Abstract: An integrated process for the production of ether-rich liquid fuels containing MTBE and TAME by etherifying a hydrocarbon feedstock containing C.sub.4 + isoalkenes in the presence of a high stoichiometric excess of lower alkyl alcohol. Unreacted alcohol and olefins are passed to a zeolite catalyzed conversion reactor under olefinic and oxygenates conversion condition whereby gasoline and light hydrocarbons are produced. The light hydrocarbon fraction comprising C.sub.4 -C.sub.5 paraffins is dehydrogenated and C.sub.4 -C.sub.5 olefins are recycled to the etherification reactor.
Abstract: An in-service formulation for the removal of scale deposits from metallic working surfaces of boilers and for the ongoing prevention of build-up of such deposits on boiler surfaces, with such deposits commonly consisting of insoluble salts of calcium together with oxides of iron. The formulation comprises a blend of selected phosphonates, sodium lignosulfonate, one or more scale-modifying polymers, along with one or more chelants. Sodium gluconate is utilized for its ability to inhibit corrosion of ferrous surfaces. The pH of the working solution is adjusted to a level of between about 10.5 to 12.5. The formulation of the present invention provides a significant capacity for the removal of scale while remaining fully compatible with the water present in the system during and after scale removal, and the materials remain effective with contaminants present in the boiler water following a substantial number of cycles of concentration.
Abstract: An in-service formulation for the removal of scale deposits from metallic working surfaces of cooling towers and for the ongoing prevention of build-up of such deposits on cooling tower surfaces, with such deposits commonly consisting of insoluble salts of calcium together with oxides of iron. The formulation comprises a blend of selected phosphonates, one or more scale-modifying polymers, along with one or more chelants. Sodium gluconate is utilized for its ability to inhibit corrosion of ferrous surfaces as well as its synergistic effect in conjunction with other constituents for the removal of scale components (as demonstrated in U.S. Pat. No. 4,279,768). In those systems having non-ferrous metallic surfaces, such surfaces have been found to be adequately protected by the formulation through the incorporation of a triazole inhibitor.
Abstract: A cost effective, efficient thermal insulation composition that will have ng shelf life and withstand severe high temperature and pressure conditions in high temperature solid propellant gas generators can be formed of an ethylene propylene, diene monomer (EPDM)/neoprene rubber binders containing silica powder filler and aramid fibers. The specific chemical constituents include EPDM elastomer, 2 Chlorobutadiene 1,3 elastomer, Silica hydrate, Polymerized Trimethyl Dihydroquinoline, Alkylated Diphenylamines and Diphenyl-p-Phenylendiamene, 40% a,a' Bis (Tert-Butylperoxy), Diisopropylbenzene, Napthenic Process Oil, Synthetic Polyterpene Resin, Aramid Fiber (0.25 inch), and Zinc Oxide, Technical.
Type:
Grant
Filed:
November 30, 1990
Date of Patent:
June 11, 1991
Assignee:
The United States of America as represented by the Secretary of the Navy
Inventors:
Thomas F. Davidson, Guy B. Spear, Timothy L. Ludlow
Abstract: Dispersant viscosity index improvers for lubricating oils contain an EPR or EPT polymer onto which has been graft polymerized with isocyanatoethyl methacrylate and thereafter reacted with N-phenyl-p-phenylene diamine.
Type:
Grant
Filed:
April 23, 1990
Date of Patent:
June 4, 1991
Assignee:
Texaco Inc.
Inventors:
Maria M. Kapuscinski, Thomas F. Derosa, Robert T. Biggs, Theodore E. Nalesnik
Abstract: A structured aqueous detergent composition containing detergent-active material in the form of at least one detergent-active component and at least one electrolyte and having the following phases:(a) an isotropic aqueous solution forming a continuous phase;(b) distributed and suspended in said solution (a) discrete units of one or more non-network-forming phases, each selected from the following:(i) solid particles containing detergent-active material,(ii) lyotropic liquid crystals containing detergent-active material; and(iii) non-encapsulated liquid droplets containing detergent-active material,(c) one or more suspending phases which cause the composition to be structured so as to suspend the non-network-forming phase (b); said non-network-forming phase (b) having a higher concentration by weight of detergent-active material than said aqueous solution (a).
Type:
Grant
Filed:
February 8, 1989
Date of Patent:
June 4, 1991
Assignee:
Lever Brothers Company
Inventors:
David Machin, Appaya Naik, Cornelis Buytenhek, Johannes C. van de Pas
Abstract: A friction reducing additive composition comprising a long chain succinimide derivative and a long chain amide has superior friction reducing properties, especially in wet brake systems for tractors and other vehicles.
Abstract: According to the present invention, oleaginous compositions having improved storage stability properties are provided, which comprise a combination of ashless dispersants, friction modifier and oil-soluble copper antioxidants, wherein the composition is substantially free of boron.
Abstract: Oligomers produced from lower alkenes by acidic zeolite catalyzed oligomerization can be converted to useful lubricant additives or lubricants by acylation of olefinic bonds in the oligomers, whereby oligomers containing alpha, beta unsaturated ketone structures are produced. The products so produced from C.sub.20 + olefins exhibit favorable lubricant qualities of viscosity index and low pour points. The discovery is particularly applicable to the acylation of oligomers produced from lower alkenes such as propylene by oligomerization using a ZSM-5 catalyst which has been surface deactivated.
