chamber and burns the same in the combustion chamber to maintain the temperature therein at about 1,600.degree. C., and forms the temperature region of the reaction chamber into an agglomerated bed of fluidized coal having a temperature between 900.degree. and 1,300.degree. C.

Abstract: A method and an apparatus for producing generator gas and activated carbon from solid fuels. A first gasification stage is supplied with fuel by an underfeed charging system and preheated air, the air and fuel being supplied in the same direction. In a second gasification stage and accompanied by the supply of secondary air, an intermediate gasification takes place. Finally, in a third gasification stage, the gas is reacted with glowing coke or charcoal, and the heat of the exiting gas is used for heating the air. The fuel centrally entering the first gasification stage is led from the inside to the outside and then upwards. Part of the entering fuel is precombusted in a precombustion chamber linked with the supply of the preheated air for reducing the oxygen content of the preheated air. In the intermediate gasification stage, the gas with the admixed air is passed through a Venturi nozzle or tube with a diffuser.

Abstract: This process pertains to a achieving high on-stream time and maintaining the temperature and composition of the raw effluent gas stream from a partial oxidation gas generator being fed simultaneously with a stream of gaseous fuel and separate stream of liquid hydrocarbonaceous fuel. Two parallel oxygen streams equipped with flow transmitters and control valves are used to supply the oxygen associated with two separate and different fuel streams. Each stream of oxygen is controlled by an O.sub.2 /fuel ratio control so that if the flow rate of either stream of fuel or its related oxygen stream changes, the oxygen/carbon atomic ratio of the remaining O.sub.2 and fuel stream in the gasifier is maintained at a desired value. Further, if either fuel flow is stopped, its associated O.sub.2 flow will stop, but the remaining fuel stream and its associated O.sub.2 stream will continue to flow at the same rate with no change in the oxygen/fuel weight ratio. Complete shut down of the unit is thereby avoided.

Abstract: A method and device are provided for producing synthetic gas by combustion of a fuel in a combustive agent deficient atmosphere, said combustive agent being gaseous, said device including first means for feeding the fuel and a part of the combustive gas into the reactor, and second means for feeding a second part of the combustive gas into the reactor, said second means including a porous wall defining at least a part of said reactor.

Abstract: Organic aromatic compounds are alkylated in a Reactive Distillation.TM. reactor, wherein the solid particulate catalyst is slurried in the aromatic feed stream and fed to a reaction zone containing inert distillation packing. Olefin is vaporized and fed to the bottom of the reaction zone and agitates the catalyst while reacting the olefin with the aromatic to form an alkylation product. The alkylation product is removed from the lower end of the reaction zone and recovered. Any unreacted aromatic is distilled overhead and recycled or recovered. Recycling the aromatic controls the molar ratio of aromatic to olefin to the extent that substantially all of the olefin is reacted.

Abstract: A device for mixing and dispensing pasty masses comprises a container 10 ing two parallel compartments 12, 13 for accommodating two components which react with each other and an opening 14 including two concentric spaces 15, 18 each communicating with a respective one of the compartments 12, 13. A static mixer 11 is screwed onto the container opening 14 and includes a sleeve-like separator 24 at its entrance end. In the assembled state, the separator 14 is sealingly contiguous with a cylindrical partition 16 which separates the two spaces 15, 18 of the container opening 14 from each other. The location where the two components are combined is thus axially spaced from the location where the component strings are interrupted upon removal of the mixer 11, so that clogging of the container 10 caused by mutual carry-over of the components is prevented.

Abstract: An apparatus for the production of hot pressurized coal gas for use, for example, in power generation is provided. The apparatus includes a step of subjecting coal fuel to staged slagging combustion, to generate raw gas and liquid slag. The liquid slag is separated from the raw gas, and the raw gas is then subjected to a mixing and separation procedure, wherein it is treated and cleaned, for exampe of sulfur dioxide content. The raw gases may then be further treated and utilized to advantage in power generation. A preferred arrangement for conducting the process is also described.

