Patents Examined by Thomas R. Neville
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Patent number: 5411856Abstract: Novel compounds represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.2 represent hydrogen or alkyl, R.sub.3 represents hydrogen, alkyl, substituted alkyl or CONR.sub.1 R.sub.2, and n is 0 to 6, can be used to harden gelatin. The compounds are particularly useful for hardening gelatin of a photographic element.Type: GrantFiled: January 10, 1994Date of Patent: May 2, 1995Assignee: Eastman Kodak CompanyInventors: Edgar E. Riecke, Kenneth G. Harbison
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Patent number: 5411843Abstract: A photographic material comprising at least one silver halide emulsion layer and a copolyester support-said copolyester comprising polyether group(s) in the side chain is disclosed.Preferably the copolyester is prepared by copolycondesing diol moieties that comprise a polyether group substituted with a sulfonic acid group in acid or salt form into the copolyester.Type: GrantFiled: September 20, 1993Date of Patent: May 2, 1995Assignee: AGFA-Gevaert, N.V.Inventors: August Marien, Marc Stevens, Joannes Verheijen
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Patent number: 5407792Abstract: The present invention relates to photosensitive silver halide recording material with reduced pressure sensitivity. The occurrence of pressure marks can be minimized by protective layers with suitable additives. Other properties of the recording material, such as sensitivity, contrast, and clarity, are not affected adversely. Recording materials with protective layers containing polyolefin oxidates are largely insensitive to pressure marks and have low haze, high sensitivity, and high contrast. The invention's recording materials can be used in all fields of photographic and radiographic image production, especially in reproducing color images in steps preliminary to printing and in recording x-ray images for medical diagnostics.Type: GrantFiled: March 30, 1994Date of Patent: April 18, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Reinhold Ruger
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Patent number: 5407791Abstract: A silver halide photographic material comprising a polyester support having formed thereon at least one light-sensitive silver halide emulsion layer is disclosed, said polyester support having a glass transition temperature of from 90.degree. to 200.degree. C. and having had at least one side thereof subjected to ultraviolet-light irradiation. The photographic material exhibits improved anticurl properties and high adhesion between the emulsion layer and the support.Type: GrantFiled: January 14, 1994Date of Patent: April 18, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Fumio Kawamoto
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Patent number: 5407790Abstract: A system for orthopedic imaging is disclosed which consists of a supply of low crossover sensitometrically asymmetric radiographic elements and cassettes with various front and back intensifying screens to produce optimal bone images and useful images of surrounding flesh.Type: GrantFiled: February 4, 1994Date of Patent: April 18, 1995Assignee: Eastman Kodak CompanyInventors: Robert E. Dickerson, Phillip C. Bunch
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Patent number: 5399470Abstract: Radiographic elements and assemblies are disclosed. The radiographic element has silver halide emulsion layer units coated on opposite sides of a film support, and are constructed to minimize crossover during exposure by the intensifying screens. The minimal crossover radiographic elements record both bone and soft tissue structure because a silver halide emulsion layer unit on one side of the support is chosen to exhibit an emission and contrast exceeding that of another silver halide emulsion layer unit on the opposite side of the support. Radiographic assemblies consisting of the radiographic elements and various front and back intensifying screens produce clear and useful X-ray images of the various bones and surrounding soft tissue structures of the body.Type: GrantFiled: February 4, 1994Date of Patent: March 21, 1995Assignee: Eastman Kodak CompanyInventors: Robert E. Dickerson, Phillip C. Bunch
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Patent number: 5399480Abstract: The invention describes silver halide packet emulsion grains or crystals that are conventionally precipitated using gelatin of a given isoelectric pH, surrounded by a layer of gelatin-grafted-polymer particles wherein the grafted gelatin has a different isoelectric pH and the said gelatin-grafted-polymer particles are optionally chemically bonded to the gelatin surrounding the silver halide microcrystals. Such packet emulsions can form the basis for a mixed-packet color photographic system.Type: GrantFiled: September 14, 1993Date of Patent: March 21, 1995Assignee: Eastman Kodak CompanyInventors: Mark A. Whitson, John D. Lewis, Tienteh Chen, Thomas J. Dannhauser, Pranab Bagchi
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Patent number: 5397687Abstract: The preparation of x-ray materials, especially suitable for non-destructive testing applications, is described. The emulsion layers of said material are comprising silver halide emulsion grains containing at least 75 mole % of silver chloride and less than 25 mole % of silver bromide and are characterized by a ratio between the amount of gelatin and the amount of silver halide, being expressed as the equivalent amount of silver nitrate, of less than 0.6. Hardening of said material is performed in such a way that the amount of demineralized water of 25.degree. C. absorbed in 3 minutes is less than 2.5 g per gram of gelatin present in said material. A rapid processing system is available with a total processing time of less than 3 minutes with a developer and fixer being substantially free from hardening agents and the fixer being substantially free from ammonium ions.Type: GrantFiled: December 14, 1993Date of Patent: March 14, 1995Assignee: Agfa-Gevaert, N.V.Inventors: Peter Willems, Freddy Henderickx, Gino De Rycke, Romain Bollen
