Patents Examined by Ralph S. Kendall
  • Patent number: 4148969
    Abstract: This invention relates to processes and techniques for forming metal and/or plastic/polyparabanic acid (PPA) laminates particularly for use as a component of electrical and electronic systems, especially as flexible circuit materials. Laminate species not requiring intermediate adhesive layers, not fabricated from preformed PPA films and not requiring subsequent cross-linking or other curing reactions are preferred. Solvent casting of PPA is a preferred method of preparing such laminates.
    Type: Grant
    Filed: September 12, 1977
    Date of Patent: April 10, 1979
    Assignee: Exxon Research & Engineering Co.
    Inventor: Don J. Henderson
  • Patent number: 4148946
    Abstract: In a line for coating a ferrous base metal strip with a molten coating metal, the line being of the type having a preparation furnace for the strip comprising a direct fired furnace, a controlled atmosphere heating furnace, one or more cooling chambers and a snout leading beneath the surface of the molten coating metal bath, all in sealed relationship to each other, the improvement comprising a method and means for maintaining a non-oxidizing atmosphere at positive pressure within the entire preparation furnace during line stop. To this end, a retractable, refractory lined door means is provided in the conduit between the direct fired furnace and its exhaust fan to seal off the direct fired furnace from its exhaust fan and an air dilution opening in that conduit. Additionally, means are provided to add excess nitrogen flow to the preparation furnace to maintain a positive pressure therein.
    Type: Grant
    Filed: February 14, 1977
    Date of Patent: April 10, 1979
    Assignee: Armco Steel Corporation
    Inventors: Fred Byrd, James A. Fisher
  • Patent number: 4147567
    Abstract: Water-soluble lignosulphonate salts when present in an acid metal phosphating solution modify the physical form of sludge produced therein when the solution is used to treat a metal substrate. Process efficiency is improved.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: April 3, 1979
    Assignee: Imperial Chemical Industries Limited
    Inventors: Michael Brock, Brian A. Cooke
  • Patent number: 4147566
    Abstract: The specification discloses a rust converting paint which may either be of an all solvent type, or a cross blend between a solvent based and a water based paint, in either case having an acid pH and consisting essentially of, a solvent based resin, alcohols and phosphoric acid in an amount sufficient to act as a rust remover, converter and inhibitor. The maximum amount of acid varies with the other components of the paint. The cross-blend paint will also contain water and hydrocarbons. Coloring matter and opacity elements are optional in either version.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: April 3, 1979
    Inventor: Clarence E. Leonard
  • Patent number: 4146410
    Abstract: A composition, and method for using the composition in applying a conversion coating on aluminum and aluminum alloy surfaces, is disclosed. In the method of this invention an aluminum containing metal surface is contacted with a ferricyanide free aqueous acidic solution containing zinc, hexavalent chromium, fluoride, and molybdate ions. The coated metal surface shows inhanced resistance to corrosion and improved paint adhesion. The absence of ferricyanide in the composition promotes easier disposal of the spent solutions.
    Type: Grant
    Filed: March 2, 1977
    Date of Patent: March 27, 1979
    Assignee: Amchem Products, Inc.
    Inventor: Earl R. Reinhold
  • Patent number: 4146657
    Abstract: Electrically-conductive films of tin oxide are prepared by a novel process utilizing gaseous chemical compounds which react to form a tin-fluorine bond at a temperature which is (1) high enough so that the newly-created tin-fluorine bond-bearing molecule remains in the vapor phase; and (2) low enough so that oxidation of the molecule occurs only after the indicated re-arrangement. Films prepared by the process of the invention are characterized by surface resistances as low as 1 ohm per square when the film thickness is as thin as about a micron. These films are also characterized by extremely good reflectance of infrared radiation.
    Type: Grant
    Filed: November 1, 1976
    Date of Patent: March 27, 1979
    Inventor: Roy G. Gordon
  • Patent number: 4146659
    Abstract: Fuser members having surfaces of gold and the platinum groups metals and alloys thereof are described for fuser assemblies in office copier machines. Preferred fuser assemblies include cylindrical rolls having at least an outer surface of gold, a platinum group metal or alloys thereof. Electroscopic thermoplastic resin toner images are fused to a substrate by using a bare gold, a platinum group metal or alloys thereof fuser member coated with polymeric release agents having reactive functional groups for example, a mercapto-functional polysiloxane release fluid.
