Abstract: Described herein is curable composition comprising a partially halogenated elastomeric gum comprising a plurality of cure sites selected from at least one of iodine, bromine, and nitrile; a silicon-containing compound; a dehydrohalogenation agent; and a peroxide cure system. Upon curing, a silicon-containing superficial layer forms, which can provide good chemical stability, increased durability, non-tackiness, and a matte finish to the cured elastomer.
Type:
Grant
Filed:
December 19, 2018
Date of Patent:
March 7, 2023
Assignee:
3M Innovative Properties Company
Inventors:
Tatsuo Fukushi, Tho Q. Nguyen, Allen M. Sohlo
Abstract: Provided herein are methods and systems for at least partially deactivating at least one component of a reactor effluent from gas phase polyolefin polymerization processes utilizing at least one glycol.
Type:
Grant
Filed:
October 26, 2018
Date of Patent:
February 28, 2023
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Chi-I Kuo, Bruce J. Savatsky, Micah A. McClure, Kevin M. Ferreira, Charles J. Harlan, Valerie H. Markham
Abstract: A process for producing water-absorbing polymer particles by suspension polymerization and thermal surface postcrosslinking, wherein the base polymer obtained by suspension polymerization has a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 100 to 190° C.
Type:
Grant
Filed:
June 26, 2020
Date of Patent:
February 28, 2023
Assignee:
BASF SE
Inventors:
Stephan Bauer, Tina Mark, Lydia König, Yvonne Hagen, Thomas Daniel
Abstract: A crosslinked rubber composition contains ethylene-propylene-diene copolymer rubber crosslinked with a rotaxane compound having a cyclic molecule and an axial molecule penetrating through the cyclic molecule. In the crosslinked rubber composition, the ethylene-propylene-diene copolymer rubber contains vinylnorbornene, dicyclopentadiene, or tetrahydroindene as a diene component, and the rotaxane compound has a nitrile oxide group on the cyclic molecule and one end of the axial molecule, and the cyclic molecule is crown ether.
Type:
Grant
Filed:
August 27, 2021
Date of Patent:
February 14, 2023
Assignees:
TOYODA GOSEI CO., LTD., TOKYO INSTITUTE OF TECHNOLOGY
Abstract: A process of preparing an aqueous solution of a cycloimide-containing polymer includes heating an aqueous solution of a cycloanhydride-containing polymer with a first neutralizing agent at a ratio of cycloanhydride to neutralizing agent of about 1:1 to about 1:1.5 at a temperature and for a time sufficient to form the aqueous solution of the cycloimide-containing polymer having a cycloimide to acid group ratio of about 1:2 to about 1.5:2.
Type:
Grant
Filed:
June 12, 2020
Date of Patent:
February 14, 2023
Inventors:
Timothy D. Klots, Amirpouyan Sardashti, Frank Reinhold
Abstract: The present invention concerns new precursors of recyclable cross-linked diene elastomers comprising at least one furanyl group along the chain and comprising chain-end units with furanyl groups, their use in the preparation of said recyclable elastomers and their process of preparation. The invention also concerns new recyclable cross-linked diene elastomers, their preparation process and their uses.
Type:
Grant
Filed:
November 16, 2018
Date of Patent:
February 7, 2023
Assignees:
UNIVERSITÉ DE BORDEAUX, INSTITUT POLYTECHNIQUE DE BORDEAUX, Centre national de la recherche scientifique
Inventors:
Frédéric Peruch, Pierre Berto, Stéphane Grelier
Abstract: Co-cured blends of fluoroelastomers of tetrafluoroethylene-propylene copolymer with cure site monomer and terpolymers of Vinylidene fluoride (VDF), Hexafluoropropylene (HFP) and Tetrafluoroethylene (TFE) with peroxide as initiator and coagent TAIC as crosslinker show improved curing performance, improved mechanical properties and improved compression set as well. The co-cured fluoroelastomers show improved chemical resistance to the solvent aging systems and better retention of mechanical properties after aging at high temperature in the solvents system.
