Patents Examined by Tracy M. Dove
  • Patent number: 11594719
    Abstract: A lithium electrode and a lithium secondary battery including the same. The lithium electrode has a surface oxide layer with a controlled thickness and surface roughness. The lithium electrode may be used as a negative electrode of a lithium secondary battery, for example, a lithium-sulfur secondary battery. A lithium-sulfur battery including the lithium electrode has an enhanced lifetime due to suppression of side reactions with polysulfide.
    Type: Grant
    Filed: February 8, 2018
    Date of Patent: February 28, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Taek Gyoung Kim, Jeehyun Ahn, Doo Kyung Yang, Eunkyung Cho, Cholong Lee
  • Patent number: 11576595
    Abstract: Briefly, a sensor for a continuous biological monitor is provided for measuring the level of a target analyte for a patient. The sensor has a working wire and a reference wire, where the working wire has an analyte limiting layer that passes more than 1 in 1000 analyte molecules from the patient to the an enzyme layer. The enzyme layer has an enzyme entrapped in a polyurethane cross-linked with acrylic polyol. As free electrons are generated, a conductor transfers the electrons to the biological monitor. In some cases, the sensor may be constructed without the use of any expensive platinum.
    Type: Grant
    Filed: April 5, 2019
    Date of Patent: February 14, 2023
    Assignee: Zense-Life Inc.
    Inventors: Robert James Boock, Huashi Zhang
  • Patent number: 11581524
    Abstract: The present disclosure relates to a lithium-sulfur battery cathode. The lithium-sulfur battery cathode comprises a carbon nanotube sponge and a plurality of sulfur nanoparticles. Wherein the carbon nanotube sponge comprises a plurality of micropores. The plurality of sulfur nanoparticles are uniformly distributed in the plurality of micropores. The present disclosure also relates a method for making the lithium-sulfur battery cathode and a lithium-sulfur battery using the lithium-sulfur battery cathode.
    Type: Grant
    Filed: November 20, 2019
    Date of Patent: February 14, 2023
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Ling-Jia Yan, Jia-Ping Wang, Kai-Li Jiang, Shou-Shan Fan
  • Patent number: 11563214
    Abstract: An anode material having 0.8?0.06×(Dv50)2?2.5×Dv50+Dv99?12 (1); and 1.2?0.2×Dv50?0.006×(Dv50)2+BET?5 (2), where Dv50 represents a value in the volume-based particle size distribution of the anode material that is greater than the particle size of 50% of the particles, Dv99 represents a value in the volume-based particle size distribution of the anode material that is greater than the particle size of 99% of the particles, and BET is a specific surface area of the anode material, wherein Dv50 and Dv99 are expressed in ?m and BET is expressed in m2/g. The anode material is capable of significantly improving the rate performance of electrochemical devices.
    Type: Grant
    Filed: March 11, 2020
    Date of Patent: January 24, 2023
    Assignee: NINGDE AMPEREN TECHNOLOGY LIMITED
    Inventors: Pengyang Feng, Jiali Dong, Jia Tang, Yuansen Xie
  • Patent number: 11563207
    Abstract: Provided is a current collector electrode sheet (10) including a slurry application area (11) formed by intermittently applying and drying a slurry containing an active material and a non-application area (12), on both surfaces of a metal foil (9), in which the application area (11) and the non-application area (12) are alternately formed in a winding direction of the metal foil (9) having a strip shape, and, in a compression step of continuously compressing the slurry application area (11) and the non-application area (12) using a pair of compression rollers in a thickness direction of the current collector electrode sheet (10), an area which is not compressed by the compression rollers, is present in a tailing portion (14) at a terminal end (13) of each application area (11).
    Type: Grant
    Filed: September 25, 2018
    Date of Patent: January 24, 2023
    Assignee: ENVISION AESC JAPAN LTD.