    Type: Grant
    Filed: December 23, 1976
    Date of Patent: March 27, 1979
    Assignee: Xerox Corporation
    Inventors: Joseph A. Swift, Arthur C. Martellock
  • Patent number: 4145234
    Abstract: To provide a substrate of aluminum with a dark surface layer of high absorption/emission ratio for luminous energy, the degreased and pickled substrate is immersed in a hot chromating bath until an oxide coating of not more than 2.5.mu. thickness is formed thereon. This coating is then colored black in a hot, acidic dyeing solution (pH between about 0.5 and 5) of potassium permanganate and a nitrate of cobalt or copper.
    Type: Grant
    Filed: March 1, 1978
    Date of Patent: March 20, 1979
    Assignee: Vereinigte Metallwerke Ranshofen-Berndorf Aktiengesellschaft
    Inventor: Herbert Meissner
  • Patent number: 4143184
    Abstract: Steel strip is first heated to a predetermined temperature suitable for imparting desired properties to the strip and is then immersed in an aqueous bath maintained at substantially its boiling temperature. The composition of the aqueous bath is preferably adjusted to ensure the formation of an oxide film on the entire surface of the strip. After the strip has been withdrawn from the bath, oxide is eliminated from at least part of the surface of the strip, e.g., from one or both faces, by removal of the oxide or by reduction of the oxide. Simultaneously or subsequently, the strip is heated to a given temperature, e.g., 420.degree.-550.degree. C., maintained at this temperature, and immersed at this temperature in molten zinc.
    Type: Grant
    Filed: March 30, 1977
    Date of Patent: March 6, 1979
    Assignee: Centre de Recherche Metallurgiques-Centrum voor Research in de Metallurgie
    Inventors: Philippe Paulus, Marios Economopoulos
  • Patent number: 4142917
    Abstract: An improved process for forming a zinc phosphate coating on a zinc surface comprises contacting the surface with an aqueous nitrate and ammonia-free solution containing zinc, phosphate, nickel or cobalt, and hydrogen peroxide.
    Type: Grant
    Filed: September 26, 1977
    Date of Patent: March 6, 1979
    Assignee: Oxy Metal Industries Corporation
    Inventors: Kuniji Yashiro, Shigeki Saida, Yoshihide Sano
  • Patent number: 4141758
    Abstract: In a process for producing a chromium protective coating on a zinc/iron alloy surface the surface has applied thereto an aqueous composition including chromium, perchlorate and fluoride ions with the chromium ion being the only metal ion present before application to the surface.
    Type: Grant
    Filed: May 3, 1977
    Date of Patent: February 27, 1979
    Assignee: Dominion Foundries and Steel, Limited
    Inventors: Wayne C. Glassman, Sydney H. Melbourne, Mary S. Morson, Urmas Soomet
  • Patent number: 4142011
    Abstract: A method of producing coatings of copper alloys in hot-dip process on workpieces made of ferrous alloys comprising dipping the workpieces to be coated into baths of molten alloys of Cu with Si, Sn, Al, P, In, Ca, Be, having a temperature within the range of 700.degree.-1100.degree. C., with a single-stage or a two-stage movement, the workpieces then being held in the bath for from 15 seconds to 60 minutes and taken out of the bath and cooled at any desirable rate.
    Type: Grant
    Filed: August 11, 1976
    Date of Patent: February 27, 1979
    Assignee: Politechnika Slaska im. Wincentego Pstrowskiego
    Inventors: Adam Gierek, Lech Bajka, Malgorzata Machnicka
  • Patent number: 4141760
    Abstract: Aluminum diffusion can be effected from continuous coatings of leafing-type aluminum particles and such leafing coatings in very thin layers are more effective than coatings of non-leafing aluminum, with or without diffusion. Other protective metals in flake or leaf form can be substituted for or added to the leafing aluminum. Adhesion of the flakes to the substrate is greatly improved and can be effected at lower temperatures if the flakes are applied from a dispersion containing a volatilizable halogen-type carrier or an ammonium chromate. The leafing coatings can be sprayed on from aqueous dispersion containing wetting agents and if desired a polyethylenetrtrafluoroethylene and/or mixtures of phosphoric acid, chromic acid and magnesium, aluminum, calcium or zinc salts of these acids.
    Type: Grant
    Filed: September 19, 1975
    Date of Patent: February 27, 1979
    Assignee: Alloy Surfaces Company, Inc.
    Inventor: Alfonso L. Baldi
  • Patent number: 4140821
    Abstract: A process for simultaneously preheating and preparing a ferrous surface, prior to the depositing thereon of galvanized zinc coatings, replaces conventional fluxing techniques with the step of immersing a ferrous object in a bath of a molten salt or salts. The salts are chosen so that they are liquid at a temperature below that of the zinc coating step. The liquid acts as a non-fuming flux and preheat for the surface. Particular salts include metallic hydroxides and halides.
