Abstract: A process for which making silicone-filler mixtures which comprises effecting the ring-opening polymerisation of a cyclosiloxane with a phosphazene base in the presence of a filler and of water, preferably from 0.5 mil to 10 mols of water per mol of phosphazene base. The filler is preferably selected from silica, alumina, titanium dioxide, carbon black and calcium carbonate, present in an amount of from 1 to 200 parts by weight per 100 parts by weight of cyclosiloxane. An agent or conditions which inhibit catalyst activity may initially be present (e.g. carbon dioxide or excess water), and polymerisation may be initiated by reducing the effect of the inhibiting agent or conditions (e.g. by heating). Silicon-elastomers produced by curing such silicone polymer-filler mixtures are also claimed.
Abstract: A glass fiber capable of withstanding temperatures in excess of 1900.degree. F. is produced by treating a glass, preferably E-glass, fiber. The glass fiber is first leached with selected acids, and then the leached fiber is treated with organo-metallic materials of low viscosity, such as a dispersion of low molecular weight water-in-oil emulsion of dimethyl polysiloxane. The fiber is used in such applications as embedding it in a fire-resistant active coating material or embedding it into one surface of a polyolefin or composite plastic, such as a polypropylene sheet. The treated fiberglass can be used as a sole component or in concert with a fire-resistant or fire retardant material to further enhance its fire-resistant properties.
Type:
Grant
Filed:
July 17, 1997
Date of Patent:
December 14, 1999
Assignee:
Nu-Chem, Inc.
Inventors:
Allen W. Thorpe, Edward W. Taylor, Jr., Rubin Feldman, Malkit S. Deogon
Abstract: A high optical density, i.e., .gtoreq.3.0, at 1 micron or less film thickness, black matrix is disclosed having improved stability and shelf life as a consequence of admixing Pigment Black 7 and organic dye or dye mixtures on a polyimide polymer vehicle.
Type:
Grant
Filed:
December 1, 1997
Date of Patent:
December 7, 1999
Assignees:
Brewer Science, Inc., Nissan Chemical Industries, Ltd.
Inventors:
Ram W. Sabnis, Terry L. Brewer, Robert E. Nichols, Edith G. Hays, Michael D. Stroder, Akira Yanagimoto, Yasuhisa Sone, Yoshitane Watanabe, Kiyomi Ema
Abstract: A film component having a) a haloelastomer with halogenated monomers, polyorganosiloxane monomers, or both halogenated and polyorganosiloxane monomers, and b) a doped metal oxide, preferably antimony doped tin oxide, dispersed therein, wherein the film component is useful as components in xerographic processes.
Type:
Grant
Filed:
January 8, 1998
Date of Patent:
November 30, 1999
Assignee:
Xerox Corporation
Inventors:
Edward L. Schlueter, Jr., Joseph Mammino, Gerald M. Fletcher, Donald S. Sypula, James F. Smith, Lucille M. Sharf, Robert M. Ferguson
Abstract: Water-soluble, nonionic cellulose ethers selected from the group consisting of alkylcelluloses and hydroxyalkylcelluloses having an average degree of polymerization of less than 900 which is substituted by, on average, from 0.01 to 0.04 2-propenyl groups per anhydroglucose unit are used as protective colloids in the preparation of aqueous polymer dispersions.
Type:
Grant
Filed:
March 2, 1998
Date of Patent:
November 30, 1999
Assignee:
Clariant GmbH
Inventors:
Reinhard Doenges, Rudolf Ehrler, Horst Wurm
Abstract: Aqueous dispersions organopolysiloxanes which are free of organic transition metal compounds and of organic compounds of the metals of the main groups III, IV and V. These dispersions can be produced using the following starting compounds:(A) organopolysiloxane containing condensation-capable groups;(B) an organosilicon compound of the formula{[(RO).sub.3 Si--R.sup.3 --].sub.e R.sup.2.sub.1-e }.sub.a Si(OR).sub.4-a(II),in whichR is identical or different and is a hydrogen atom or alkyl radical having 1 to 6 carbon atoms,R.sup.2 is identical or different and is an SiC-bonded hydrocarbon radical having 1 to 18 carbon atoms, optionally substituted with halogen atoms, ether groups, ester groups, epoxy groups, mercapto groups or (poly)glycol radicals comprised of oxyethylene units, oxypropylene units and mixtures thereofR.sup.3 is identical or different and is a divalent hydrocarbon radical,a is 0 or 1, ande is 0 or 1 where {[(RO).sub.3 Si--R.sup.3 --].sub.e R.sup.2.sub.1-e }.sub.