    Inventors: Dai Aya, Mayuko Koyama
  • Patent number: 11557754
    Abstract: A positive electrode active material for a lithium secondary battery, comprising a lithium-containing composite metal oxide in the form of secondary particles formed by aggregation of primary particles capable of being doped and undoped with lithium ions, each of the secondary particles having on its surface a coating layer, the positive electrode active material satisfying the following requirements (1) to (3): (1) the metal oxide has an ?-NaFeO2 type crystal structure of following formula (A): Lia(NibCocM11-b-c)O2??(A) wherein 0.9?a?1.2, 0.9?b<1, 0<c?0.1, 0.9<b+c?1, and M1 represents at least one optional metal selected from Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In and Sn; (2) the coating layer comprises Li and M2, wherein M2 represents at least one optional metal selected from Al, Ti, Zr and W; and (3) the active material has an average secondary particle diameter of 2 to 20 ?m, a BET specific surface area of 0.1 to 2.
    Type: Grant
    Filed: January 26, 2015
    Date of Patent: January 17, 2023
    Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, TANAKA CHEMICAL CORPORATION
    Inventors: Tetsuri Nakayama, Kenji Takamori, Kyousuke Doumae, Takashi Kitamoto
  • Patent number: 11552282
    Abstract: According to an exemplary embodiment of the present invention, a roll press apparatus is provided. The roll press apparatus presses electrode sheets, each including a both-side coated portion where an electrode mixture is applied to both sides of a current collector and a one-side coated portion where the electrode mixture is applied to one side of a current collector, by passing the electrode sheet through a separated space between a pair of press rolls.
    Type: Grant
    Filed: October 8, 2019
    Date of Patent: January 10, 2023
    Inventor: Jong Min Bang
  • Patent number: 11545659
    Abstract: A negative electrode for a lithium secondary battery, where the negative electrode includes a negative electrode current collector, a negative electrode active material layer, a lithium layer that is positioned between the negative electrode current collector and the negative electrode active material layer, and a primer layer that is positioned between the negative electrode current collector and the lithium layer, and a manufacturing method thereof. This results in a simple method and a negative electrode with high capacity characteristics.
    Type: Grant
    Filed: November 21, 2018
    Date of Patent: January 3, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Yeon Suk Hong, Seok Koo Kim, Sun Kyu Kim, Ji Won Min
  • Patent number: 11527748
    Abstract: In accordance with some embodiments of the present invention, an electrode was provided. The electrode includes an electrode composite layer and a porous insulating layer on the electrode composite layer. The electrode composite layer contains an active material. A surface roughness Rz of the electrode composite layer is smaller than an average film thickness of the porous insulating layer.
    Type: Grant
    Filed: January 24, 2020
    Date of Patent: December 13, 2022
    Assignee: RICOH COMPANY, LTD.
    Inventors: Eiko Hibino, Hiromichi Kuriyama, Satoshi Nakajima, Shigeo Takeuchi, Toru Ushirogochi, Hideo Yanagita, Keigo Takauji, Miku Ohkimoto
  • Patent number: 11527754
    Abstract: A solid-state composite electrode includes active electrode particles, ionically conductive particles, and electrically conductive particles. Each of the ionically conductive particles is at least partially coated with an isolation material that inhibits inter-diffusion of the ionically conductive particles with the active electrode particles. A battery cell includes a first current collector, a solid electrolyte layer, a first solid-state composite electrode having ionically conductive particles coated with an isolation material and positioned between the first current collector and the solid electrolyte layer, a second current collector, and a second electrode positioned between the solid electrolyte layer and the second current collector. A method of forming a solid-state composite electrode includes mixing together active electrode particles and electrically conductive particles with ionically conductive particles that are each at least partially coated with an isolation material.
    Type: Grant
    Filed: September 21, 2018
    Date of Patent: December 13, 2022
    Assignee: Robert Bosch GmbH
    Inventors: John F. Christensen, Nathan P. Craig, Sondra Hellstrom, Boris Kozinsky, Saravanan Kuppan
  • Patent number: 11508959
    Abstract: A lithium coating method includes: coating an oxide layer having lithiophilic properties on a metal material by heating the metal material at a certain temperature; and coating a lithium layer on the oxide layer by bringing the metal material coated with the oxide layer into contact with molten lithium.
