Abstract: A process for converting waste plastic into oil includes: subjecting the waste plastic to be in contact with a plurality of far-infrared ray heating rods in a reactor which contains an agitator configured to distribute the waste plastic; converting the waste plastic into a liquid form resultant decomposition by thermal decomposition and pyrolysis in the reactor; fractionating the resultant decomposition product to obtain gas, light oil, and crude diesel oil; obtaining a sludge from a bottom portion of the reactor and transferring the sludge to a blending tank; transferring the light oil to the blending tank; mixing the sludge and the light oil using a high-speed shearing machine to produce a sludge and light oil mixture; transferring the sludge and light oil mixture to a homogenizer; and blending the sludge and light oil mixture at the homogenizer to form a blended oil.
Abstract: The present invention provides a process of catalytic depolymerization of polystyrene involving a spherical catalyst, an apparatus for carrying out the depolymerization, recovering the aromatic rich liquid product and recycling the catalyst without any decrease in the catalytic performance. Further, the present invention provides that the aromatic rich liquid product includes styrene, xylene, benzene, ethyl benzene, with styrene content greater than 65%. Additionally, the catalyst involved in the depolymerization process is a spherical catalyst that is easily recovered from coke/char formed during the process and is recycled and reused without any decrease in the catalytic performance.
Abstract: Disclosed in the present invention are a pressure equalizing system for air separation purification, and a control method. The system comprises: a first air main pipe; a pressurizing gas pipeline, which is connected to the first air main pipe and used for receiving a pressurizing gas and delivering same to the first air main pipe; and a control valve, located on the pressurizing gas pipeline, and having a degree of opening regulated by the flow regulator, thereby regulating an air intake amount of the pressurizing gas pipeline.
Type:
Grant
Filed:
October 28, 2020
Date of Patent:
March 28, 2023
Assignee:
L'Air Liquide, Societe Anonyme Por L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: The invention relates to a process for preparing methyl mercaptan from a mixture of carbon oxide, hydrogen sulfide and hydrogen, in the presence of a catalyst based on molybdenum and potassium supported on zirconia, said catalyst not comprising any promoter.
Type:
Grant
Filed:
December 20, 2018
Date of Patent:
March 21, 2023
Assignees:
Arkema France, Universite Lille 1-Sciences et Technologies, Centre National de la Recherche Scientifique (CNRS)
Inventors:
Georges Frémy, Hélori Salembier, Carole Lamonier, Pascal Blanchard
Abstract: The invention relates to a method (200-400) for extracting pure helium using a first membrane separation stage (1), a second membrane separation stage (2), and a third membrane separation stage (3), in which a first helium-containing feed mixture is supplied to the first membrane separation stage (1), a second helium-containing feed mixture is supplied to the second membrane separation stage (2), and a third helium-containing feed mixture is supplied to the third membrane separation stage (3), and in which a first permeate and a first retentate are formed in the first membrane separation stage (1), a second permeate and a second retentate are formed in the second membrane separation stage (2), and a third permeate and a third retentate are formed in the third membrane separation stage (3).
Type:
Grant
Filed:
January 10, 2019
Date of Patent:
March 21, 2023
Assignee:
Linde GmbH
Inventors:
Tobias Keller, Martin Bauer, Patrick Schiffmann
Abstract: In accordance with one or more embodiments of the present disclosure, a multi-stage process for upgrading pyrolysis oil comprising polyaromatic compounds to benzene, toluene, ethylbenzene, and xylenes (BTEX) includes upgrading the pyrolysis oil in a slurry-phase reactor zone to produce intermediate products, wherein the slurry-phase reactor zone comprises a mixed metal oxide catalyst; and hydrocracking the intermediate products in a fixed-bed reactor zone to produce the BTEX, wherein the fixed-bed reactor zone comprises a mesoporous zeolite-supported metal catalyst.
Type:
Grant
Filed:
November 5, 2021
Date of Patent:
March 14, 2023
Assignee:
Saudi Arabian Oil Company
Inventors:
Miao Sun, Sohel K. Shaikh, Ibrahim A. Abba, Noor Al-Mana, Ke Zhang, Zhonglin Zhang
Abstract: A method for producing a bio-jet fuel includes a reaction step of hydrogenating, isomerizing, and decomposing a crude oil obtained by a deoxygenation treatment of a raw oil containing a triglyceride and/or a free fatty acid, by using a hydrogenation catalyst and an isomerization catalyst in a hydrogen atmosphere under conditions of a reaction temperature of 180° C. to 350° C. and a pressure of 0.1 MPa to 30 MPa.
