Patents Examined by Raymond K. Covington
  • Patent number: 4246180
    Abstract: A process for separating off 1-amino-4-bromoanthraquinone-2-sulphonic acid from the reaction mixture formed by the bromination of 1-aminoanthraquinone-2-sulphonic acid in sulphuric acid, which process comprises adjusting the sulphuric acid concentration of the reaction mixture under the prevailing conditions of temperature and pressure to effect precipitation of 1-amino-4-bromoanthraquinone-2-sulphonic acid as the sulphate and thereafter separating the resultant sulphate precipitate from the reaction mixture.
    Type: Grant
    Filed: August 31, 1978
    Date of Patent: January 20, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinrich Leister, Helmut Dittmer, Hubert Schonhagen
  • Patent number: 4244880
    Abstract: A process for synthesizing the 7-substituted or unsubstituted 5,12-dihydroxy-1,2,3,4,6,11-hexahydro-2,6,11-trioxonaphthacene precursors for doxorubicin and related compounds from butadiene and p-benzoquinone and intermediates useful in the synthesis.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: January 13, 1981
    Assignee: University of Kansas Endowment Association
    Inventors: Jose Alexander, Lester A. Mitscher
  • Patent number: 4243600
    Abstract: A process for the manufacture of 1,4-diaminoanthraquinone-2-carboxylic acid, which comprises reacting 1-nitroanthraquinone-2-carboxylic acid or derivatives thereof with hydroxylamine or derivatives thereof, in alcohol/water mixtures at basic value pH values.
    Type: Grant
    Filed: April 26, 1979
    Date of Patent: January 6, 1981
    Assignee: Ciba-Geigy AG
    Inventor: Athanassios Tzikas
  • Patent number: 4242259
    Abstract: Dyestuffs of the formula ##STR1## wherein D, W, R.sub.1, R.sub.2, R.sub.3, x and D' have the meaning indicated in the description, and their use for dyeing and printing textile materials containing hydroxyl groups and textile materials containing nitrogen, in particular textile materials of natural and regenerated cellulose, and also of wool, silk, and synthetic polyamide and polyurethane fibres. The resulting dyeings are distinguished by good fastness properties.
    Type: Grant
    Filed: March 20, 1979
    Date of Patent: December 30, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Klaus von Oertzen, Klaus Wunderlich
  • Patent number: 4240803
    Abstract: Fuel compositions are provided that contain an alkenylsuccinimide, where the alkenyl is derived from a mixture of C.sub.16 -C.sub.28 olefins.
    Type: Grant
    Filed: September 11, 1978
    Date of Patent: December 23, 1980
    Assignee: Mobil Oil Corporation
    Inventor: Harry J. Andress, Jr.
  • Patent number: 4240804
    Abstract: Disclosed are additives for hydrocarbon fuels which are the reaction products of a polyamine and an alkyl ester of acrylic or alkyl acrylic acid. A preferred composition is a mixture of the reaction product and oxygenated or non-oxygenated mono- or polyamines.
    Type: Grant
    Filed: January 24, 1978
    Date of Patent: December 23, 1980
    Assignee: Sherex Chemical Company, Inc.
    Inventor: Theodore C. Shields
  • Patent number: 4239885
    Abstract: A process is disclosed whereby acrylonitrile and diacetone alcohol are reacted in at least 93% sulfuric acid to form a novel intermediate reaction product which is recovered as a crystalline solid, washed with an organic solvent to remove colored oily impurities along with sulfuric acid, and hydrolyzed to produce diacetone acrylamide, a reactive monomer useful for preparing polymeric components of photographic films and adhesives. The intermediate reaction product is identified as 5,6-dihydro-6-hydroxy-4,4,6-trimethyl-2-vinyl-1,3(4H)-oxazine sulfate (1:1).
    Type: Grant
    Filed: June 28, 1978
    Date of Patent: December 16, 1980
    Assignee: American Cyanamid Company
    Inventor: Henry Richmond
  • Patent number: 4238400
    Abstract: Anthraquinone dyes having the formula: ##STR1## wherein R represents an optionally substituted alkyl, aryl, cycloalkyl, alkoxy, aryloxy or cycloalkoxy radical and each of R.sup.1 and R.sup.2, independently, represents hydrogen or a C.sub.1-4 alkyl radical.The dyes are applicable as acid dyes to natural and synthetic polyamide textiles.