    Type: Grant
    Filed: May 21, 2020
    Date of Patent: November 22, 2022
    Assignee: AGENCY FOR DEFENSE DEVELOPMENT
    Inventors: Yu Song Choi, Tae Young Ahn, Hye Ryeon Yu, Jang Hyeon Cho
  • Patent number: 11508956
    Abstract: A method of manufacturing a free-standing electrode film includes preparing a mixture including an electrode active material, a binder, and an additive solution or conductive paste, the additive solution or conductive paste being in an amount less than 5% by weight of the mixture and including a polymer additive and a liquid carrier, as well as a conductive material in the case of a conductive paste. The mixture may have total solid contents greater than 95% by weight. Preparing the mixture may include mixing the additive solution or conductive paste with the electrode active material to lubricate the electrode active material and subsequently adding and mixing in the binder. The method may further include subjecting the mixture to a shear force and, after the mixture has been subjected to the shear force, pressing the mixture into a free-standing film.
    Type: Grant
    Filed: September 8, 2020
    Date of Patent: November 22, 2022
    Assignee: LiCap Technologies, Inc.
    Inventors: Linda Zhong, Erika Shaw, Bae Kyun Kim
  • Patent number: 11489186
    Abstract: An air-water concentration cell is provided as follows. A cathode electrode is formed of a first material for catalyzing an oxygen reduction reaction (ORR). An anode electrode is formed of a second material for catalyzing an oxygen evolution reaction (OER). A proton conductive membrane is interposed between the cathode electrode and the anode electrode. A fuel reservoir is interposed between the proton conductive membrane and the anode electrode. The fuel reservoir contains water. The water of the fuel reservoir is in contact with the anode electrode and the proton conductive membrane.
    Type: Grant
    Filed: November 10, 2020
    Date of Patent: November 1, 2022
    Inventors: Typher Yom, Jong Won Yom, Phillip Yom
  • Patent number: 11489159
    Abstract: A method for producing a graphene oxide-based compound for an air electrode of a metal-air battery. A nitrogen and sulfur-based organic compound is added to an aqueous suspension of a graphene oxide. The water of the suspension is evaporated in order to obtain a powder. This powder is heated under an inert atmosphere in order to sublime the organic compound and stimulate the incorporation of nitrogen from the organic compound into the graphitic sites of the graphene oxide. The nitrogen and sulfur-doped graphene oxide is added to a second aqueous suspension comprising a cobalt nitrate-based compound. This second suspension is heated in order to form nanoparticles of cobalt oxide at the surface of at least one nitrogen and sulfur-doped graphene oxide sheet.
    Type: Grant
    Filed: December 5, 2018
    Date of Patent: November 1, 2022
    Assignees: ELECTRICITE DE FRANCE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE—CNRS
    Inventors: Philippe Stevens, Gwenaelle Toussaint, Aurelien Louis Habrioux, Clement Aime Comminges, Boniface Kokoh, Ismail Abidat, Teko Wilhelmin Napporn, David Portehault, Emmanuelle Cazayus-Claverie, Olivier Durupthy, Corinne Chaneac
  • Patent number: 11469421
    Abstract: A conductive material dispersion containing a conductive material containing carbon fibers, a dispersant, and an amide-based organic solvent, in which the dispersant contains a copolymer A containing a nitrile group-containing structural unit and satisfies following conditions. (I) A pH of the conductive material dispersion is 9.0 or greater. (II) A phase angle of the conductive material dispersion at a frequency of 1 Hz obtained by dynamic viscoelasticity measurement is 19° or greater, and a complex elastic modulus of the conductive material dispersion obtained by dynamic viscoelasticity measurement is less than 20 Pa.
    Type: Grant
    Filed: February 21, 2022
    Date of Patent: October 11, 2022
    Assignees: TOYO INK SC HOLDINGS CO., LTD., TOYOCOLOR CO., LTD.
    Inventor: Honami Hirabayashi
  • Patent number: 11437607
    Abstract: A composition that includes a dispersion stabilizer for an electrode coating liquid for a power storage device is provided. The composition has superior ability to stably disperse an electrode active material and a conductive material, and makes it possible to manufacture a uniform electrode, even when a dispersion device that has weak shear force is used. A dispersant for an electrode coating liquid for a power storage device, the dispersant being characterized by containing cellulose fibers that satisfy (a)-(c). (a) The number average width of the short widths is 2-200 nm. (b) The aspect ratio is 7.5-250. (c) Cellulose I crystals are included and the crystallinity thereof is 70%-95%.