Type:
Grant
Filed:
May 17, 2019
Date of Patent:
March 14, 2023
Assignees:
HIBD LABORATORY ASSOCIATION, ENVIRONMENT ENERGY CO., LTD.
Abstract: A process for the treatment of a light naphtha feedstock that comprises normal paraffins and iso-paraffins may include separating the feedstock into a first iso-paraffin stream and a normal paraffin stream. The separating may be performed with 5A molecular sieves, a pressure of about 1-3 bars, and a temperature of 100-260° C. A product stream may be provided by subjecting the normal paraffin stream to at least one of steam cracking, isomerizing, and aromatizing.
Abstract: According to embodiment, a carbon dioxide capturing system cools a regenerator discharge gas discharged from a regenerator 5 containing carbon dioxide by a cooling unit 8, and then sends the gas to a cleaner 9. The cleaner 9 receives condensed water generated from the regenerator discharge gas cooled by the cooler 9, and a gaseous cooled regenerator discharge gas, and cleans the cooled regenerator discharge gas by a cleaning liquid. The cleaner 9 has a first liquid reservoir 9b configured to store the condensed water, and a second liquid reservoir 9c configured to store the cleaning liquid having cleaned the cooled regenerator discharge gas.
Abstract: Disclosed herein are a calcium salts-supported metal catalyst, a method for preparing the same, and a method for the hydrodeoxygenation reaction of oxygenates using the same. The catalyst, in which a metal catalyst is supported on a carrier of a calcium salt, for example, calcium carbonate, has the effect of increasing the efficiency of hydrodeoxygenation reaction of oxygenates.
Type:
Grant
Filed:
February 11, 2021
Date of Patent:
February 21, 2023
Assignee:
KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
Inventors:
Jeong-Myeong Ha, Adid Adep Dwiatmoko, Jae Wook Choi, Dong Jin Suh, Jungho Jae, Young Hyun Yoon, Kwang Ho Kim
Abstract: In accordance with one or more embodiments of the present disclosure, a multi-stage process for upgrading pyrolysis oil comprising polyaromatic compounds to benzene, toluene, ethylbenzene, and xylenes (BTEX) includes upgrading the pyrolysis oil in a slurry-phase reactor zone to produce intermediate products, wherein the slurry-phase reactor zone comprises a mixed metal oxide catalyst; and hydrocracking the intermediate products in a fixed-bed reactor zone to produce the BTEX, wherein the fixed-bed reactor zone comprises a mesoporous zeolite-supported metal catalyst.
Type:
Grant
Filed:
November 5, 2021
Date of Patent:
February 14, 2023
Assignee:
Saudi Arabian Oil Company
Inventors:
Miao Sun, Sohel K. Shaikh, Ibrahim A. Abba, Noor Al-Mana, Ke Zhang, Zhonglin Zhang
Abstract: Methods of sequestering CO2 from a gaseous source of CO2 are provided. Aspects of the methods include employing an alkali enrichment protocol, such as a membrane mediated alkali enrichment protocol, in a CO2 sequestration protocol. Also provided are systems for practicing the methods.
Type:
Grant
Filed:
December 18, 2020
Date of Patent:
February 14, 2023
Assignee:
Blue Planet Systems Corporation
Inventors:
Brent R. Constantz, Chris L. Camire, Jacob Schneider, Mark Bewernitz
Abstract: Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally pyrolysis wax comprising a naphtha/diesel fraction and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC feed pretreater unit. A heavy fraction is recovered and sent to a refinery FCC unit, from which a C3 olefin/paraffin mixture fraction is recovered, which is passed to a steam cracker for ethylene production. In another embodiment, a propane fraction (C3) is recovered from a propane/propylene splitter and passed to the steam cracker.
