Abstract: The present invention relates to novel associative thickeners pertaining to the HEUR category (Hydrophobically-modified Ethoxylated URethane), to intermediate aqueous formulations containing such thickeners, and to the final compositions, for example paint, lacquer, varnish or paper coating slip compositions.

Abstract: The present disclosure relates to a method for producing rigid polyurethane foam composite elements, including at least one outer layer and a rigid polyurethane foam layer, by mixing (a) polyisocyanates with (b) compounds having at least two hydrogen atoms reactive with isocyanate groups, (c) optionally flame retardant(s), (d) blowing agent, (e) catalyst, and (f) optionally auxiliaries and adjuvants to form a reaction mixture, applying the reaction mixture to the outer layer, and curing it to form the rigid polyurethane foam. The present disclosure further relates to a rigid polyurethane foam composite element obtainable by such a method.

Abstract: The invention relates to an aqueous dispersion of microcapsules, said microcapsules comprising a hydrophobic core and a polymeric shell wherein said polymeric shell is formed of the reaction product of (i) at least one monofunctional or multifunctional ?,?-unsaturated carbonyl compound, and (ii) at least one nanocellulose or microcrystalline cellulose. The invention also relates to a process for the manufacture of such an aqueous dispersion, as well as consumer products containing an aqueous dispersion of microcapsules according to the invention.

Abstract: An alkylene oxide mixture containing greater than 50% by weight ethylene oxide is continuously polymerized in the presence of a double metal cyanide polymerization catalyst and an alkoxylated initiator having a hydroxyl equivalent weight of up to 200. The catalyst remains active, producing a polyol having an equivalent weight of up to 700 with a high oxyethylene content continuously at fast reaction rates.

Abstract: The invention relates to polycarbodiimides and to a process for their preparation using special catalysts.

Abstract: The present invention relates to a method for bonding substrates of the same or different type using two-component structural adhesives on the basis of aliphatic polyisocyanates and polyaspartic acid esters, and to a two-component structural adhesive, which contains said two components and has a high strength when hardened.

Abstract: A functional resin material is manufactured by the following reagents including a polyol, a polyamine, a first cross-linking agent, a second cross-linking agent, and a nanocellulose. Each of the first cross-linking agent and the second cross-linking agent includes an isocyanate block.

Abstract: A phenol compound comprises a phenyl group, a hydroxy group directly bonded to the phenyl group, and at least one polymeric substituent bound to the phenyl group. The polymeric substituent comprises three or more monomers units. A method for producing a polyurethane polymer comprises the steps of (a) providing a polyol; (b) providing a polyisocyanate compound; (c) providing the phenol compound described above; (d) combining the polyol, the polyisocyanate compound, and the phenol compound to produce a reaction mixture; and (e) allowing the polyol and the polyisocyanate compound to react to produce a polyurethane polymer.

Abstract: A method of producing an alcohol ethoxylate surfactant or lubricant, the method including reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a nominal hydroxyl functionality at least 1, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)I(R2)I(R3)I(R4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R1, R2, R3, and R4 are each independent, R1 includes a first fluoroalkyl-substituted phenyl group, R2 includes a second fluoroalkyl-substituted phenyl group or a first fluoro/chloro-substituted phenyl group, R3 includes a third fluoroalkyl-substituted phenyl group or a second fluoro/chloro-substituted phenyl group, and optional R4 includes a functional group or functional polymer group, R1 being different from at least one of R2 and R3.

Abstract: A ternary composite catalyst of diethylzinc and yttrium trifluoroacetate loaded on chitin for copolymerization of carbon dioxide, epoxy cyclohexane and ethylene oxide is provided. The ternary composite catalyst exhibits strong catalytic activity for the ternary copolymerization of carbon dioxide, cyclohexane oxide and ethylene oxide. A high molecular weight and content of ester chain is maintained. Conventional rare earth ternary catalysts leave residues in the polymer, and the polymer requires rinsing with hydrochloric acid. The ternary composite catalyst can be removed through filtration. The average molecular weight of the resulting polycarbonate is more than 100,000, and the ester chain content is more than 90%. The resulting polymer has a lower metal content. The ternary composite catalyst can be used in agricultural film, disposable packaging and other polymer materials.

Abstract: One embodiment relates to a polymerizable composition and an optical material produced therefrom which has excellent lightfastness and minimized color defects, and more specifically, the polymerizable composition according to one embodiment includes UV absorbers having, as the main absorption wavelength, either a long-wavelength region or a short-Wavelength region Within the UV region, wherein the UV absorbers do not absorb in the Visible light region. Accordingly, the polymerizable composition may be used to provide an optical material having excellent lightfastness and minimized color defects.

