Abstract: The present disclosure provides systems and methods for processing ammonia. A heater may heat reformers, where the reformers comprise ammonia (NH3) reforming catalysts in thermal communication with the heater. NH3 may be directed to the reformers from storage tanks, and the NH3 may be decomposed to generate a reformate stream comprising hydrogen (H2) and nitrogen (N2). At least part of the reformate stream can be used to heat reformers. Additionally, the reformate stream can be directed to a hydrogen processing module such as a fuel cell.

Abstract: Provided is a method for manufacturing a catalyst with which it is possible to obtain a supported metal ammonia synthesis catalyst, in which there are restrictions in terms of producing method and producing facility, and particularly large restrictions for industrial-scale producing, in a more simple manner and so that the obtained catalyst has a high activity. This method for manufacturing an ammonia synthesis catalyst includes: a first step for preparing 12CaO·7Al2O3 having a specific surface area of 5 m2/g or above; a second step for supporting a ruthenium compound on the 12CaO·7Al2O3; and a third step for performing a reduction process on the 12CaO·7Al2O3 supporting the ruthenium compound, obtained in the second step. This invention is characterized in that the reduction process is performed until the average particle diameter of the ruthenium after the reduction process has increased by at least 15% in relation to the average particle diameter of the ruthenium before the reduction process.

Abstract: An apparatus for producing ammonia or hydrogen may include a) a gas stream feed conduit having a connecting conduit to a steam reformer with a waste heat section; b) a heat exchanger downstream of the gas stream feed conduit; c) a gas stream preheater downstream of the heat exchanger; d) a recirculation conduit which is located downstream of the gas stream preheater and leads to the gas stream feed conduit or, upstream of the heat exchanger, to the connecting conduit; and e) the steam reformer with the waste heat section, where the waste heat section may be in thermal contact with the gas stream preheater and the flow of the gas stream which has been heated in the gas stream preheater through the recirculation conduit can be regulated. A process for producing ammonia or hydrogen may employ such an apparatus.

Abstract: Disclosed in the present invention is a method for preparing nickel sulfate from a nickel-iron-copper alloy. The method comprises: in a high-pressure oxygen environment, mixing a nickel-iron-copper alloy crushed material, aqueous ammonia, ammonium sulphate, and a corrosion assisting agent, leaching, then performing solid-liquid separation on the leached slurry, adding a precipitant into a filtrate, and performing ammonia distillation to obtain a nickel-containing leachate; then adding an extractant into the nickel-containing leachate to extract nickel so as to obtain a nickel-containing extraction organic phase; and then adding sulfuric acid into the nickel-containing extraction organic phase to perform back extraction of nickel so as to obtain a nickel sulfate solution.

Abstract: A process for on-site hydrogen reforming is disclosed. The process includes providing a combined reformer heat exchanger component in which heated air, steam, and hydrocarbon fuel react to form process gas containing hydrogen, and the process gas is cooled via the heat exchanger. The combined components enable reductions in size, materials, costs, and heat loss. Additionally, as the heat exchanger side of the component operates at a cooler temperature, an uninsulated flange for access to the catalyst chamber can be used. A combined combustion heat exchanger component is also provided with similar advantages. Process gas is processed, and hydrogen gas is produced via a purification process.

Abstract: A method for producing a sulfide solid electrolyte having an argyrodite-type crystal structure may involve: mixing a raw material containing elemental phosphorus at an integrated power of 0.5 kWh/kg or more, and heat-treating a precursor obtained in the mixing at 350 to 500° C.

Abstract: The present disclosure provides systems and methods for processing ammonia. A heater may heat reformers, where the reformers comprise ammonia (NH3) reforming catalysts in thermal communication with the heater. NH3 may be directed to the reformers from storage tanks, and the NH3 may be decomposed to generate a reformate stream comprising hydrogen (H2) and nitrogen (N2). At least part of the reformate stream can be used to heat reformers. Additionally, the reformate stream can be directed to a hydrogen processing module such as a fuel cell.

