Abstract: Disclosed are such co-polymers of vinylidene substituted aromatic monomers and unsaturated compounds containing nucleophilic groups chain extended by a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds having pendant electrophilic groups which copolymerize with the one or more vinylidene aromatic monomers. Disclosed are compositions comprising vinylidene substituted aromatic monomers and unsaturated compounds containing nucleophilic groups and a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds having pendant electrophilic groups, which may optionally, contain salts of alkaline earth metals, alkali metals, transition metals, post transition metals or metalloids. Disclosed are methods of preparing such chain-extended and/or branched copolymers.

Abstract: A method for producing a carboxy group-containing hydrogenated nitrile rubber includes a step of preparing a latex of a carboxy group-containing nitrile rubber by polymerizing a monomer mixture in a dispersive medium, the monomer mixture containing at least an ?,?-ethylenically unsaturated nitrile monomer and a carboxy group-containing monomer; a step of heating the latex of the carboxy group-containing nitrile rubber at 50 to 85° C. in the state where the pH is adjusted in the range of 8.5 to 12; and a step of subjecting the latex of the carboxy group-containing nitrile rubber after the heating to a hydrogenation reaction in the presence of a hydrogenation catalyst in the state where the pH is adjusted in the range of 5 to 8.

Abstract: This present invention relates to a polymer of ?-glutamyl transpeptidase catalyzing hydrolysis-induced charge reversal. The polymer comprises a ?-glutamyl transpeptidase-responsive element represented by Formula (I). When the polymer is used as drug carrier for anticancer drug, it can have a long circulation time in the blood, and can realize a charge reversal from negatively charged or the neutral to positively charged around the tumor blood vessel region, so that the positively charged polymer effectively penetrates deep into the tumor tissue, fast entering into the tumor cells, and greatly improves the therapeutic effect of the drug on the tumor. This overcomes the problems of slow diffusion of traditional polymer drug carriers in tumors and weak interaction with tumor cells, and has great significance in the field of anticancer treatment in the medical field.

Abstract: The present invention relates to a fluorine-containing alternating copolymer macromonomer and a synthesis method thereof. The synthesis method comprises steps of: subjecting a fluorine-containing alternating copolymer to a reduction reaction at 60-100° C. in an organic solvent in the presence of a reducing agent and a first catalyst to obtain a reduction product; in the presence of a second catalyst, reacting the reduction product with a mercapto-monohydric alcohol in an organic solvent at 60-100° C., to obtain a hydroxyl-terminated fluorine-containing alternating copolymer; and in the presence of a third catalyst, reacting the hydroxyl-terminated fluorine-containing alternating copolymer with an acrylic monomer or acryloyl chloride monomer at 0-30° C., to obtain the fluorine-containing alternating copolymer macromonomer. In the present invention, a fluorine-containing alternating copolymer macromonomer is initially synthesized from a fluorine-containing alternating copolymer through polymer modification.

Abstract: A method for the direct fluorination of plastics and articles made from plastics is presented. The novel method includes ensuring extremely low oxygen and moisture content in the chamber before the primary fluorination step, ramping the fluorine concentration during the fluorination step, and providing a quenching step for improved shelf-life. Containers processed by the novel method demonstrate a marked improvement in barrier properties for organic solutions.

Abstract: The present invention relates to a modifier represented by Formula 1, a method of preparing the same, a modified conjugated diene-based polymer having a high modification ratio which includes a modifier-derived functional group, and a method of preparing the polymer.

Abstract: Silicon (Si) based high temperature coatings and base materials and methods of making those materials. More specifically, methods and materials having silicon, oxygen and carbon containing polymer derived ceramic liquids that form filled and unfiled coatings, including high temperature crack resistant coatings.

Abstract: The invention pertains to a polymer composition possessing improved resistance towards degradation and discolouring phenomena induced by UV radiation, said composition comprising at least one aromatic sulfone polymer; at least one organic UV absorber and at least one basic compound selected from the group consisting of (i) basic oxides and hydroxides of divalent metals and (ii) salts of a weak acid, and to methods for its manufacture and to shaped articles obtained therefrom.