    Type: Grant
    Filed: May 21, 1979
    Date of Patent: December 9, 1980
    Assignee: Imperial Chemical Industries Limited
    Inventor: Michael Yelland
  • Patent number: 4235666
    Abstract: A new industrial product, namely 1,2,3,4,4a,9a-hexahydro-9,10-anthracene-dione, is disclosed together with a process for its preparation and its use in conventional alkali metal hydroxide cook or Kraft cook processes for the delignification of lignocellulose materials.
    Type: Grant
    Filed: June 27, 1979
    Date of Patent: November 25, 1980
    Assignee: Produits Chimiques Ugine Kuhlmann
    Inventors: Lucien E. Bourson, Serge Y. Delavarenne, Pierre Tellier
  • Patent number: 4235789
    Abstract: A process for preparing 1-amino-2-bromo-4-hydroxyanthraquinone by bromination of 1-aminoanthraquinone to 1-amino-2, 4-dibromoanthraquinone and subsequent hydroxylation (debromohydroxylation) of the resulting bromination product.
    Type: Grant
    Filed: March 19, 1979
    Date of Patent: November 25, 1980
    Assignee: Mobay Chemical Corporation
    Inventor: James R. Stout
  • Patent number: 4226783
    Abstract: A process for .alpha.-chlorination of side chains of electronegatively substituted aromatic compounds with dichlorine monoxide.
    Type: Grant
    Filed: July 3, 1978
    Date of Patent: October 7, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Frank D. Marsh
  • Patent number: 4225523
    Abstract: Anthraquinone dyestuffs which in the free acid form are of the formula: ##STR1## where Z is H or SO.sub.3 H,R is H, C.sub.1-4 alkyl or hydroxy C.sub.1-4 alkyl,the ring A may optionally be additionally substituted by OCH.sub.3 and/or SO.sub.3 H.These dyes are especially valuable for application to cellulose and fixation by heating with a carbodiimide such as dicyandiamide.
    Type: Grant
    Filed: August 7, 1979
    Date of Patent: September 30, 1980
    Assignee: Imperial Chemical Industries Limited
    Inventor: Dennis Eckersley
  • Patent number: 4224228
    Abstract: There are described new violet water-soluble anthraquinone dyes of the formula ##STR1## wherein R.sub.1 represents a straight-chain or branched-chain alkyl group having 4 to 8 carbon atoms,R.sub.2 and R.sub.3 independently of one another represent a straight-chain or branched-chain alkyl group having 1 to 4 carbon atoms,R.sub.4 represents hydrogen, an optionally acylated amino group, or a fibre-reactive radical bonded by way of an amino group,R.sub.5 represents hydrogen, or a straight-chain or branched-chain alkyl group having 1 to 4 carbon atoms, and the phenylene ringA can be further substituted;processes for producing them; as well as the use thereof for dyeing and printing textile materials, particularly natural and synthetic polyamide materials.
    Type: Grant
    Filed: December 19, 1978
    Date of Patent: September 23, 1980
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean-Marie Adam
  • Patent number: 4222947
    Abstract: Dyestuffs, which are free from nitro groups and sulphonic acid groups, of the formulaF--Z--(OA).sub.n --OR IwhereinF denotes an anthraquinone nucleus which contains at least one auxochromic group in the .alpha.-position,Z denotes a direct bond or a bridge member,A denotes alkylene,R denotes alkyl, aralkyl, cycloalkyl, aryl or acyl andn denotes 3 to 8,with the proviso that R does not represent aralkyl if n denotes the number 3 and the number of the auxochromic groups is two, have a melting point below 140.degree. C., in particular below 100.degree. C., and are outstandingly suitable for dyeing and printing synthetic fibre materials, in particular those of polyesters, on which they produce dyeings with good fastness to sublimation, washing and light.The dyestuffs are advantageously employed in the form of liquid or pulverulent preparations which contain, in addition to the dyestuff, emulsifying polar/non-polar compounds and, if appropriate, formulating agents and extenders.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: September 16, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Hederich, Winfried Kruckenberg, Karl H. Schundehutte
  • Patent number: 4220597
    Abstract: A process has been found for the preparation of anthraquinone by catalytic oxidation of naphthalene in the gas phase to provide a reaction product, obtained by quenching, cooling or quenching and cooling, containing naphthaquinone and phthalic anhydride, treating said reaction product directly with butadiene to provide tetrahydroanthraquinone, oxidation by means of molecular oxygen to the tetrahydroanthraquinone contained in this reaction product, to give anthraquinone, and separation of naphthalene, phthalic anhydride, anthraquinone and by-products by distillation, the gases produced in the quenching and/or cooling of the gases from the naphthalene oxidation and the gases from the oxidation of the tetrahydroanthraquinone to give anthraquinone being completely or partially recycled to the oxidation of naphthalene, in which a compound with an alkaline reaction is introduced between the reactor in which naphthalene is oxidized and the reactor in which the reaction with butadiene takes place, and/or into the gas
    Type: Grant
    Filed: January 25, 1979
    Date of Patent: September 2, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kurt Halcourt, Paul Losacker, Manfred Martin, Norbert Schenk, Wulf Schwerdtel
  • Patent number: 4216157
    Abstract: Compounds having the formula: ##STR1## wherein (a) when R.sup.1 is --COCH.sub.3 or --COCH.sub.2 OH, R.sup.2 is --OH, R.sup.3 is --OCH.sub.3 and R.sup.4 is --H;(b) when R.sup.2 is --COCH.sub.3 or --COCH.sub.2 OH; R.sup.1 is --OH, R.sup.3 is --H and R.sup.4 is --OCH.sub.3 ;and which are useful in treating certain mammalian tumors, are prepared from 9,10-anhydro-N-trifluoroacetyl daunorubicin, a known compound.