Type:
Grant
Filed:
November 10, 1997
Date of Patent:
November 16, 1999
Assignee:
Wacker-Chemie GmbH
Inventors:
Stefan Oberneder, Karl Braunsperger, Alfred Heinrich, Rudolf Braun, Herbert Soellradl
Abstract: Allylic copolymer resins and processes for making them are disclosed. The resins are made by copolymerizing an ethylenic monomer, a monofunctional allyl monomer, and a multifunctional allyl monomer under free-radical conditions. The multifunctional allyl monomer is used in an amount and manner effective to give a copolymer resin having a polydispersity (Mw/Mn) within the range of about 5 to about 30. The resins, which are easy to make with even bulk polymerization, are particularly valuable, for example, as toner resins, thermoset resins, reactive plasticizers, and rheology modifiers.
Abstract: This invention relates to a gas refining system wherein a high-temperature and high-pressure reducing gas is introduced into a fixed-bed desulfurizer packed with an adsorbent by which sulfur compounds contained in the high-temperature and high-pressure reducing gas are adsorbed and removed in the form of a sulfide, and the adsorbent having the sulfide adsorbed thereon is regenerated by roasting it with a regenerating gas containing oxygen, characterized in that the gas refining system is equipped with oxygen concentration control means for controlling the oxygen concentration in the regenerating gas introduced into the desulfurizer so as to keep the internal temperature of the desulfurizer during the regeneration reaction within the allowable temperature range of the adsorbent.
Abstract: Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (between 15% and 30% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor.
Type:
Grant
Filed:
September 5, 1997
Date of Patent:
November 9, 1999
Assignee:
The Regents of the University of California
Abstract: The invention relates to a pigment with color dependent on the viewing angle, which has been obtained by three-dimensional crosslinking of oriented substances of liquid-crystalline structure having a chiral phase. In order to stabilize the color of such a pigment at elevated temperatures, crosslinking is carried out in the presence of at least one additional, color-neutral compound comprising at least two crosslinkable double bonds.
Type:
Grant
Filed:
January 16, 1997
Date of Patent:
November 2, 1999
Assignee:
DaimlerChrysler AG
Inventors:
Fritz Dannenhauer, Kaarl Holdik, Fritz Mezger
Abstract: Disclosed is a resol phenolic thermosetting resin made by preparing a composition of formaldehyde and a phenol in a molar ratio of about 1:1 to about 3:1, about 1 to about 20 wt %, based on the weight of said composition, of a phenol-formaldehyde polymerization catalyst, and about 0.5 to about 10 wt %, based on the weight of said phenol, of a polyvinyl alcoholic compound. The phenol can be benzophenol, an alkyl from C.sub.1 to C.sub.12 phenol, a bisphenol, or a mixture thereof. The bisphenol can be bisphenol A, bisphenol F, or bisphenol S. The polyvinyl alcoholic compound can be polyvinyl alcohol, polyvinyl acetate, an acetal derived from polyvinyl alcohol, or a mixture thereof. The composition is heated at about 50 to about 120.degree. C. to form the resin.
Abstract: A conductive paste compound for via hole filling includes a conductive filler at 80 to 92 weight percent with an average particle size of from 0.5 to 20 .mu.m and specific surface of from 0.1 to 1.5 m.sup.2 /g, a liquid epoxy resin at 4.5 to 20 weight percent containing 2 or more epoxy groups with room temperature viscosity of 15 Pa.sec or less, and a hardener at 0.5 to 5 weight percent, wherein the viscosity is 2,000 Pa.sec or less and the volatile amount is 2.0 weight percent or less. A filling paste and a printed circuit board with use thereof are provided which can conduct an inner-via-hole connection between electrode layers without using a through-hole plating technique.The conductive paste comprises a metallic particle such as copper, an epoxy resin, a hardener, and if necessary, a dispersant. The paste having low viscosity and low volatility under high shear is used to fill holes disposed in a laminated substrate.
Abstract: A chiral (R) stereospecific polyhydroxyalkanoate (PHA) in aqueous latex form having virgin disperse phase particles of very low or undetectable crystallinity is useful in making a water-sensitive structure water-resistant. It may be used as a mixture with a latex of a synthetic polymer. Processes for making the PHA latex are disclosed.
