Patents Examined by Ronald A. Krasnow
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Patent number: 4908039Abstract: Narrow range ethoxylate nonionic detergents, in combination with soil release promoting polyethylene terephthalate-polyoxyethylene terephthalate (PET-POET) copolymer (in place of broad range ethoxylate nonionic detergent and PET-POET copolymer) are of significantly and unexpectedly improved soil release promoting activity in built synthetic organic detergent compositions, of either the phosphate-built or non-phosphate-built types. Preferably, there will be present with the PET-POET copolymer a stabilizing proportion of polyacrylate, to stabilize the PET-POET copolymer against deterioration and loss of soil release promoting activity on storage at elevated temperature, especially when in contact with alkaline components of the detergent composition. The improved soil release promoting activity is most pronounced when the laundry to be washed and treated is subjected to repeated launderings with the invented compositions in cold water and when it includes polyester-containing fibrous materials.Type: GrantFiled: August 10, 1987Date of Patent: March 13, 1990Assignee: Colgate-Palmolive Co.Inventors: Richard J. Holland, Charles Buda
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Patent number: 4842764Abstract: Azeotrope-like compositions comprising 1,1-dichloro-1-fluoroethane and methanol are stable and have utility as degreasing agents and as solvents in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards.Type: GrantFiled: May 3, 1988Date of Patent: June 27, 1989Assignee: Allied-Signal Inc.Inventors: Earl A. E. Lund, Robert G. Richard, Ian R. Shankland, David P. Wilson
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Patent number: 4834895Abstract: Dryer-added fabric conditioning articles and methods utilizing fabric softener agent, polymeric soil release agent, and protecting agent to protect dryer surfaces.Type: GrantFiled: August 17, 1987Date of Patent: May 30, 1989Assignee: The Procter & Gamble CompanyInventors: Thomas E. Cook, Rodolfo Delgado, Carlos G. Linares, Nabil Y. Sakkab, Toan Trinh
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Patent number: 4832863Abstract: A detergent composition which is distinguished by high detergency with respect to soil containing mineral oil and by low foaming both in the wash cycle and in the rinse cycle of automatic washing machines comprising (A) from 0.5 to 2% by weight C.sub.9 -C.sub.13 alkyl benezenesulfonate, (B) from 10 to 15% by weight of a fatty alcohol or oxo alcohol containing 2 to 4 ethylene oxide groups, (C) from 4 to 8% by weight of a fatty alcohol or oxo alcohol containing 6 to 8 ethylene oxide groups, the alcohols in (C) and (D) containing 12 to 15 carbon atoms, (E) from 0 to 2% by weight of a saturated or mono-unsaturated C.sub.16 -C.sub.18 alcohol containing 3 to 7 ethylene oxide groups, (E) from 5 to 20% by weight finely-divided crystalline zeolite, (F) from 40 to 60% by weight anhydrous sodium carbonate, (G) from 2 to 7% by weight sodium silicate and (H) from 0.5 to 2% by weight of a polymeric soil redeposition inhibitor.Type: GrantFiled: December 22, 1987Date of Patent: May 23, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Uwe Trabitzsch, Helmut Grund
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Patent number: 4832862Abstract: Silicate/silica composite particulates, well adapted for detergency applications, e.g., in detergent formulations for automatic dishwashers, comprise granules having an average molar ratio SiO.sub.2 /Na.sub.2 O of from 1.2 to 2.6, a metasilicate core and an enveloping silica outer sheath therefor.Type: GrantFiled: May 27, 1987Date of Patent: May 23, 1989Assignee: Rhone-Poulenc ChimieInventors: Daniel Joubert, Philippe Parker
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Patent number: 4830763Abstract: A process for increasing the degree of whitness of polyester-containing textile material by the combined application of a fluorescent whitening agent and, as booster, a compound which fluoresces in the absorption range of said fluorescent whitening agent, and a composition for whitening polyester-containing textile material.Type: GrantFiled: February 16, 1988Date of Patent: May 16, 1989Assignee: Ciba-Geigy CorporationInventors: Heinz Hefti, Urs Lehmann, Dieter Reinehr, Jurgen Kaschig
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Patent number: 4830772Abstract: Stripper compositions for coatings comprise an aromatic hydrocarbon, an aliphatic alcohol, and trioxane. Xylene and methanol are the preferred solvents. A useful composition for use at room temperature is 33% xylene, 33% methanol, and 33% trioxane. Trioxane slurries at ambient temperature are also useful for hot dip stripping when heated to a temperature which causes the trioxane to be dissolved.Type: GrantFiled: June 10, 1988Date of Patent: May 16, 1989Assignee: Hoechst Celanese CorporationInventor: Michael R. Van De Mark