Abstract: Liquid crystal polymers (LCPs) are described herein that include novel arrangements of bio-mimicking properties for use in surgery, therapy, and treatment of medical or comfort issues. Through the particular arrangements medical devices and portions of them may be adapted to have properties that dampen and dissipate vibrations such as shocks to body tissues during surgical recovery and/or during subsequent use. This dampening is attained by novel arrangements of LCP and processes for forming them that vary from prior attempts at synthesizing activated LCP elements. These novel arrangements include using LCP bodies that include thicknesses and properties that have not been demonstrated or achieved for medical or other purposes and that are achieved using distinct processes. These novel LCP arrangements and methods of creating them can produce medical devices that bio-mimic natural tissue or operation to provide better results for patients.

Abstract: Eco-friendly aqueous synthesis of substantive, UV-absorbing, cationic polymers with ‘inverse temperature dependent solubility’ are described in the present invention. These polymers are water-soluble at ambient temperature and water-resistant at temperature of human body as well as in the presence of electrolytes. This property makes these polymers useful for personal care products that are designed for protecting skin and hair from damages of UV radiation. The invention relates to aqueous synthesis of polymers of Formula I wherein, ArCO is an UV absorbing moiety selected from 2-cyano-3,3-diphenyl acryloyl, and p-methoxy cinnamoyl, R1 is selected from H and C1-C3 alkyl group, and R2 is selected from C1-C3 alkyl group, m and n are integers and a ratio of m to n is 40:5 to 40:1.

Abstract: Disclosed are novel polymers that contain monomer units derived from 4-vinylpyridine and monomer units derived from a co-monomer. The polymers may be complexed with a metal, and linear or crosslinked. Also disclosed are methods for preparing these polymers by radical polymerization, as well as to their use for metal capture in aqueous media, particularly uranium capture in seawater or in final nuclear waste from nuclear power plants.

Abstract: In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core, a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group, wherein the polymer segments comprise one or more free-radical-polymerizable monomers. In some aspects, systems are provided that comprise a first composition comprising such a multi-arm polymer and a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer. In some aspects, systems are provided that comprise crosslinked reaction products of such a multi-arm polymer and such a multifunctional compound.

Abstract: The process of curing a silane-functionalized ethylenic polymer using a tin-based catalyst, e.g., dibutyltin dilaurate, is accelerated by the addition of a titanium (IV) oxide.

Abstract: Methods of manufacturing highly crosslinked polymer particulate. The methods include positioning a granular polymeric material within a crosslinking apparatus and crosslinking the granular polymeric material with the crosslinking apparatus to form a highly crosslinked polymeric material. The methods also include forming a plurality of crosslinked polymer granules from the highly crosslinked polymeric material.

Abstract: A composition of polyvinyl for powder molding may include a polyvinyl chloride (A), a polyvinyl chloride (B), a plasticizer, and an alkyl phosphate. The polyvinyl chloride (A) may have an average particle diameter of 50 ?m to 500 ?m, and the polyvinyl chloride (B) may have an average particle diameter of 0.01 ?m or more and less than 50 ?m. An average polymerization degree of the polyvinyl chloride (A) may be 1350 or more, the alkyl phosphate may comprise a mono-alkyl phosphate, and the number of carbon atoms of an alkyl group in the alkyl phosphate may be 5 or more.

Abstract: This invention relates to a novel process for selectively and efficiently hydrogenating nitrile rubber in the presence of specific complex catalysts system comprising an NHC-ligand comprising Ru-complex catalyst and a specific hydrogenation enhancer.

Abstract: The present invention relates to the use of specific catalysts for the metathesis degradation of nitrile rubber (NBR). The invention further relates to a method for preparing nitrile rubber with reduced molecular weight using specific catalysts.

Abstract: Disclosed is a method of: providing a solution having a solvent, a polybutadiene, and an acrylate; and functionalizing the polybutadiene with the diacrylate to produce an ionic polymer. The polymer may be useful as an additive manufacturing binder.

Abstract: The present invention relates to nitrile-diene-carboxylic ester copolymers, to the preparation thereof, to vulcanizable compositions containing nitrile-diene-carboxylic ester copolymers and the production thereof, and to vulcanizates based on nitrile-diene-carboxylic ester copolymers and to the use thereof in elastomeric components.

Abstract: 1) Hydrocarbon-based copolymer comprising two end groups preceded by an ether function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) in which R0 is notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.