Abstract: The present invention relates to a crosslinked glycerol or oligoglycerol ester which can be obtained by crosslinking a non-crosslinked glycerol or oligoglycerol ester which can be obtained by reacting an (A) acid phase comprising (a1) a fatty acid, (a2) a dicarboxylic acid, (a3) a dimeric fatty acid, (a4) an oligomeric fatty acid, (a5) a hydroxy fatty acid or (a6) a mixture of at least two thereof, with a (B) alcohol phase comprising (b1) monoglycerol, (b2) diglycerol, (b3) triglycerol, (b4) oligoglycerol made up of more than three glycerol units, (b5) an alkoxylate of glycerols (b1), (b2), (b3) or (b4), or (b6) a mixture of at least two thereof, forming a full or partial ester and crosslinking the full or partial ester by means of a crosslinking agent, wherein the crosslinking can take place during or after the formation of the full or partial ester.
Type:
Grant
Filed:
February 6, 2009
Date of Patent:
June 5, 2012
Assignee:
Emery Oleochemicals GmbH
Inventors:
Heinz Muller, Diana Maker, Nadja Herzog, Alfred Westfechtel
Abstract: The present invention describes the use of EDTA and/or alkali treated hard brine at high pH for making ASP formulations for EOR applications.
Type:
Grant
Filed:
September 10, 2010
Date of Patent:
May 29, 2012
Assignee:
Board of Regents, The University of Texas System
Abstract: The present disclosure is directed to a method comprising: mixing (i) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba, (ii) a surfactant and (iii) produced water to form a well servicing fluid. The resulting well servicing fluid is introduced into a hydrocarbon well.
Type:
Grant
Filed:
November 19, 2010
Date of Patent:
May 22, 2012
Assignee:
Baker Hughes Incorporated
Inventors:
D. V. Satyanarayana Gupta, Madhukar Chetty, Paul Scott Carman
Abstract: A method for treating a subterranean formation is made of steps of providing a composition comprising a carrier fluid, a polymer viscosifying agent, carbon dioxide and a formate salt or formic acid; injecting into a wellbore, the composition; contacting the composition with the subterranean formation, wherein the temperature is above 100 degrees Celsius at this contact; and allowing the composition to treat the subterranean formation.
Type:
Grant
Filed:
June 23, 2010
Date of Patent:
May 22, 2012
Assignee:
Schlumberger Technology Corporation
Inventors:
Leiming Li, Lijun Lin, Curtis L. Boney, Michael D. Parris, Kevin W. England
Abstract: A method for treating a subterranean formation includes forming a treatment fluid including a carrier fluid, a solid acid-precursor, and a solid scale inhibitor. The solid acid-precursor includes a material that forms an acid at downhole conditions in the subterranean formation. The method further includes adding a solid acid-responsive material into the treatment fluid, where the solid acid-responsive material enhances formation of acid from the solid acid-precursor in acidic conditions. The method includes performing an acid fracture treatment and inhibiting scale formation within the subterranean formation. The solid scale inhibitor allows for long-term scale inhibition after the treatment.
Type:
Grant
Filed:
February 11, 2011
Date of Patent:
May 22, 2012
Assignee:
Schlumberger Technology Corporation
Inventors:
Marieliz Garcia-Lopez De Victoria, John W. Still, Toan Bui
Abstract: A polyelectrolyte complex for the controlled release of an oil and gas field chemical selected from the group consisting of (a) a gel-forming or cross-linking agent, (b) a scale inhibitor, (c) a corrosion inhibitor, (d) an inhibitor of asphaltene or wax deposition, (e) a hydrogen sulfide scavenger, (f) a hydrate inhibitor, (g) a breaking agent, and a surfactant.
Type:
Grant
Filed:
September 5, 2006
Date of Patent:
May 22, 2012
Assignee:
University of Kansas
Inventors:
Cory Berkland, Mary Cordova, Jenn-Tai Liang, G. Paul Willhite
Abstract: A composition of a microemulsion including a mixture of a combination of surfactants and co-surfactants, an oil phase and an aqueous phase is described. In addition, a method for the advanced recovery of heavy oils is described which includes the steps of injecting a bank containing a microemulsion composition, injecting a bank of a polymer solution, and injecting water. The microemulsion composition can be applied in arenitic and carbonatic reservoirs, containing oils with API below 22.3° API, in both onshore and offshore fields.
Abstract: A well servicing fluid is disclosed. The well servicing fluid is formulated with components comprising: an organic salt, the organic salt being the product of an organic acid and an organic amine base; and an aqueous based solvent. A method of servicing a well is also disclosed.
Abstract: Drilling fluids comprising graphenes and nanoplatelet additives and methods for production thereof are disclosed. Graphene includes graphite oxide, graphene oxide, chemically-converted graphene, and functionalized chemically-converted graphene. Derivatized graphenes and methods for production thereof are disclosed. The derivatized graphenes are prepared from a chemically-converted graphene through derivatization with a plurality of functional groups. Derivatization can be accomplished, for example, by reaction of a chemically-converted graphene with a diazonium species. Methods for preparation of graphite oxide are also disclosed.
Type:
Grant
Filed:
July 8, 2010
Date of Patent:
May 22, 2012
Assignee:
William Marsh Rice University
Inventors:
James M. Tour, Howard K. Schmidt, Jay R. Lomeda, Dmitry V. Kosynkin, Condell D. Doyle
Abstract: Methods for preparing high quality and high yields of nanocrystals, i.e., metal-oxide-based nanocrystals, using a novel solvent-free method. The nanocrystals advantageously comprise organic alkyl chain capping groups and are stable in air and in nonpolar solvents.
Abstract: The present invention relates to glass-ceramic proppants which can be used to prop open subterranean formation fractions, as well as other uses. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the glass-ceramic proppants.