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Patent number: 4828751Abstract: There is provided an improved solvent especially adapted for cleaning silicon wafers and consisting essentially of a haloalkylhydrocarbon and a partially fluorinated alcohol. This solvent provides excellent cleaning and drying of the wafer.Type: GrantFiled: August 28, 1987Date of Patent: May 9, 1989Assignee: PCR, Inc.Inventor: Paul W. Kremer
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Patent number: 4828723Abstract: A non-aqueous liquid heavy duty laundry detergent composition in the form of a suspension of builder salt in liquid nonionic surfactant is stabilized against phase separation by the addition of small amounts of low density filler, such as hollow plastic or glass microspheres. The low density particulate filler is added in an amount to equalize the densities of the continuous liquid phase and the dispersed phase. Further stabilization against phase separation under strong vibration conditions is provided by addition of a small amount of organophilic modified clay, such as a water-swellable smectite clay in which the metal cations are total or partially exchanged with mono- or di-long chain quaternary ammonium compound.Type: GrantFiled: July 15, 1987Date of Patent: May 9, 1989Assignee: Colgate-Palmolive CompanyInventors: Hoai-Chau Cao, Marie-Christine Houben, Michel Julemont
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Patent number: 4828750Abstract: A fabric rinse composition that removes residual soap and surfactant particularly anionic, left in the clothes during washing, which is disliked by consumers, consisting of low levels of a nonionic surfactant, low levels of an organic acid such as citric and/sodium citrate, and a major amount of water, in the form of a liquid or gel.Type: GrantFiled: December 2, 1987Date of Patent: May 9, 1989Assignee: Colgate-Polmolive CompanyInventors: Frederick A. Simion, Linda D. Rhein, John C. Blake-Haskins, Stephen W. Babulak, Robert V. Cantore
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Patent number: 4826632Abstract: A liquid surfactant composition mobile at 20.degree.-80.degree. C. contains up to 80% anionic surfactant (sodium or potassium alkylbenzene sulphonate and/or alkyl sulphate), up to 80% nonionic surfactant and less than 10% by weight of water. The liquid composition may be sprayed onto a solid particulate absorbent material to form a detergent powder or component thereof.Type: GrantFiled: October 16, 1987Date of Patent: May 2, 1989Assignee: Lever Brothers CompanyInventors: Stephen N. Blackburn, Francois Delwel, Elfed H. Evans
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Patent number: 4824603Abstract: Amphoteric and zwitter-ionic phosphate surfactants corresponding to the following formula ##STR1## (a) in which R.sup.1 is a C.sub.6 -C.sub.22 alkyl group, a group R.sup.4 (OC.sub.n H.sub.2n).sub.x --, where n=2 to 4, x=1 to 6, and R.sup.4 is a C.sub.6 -C.sub.22 alkyl group, or a group R.sup.5 --CONH(CH.sub.2).sub.m, where R.sup.5 is a C.sub.5 -C.sub.21 group and m=2 to 4; R.sup.2 is hydrogen; and R.sup.3 is a C.sub.1 -C.sub.4 alkyl group or a group --(C.sub.n H.sub.2n O).sub.x --H or --(C.sub.n H.sub.2n O).sub.x --PO.sub.3 H.sub.2, where n=2 to 4 and x=1 to 6, or(b) in which R.sup.1 is a C.sub.1 -C.sub.4 alkyl group or a C.sub.2 -C.sub.4 2-hydroxyalkyl group; R.sup.2 is a C.sub.6 -C.sub.22 alkyl group; and R.sup.3 is as defined above.to mixtures thereof with correspondingly substituted phosphate surfactants corresponding to formula (I), in which the --PO.sub.3 H.sub.2 group or groups are replaced by hydrogen; and to neutral and basic salts of the foregoing.Type: GrantFiled: October 28, 1987Date of Patent: April 25, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hinrich Moller, Ulrich Zeidler
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Patent number: 4822854Abstract: An acidic, aqueous cleaning composition comprising a surfactant; up to about 50% of a higher boiling solvent, typically in alkyl ether of an alkylene glycol, said solvent introducing impurities into the composition in an amount and of a nature normally chemically incompatible with oxidizable dye chromophores; a dye in an amount to provide a desired tinctorial value, and oxalic acid or a salt thereof in an amount effective to retard fading of the dye. In another aspect of the invention, the oxalic acid incorporated into compositions containing a solvent, a surfactant, and water, and optionally a dye provides a beneficial cleaning result. In yet another aspect of the invention, the oxalic acid beneficially retards the development of malodors when the compositions of the present invention are contained in a PVC container. Broadly, the incorporation of oxalic acid in said solvent can be employed to neutralize said impurities.Type: GrantFiled: September 23, 1987Date of Patent: April 18, 1989Assignee: The Drackett CompanyInventor: Laura A. Ciolino
