Patents Examined by Raymond K. Covington
  • Patent number: 4276187
    Abstract: An oxidation-reducing reagent for a wet desulfurization process, which comprises (a) one or more compounds selected from the group consisting of salts of substituted anthraquinonesulfonic acids of the general formulas: ##STR1## wherein M stands for a sodium atom, a potassium atom or an ammonium group, and n is an integer of 1 or 2, or (b) a mixture of a salt of anthraquinone-2,7-disulfonic acid and one or more compounds shown by the general formula (I) and/or (II), as well as a process for preparing the compounds of the general formulas (I) and (II).
    Type: Grant
    Filed: April 4, 1979
    Date of Patent: June 30, 1981
    Assignee: Mitsui Toatsu Chemicals Incorporated
    Inventors: Katsuya Sakai, Ryuichi Mita, Toshio Kato, Chojiro Higuchi, Hisamichi Murakami
  • Patent number: 4276213
    Abstract: The invention discloses a process for the coloration of organic material of high molecular weight, wherein the colorant is a compound of the formula ##STR1## wherein Hal represents a chlorine or bromine atom, X represents a hydrogen or halogen atom, an alkyl or alkoxy group of 1 to 6 carbon atoms, an alkoxycarbonyl group of 2 to 7 carbon atoms, a phenyl group or a phenoxy group which is unsubstituted or substituted by chlorine atoms or methyl groups, and Y and Z represent hydrogen or halogen atoms or methyl groups.
    Type: Grant
    Filed: June 18, 1979
    Date of Patent: June 30, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Max Jost
  • Patent number: 4276224
    Abstract: Compounds having the general formula: ##STR1## where A is a C.sub.1 -C.sub.4 straight or branched chain alkylene radical, B is a --SO.sub.3 M, --CO.sub.2 M, --PO.sub.3 HM or --PO.sub.3 M.sub.2 grouping,M is hydrogen, or a cation giving a water-soluble derivative,R is hydrogen, a cation giving a water-soluble derivative or a C.sub.1 -C.sub.4 straight or branched alkyl, R.sub.1 is hydrogen, methyl or --COOH, and m is 0 or 1 and processes of preparing them.
    Type: Grant
    Filed: July 12, 1979
    Date of Patent: June 30, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Donald R. Randell, Emyr Phillips
  • Patent number: 4275009
    Abstract: This disclosure describes 1-(aminoalkylamino)-5,8-dihydroxy-4-substituted-anthraquinones useful as chelating agents and for inhibiting the growth of transplanted mouse tumors.
    Type: Grant
    Filed: May 29, 1979
    Date of Patent: June 23, 1981
    Assignee: American Cyanamid Company
    Inventor: Keith C. Murdock
  • Patent number: 4273720
    Abstract: The present invention relates to anionic dyestuffs of the 1-amino-4-aryl- or -4-alkylamino anthraquinone series which are unsubstituted in the 3-position and bear in the 2-position an arylalkyleneoxy group, and in which at least one aryl group bears a sulpho group, with the proviso that when the substituent in the 4-position is alkylamino such alkyl is linear, branched or cyclic and contains at least 9 carbon atoms and the sum of the carbon atoms of the alkylamino group in the 4-position and the alkylene group in the 2-position is at least 12, which dyestuffs are in the free acid or salt form.
    Type: Grant
    Filed: September 18, 1978
    Date of Patent: June 16, 1981
    Assignee: Sandoz Ltd.
    Inventor: Roland Wald
  • Patent number: 4268451
    Abstract: Daunomycin derivatives of the formula: ##STR1## wherein R.sub.1 is a lower alkyl having from 1 to 4 carbon atoms and R is a hydrogen atom or a trifluoroacetyl group are useful in treating certain mammalian tumors.
    Type: Grant
    Filed: May 14, 1979
    Date of Patent: May 19, 1981
    Assignee: Farmitalia Carlo Erba S.p.A.
    Inventors: Paolo Masi, Antonino Suarato, Luigi Bernardi, Federico Arcamone
  • Patent number: 4267116
    Abstract: Daunomycin derivatives of the formula: ##STR1## wherein R.sub.1 is a lower alkyl having from 1 to 4 carbon atoms and R is hydrogen or a trifluoroacetyl group are useful in treating certain mammalian tumors.
    Type: Grant
    Filed: May 14, 1979
    Date of Patent: May 12, 1981
    Assignee: Farmitalia Carlo Erba S.p.A.