    Type: Grant
    Filed: April 27, 1979
    Date of Patent: August 5, 1980
    Assignee: Farmitalia Carlo Erba S.p.A.
    Inventors: Sergio Penco, Fausto Gozzi, Francesco Angelucci, Federico Arcamone
  • Patent number: 4215063
    Abstract: Anthraquinone is prepared by the oxidation of diphenylmethane compounds in the gas phase in the presence of vanadium (V) oxide and a metal selected from ruthenium, rhenium, cerium, niobium and rhodium, and optionally a third metal selected from manganese, barium, cerium and iron.
    Type: Grant
    Filed: May 3, 1979
    Date of Patent: July 29, 1980
    Assignee: American Cyanamid Company
    Inventors: Joseph L. Schmitt, Jr., Hiei Ando
  • Patent number: 4214082
    Abstract: Dyestuffs of the formula ##STR1## wherein S, m, X, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and n have the meaning indicated in the description, and their use for dyeing and printing textile materials containing hydroxyl groups and textile materials containing nitrogen, in particular textile materials of natural and regenerated cellulose, and furthermore of wool, silk and synthetic polyamide and polyurethane fibres. The resulting dyeings are distinguished by good fastness to light and wet processing.
    Type: Grant
    Filed: April 20, 1979
    Date of Patent: July 22, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Klaus Wunderlich, Klaus von Oertzen
  • Patent number: 4213910
    Abstract: A process for preparing 1-amino-4-bromoanthraquinone-2-sulphonic acid or an alkali metal salt thereof which comprises contacting 1-amino-anthraquinone at a temperature in the range of 90.degree. to 150.degree. C. with an SO.sub.3 -containing sulphuric acid (oleum) and thereafter treating the resultant sulphonated 1-amino-anthraquinone with at least 0.5 molar equivalent of bromine, relative to 1 mol of 1-amino-anthraquinone, at temperatures in the range from 60.degree. to 100.degree. C.
    Type: Grant
    Filed: September 5, 1978
    Date of Patent: July 22, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Muders, Heinrich Leister, Helmut Dittmer, Hubert Schonhagen
  • Patent number: 4213909
    Abstract: A process for the preparation of 1-amino-4-bromoanthraquinone-2-sulfonic acid or an alkali metal salt thereof by converting 1-aminoanthraquinone (which can be obtained by reduction of 1-nitroanthraquinone with sodium sulfide and/or sodium bisulfide or reaction of the 1-nitroanthraquinone with ammonia) by contacting the same with oleum at a temperature in the range of 90.degree. to 150.degree. C. optionally in the presence of an alkali metal sulfate and thereafter treating the so-sulfonated composition with bromine at a temperature in the range of from 60.degree. to 100.degree. C. 1-amino-4-bromoanthraquinone-2-sulfonic acid or an alkali metal salt thereof can be precipitated from the reaction mixture either by adjusting the sulfuric acid concentration thereof to 60 to 85 percent by weight or by stirring the reaction mixture into water, which optionally contains an alkali metal sulfate.
    Type: Grant
    Filed: September 5, 1978
    Date of Patent: July 22, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Berg, Walter Hohmann, Karl-Julius Reubke, Klaus Wunderlich