Type:
Grant
Filed:
November 24, 1997
Date of Patent:
November 2, 1999
Assignee:
Monsanto Company
Inventors:
Neil George, Timothy Hammond, John MacDonald Liddell, Rajasingham Satgurunathan, Peter Deryk Turner
Abstract: The present invention provides polyester/vinyl dioxolane based coating compositions containing no or essentially no volatile organic components. Oligomers for forming the coating compositions of the present invention are vinyl dioxolane end-capped polyester oligomers.
Type:
Grant
Filed:
October 30, 1997
Date of Patent:
November 2, 1999
Assignee:
Foster-Miller, Inc.
Inventors:
Robert F. Kovar, William E. Dorogy, Jr., Brian P. Farrell, Nelson Landrau
Abstract: In the process according to the invention molding compounds based on duroplastic bonding agents are produced thereby that the bonding agents are mixed as a melt with the filler and additive substances. Curing is achieved thereby that the temperature of the mixture during the mixing process increases above the onset temperature of the curing reaction and, after the desired degree of curing has been attained, is suddenly lowered.
Type:
Grant
Filed:
January 20, 1998
Date of Patent:
November 2, 1999
Assignee:
Bakelite AG
Inventors:
Herbert Knorr, Peter Adolphs, Werner Nolte, Bernd Rau, Bernhard Muller, Michael Hermann
Abstract: A flash-spinning solution of a polyolefin dissolved in a primary solvent selected from the group consisting of methylene chloride and dichloroethylene, and a co-solvent selected from the group of hydrofluoroethers, cyclic perfluorinated hydrocarbons, and cyclic partially fluorinated hydrocarbons.
Abstract: A process and materials made by the process which includes a bicomponent fiber, made of a nonconductive first component, including a first fiber-forming polymer selected from the group consisting of polyethylene terephthalate, nylon 6, nylon 6,6, cellulose, polypropylene cellulose acetate, polyacrylonitrile and copolymers of polyacrylonitrile; a conductive second component, including carbon particles and a second fiber-forming polymer selected from the group consisting of polyethylene terephthalate, nylon 6, nylon 6,6, cellulose, polypropylene cellulose acetate, polyacrylonitrile and copolymers of polyacrylonitrile; and a conductive third component, including a polymer selected from the group consisting of polypyrrole and polyaniline, said polymer formed in situ and being interspersed among at least a portion of the carbon particles of the second component.
Type:
Grant
Filed:
June 4, 1997
Date of Patent:
October 26, 1999
Assignee:
Sterling Chemicals International, Inc.
Inventors:
Edgardo Rodriguez, John W. Lindsay, William E. Streetman
Abstract: Dispersible additive systems for polymeric materials include dispersant-coated pigments in a liquid nonaqueous polymeric carrier. The additive systems are most preferably in the form of a particulate nonaqueous paste which can be added in metered amounts (dosed) to a melt flow of the polymeric host material prior to being shaped (for example, prior to being spun into synthetic filaments). By providing a number of additive systems having a number of different additive attributes, and controllably dosing one or more into the melt flow of polymeric material, shaped objects of the polymeric material (e.g., melt-spun filaments) having different additive attributes may be produced on a continuous basis without shutting down the shaping operation.
Type:
Grant
Filed:
October 14, 1997
Date of Patent:
October 26, 1999
Assignee:
BASF Corporation
Inventors:
Donald Caswell, Frank R. Jones, Stanley A. McIntosh, Gary W. Shore, G. Daniel Gasperson
Abstract: A silicone resin-containing emulsion composition is prepared by emulsion polymerizing a solution containing a water-insoluble silanol group-bearing silicone resin and a radical polymerizable vinyl monomer and substantially free of an organic solvent. The emulsion may further contain a film-forming assistant having a boiling point of at least 100.degree. C. and soluble or uniformly dispersible in water. The emulsion can be coated and cured into a film having mar resistance, weather resistance, and chemical resistance.
Abstract: The novel polyfunctional peroxides are compounds represented by the following general formula (1):R.sup.1 --CX.sub.3 (1)wherein R.sup.1 represents a linear alkyl group having 1 to 3 carbon atoms; and X represents a group: ##STR1## (wherein R.sup.2 represents a linear or branched alkyl group having 1 to 5 carbon atoms).Such polyfunctional peroxides include 1,1,1-tris(t-butylperoxycarbonyloxymethyl)propane and the like. The polymerization initiators for vinyl monomers comprise such polyfunctional peroxides. In the process for polymerizing vinyl monomers, a vinyl monomer is polymerized employing such polyfunctional peroxide at 60 to 160.degree. C.