    Inventors: Paolo Masi, Antonino Suarato, Luigi Bernardi, Federico Arcamone
  • Patent number: 4267115
    Abstract: Water-soluble anthraquinone dyes which bear one or two 3,5,5-trimethylcyclohexylamino groups in the 1- and/or 4-positions and one or two -SO.sub.3 H groups bound either directly to a carbon atom of an aromatic ring or indirectly over an oxygen atom to a carbon atom of an aliphatic chain.
    Type: Grant
    Filed: August 7, 1978
    Date of Patent: May 12, 1981
    Assignee: Sandoz Ltd.
    Inventors: Wolfgang Frey, Wolfgang Schoenauer
  • Patent number: 4267366
    Abstract: Disclosed are novel cyclic terpenoid amines which can be prepared by cyclizing the corresponding acyclic terpenoid amine.
    Type: Grant
    Filed: June 18, 1979
    Date of Patent: May 12, 1981
    Assignee: SCM Corporation
    Inventors: Bernard J. Kane, Richard A. Von Genk
  • Patent number: 4264511
    Abstract: New anthraquinone compounds of the formula ##STR1## in which Y denotes chlorine, bromine, --O--R or ##STR2## R denotes aryl, R.sub.1 and R.sub.2 denote hydrogen, alkyl, cycloalkyl or aryl andX.sub.1 and X.sub.2 denote hydrogen, halogen or nitro,are obtained when the corresponding 2-sulphonic acids are treated with inorganic acid halides and the products are then optionally treated with alcohols or amines. The compounds I are valuable dyestuffs for dyeing polyester fibres and starting materials for the preparation of such dyestuffs.
    Type: Grant
    Filed: May 11, 1979
    Date of Patent: April 28, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff
  • Patent number: 4263014
    Abstract: Anti-rust motor fuel composition comprising a major proportion of a mixture of hydrocarbons boiling in the gasoline boiling range, a minor amount of a polymeric acid comprising a dimer or trimer of a dienoic or trienoic acid containing from 16 to 18 carbon atoms and a minor amount of an aminoalkyl or polyalkyl polyamine imidazoline derivative of a hydrocarbon-substituted gamma or delta lactone reaction product.
    Type: Grant
    Filed: June 23, 1978
    Date of Patent: April 21, 1981
    Assignee: Texaco Inc.
    Inventors: Marshall E. Davis, Kenneth L. Dille
  • Patent number: 4261909
    Abstract: A process for the reductive removal of halogen atoms from amino-, acylamino- or hydroxyanthraquinones, said halogen atoms being bonded in the .alpha.-position and/or ortho-position to amino, acylamino or hydroxyl groups, which comprises carrying out the reductive removal in basic medium with hydrazine or hydrazine derivatives.
    Type: Grant
    Filed: April 26, 1979
    Date of Patent: April 14, 1981
    Assignee: Ciba-Geigy AG
    Inventors: Athanassios Tzikas, Jurgen Markert
  • Patent number: 4259248
    Abstract: A process has been developed for the preparation of mixtures of dinitroanthraquinones with a high content of 1,5- and 1,8- dinitroanthraquinone by nitration with nitric acid in the presence of sulphuric acid with heating wherein anthraquinone, 1-nitroanthraquinone or a mixture of them is treated with about 1.5 to about 2.5 times the amount by weight of nitric acid, relative to the feed material, in the presence of about 0.75 times to twice the amount by weight, relative to nitric acid, of sulphuric acid, the temperature first being kept in the range from room temperature to about 50.degree. C. until at least 50% of the starting material or materials has been dinitrated, then adjusting the temperature to about 50.degree. C. to about 70.degree. C. to complete the dinitration.
    Type: Grant
    Filed: June 18, 1979
    Date of Patent: March 31, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Walter Hohmann, Klaus Wunderlich
  • Patent number: 4255342
    Abstract: A method of synthesizing phenoxyanthraquinones in the absence of excess phenol, water-miscible alcohols or polar aprotic solvents. Phenoxyanthraquinones are synthesized in high yield and purity by treatment of the corresponding chloro- or nitroanthraquinone with an equivalent of alkali metal phenoxide, particularly potassium phenoxide in a liquid aromatic solvent which is a chloro-substituted benzene, a lower alkyl-substituted benzene, or a loweralkyl-chloro-substituted benzene. The use of the inventive solvents results in high yields of readily isolable, substantially pure product. The used solvent is readily recoverable without the pollution potential of excess phenol or difficultly recoverable water-miscible solvents.
