Patents Examined by Wilbert J. Briggs, Sr.
  • Patent number: 4885333
    Abstract: A polyvinyl chloride resin-based composition can be imparted with improved thermal stability of compounding the same with a polygylcerin in an amount of 0.01 to 0.5% by weight based on the resin even when the composition is compounded with a heat stabilizer having relatively low effectiveness although the use of such a heat stabilizer is desirable in respect of the physiological inertness. Similar improving effects on the thermal stability of a polyvinyl chloride resin-based composition can be obtained when the resin is prepared by suspension-polymerizing vinyl chloride monomer in an aqueous medium containing a polyglycerin.
    Type: Grant
    Filed: March 23, 1988
    Date of Patent: December 5, 1989
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tadashi Amano, Tokuji Abe
  • Patent number: 4885340
    Abstract: A high impact polyamide composition comprising at least one polyamide, at least one ethylene ionomer resin and at least one oxide or carbonate compound is specific weight proportions, wherein the polyamide has a relative viscosity of at least 3.15 in 98% sulfuric acid. The composition may further comprise an elastomeric olefin copolymer, an elastomeric styrene copolymer and/or a polyvalent alcohol. The polyamide composition has excellent mechanical strength, thermal resistance and impact strength even at weld-line portions so that it can advantageously be employed for manufacturing various shaped articles, such as automobile parts and sporting goods.
    Type: Grant
    Filed: March 28, 1988
    Date of Patent: December 5, 1989
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tetsuo Hamada, Junichi Nakahashi, Ryoichi Nakai
  • Patent number: 4885338
    Abstract: A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of a nitroalkyl acrylate of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently an alkyl group and n is an integer, and a nitroamino compound of the formula: ##STR2## wherein R.sup.3 to R.sup.6 are independently an alkyl group, and m is an integer, said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent.
    Type: Grant
    Filed: May 4, 1988
    Date of Patent: December 5, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyoshi Takao, Akio Imai, Tomoaki Seki
  • Patent number: 4882384
    Abstract: A thermoplastic polymer having good tensile strength at elevated temperatures is obtained by modifying a block copolymer composed of a conjugated diene compound and an alkenyl arene compound. The block copolymer is first selectively hydrogenated and thereafter modified by grafting silicon or boron containing functional groups primarily in the alkenyl arene block via metalation. Each silicon containing functional group preferably contains at least two functional groups which allow crosslinking by condensation reactions.
    Type: Grant
    Filed: February 1, 1988
    Date of Patent: November 21, 1989
    Assignee: Shell Oil Company
    Inventors: Carl L. Willis, Steven S. Chin
  • Patent number: 4882380
    Abstract: A process for the production of a product comprising ethylene/propylene copolymer incorporated into a matrix of propylene homopolymer or copolymer comprising the following steps:(a) contacting propylene or propylene and at least one alpha-olefin having 2 to 8 carbon atoms, and hydrogen, wherein the alpha-olefin is present in a ratio of about 0.01 to about 0.06 mole of alpha-olefin per mole of propylene and the hydrogen is present in a ratio of about 0.001 to about 0.
    Type: Grant
    Filed: July 7, 1987
    Date of Patent: November 21, 1989
    Assignee: Union Carbide Chemicals and Plastics Company Inc.
    Inventors: Harold K. Ficker, William G. Sheard
  • Patent number: 4880878
    Abstract: A thermoplastic blend with the ability to absorb less than 40% of an oil, and having a superior tensile strength comprises about 80 to about 20 phr of an elastomeric block copolymer having the general configuration A-B-A, wherein the B block is a butadiene hydrocarbon block consisting of about 35 to about 55 mole percent of condensed butadiene units in the 1,2 configuration, and about 20 to about 80 phr of a block copolymer having the general configuration A-B-A, wherein the B block is a hydrogenated butadiene hydrocarbon block consisting of about 18 to about 34 mole percent of condensed butadiene units in the 1,2 configuration.
    Type: Grant
    Filed: December 29, 1987
    Date of Patent: November 14, 1989
    Assignee: Shell Oil Company
    Inventors: Glenn R. Himes, Andrea Sanders
  • Patent number: 4879354
    Abstract: Described herein are miscible blends of polycarbonomides, defined as amide and/or imide containing polymers, and a polyarylate or arylate-carbonate copolymer which are useful in the manufacture of extruded sheets, high temperature connectors, aircraft and mass transportation vehicle interiors, injection molded articles, and extruded profiles and thermoformable articles.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: November 7, 1989
    Assignee: Amoco Corporation
    Inventors: James E. Harris, Markus Matzner, Lloyd M. Robeson
  • Patent number: 4879339
    Abstract: A room temperature-curable organopolysiloxane composition is proposed which is useful as a material for imprinting or blocking of forms of, for example, medical and dental prostheses without the problem of curing retardation or incomplete curing. The composition comprises a vinyl-containing organopolysiloxane, organohydrogenpolysiloxane, platinum catalyst, inorganic filler, liquid paraffin or petrolatum and antioxidant. The antioxidant serves to protect the liquid paraffin or petrolatum from oxidation to produce oxidized compounds which may deactivate the platinum catalyst to cause curing retardation or incomplete curing.
    Type: Grant
    Filed: March 3, 1988
    Date of Patent: November 7, 1989
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masachika Yoshino, Nobuyuki Hasebe, Hironao Fujiki, Hiroshi Inomata
  • Patent number: 4877822
    Abstract: An epoxy resin composition which comprises a curable epoxy resin, a curing agent, an inorganic filler, and at least one copolymer selected from copolymers obtained by an addition reaction between aromatic polymers containing one or more epoxy groups and one or more alkenyl groups and the specific organopolysiloxanes; copolymers obtained by an addition reaction between aromatic polymers containing one or more epoxy groups and the specific amino group-containing organopolysiloxanes.