Abstract: Systems and processes herein improve the conversion of propylene to ethylene via metathesis. On a mass basis, embodiments herein may be used to convert greater than 40% propylene, on a mass basis, to ethylene, such as 43% to 75%, on a mass basis. In one aspect, processes for the conversion of propylene to ethylene herein may include introducing a propylene feed stream to a metathesis reactor, and contacting the propylene with a metathesis catalyst in the metathesis reactor to convert the propylene to ethylene and 2-butene. An effluent from the metathesis reactor may be recovered, the effluent including ethylene, 2-butene, and unconverted propylene. The effluent may then be separated in a fractionation system to recover an ethylene fraction, a propylene fraction, a c4 fraction, and a C5+ fraction. The propylene fraction and the C4 fraction may then be fed to the metathesis reactor to produce additional ethylene.
Abstract: In one embodiment, a carbon dioxide capturing system includes an absorber to absorb CO2 from first gas into lean liquid, and produce rich liquid that is the lean liquid absorbing the CO2 and second gas that is the first gas removing the CO2, and a regenerator to separate third gas including the CO2 from the rich liquid flowing from the absorber, and provide the lean liquid and the third gas. The system further includes a flowmeter to measure a flow rate of the third gas, a liquid level gauge to measure a liquid level of the lean liquid and/or the rich liquid, and a controller to regulate a quantity of heat energy supplied to the regenerator based on the flow rate of the third gas, and regulate a total amount of the lean liquid and the rich liquid in the system based on the liquid level.
Type:
Grant
Filed:
July 27, 2020
Date of Patent:
January 24, 2023
Assignees:
KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATION
Abstract: The present invention relates to a process for the conversion of a feedstock comprising at least 50 wt % related to the total weight of the feedstock of triglycerides, fatty acid esters and/or fatty acids having at least 10 carbon atoms into hydrogen, olefins, dienes, aromatics, gasoline, diesel fuel, jet fuel, naphtha and liquefied petroleum gas comprising: a) introducing of said feedstock in a first reactor to produce linear paraffins in presence of a hydrodesulfurization catalyst and hydrogen, b) separating the effluent of said first reactor in at least three parts to produce at least a first stream comprising part of said linear paraffins and at least a second stream comprising part of said linear paraffins, and at least a third stream comprising part of said linear paraffins c) sending said first stream to a steam cracker to produce hydrogen, olefins, dienes, aromatics and gasoline, diesel fuel being further fractionated; d) introducing said second stream into a second reactor in presence of a hydrocr
Abstract: Oxidative dehydrogenation (ODH) of alkanes to alkenes, e.g., propane to propylene, may use solid phase oxygen in VOx based mixed oxide catalysts. Beyond catalysis, the metal oxide species provide lattice oxygen. The catalysts can be prepared by depositing vanadium oxide(s) on ?-Al2O3 mixed with various alkaline earth metal oxide support, e.g., CaO, MgO, BaO, etc. Surface area, acidity, and reduction properties of the catalyst systems can be modified by the support. The catalysts may allow multistage reduction of VOx, indicating different VOx species. Vanadium on ?-Al2O3/CaO can suppress COx species, while vanadium on ?-Al2O3/BaO can yield at least ca. 49% olefins.
Type:
Grant
Filed:
October 15, 2019
Date of Patent:
January 10, 2023
Assignee:
KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
Inventors:
Mohammad Mozahar Hossain, Idris Akolade Bakare, Sagir Adamu
Abstract: Methods for utilizing a supercritical water unit to convert waste plastics to product through hydrothermal treatment in a supercritical unit are provided. Waste plastic is treated in a pretreatment unit, melting the plastic into a liquid and prepares the plastic for the supercritical water unit. The pretreatment unit can dehalogenate the waste plastic. The molten plastic is introduced into a supercritical water unit with water, which generates a product. A flushing stream of product and steam or water from the supercritical water unit is recycled from the supercritical water unit into the pretreatment unit, preheating and pretreating the waste plastic, and acting as a catalyst in the dechlorination reaction. A purge stream removes the products of the dehalogentation reaction occurring in the melting section.
Abstract: Disclosed herein are methods for removing acetylene from an ethylene gas stream wherein a catalyst reacts with the acetylene to polymerize said acetylene forming an ethylene gas stream substantially free of acetylene.
Type:
Grant
Filed:
September 25, 2020
Date of Patent:
January 3, 2023
Assignee:
UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INCORPORATED
Inventors:
Adam S. Veige, Brent S. Sumerlin, Zhihui Miao