Type:
Grant
Filed:
December 14, 2010
Date of Patent:
May 15, 2012
Assignee:
Oxane Materials, Inc.
Inventors:
Yuming Xie, Dilip Chatterjee, Christopher E. Coker, Christopher Y. Fang
Abstract: A coating composition is provided. The composition comprises as component I, a) a polyaspartic acid ester comprising the reaction product of one more diamines, one or more difunctional acrylate-containing compounds and one or more maleic/fumaric acid esters; b) at least one moisture scavenger; c) at least one deaerator; d) at least one plasticizer; and e) optionally additives; and as component II, one or more polyisocyanates. Methods of making and applying the composition to a substrate are also provided. The coating is particularly suitable for use as a gel coat.
Type:
Grant
Filed:
June 2, 2008
Date of Patent:
May 15, 2012
Assignee:
Bayer MaterialScience LLC
Inventors:
Myron W. Shaffer, John P. Forsythe, Leone Hermans-Blackburn, Amy S. Wylie, Aaron A. Lockhart, Emery Yuhas, Roy B. Clemens
Abstract: Proppants which can be used to prop open subterranean formation fractions are described. Proppant formulations which use one or more proppants of the present invention are described, as well as methods to prop open subterranean formation fractions, and other uses for the proppants and methods of making the proppants.
Type:
Grant
Filed:
September 14, 2011
Date of Patent:
May 15, 2012
Assignee:
Oxane Materials, Inc.
Inventors:
Robert D. Skala, John R. Loscutova, Christopher E. Coker
Abstract: Compositions and methods of preparing functional thin films or surface coatings with low non-specific binding are described. The thin films contain specified functional groups and non-specific binding repellant components. The thin films are either covalently bound to or passively adsorbed to various solid substrates. The specified functional group provides specified activity for the thin film modified solid surfaces and non-specific binding repellant components significantly reduce the non-specific binding to the thin film modified solid surfaces. Non-specific binding repellant components do not affect specified functional group's activity in the thin films. In these methods, specified functional groups are anchored to the solid substrates through a spacer.
Type:
Grant
Filed:
December 7, 2009
Date of Patent:
May 15, 2012
Assignee:
Accelr8 Technology Corporation
Inventors:
Guoqiang Mao, Steven W. Metzger, Michael J. Lochhead
Abstract: A method of coating an implantable medical device may include providing an implantable medical device, applying a polymer base to the medical device, and directing a first solution including therapeutic agent and solvent through the nozzle onto a target zone of the polymer base coating to penetrate the polymer base coating. The solution may be directed at the target zone until a predetermined concentration of the therapeutic agent can be integrated within the polymer base coating.
Type:
Grant
Filed:
May 2, 2008
Date of Patent:
May 8, 2012
Assignee:
Boston Scientific Scimed, Inc.
Inventors:
Liza J. Davis, Thomas Priebe, Kim Robertson
Abstract: A writing implement with a thermochromic coloring color-memory composition which comprises a homogeneous solubilized mixture of (A) an electron donative coloring organic compound, (B) an electron accepting compound and (C) a reaction medium which controls color reactions of the components (A) and (B), wherein a complete decoloring temperature (T4) of the thermochromic coloring color-memory composition is 50° C. or higher and a coloring starting temperature (T2) of thermochromic coloring color-memory composition is 10° C. or lower regarding the color density-temperature curve, and the thermochromic coloring color-memory composition has color-memory ability at the ordinary temperature range.
Abstract: Proppants having added functional properties are provided, as are methods that use the proppants to track and trace the characteristics of a fracture in a geologic formation. Information obtained by the methods can be used to design a fracturing job, to increase conductivity in the fracture, and to enhance oil and gas recovery from the geologic formation. The functionalized proppants can be detected by a variety of methods utilizing, for example, an airborne magnetometer survey, ground penetrating radar, a high resolution accelerometer, a geophone, nuclear magnetic resonance, ultra-sound, impedance measurements, piezoelectric activity, radioactivity, and the like. Methods of mapping a subterranean formation are also provided and use the functionalized proppants to detect characteristics of the formation.
Type:
Grant
Filed:
May 19, 2009
Date of Patent:
May 1, 2012
Assignee:
Oxane Materials, Inc.
Inventors:
Andrew R. Barron, Robert D. Skala, Christopher E. Coker, Dilip K. Chatterjee, Yuming Xie
Abstract: The invention relates to novel composition comprising hydroxylamine esters and thio compounds, which are suitable for lowering the molecular weight of polypropylene, propylene copolymers or polypropylene blends and result in an excellent degradation performance at temperatures below 220° C.
Type:
Grant
Filed:
May 2, 2011
Date of Patent:
May 1, 2012
Assignee:
BASF SE
Inventors:
Michael Roth, Peter Nesvadba, David E. Horst
Abstract: A cement composition and method of applying remedial cement to a downhole perforation is described. The method involves the sequential delivery of a phosphate acid activator and a silicate suspension to the perforation to allow in situ reaction of the activator with the binder within the perforation, thereby forming a phosphosilicate plug.
Abstract: An oil-in-water emulsion that includes a brine continuous phase; and an oleaginous discontinuous phase stabilized by an emulsifier blend, the emulsifier blend comprising: an emulsifier having an HLB greater than 11; and an amphoteric chemotrope is disclosed. Emulsifier blends comprising an emulsifier having an HLB greater than 11 and an amphoteric chemotrope and methods of using emulsifier blends are also disclosed.
Type:
Grant
Filed:
November 21, 2008
Date of Patent:
April 24, 2012
Assignee:
M-I L.L.C.
Inventors:
Eugene Dakin, Hui Zhang, Bethicia B. Prasek