Abstract: A method of producing a polyether polyol includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, and the low molecular weight initiator has a nominal hydroxyl functionality of at least 2. The one or more monomers includes at least one selected from propylene oxide and butylene oxide. The polymerization catalyst is a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R1, R2, R3, and R4 are each independent, R1 includes a fluoroalkyl-substituted phenyl group, R2 incudes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, R3 includes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, and optional R4 includes a functional group or functional polymer group, R1 being different from at least one of R2 and R3.

Abstract: The present invention is directed to a polyisocyanate polyaddition product, obtained or obtainable according to a process containing reacting at least a polyisocyanate composition (C-I) comprising at least one polyisocyanate; and a composition (C-II) comprising at least one compound (C-A) having at least two functional groups which are reactive towards isocyanate groups, wherein the compound (C-A) has a molecular weight of 500 g/mol or more and comprises polycyclic aromatic moieties. The present invention is further directed to a process for preparing said polyisocyanate polyaddition product and the use thereof in a cable, conveyor belt, roller, seal for gasket or railway pad.

Abstract: Embodiments of the present disclosure are directed towards solventless compositions that include a reaction product formed by reacting a polyol and an aminopolycarboxylic compound.

Abstract: A crosslinked polymeric composition comprising A, B, C, D, and E units having the following structures, respectively: and wherein dashed bonds represent optional bonds; the asterisks (*) in C units represent covalent bond connection points with asterisks in A units and E units; the asterisks (*) in D units represent covalent bond connection points with asterisks in B units and E units; wherein a portion of E units are bound to C units, a portion of E units are bound to D units, and a portion of E units are bound to both C and D units; and the composition contains a multiplicity of A, B, C, D, and E units. Also described is a method for producing the crosslinked polymeric composition by reacting epoxy-containing molecules (A molecules), isocyanate-containing molecules (B molecules), and disulfide-containing molecules (C molecules).

Abstract: A two-component polyurethane composition comprising: an aqueous dispersion comprising an emulsion polymer and a specific sulphate and/or sulfonate surfactant, and a water-dispersible polyisocyanate; the emulsion polymer with a weight average molecular weight of 70,000 g/mol or less comprising, by weight based on the weight of the emulsion polymer, greater than 0.25% of structural units of a phosphorous-containing acid monomer and/or salts thereof, greater than 15% of structural units of a hydroxy-functional alkyl (meth)acrylate, structural units of an monoethylenically unsaturated nonionic monomer, and from zero to 10% of structural units of an additional acid monomer and/or salts thereof; and a process of preparing the two-component polyurethane composition.

Abstract: An inventive flexible medical item container comprises a unique adhesive and cohesive viscoelastomeric thermoset polymer. In preferred embodiments, medical items can be repeatedly releasably adhered to and removed from the top side of the container. In addition, the bottom side of the container can be disposed upon and adhered to an object, such as a medical garment, such that the container can be located proximate or adjacent to a medical, dental or hygienic procedure location. In some preferred embodiments, the container further comprises antimicrobial properties. In some preferred embodiments, the container further comprises cleansability properties.

Abstract: The present disclosure relates to methods for making polyols, esters, and surfactants. Generally, a carboxyl-containing molecule is reacted with an epoxide-containing molecule to obtain a hydroxylated ester. If multiple epoxide groups are present in the epoxide-containing molecule, the resulting molecule can also be considered a polyol. The hydroxyl groups can be further ethoxylated to obtain a surfactant/stabilizer.

Abstract: Provided herein is a porous ?-cyclodextrin-containing monolith having a microstructure templated by the external phase of a HIPE, as well as processes of manufacturing the same and uses thereof.

Abstract: The invention provides a polishing pad suitable for polishing at least one of semiconductor, optical, magnetic or electromechanical substrates. The polishing pad includes a polyurea polishing layer and a polyurea matrix. The polyurea matrix has a soft phase and a hard phase. The soft phase is formed from soft segments and the hard phase is formed from diisocyanate hard segments and a curative agent. The soft segment areva copolymer of aliphatic fluorine-free polymer groups and a fluorocarbon having a length of a least six carbons. The polyurea matrix is cured with the curative agent and includes gas or liquid-filled polymeric microelements. The soft segments form a fluorine rich phase that concentrates adjacent the polymeric microelements and at the polishing layer during polishing. The polishing layer remains hydrophilic during polishing in shear conditions.