    Type: Grant
    Filed: January 24, 2018
    Date of Patent: September 6, 2022
    Assignee: DAI-ICHI KOGYO SEIYAKU CO., LTD.
    Inventors: Ayano Sofue, Yasuteru Saito, Yosuke Goi, Yoshiki Ito, Tetsuya Higashizaki, Yuji Hoshihara, Masaaki Matsumoto
  • Patent number: 11430973
    Abstract: The present invention provides a viscous adhesive capable of retaining the shape of an electrode and allowing for production of an electrode for a lithium-ion battery having a structure in which the energy density of the electrode does not decrease. The present invention relates to a viscous adhesive for a lithium-ion electrode which allows active materials to adhere to each other in a lithium-ion electrode, the viscous adhesive having a glass transition temperature of 60° C. or lower, a solubility parameter of 8 to 13 (cal/cm3)1/2, and a storage shear modulus and a loss shear modulus of 2.0×103 to 5.0×107 Pa as measured in a frequency range of 10?1 to 101 Hz at 20° C.
    Type: Grant
    Filed: April 20, 2018
    Date of Patent: August 30, 2022
    Assignee: SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Tomoya Ohta, Kotaro Nasu, Kenichi Kawakita, Takuya Suenaga, Yusuke Mori, Yasuhiko Ohsawa, Yuki Kusachi, Hajime Satou, Hiroshi Akama, Hideaki Horie
  • Patent number: 11424442
    Abstract: A method of making a negative electrode material for an electrochemical cell that cycles lithium ions is provided that includes centrifugally distributing a molten precursor comprising silicon and lithium by contacting the molten precursor with a rotating surface in a centrifugal atomizing reactor. The molten precursor is solidified to form a plurality of substantially round solid electroactive particles comprising an alloy of lithium and silicon and having a D50 diameter of less than or equal to about 20 micrometers. In certain variations, the negative electroactive material particles may further have one or more coatings disposed thereon, such as a carbonaceous coating and/or an oxide-based coating.
    Type: Grant
    Filed: December 6, 2019
    Date of Patent: August 23, 2022
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Bradley R. Frieberg, Xiaosong Huang, Zhongyi Liu, Mark W. Verbrugge
  • Patent number: 11424479
    Abstract: The solid electrolyte layer of the all-solid-state battery disclosed herein includes insulating inorganic filler particles (hollow particles) having a hollow shape at least before the initial charging. Preferably, Fs/Ns which is the ratio of an average particle diameter (Fs) of the filler particles to an average particle diameter (Ns) of the negative electrode active material is 0.25 or less at least before the initial charging. Also, preferably, Fp/Nv which is the ratio of a hollow volume (Fp) created by the hollow particles included in the solid electrolyte layer per unit area before the initial charging to an expansion volume (Nv), which is a difference between a volume after full charging and a volume before the initial charging in the negative electrode active material layer per unit area, is at least 0.1.
    Type: Grant
    Filed: March 27, 2019
    Date of Patent: August 23, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Masaharu Senoue
  • Patent number: 11417885
    Abstract: Filled carbon nanotubes (CNTs), methods of synthesizing the same, and lithium-ion batteries comprising the same are provided. In situ methods (e.g., chemical vapor deposition techniques) can be used to synthesize CNTs (e.g., multi-walled CNTs) filled with metal sulfide nanowires. The CNTs can be completely (or nearly completely) and continuously (or nearly continuously) filled with the metal sulfide fillers up to several micrometers in length. The filled CNTs can be synthesized on a carbon substrate. A lithium-ion battery can comprise a cathode, an anode comprising filled CNTs as described herein, and an electrolyte in contact with the cathode and/or the anode.
    Type: Grant
    Filed: March 28, 2022
    Date of Patent: August 16, 2022
    Assignee: THE FLORIDA INTERNATIONAL UNIVERSITY BOARD OF TRUSTEES
    Inventors: Wenzhi Li, Yuba Poudel