Abstract: A flow reactor for simulating the interaction in the troposphere is set forth. A first reactant mixed with a carrier gas is delivered from a pump and flows through a duct having louvers therein. The louvers straighten out the flow, reduce turbulence and provide laminar flow discharge from the duct. A second reactant delivered from a source through a pump is input into the flowing stream, the second reactant being diffused through a plurality of small diffusion tubes to avoid disturbing the laminar flow. The commingled first and second reactants in the carrier gas are then directed along an elongate duct where the walls are spaced away from the flow of reactants to avoid wall interference, disturbance or turbulence arising from the walls. A probe connected with a measuring device can be inserted through various sampling ports in the second duct to complete measurements of the first and second reactants and the product of their reaction at selected XYZ locations relative to the flowing system.

Abstract: In plant for the production of alkylated resins from an alcohol of boiling point greater than 100.degree. C. at atmospheric pressure, comprising an alkylation reactor, a distillation column, a condenser, and a separator, structure is provided to ensure that contact between descending alcohol-rich liquid phase and the vapor stream of alcohol and water ascending from the reactor is confined essentially to the walls of the column.

Abstract: Toxic refractory organic substances are decomposed by exposing them to an oxidizing medium and steam at a temperature in the range of 2500.degree. F. to 3200.degree. F. for a period of 5 to 500 milliseconds in a reaction chamber. The toxic refractory organic substance can be dioxins, polyhalogenated byphenyls, organophosphates, halogenated biocides, waste streams from the production of said toxic substances, and mixtures thereof.

Abstract: The invention relates to a means for heating the charge of a catalytic reforming unit operating under low pressure.The invention more particularly relates to an apparatus having in combination a first heat exchanger (6), in which a recycling gas/liquid charge mixture introduced by pipe (5) is completely vaporized, and a second exchanger (9) in which the charge is heated to an adequate temperature by indirect contact with reforming effluent delivered by pipe (17), which successively passes through the two heat exchangers.

Abstract: Provided is a process for preparing a homogeneous fluoride glass containing high purity BaF.sub.2 through the CVD process characterized in that the used gaseous mixture comprising: a barium .beta.-diketonate complex serving as a first starting material and represented by the following general formula (1) of: ##STR1## wherein R is an alkyl group having 1 to 7 carbon atoms, R' is a substituted alkyl group having fluorine atoms substituting hydrogen atoms and represented by C.sub.n F.sub.2n+1 where n is an integer of from 1 to 3;a gaseous or vaporizable compound of the metallic element constituting said fluoride glass, the gaseous or vaporizable compound serving as a second starting material; and a fluorine-containing gas serving as fluorinating agent.

Abstract: The present invention is directed to a system which effectively integrates a two-stage, fixed-bed coal gasification arrangement with hot fuel gas desulfurization of a first stream of fuel gas from a lower stage of the two-stage gasifier and the removal of sulfur from the sulfur sorbent regeneration gas utilized in the fuel-gas desulfurization process by burning a second stream of fuel gas from the upper stage of the gasifier in a combustion device in the presence of calcium-containing material. The second stream of fuel gas is taken from above the fixed bed in the coal gasifier and is laden with ammonia, tar and sulfur values. This second stream of fuel gas is burned in the presence of excess air to provide heat energy sufficient to effect a calcium-sulfur compound forming reaction between the calcium-containing material and sulfur values carried by the regeneration gas and the second stream of fuel gas.

Abstract: A carbon black reactor having an extended reaction choke substantially reduces the presence of coke and refractory grit in the carbon black product and erosion of the carbon black reactor due to impingement of particles of forming carbon black within the reactor. The carbon black reactor generally comprises a reaction choke which extends into an exit chamber to an outlet opening within the exit chamber. Hot gas and particles of forming carbon black flow through the reaction choke, through the outlet opening into the exit chamber. The outlet opening of the reaction choke is located within the exit chamber sufficiently distal from the upstream end of the exit chamber to substantially eliminate impingement of the particles of forming carbon black against the upsteam end of the exit chamber.

Abstract: A process is disclosed for allothermic gasification of coal under pressure with water vapor in a gas generator containing heat-exchange tubes for a heat transfer medium. The hot heat transfer medium that enters the gas generator by the heat-exchange tubes is first introduced in the gasification zone, then in the pyrolysis zone. The coal to be gasified flows counter-currently through the gas generator, so that the current of cooled heat transfer medium is used for heating and pyrolyzing the coal, whereas the heat for gasification is taken from the current of the still hot heat transfer medium. Gas generators vertically or horizontally arranged with fitting designs are used for implementation of the process.