    Type: Grant
    Filed: April 2, 1979
    Date of Patent: March 10, 1981
    Assignee: Toms River Chemical Corporation
    Inventor: Arthur D. Olin
  • Patent number: 4255343
    Abstract: Process for preparing 2-t-alkylanthracene, which process comprises contacting and reacting, with good mixing, at a temperature of at least 110.degree. C., anthracene and a branched-chain alkylating agent, the alkylating moiety of which contains at least four carbon atoms, in the presence of a catalyst selected from hydrocarbonsulfonic acids which are free of nonaromatic unsaturation, organic carboxylic acids having a K.sub.a of 0.6 to 0.001, acid zeolites, amorphous silica-aluminas, and polymeric arenesulfonic acid resins, to give a product mixture of which the major constituent is 2-t-alkylanthracene.
    Type: Grant
    Filed: August 13, 1979
    Date of Patent: March 10, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Lawrence W. Gosser
  • Patent number: 4250109
    Abstract: Hexamethylene.bis-dicyandiamide is safely prepared in good yield and desired purity by a novel method which comprises reacting N-cyano-O (or S)-alkyl-iso (or isothio) urea with hexamethylenediamine. The desired product is useful as an intermediate of chlorhexidine which is an antibacterial agent.
    Type: Grant
    Filed: August 7, 1979
    Date of Patent: February 10, 1981
    Assignee: Sogo Pharmaceutical Company Limited
    Inventors: Saburo Uchikuga, Michiro Itoh, Katsuyasu Nagahama
  • Patent number: 4250102
    Abstract: The invention relates to a process for the manufacture of an aminohydroxyanthraquinone of the formula ##STR1## wherein both of X are hydrogen or one X is --NH.sub.2 and the other is --OH and Z is hydrogen, C.sub.1 -C.sub.4 alkyl or carboxyl, with the proviso that, if Z is C.sub.1 -C.sub.4 alkyl or carboxyl, both of X must be hydrogen, which process comprises reacting a nitroanthraquinone of the formula ##STR2## wherein both of Y are hydrogen or one Y is --NO.sub.2 and the other is hydrogen and Z is as defined for formula (1), with the proviso that, if Z is C.sub.1 -C.sub.4 alkyl or carboxyl, both of Y must be hydrogen, in an aprotic dipolar solvent, with an alkali metal azide or alkaline earth metal azide, in the temperature range between 0.degree. and 30.degree. C. The reaction products are disperse dyes or intermediates for obtaining vat dyes and disperse dyes.
    Type: Grant
    Filed: August 21, 1979
    Date of Patent: February 10, 1981
    Assignee: Ciba-Geigy AG
    Inventor: Athanassios Tzikas
  • Patent number: 4249912
    Abstract: A detergent additive aminoamide, prepared by reacting a polycarboxylic amino acid with alkylamines, is combined into fuel for an internal combustion engine or lubricating oil as a composition suitable for reducing deposits in an internal combustion engine. In an embodiment of the invention, the aminoamide is further combined with a sulfonic acid to obtain a fuel detergent of improved operability.
    Type: Grant
    Filed: April 27, 1978
    Date of Patent: February 10, 1981
    Assignee: Phillips Petroleum Company
    Inventors: Hans D. Holtz, deceased, Benedict R. Bonazza
  • Patent number: 4247300
    Abstract: A detergent additive imidazoline prepared by reacting carboxylic acid with polyamine is combined into fuel for an internal combustion engine or lubricating oil as a composition suitable for reducing deposits in an internal combustion engine. In an embodiment of the invention, the imidazoline is further combined with a sulfonic acid to obtain a fuel detergent of improved operability.
    Type: Grant
    Filed: April 27, 1978
    Date of Patent: January 27, 1981
    Assignee: Phillips Petroleum Company
    Inventors: Benedict R. Bonazza, Hans D. Holtz, deceased
  • Patent number: 4247470
    Abstract: Process for isolating dyestuffs of the formula ##STR1## wherein R.sub.1 -R.sub.12 denote hydrogen, alkyl, halogenoalkyl, halogen, alkoxy, alkylmercapto, alkylsulphonyl, alkoxysulphonyl, alkylcarbonyl, alkoxycarbonyl, nitro or cyano, X and Y denote ##STR2## and R.sub.13 and R.sub.14 denote hydrogen, alkyl, halogenoalkyl, cyanoalkyl, cycloalkyl, aryl or aralkyl, and whereinX and R.sub.2, Y and R.sub.10, R.sub.1 and R.sub.2, R.sub.5 and R.sub.6 and R.sub.9 and R.sub.10 can form a 5- or 6-membered ring and A.sup.(-) denotes an anion,by dissolving the crude dyestuffs, which have been obtained by known processes, in aqueous acids, adding an organic solvent which is immiscible with water or of limited miscibility with water and then isolating the dyestuffs in a known manner.
    Type: Grant
    Filed: December 8, 1976
    Date of Patent: January 27, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Heinz Hermann, Hans-Lothar Dorsch