Type:
Grant
Filed:
February 19, 2020
Date of Patent:
January 31, 2023
Assignees:
CNPC USA CORPORATION, BEIJING HUAMEI INC.
Abstract: The present disclosure relates to a novel cross-linking agent compound and a polymer prepared using the same. Specifically, the present disclosure relates to a cross-linking agent compound having a novel structure and excellent in cross-linking and pyrolysis, and a polymer prepared using the same.
Type:
Grant
Filed:
November 20, 2018
Date of Patent:
January 24, 2023
Inventors:
Won Taeck Lim, Wonmun Choi, Gicheul Kim, Ki Hyun Kim
Abstract: The invention relates to silane mixtures comprising a silane of the formula I (R1)y(R2)3-ySi—R3—(S—R4)n—Sx—R5??(I) and a silane of the formula II (R1)y(R2)3-ySi—R3—Si(R1)y(R2)3-y??(II) where the molar ratio of silane of the formula I to silane of the formula II is 15:85-90:10. The silane mixture according to the invention can be prepared by mixing the silanes of the formula I and silanes of the formula II.
Type:
Grant
Filed:
November 16, 2018
Date of Patent:
January 3, 2023
Assignee:
Evonik Operations GmbH
Inventors:
Alexander Koepfer, Caren Roeben, Andre Hasse, Frank Forster
Abstract: The present disclosure is directed to a thermoplastic polymer for additive manufacturing, wherein the thermoplastic polymer is derived from a chlorinated monomer unit, wherein the thermoplastic polymer has a melt flow rate (MFR) suitable for additive manufacturing. The present disclosure is also directed to a method of making a 3D product formed by additive manufacturing, wherein the 3D product comprises a thermoplastic polymer derived from a chlorinated monomer unit or a thermoplastic composition comprising at least one thermoplastic polymer derived from a chlorinated monomer unit; and at least one stabiliser, wherein the thermoplastic polymer or composition has a MFR suitable for additive manufacturing.
Type:
Grant
Filed:
September 30, 2020
Date of Patent:
January 3, 2023
Assignee:
Akdeniz Chemson Additives AG
Inventors:
Greg Harrison, Dennis Planner, Joerg-Dieter Klamann, Hugh Dennis, Stephen Dennis
Abstract: This present invention relates to a drug carrier comprising a polymer of ?-glutamyl transpeptidase catalyzing hydrolysis-induced charge reversal, and a method for preparing the same. It can have a long circulation time in the blood, and can realize a charge reversal from negatively charged or the neutral to positively charged around the tumor blood vessel region, so that the positively charged polymer effectively penetrates deep into the tumor tissue, fast entering into the tumor cells, and greatly improves the therapeutic effect of the drug on the tumor. This overcomes the problems of slow diffusion of traditional polymer drug carriers in tumors and weak interaction with tumor cells, and has great significance in the field of anticancer treatment in the medical field.
Type:
Grant
Filed:
May 6, 2022
Date of Patent:
December 27, 2022
Assignee:
Hainan Poly Pharm Co., Ltd.
Inventors:
Youqing Shen, Quan Zhou, Changhuo Xu, Jiajia Xiang
Abstract: Described herein are organoborane polymers and methods for the oxidation of these organoborane polymers to poly (vinyl alcohol) PVA. The organoborane polymers of the present invention respond to an external trigger by changing from a hydrophobic to a hydrophilic state.