Abstract: A production method of boron carbide nano-sized particles and/or submicron particles includes the following sequential steps: obtention of a fluid mixture including elemental boron, glycerin and one or more carboxylic acid, wherein a molar ratio of glycerin to the one or more carboxylic acids is within a range between 10:1 and 10:7.5. Heating of the fluid mixture to obtain a first mid-product in a form of a gel including borate ester bonds. Solidification of the first mid-product by heating a reaction product to obtain a second mid-product in solid form. Sintering the second mid-product to obtain boron carbide in a form of particles.

Abstract: Bimetallic polyanionic materials, such as silver vanadium phosphorus oxide (Ag2VO2PO4, SVOP), are promising cathode materials for Li batteries due in part to their large capacity and high current capability. A new synthesis of Ag2VO2PO4 based on microwave heating is disclosed, where the reaction time is reduced by approximately 100 times relative to other reported methods, and the crystallite size is controlled via synthesis temperature, showing a linear positive correlation of crystallite size with temperature. Reaction times of an hour or less are sufficient to render phase-pure material after reaction at 50° C. to 180° C., significantly lower than the temperatures reported for other methods. Crystallite sizes between 42 nm and 60 nm are achieved by the novel method, smaller than by other methods. Silver/vanadium atomic ratios of 1.96 to 2.04 in the as-synthesized SVOP result and appear temperature-dependent.

Abstract: Flow through reactors and related methods for use with slurries including water reactive particles are generally described.

Abstract: The reaction of sodium hypochlorite with sodium bromide is slow, and commonly only part of the bromide is converted to hypobromite. Methods to accelerate the reaction by adding a regulated amount of acid to a solution comprising bleach and bromide are provided, whereby the yield of hypobromite can be increased. The amount of acid added can be predetermined based on the content of a base in the bleach, and acid can be added to neutralize the base. The amount of acid added can be based on a measured parameter of the reaction that is indicative of reaction kinetics. For example, the amount of acid can be actively controlled by measuring pH, absorbance of visible or near Ultraviolet light, or temperature of the reacting solution and adjusting acid.

Abstract: A method of operating a mass spectrometer vacuum interface, the vacuum interface comprising an evacuated expansion chamber downstream of a plasma ion source at atmospheric or relatively high pressure, the expansion chamber having a first aperture that interfaces with the plasma ion source to form an expanding plasma downstream of the first aperture and a second aperture downstream of the first aperture from the plasma for skimming the expanding plasma to form a skimmed expanding plasma; wherein the expansion chamber is pumped by an interface vacuum pump to provide an interface pressure in the chamber; the method comprising using a controller to automatically, or according to user input, control the throughput of the interface vacuum pump to control the interface pressure dependent on one or more operating modes of the spectrometer. A pressure gauge can be located in the expansion chamber and a feedback loop provided between the pressure gauge and controller.

Abstract: Embodiments of the disclosure provide an apparatus and process for producing ammonia. The apparatus includes a reactor having (i) an inlet to receive an inlet gas comprising nitrogen and hydrogen, (ii) a catalyst and an absorbent disposed within an internal volume of the reactor, the catalyst configured to convert the nitrogen and hydrogen to a reaction mixture including ammonia, unreacted nitrogen, and unreacted hydrogen, the absorbent configured to selectively absorb a portion of the ammonia in the reactor during formation of the reaction mixture, and (iii) an outlet to discharge the reaction mixture from the reactor.

Abstract: A manganese carbide (Mn4C) magnetic material and a production method therefor are provided. According to one embodiment, the saturation magnetization of the Mn4C magnetic material increases with increasing temperature, and thus the Mn4C magnetic material is applicable to fields in which thermally induced magnetization reduction is critical.