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Patent number: 5395748Abstract: An inexpensive, ballasted optical brightener for use in photographic elements is prepared by reacting an optical brightener of the formula ##STR1## where M is a cation; X is a group capable of undergoing nucleophilic displacement; and Z is ##STR2## or --O--R.sub.3, where each of R1 and R2 is a hydrogen atom, or an aromatic group which can be unsubstituted or substituted with one or more groups unreactive towards X; and R3 is an aromatic group which can be unsubstituted or substituted with one or more groups unreactive towards Xwith a water soluble polymer, such as gelatin. The resulting ballasted optical brightener is stable in aqueous photographic compositions.Type: GrantFiled: December 8, 1993Date of Patent: March 7, 1995Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Pranab Bagchi
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Patent number: 5393649Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating include an adhesive interlayer interposed between the imaging layer and a protective overcoat layer. The adhesive interlayer, which is comprised of a polymer having pyrrolidone functionality, strongly bonds the overcoat layer to the imaging layer.Type: GrantFiled: March 16, 1994Date of Patent: February 28, 1995Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Wayne A. Bowman
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Patent number: 5391469Abstract: Radiographic elements are disclosed each containing a support and, coated on the support, at least two high tabularity tabular grain emulsions. The tabular grains coated on the support exhibit a face centered cubic crystal lattice structure formed by silver bromide with a selected portion of the tabular grains additionally containing iodide substantially uniformly distributed through the crystal lattice structure in an overall concentration of at least 0.5 mole percent with the iodide concentration at any one grain site being less than 5 mole percent. The proportion of the tabular grains selected to contain iodide as well as the distribution of iodide within the tabular grains results in a reduction in pressure induced variance of radiographic imaging response as a function of applied pressure, such as that inadvertently applied during film handling and processing.Type: GrantFiled: October 27, 1993Date of Patent: February 21, 1995Assignee: Eastman Kodak CompanyInventor: Robert E. Dickerson
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Patent number: 5391472Abstract: There is provided a method for preparing a biaxially oriented polyester sheet or web, with improved antistatic properties, comprising the steps of(i) stretching said polyester sheet or web first in one direction and second in a direction perpendicular thereto(ii) coating said hydrophobic polyester sheet or web, either before stretching or between said first and second stretching operation, on one or both sides, with a transparent antistatic primer layer, wherein the coating composition of said transparent antistatic primer layer comprises (1) a dispersion of a polythiophene with conjugated polymer backbone and a polymeric polyanion compound and (2) a latex polymer having hydrophilic functionality.The primer layer is coated from an aqueous composition and does not show a substantial change in resistivity depending on relative humidity or wet processing.Type: GrantFiled: December 8, 1993Date of Patent: February 21, 1995Assignee: AGFA-Gevaert, N.V.Inventors: Bavo Muys, Dirk Quintens, Jozef Boeykens, Etienne Van Thillo, Geert Defieuw
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Patent number: 5391471Abstract: A novel silver halide color photographic material comprising on a support at least one light-sensitive emulsion layer and at least one hydrophilic colloidal layer containing a white pigment between said support and said light-sensitive emulsion layer is provided, wherein (i) said white pigment is incorporated in such an amount that the coated amount thereof in said hydrophilic colloidal layer is in the range of 2 g/m.sup.Type: GrantFiled: June 14, 1993Date of Patent: February 21, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Ohshima, Kentaro Okazaki, Shigeaki Ohtani
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Patent number: 5391459Abstract: Novel compounds have been discovered that are particularly effective as nucleation accelerators or boosters when employed with hydrazide nucleators in the formulation of silver halide emulsions for lithographic film. The novel compounds contain bis ureido groups joined by an alkyleneoxy moiety or recurring alkyleneoxy moieties. The 2-nitrogen of each ureido group can carry groups comprising hydrogen, aryl, alkyl or dialkylaminoalkyl, alike or different.Type: GrantFiled: June 23, 1994Date of Patent: February 21, 1995Assignee: Sun Chemical CorporationInventors: Syeda Husain, Allan P. Piechowski, John F. Pilot
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Patent number: 5389506Abstract: A process of producing a viewable photographic image is disclosed wherein an imagewise exposed photographic element containing at least two silver halide emulsion layers capable of recording within the same region of the spectrum and having differing threshold sensitivities produces during photographic processing spectrally distinguishable images. Separate image records are obtained from the emulsion layers, and the image record corresponding to the photographically superior image is preferentially employed in producing a viewable image.Type: GrantFiled: August 25, 1993Date of Patent: February 14, 1995Assignee: Eastman Kodak CompanyInventor: James E. Sutton