Type:
Grant
Filed:
October 16, 2018
Date of Patent:
December 6, 2022
Assignee:
The Johns Hopkins University
Inventors:
Rebekka Klausen, Heidi Lee VanDeWouw, Jae Young Lee
Abstract: Process for obtaining polyethylene with an MFI (190° C./2.16 kg) of at least 4 g/10 minutes and a melt strength (190° C.) of at least 8.0 cN, said process involving extrusion of low density polyethylene (LDPE) with an MFI of at least 5 g/10 minutes and a vinyl content of less than 0.25 terminal vinyl groups per 1000 C-atoms (measured with NMR in deuterated tetrachloroethane solution)—in the presence of 500-5,000 ppm, based on the weight of low density polyethylene, of an organic peroxide.
Type:
Grant
Filed:
November 23, 2018
Date of Patent:
December 6, 2022
Assignee:
NOURYON CHEMICALS INTERNATIONAL B.V.
Inventors:
Wilhelm Klaas Frijlink, Jan Martijn Van Der Schuur
Abstract: Vulcanizates with desirable properties such as reduced hysteresis and improved wear resistance can be obtained from a composition that includes particulate filler(s) and at least two types of terminally functionalized polymers. One type of polymer has a heterocyclic moiety at a terminus, while another type has at one of its termini an aryl group that includes at least two hydroxyl substituents. The functionalized polymers are provided by reacting terminally active polymers with, respectively, a heterocyclic nitrile and a compound that includes an aryl group having at least two directly bonded OGp substituents, where Gp is a protecting group, and a substituent that can react with the active terminus. The protecting groups can be removed so as to provide a terminal moiety that includes an aryl group having at least two directly bonded hydroxyl groups.
Abstract: A process for producing a halogenated isoolefin copolymer involves contacting an unsaturated isoolefin copolymer cement, the cement containing an unsaturated isoolefin copolymer dissolved in an organic solvent, under halogenation conditions with a halogenating agent and an aqueous solution of an organic peracid oxidant to form a two-phase reaction medium having an organic phase and an aqueous phase, the organic peracid oxidant capable of converting hydrogen halide to free halogen. The process leads to higher halogen utilization even when the cement contains significant amounts of water and without the use of an emulsifier.
Abstract: A continuous process for producing a halogenated isoolefin copolymer involves: polymerizing at least one isoolefin monomer and at least one copolymerizable unsaturated monomer in an organic diluent to produce a halogenatable isoolefin copolymer in an organic medium; contacting the organic medium with an aqueous medium comprising an LCST anti-agglomerant compound; removing or partially removing the organic diluent to produce an aqueous slurry of the halogenatable isoolefin copolymer; dissolving the aqueous slurry in an organic solvent in a closed apparatus to form an unsaturated halogenatable copolymer cement in water, and phase separating the water from the cement in the apparatus; contacting the separated halogenatable isoolefin copolymer cement with a halogenating agent and an aqueous solution of a C1-20 organic peracid oxidant to form a two-phase reaction medium having an organic phase and an aqueous phase, the organic peracid oxidant capable of converting hydrogen halide to free halogen; and, recovering h
Abstract: The invention pertains generally to a polymer composition comprising a certain secondary polymeric polyphosphite anti-oxidant, that can also act as a polymer processing aid alone or in combination with another polymer processing aid.
Type:
Grant
Filed:
February 12, 2019
Date of Patent:
October 18, 2022
Inventors:
Michael R Jakupca, Jacob M. Lance, John T. Regula
Abstract: A resin composition for forming a phase-separated structure containing a block copolymer having a first block and a second block, in which the first block is formed of a constituent unit represented by Formula (b1), the second block is formed of a constituent unit represented by Formula (b2m) and a random copolymer having a constituent unit represented by Formula (b2g), and a ratio of a volume of the first block is 20% to 80% by volume.
Type:
Grant
Filed:
July 12, 2021
Date of Patent:
October 18, 2022
Assignees:
TOKYO OHKA KOGYO CO., LTD., TOKYO INSTITUTE OF TECHNOLOGY
Inventors:
Teruaki Hayakawa, Lei Dong, Takahiro Dazai, Ken Miyagi, Takayoshi Mori, Daisuke Kawana