    Type: Grant
    Filed: March 5, 1976
    Date of Patent: February 20, 1979
    Assignee: International Lead Zinc Research Organization, Inc.
    Inventors: Schrade F. Radtke, David C. Pearce
  • Patent number: 4140551
    Abstract: Microcrystalline zinc phosphate coatings and compositions for their formation are provided, which can be applied to metals at low temperatures, the coating compositions containing as principal ingredients a specific balance of calcium and zinc together with phosphates, nitrates, and nitrites. Processes for preparing and using the coating compositions are also provided.
    Type: Grant
    Filed: August 19, 1977
    Date of Patent: February 20, 1979
    Assignee: Heatbath Corporation
    Inventor: William C. Jones
  • Patent number: 4136216
    Abstract: Metallic surfaces are imparted to non-conductive or dielectric substrates by an electroless coating process comprising coating the surface of the substrate with a hydrous oxide colloid of non-precious metal ions preferably selected from the group consisting of cobalt, nickel and copper ions, reducing the selected metal ions to a reduced or zero valence state with a suitable reducing agent, and exposing the substrate to an electroless plating bath.
    Type: Grant
    Filed: October 12, 1976
    Date of Patent: January 23, 1979
    Assignee: Surface Technology, Inc.
    Inventor: Nathan Feldstein
  • Patent number: 4136217
    Abstract: In a continuous process wherein corrosion resistant and paint adherent coatings are formed on metallic articles and wherein prior to the formation of said coatings, the articles are first subjected to a pre-cleaning stage in which oil emulsion is removed from the surfaces of the articles by washing the articles with an aqueous solution of wash water and demulsifier and the removed oil emulsion is broken and the oil recovered, and wherein the articles having the oil emulsion removed from their surfaces are thereafter subjected to a second cleaning stage in which the articles are contacted with a cleaning solution to remove metal fines from the surfaces of the articles, the improvement comprising including a chelating agent in said aqueous solution of wash water and demulsifier to aid in breaking said oil emulsion and to deter or prevent the formation of precipitates in the cleaning solution of said second cleaning stage.
    Type: Grant
    Filed: January 27, 1977
    Date of Patent: January 23, 1979
    Assignee: Amchem Products
    Inventor: Thomas D. Henley
  • Patent number: 4135009
    Abstract: The application discloses a mixture of high molecular weight hard resins, such as polymethyl methacrylate, cellulose acetate butyrate and cellulose nitrate with low molecular weight benzoic acid terminated polyesters having a glass transition temperature in the range of -30.degree. C. to 40.degree. C. and a molecular weight in the range of 500 to 1500. The hard polyesters of this invention are obtained by the use of small diols and hard dibasic acids in addition to termination of the chain by the hardening component benzoic acid. Saturated linear dicarboxylic acids are used for less than half of the acid monomer content, on a molar basis, since these are softening components. The polyesters are used to lower the melting point and improve the flow of the high molecular weight polymers without excessively plasticizing these high molecular weight polymers to the point where they are noticeably softened at use temperatures.
    Type: Grant
    Filed: November 26, 1975
    Date of Patent: January 16, 1979
    Assignee: Rohm and Haas Company
    Inventor: Andrew Mercurio
  • Patent number: 4135013
    Abstract: Equipment used in a substantially water free, but corrosive environment is protected from corrosion by coating only certain welded parts thereof with a metal more base than the metal part coated.
    Type: Grant
    Filed: January 31, 1977
    Date of Patent: January 16, 1979
    Assignee: Nippon Mining Co., Ltd.
    Inventors: Kineo Yamaguchi, Katsuhiko Kawakami
  • Patent number: 4133921
    Abstract: A process for protecting, preserving, and renewing surfaces, especially rubber and other natural and synthetic polymers, leather, wood, painted surfaces and metal. An aqueous emulsion of an unsubstituted or substituted dimethylpolysiloxane fluid, or mixtures thereof, is used to thoroughly wet the surface to be protected. After a period of penetration, preferably about twenty four hours, the surface is rewetted and allowed to penetrate as in the first application. At least one additional application and penetration gives optimum protection.A unique preservative composition preferred for use in the above process is also provided. In addition to a dimethylpolysiloxane fluid aqueous emulsion as above described, the preservative also includes, based on the weight of the polysiloxane fluid, of from about 15% to about 65% by weight of one or more polyol compounds, preferably diethylene glycol and glycerin.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: January 9, 1979
    Assignee: Very Important Products, Inc.
    Inventor: Joseph J. Palcher