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Patent number: 5389505Abstract: A color photographic material has on a support at least one blue-sensitive layer, at least one green-sensitive layer and at least one red-sensitive layer, and further has an emulsion layer capable of imparting an interlayer effect to the red-sensitive layer. The interlayer effect-donating layer is color-sensitized with both a sensitizing dye of formulae (I) and a sensitizing dye of formula (II): ##STR1## where R.sub.11, R.sub.12, R.sub.21 and R.sub.22 each represents an alkyl group; Z.sub.11 and Z.sub.21 each represents a group of atoms necessary for forming a benzene ring; Z.sub.12 represents a group of atoms necessary for forming a benzothiazzole nucleus or a benzoselenazole nucleus; Z.sub.22 represents a group of atoms necessary for forming a benzoxazole nucleus or a naphthoxazole nucleus; X.sub.11 and X.sub.21 each represents a charge-balancing pair ion; and m and n each represents 0 or 1. The material has an excellent color reproducibility and gives a color image with high chroma and graininess.Type: GrantFiled: August 31, 1993Date of Patent: February 14, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Junji Nishigaki
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Patent number: 5385812Abstract: The invention discloses a continuous method of manufacture of gelled dispersion melts of "small-particle" microprecipitated photographic agents. The continuous melt manufacturing process of this invention provides dispersion melts that are invariant in agent concentration, melt viscosity, and turbidity as a function of the run time and are also very reproducible and robust in repetitive preparations. Many photographic melts of this invention exhibit high photographic activity and light stability of the agents when exposed to light.Type: GrantFiled: December 28, 1992Date of Patent: January 31, 1995Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, James T. Beck, Vincent J. Flow, III
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Patent number: 5384237Abstract: A thermal-dye-bleach construction comprising a dye in association with a thermal dye-bleaching agent of general formula I: ##STR1## wherein: each of R.sup.a and R.sup.b are individually selected from: hydrogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group, and a heterocyclic group, and preferably, both R.sup.a and R.sup.b represent hydrogen;p is one or two, and when p is one, Z is a monovalent group selected from: an akyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, and a heterocyclic group, and when p is two, Z is a divalent group selected from: an alkylene group, an arylene group, an alkenylene group, an alkynylene group, an aralkylene group, a cycloalkene group, and a heterocyclic group; and,M.sup.+ is a cation which will not react with a carbanion generated from the thermal-carbanion-generating agent in such manner as to render the carbanion ineffective as a bleaching agent for the dye.Type: GrantFiled: January 25, 1994Date of Patent: January 24, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Dian E. Stevenson, Mark P. Kirk, Sylvia A. Farnum, William C. Frank, Randall H. Helland, Jonathan P., Kitchin, Roger A. Mader, Mark B. Mizen, Richard A. Newmark, William D. Ramsden, Kumars Sakizadeh, Terence D. Spawn, George V. Tiers
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Patent number: 5382506Abstract: A silver halide color photographic light sensitive material comprising a support which is both side coated with a polyolefin resin is disclosed. A hydrophilic colloidal layer containing a white pigment and a silver halide emulsion layer are provided on the support and the silver halide emulsion layer contains at least one of the compounds represented by the following Formula I, ##STR1## wherein R.sub.1 represents an alkyl group, a cycloalkyl group or an aryl group; R.sub.2 represents a fluorine atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a dialkylamino group, an alkylthio group or an arylthio group; R.sub.3 represents a group substitutable to a benzene ring; n is an integer of 0 or 1; Z represents a hydrogen atom or a group capable of splitting off when coupling it to the oxidized product of a developing agent; and Y represents a monovalent organic group including a ballast group.Type: GrantFiled: August 20, 1993Date of Patent: January 17, 1995Assignee: Konica CorporationInventors: Yasuo Tosaka, Masayuki Sasagawa
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Patent number: 5382496Abstract: There is disclosed a silver halide light-sensitive material and a method for forming image using thereof, in which a high contrast negative image useful in a photographic plate making process can be obtained in a processing solution with a pH lower than 11.0. The silver halide light-sensitive material comprises a support having provided thereon at least one silver halide emulsion layer and containing a hydrazine derivative in the above emulsion layer and/or a layer adjacent thereto. At least one compound represented by the following Formula (I) or (II) is contained in the above emulsion layer and/or a layer adjacent thereto: ##STR1## wherein A represents an organic group necessary for completing a hereto ring; B and C each represents a group constituted of one or more members selected from the group consisting of an alkylene group, an arylene group, an alkenylene group, --SO.sub.2 --, --SO--, --O--, --S--, and --N(R.sub.5)--, where R.sub.5 represents an alkyl group, an aryl group, or a hydrogen atom; R.sub.Type: GrantFiled: December 7, 1993Date of Patent: January 17, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Minoru Sakai, Kazunobu Katoh, Kiyoshi Morimoto