Abstract: Lubricating oil additives are provided which have extreme pressure, antiwear and antioxidant properties. The additives are dithiophosphorous disymmetric bisulphides of the formula: ##STR1## wherein X and Y represent an oxygen or sulphur atom or a methylene group and R.sub.1 and R.sub.2 and R.sub.3 represent a hydrocarbon radical, a polyether, a polythioether or a hydrogen atom.The invention also relates to a process for their preparation and to lubricating compositions containing the additives.
Abstract: Lubricants are stablized against oxidative degradation by the incorporation therein of hydroxylamines substituted with thioalkanoic acid residues of the formula ##STR1## wherein R and R.sub.1 are independently H, alkyl or aryl, X is independently OR.sub.2 SR.sub.2 or NR.sub.3 R.sub.4 wherein Rhd 2 is H, alkyl, cycloalkyl or aralkyl, and R.sub.3 and R.sub.4 are independently H, alkyl or aryl and n is 1 or 2.
Type:
Grant
Filed:
January 26, 1990
Date of Patent:
May 28, 1991
Assignee:
Ciba-Geigy Corporation
Inventors:
Samuel Evans, David Chasan, Raymond Seltzer
Abstract: Serine-N,N-diacetic acid and derivatives thereof are prepared in various ways and used in particular as complexing agents, bleaching agent stabilizers and builders in detergents.
Type:
Grant
Filed:
August 7, 1990
Date of Patent:
May 28, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Richard Baur, Felix Richter, Stefan Birnbach, Rolf Fikentscher, Alfred Oftring, Ekhard Winkler
Abstract: Ashless hydrogen phosphonate dihydrocarbyl dithiocarbamates have been found to be effective antioxidant/antiwear multifunctional additives for lubricants.
Abstract: A blend of tetrafluoroethane refrigerant with at least one polymer of the following: (a) an acrylic polymer having the formula ##STR1## where R is at least one alkyl group selected from CH.sub.3, C.sub.2 H.sub.5, C.sub.3 H.sub.7 and C.sub.4 H.sub.9 ; andx is an integer from 3 to 20;and (b) random copolymers from at least one alkyl acrylate monomer wherein the alkyl group may be anywhere from CH.sub.3 -- to C.sub.18 H.sub.37 -- provided that the average chain length of the alkyl groups in a major portion of said copolymer contains from 1 to 4 carbon atoms, and, optionally, with at least one other polar or nonpolar vinyl monomer said polymer (homopolymer or copolymer) having an SUS viscosity at 100.degree. F. of at least 50 and a pour point of less than -20.degree. C. is disclosed for use in compression refrigeration.
Abstract: Aqueous-based functional products or corrosive products such as cleansers, household products, commercial products, and personal care products are thickened or viscosity-modified by the addition of at least a small, but effective, amount of at least one crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.a) A.sub.a.sup.n.xH.sub.2 Owhere m is zero to one, D is a divalent metal, d is from zero to 4, T is a trivalent metal, A represents at least one anion or negative-valence radial of valence n, where n is 1 or more, (m+2d+3+n.a) is equal to or greater than 3, (m+d) is greater than zero, and xH.sub.2 O represents excess waters of hydration.
Type:
Grant
Filed:
March 11, 1988
Date of Patent:
May 14, 1991
Assignee:
The Dow Chemical Company
Inventors:
Arthur E. Read, Jr., John L. Burba, III, Peter A. Doty, Clarence R. Crabb
Abstract: A process for the pre-treatment of natural and regenerated cellulosic fibres and blends thereof with synthetic fibres for the purpose of subsequent transfer printing comprises applying to said fibres a composition comprising a mixture of hexamethoxymethyl melamine and a C.sub.4-8 glycol in the presence of water, and drying said fibres at a temperature below 180.degree. C.The above compositions per se, with or without water and polyvinyl chloride or polyvinylidene chloride polymer or copolymer emulsions or dispersions, are also claimed.
Abstract: A heavy duty lubricating grease as shown which includes a multi-purpose heavy duty hydrocarbonaceous lubricant thickened by an alkaline soap to form a lubricating grease, molybdenum disulfide and powdered calcium fluoride. The heavy duty grease can be used in a journal bearing of a drill bit in heavy duty, high temperature applications, such as journal bearings on its used to drill hot subterranean formations.
Abstract: Cyclic phosphazenes completely substituted with fluorinated phenoxy and m-perfluoroalkylphenoxy moieties in ratios ranging from about 1:1 to about 1:5 are disclosed. These compounds, either alone or as additives, are useful as high temperature lubricants.
Abstract: A dispersant/antioxidant bound VII polymethacrylate lubricant additive composition prepared by:(a) reacting a methacrylamide with an amino-alkyl, methacrylamide, an alkyl methacrylate and an oil solvent to provide a intermediate reaction mixture;(b) stirring and purging the reaction mixture;(c) heating the purged mixture and adding a mercaptan and a radical polymerization catalyst to the purged mixture;(d) heating the mixture to a sufficiently high temperature to remove any excess of the polynmerization catalyst therefrom; and(e) recovering the product polymethacrylate.