Abstract: The present disclosure provides systems and methods for processing ammonia. A heater may heat reformers, where the reformers comprise ammonia (NH3) reforming catalysts in thermal communication with the heater. NH3 may be directed to the reformers from storage tanks, and the NH3 may be decomposed to generate a reformate stream comprising hydrogen (H2) and nitrogen (N2). At least part of the reformate stream can be used to heat reformers. Additionally, the reformate stream can be directed to a hydrogen processing module such as a fuel cell.

Abstract: An exemplary hydrogen production apparatus 100 according to the present invention includes a grinding unit 10 configured to grind a silicon chip or a silicon grinding scrap 1 to form silicon fine particles 2, and a hydrogen generator 70 configured to generate hydrogen by causing the silicon fine particles 2 to contact with as well as disperse in, or to contact with or dispersed in water or an aqueous solution. The hydrogen production apparatus 100 can achieve reliable production of a practically adequate amount of hydrogen from a start material of silicon chips or silicon grinding scraps that are ordinarily regarded as waste. The hydrogen production apparatus thus effectively utilizes the silicon chips or the silicon grinding scraps so as to contribute to environmental protection as well as to significant reduction in cost for production of hydrogen that is utilized as an energy source in the next generation.

Abstract: A method of co-producing liquid hydrogen and ammonia, including a hydrogen generator, a nitrogen generator, and a HLU is presented. The method includes pressurizing a hydrogen stream from the hydrogen generator in a hydrogen compressor, dividing the pressurized hydrogen into at least a first portion and a second portion, wherein the first portion includes at least part of the flow of a first refrigeration cycle in the HLU, and the second part comprises at least part of the feed to an ammonia plant. The method also includes pressurizing a nitrogen stream from the nitrogen generator in a HP nitrogen compressor, dividing the pressurized nitrogen stream into at least a first part and a second part, wherein the first part comprises at least part of the flow of a second refrigeration cycle in the HLU, and the second part comprises at least part of the feed to the ammonia plant.

Abstract: The present disclosure provides systems and methods for processing ammonia. A heater may heat reformers, where the reformers comprise ammonia (NH3) reforming catalysts in thermal communication with the heater. NH3 may be directed to the reformers from storage tanks, and the NH3 may be decomposed to generate a reformate stream comprising hydrogen (H2) and nitrogen (N2). At least part of the reformate stream can be used to heat reformers. Additionally, the reformate stream can be directed to a hydrogen processing module such as a fuel cell.

Abstract: A method for preparing a cathode active material precursor for a secondary battery, including: moving a co-precipitation filtrate generated after a co-precipitation reaction to a co-precipitation filtrate storage tank; removing a metal hydroxide by passing the co-precipitation filtrate through a filter; reacting the co-precipitation filtrate from which the metal hydroxide is removed with sulfuric acid or nitric acid to produce an ammonium sulfate or an ammonium nitrate while removing ammonia from the co-precipitation filtrate from which the metal hydroxide is removed; cooling and crystallizing the co-precipitation filtrate from which the metal hydroxide and ammonia are removed to precipitate a sodium sulfate; filtering the precipitated sodium sulfate to separate the precipitated sodium sulfate from the co-precipitation filtrate from which the metal hydroxide and ammonia are removed; drying the sodium sulfate separated from the co-precipitation filtrate and moving the co-precipitation filtrate separated from t

Abstract: The disclosure provides a silicon carbide seed crystal and a method of manufacturing a silicon carbide ingot. The silicon carbide seed crystal has a silicon surface and a carbon surface opposite to the silicon surface. A difference D between a basal plane dislocation density BPD1 of the silicon surface and a basal plane dislocation density BPD2 of the carbon surface satisfies the following formula (1), a local thickness variation (LTV) of the silicon carbide seed crystal is 2.5 ?m or less, and a stacking fault (SF) density of the silicon carbide seed crystal is 10 EA/cm2 or less: D=(BPD1?BPD2)/BPD1?25%??(1).