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Patent number: 4820436Abstract: Detergents on the basis of anionic and nonionic surfactants contain as laundering power-enhancing additives an aliphatic amine compound which is selected such that its pK.sub.b value is at least equal to 14, minus the initial pH value of a 1% aqueous solution of the detergent containing the amine compound. Laundering power-enhancing amine compounds selected according to the rule mentioned are certain ether amines, amidoamines, glucamine derivatives or morpholine derivatives.Type: GrantFiled: February 20, 1987Date of Patent: April 11, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hans Andree, Horst Baumann, Manfred Biermann, Frantisek Jost, Horst-Juergen Krause, Fritz Lange, Herbert Leiter, Alfred Meffert, Uwe Ploog, Harald Schnegelberger, Eduard Smulders, Eric Sung, Andreas Syldatk, Guenter Uphues, Guenther Vogt
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Patent number: 4820448Abstract: A low-water content surfactant mixture which is pourable and pumpable at ambient temperature having high wetting power and detergency when used in a fabric detergent composition has a water content of no more than about 20% by weight, and consists essentially of (1) from about 50 to about 65% by weight of a C.sub.12 -C.sub.18 fatty alcohol ethoxylate containing an average of about 10 moles of ethylene oxide, (2) from about 5 to about 15% by weight of an alkali metal salt of a C.sub.16 -C.sub.18 tallow alcohol sulfate; (3) from about 4 to about 15% by weight of a C.sub.12 -C.sub.16 alkane sulfonate alkali metal salt and/or the disodium salt of n-octyl sulfosuccinate; and (4) from about 5 to about 13% by weight of a free C.sub.16 -C.sub.18 fatty acid.Type: GrantFiled: September 8, 1987Date of Patent: April 11, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ingo Wegener, Alfred Meffert, Ditmar Kischkel
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Patent number: 4820438Abstract: Soap bars having improved lathering properties of flash foam, lather volume and lather richness are prepared by stripping natural short chain saturated fatty acids in the ranges of C.sub.6 to C.sub.10 and replacing with approximately the same weight percentage of pelargonic acid.Type: GrantFiled: January 29, 1988Date of Patent: April 11, 1989Assignee: Quantum Chemical CorporationInventor: Karl T. Zilch
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Patent number: 4818427Abstract: A pretreatment or steeping preparation for cleaning stubbornly soiled dishes in an automatic dishwashing machine comprising from about 0.5 to about 20% by weight of a low-foaming nonionic surfactant, from about 0.5 to about 25% by weight of a polyhydric alcohol and/or glycol ether, from about 0.5 to about 10% by weight of a hydrotropic compound, and from about 0.01 to about 6% by weight of a viscosity regulator, all weights based on the weight of said preparation, in an aqueous suspension or solution adjusted to a viscosity of at least 5 mPa.s. and to a pH of from about 2 to about 7. In the cleaning process, the preparation is applied to the soiled dishes, the dishes are placed in an automatic dishwashing machine, and after waiting about 30 minutes the dishwashing machine is started for the normal washing cycle.Type: GrantFiled: October 19, 1987Date of Patent: April 4, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Theodor Altenschoepfer, Peter Jeschke, Klaus-Dieter Wisotzki
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Patent number: 4816175Abstract: Azeotrope-like compositions comprising dichlorotrifluoroethane, methanol, cyclopentane and nitromethane are stable and have utility as degreasing agents and as solvents in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards.Type: GrantFiled: April 25, 1988Date of Patent: March 28, 1989Assignee: Allied-Signal Inc.Inventors: Earl A. E. Lund, Rajat S. Basu, David P. Wilson
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Patent number: 4810414Abstract: Lipase is derived from Humicola sp. (incl. Theremomyces sp.), preferably H. lanuginosa. This lipase is found to have high activity at alkaline pH and to be compatible with anionic surfactants, and it is more effective as a detergent additive than previously described detergent lipases.Type: GrantFiled: August 28, 1987Date of Patent: March 7, 1989Assignee: Novo Industri A/SInventors: Ida B. Huge-Jensen, Erik Gormsen
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Patent number: 4808329Abstract: A paste-form glass cleaning preparation having the composition:(a) from 2 to 30% by weight of gasoline having a boiling point in the range of from 120.degree. to 250.degree. C.(b) from 0 to 10% by weight of organic solvent selected from the group consisting of alcohols, ketones and glycol ethers having a boiling point in the range of from 55.degree. to 250.degree. C., the organic solvent content making up less than half the gasoline content,(c) from 5 to 40% by weight of microcrystalline calcium carbonate wherein more than 98% by weight of the particles are smaller than 300 .mu.m,(d) from 0.2 to 2.5% by weight of silicone oil having a viscosity of from 20 to 1000 mPas,(e) from 0.05 to 2% by weight of nonionic and/or anionic emulsifier for oil-in-water emulsions,(f) from 0.1 to 3% by weight of polyacrylic acid having an average molecular weight of from 0.8.times.10.sup.6 to 5 .times.10.sup.Type: GrantFiled: March 16, 1987Date of Patent: February 28, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Heinz-Dieter Soldanski, Marlis Kallbe, Bernd-Dieter Holdt