    Type: Grant
    Filed: April 8, 1988
    Date of Patent: October 31, 1989
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kunio Itoh, Toshio Shiobara, Koji Futatsumori, Kazutoshi Tomiyoshi, Hisashi Shimizu
  • Patent number: 4877844
    Abstract: A process for producing a low gloss thermoplastic resin which comprises polymerizing in two steps from 20 to 70 parts by weight of a butadiene polymer, at least 70% by weight of which is constituted by butadiene, with from 30 to 80 parts by weight of a total of from 15 to 40% by weight of a vinyl cyanide monomer and from 60 to 85% by weight of an aromatic vinyl monomer, characterized in that for the polymerization of the first step, the butadiene polymer, the vinyl cyanide monomer and the aromatic vinyl monomer were charged in amounts corresponding to from 20 to 80% by weight of the entire butadiene polymer, from 20 to 80% by weight of the entire vinyl cyanide monomer and from 20 to 80% by weight of the entire aromatic vinyl monomer, respectively, and after the completion of the polymerization of the first step, the rest of the butadiene polymer, the vinyl cyanide monomer and the aromatic vinyl monomer were charged for the polymerization of the second step.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: October 31, 1989
    Assignee: Mitsubishi Rayon Company Limited
    Inventors: Kazuo Kishida, Yutaka Toyooka, Yoshiyuki Mikami
  • Patent number: 4877831
    Abstract: A polycarbonate resin composition excellent in chemical resistance, weather resistance, heat resistance, and low-temperature impact resistance, which comprises,either a polycarbonate resin (A) or a mixture (A') of the polycarbonate resin and a saturated polyester and/or a polyester elastomer andeither a siloxane based graft copolymer (B) obtained by graft polymerization of 95 to 10% by weight of at least one vinyl monomer onto 5 to 90% by weight of a polyorganosiloxane rubber which exhibits a degree of swelling of 3 to 30 as measured to toluene at 25.degree. C., contains constitutional units derived from a graft-linking agent, and has an average particle size of 0.08 to 0.8 .mu.m or a mixture (B) of the siloxane-based graft copolymer and a vinyl polymer,wherein the component (B) is blended so that the content of the polyorganosiloxane rubber may be from 0.5 to 60% by weight based on the whole resin composition.
    Type: Grant
    Filed: June 16, 1987
    Date of Patent: October 31, 1989
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Masafumi Hongo, Hideyuki Shigemitsu, Naoki Yamamoto, Akira Yanagase
  • Patent number: 4877836
    Abstract: A polymeric blend particularly useful as a VI improver, which polymeric blend comprises a selectively hydrogenated asymmetric radial polymer comprising a plurality of polymeric arms containing hydrogenated conjugated diolefin monomer units and at least one block copolymer arm comprising a single polymeric block containing predominantly monoalkenyl aromatic hydrocarbon monomer units and a single polymeric block containing predominantly hydrogenated conjugated diolefin monomer units and a selectively hydrogenated linear diblock copolymer containing a single polymeric block containing principally monoalkenyl aromatic hydrocarbon monomer units and a single polymeric block containing predominantly hydrogenated conjugated diolefin monomer units. Both polymers in the blend will be selectively hydrogenated so as to convert (saturate) at least 95% of the ethylenic unsaturation initially contained therein.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: October 31, 1989
    Assignee: Shell Oil Company
    Inventor: Robert B. Rhodes
  • Patent number: 4874821
    Abstract: A linear copolymer constituted by four alternating blocks:B1-A1-B2-A2wherein:B1 and B2 are polydienic blocks, and preferably polybutadiene blocks, andA1 and A2 are polyvinylaromatic, and preferably polystyrene blocks;which polymer has a weight average molecular weight of from 30,000 to 250,000, and a global content of monomer dienic units of from 40 to 80% by weight, wherein the weight average molecular weight of B1 block is comprised within the range of from 0.1 to 0.5 times the weight average molecular weight of B2 block, and the weight average molecular weight of A1 block is comprised within the range of from 0.25 to 2.0 times the weight average molecular weight of A2 block, and which contains between B1 and A1 blocks a copolymeric moiety formed by randomly linked monomer dienic and vinylaromatic units; is endowed with a desired balance of mechanical characteristics, rheologic characterisatics and characteristics of thermooxidative resistance.The process to prepare such a block copolymer is disclosed.
    Type: Grant
    Filed: November 5, 1987
    Date of Patent: October 17, 1989
    Assignee: Enichem Elastomeri S.p.A.
    Inventors: Enrico Agostinis, Sergio Custro, Alessandro Zazzetta
  • Patent number: 4871810
    Abstract: Partially grafted flexible thermoplastic compositions formed by melt blending under high shear, a thermoplastic material which does not contain available graft sites, said thermoplastic material being at least one continuous phase of the composition, an ethylene copolymer containing an unsaturated mono-carboxylic acid, and a polymeric grafting agent having reactive groups capable of reacting with the mono-carboxylic acid in the ethylene copolymer and with the available graft sites in the thermoplastic material.
    Type: Grant
    Filed: November 13, 1987
    Date of Patent: October 3, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert P. Saltman
  • Patent number: 4871814
    Abstract: High molecular weight linear block copolymers containing 5 or more alternating blocks of (A) polymerized styrene or alkyl substituted styrene units, and (B) polymerized conjugated diene units, terminated by (A) units, are prepared by anionic dispersion polymerization to give clear polymers having excellent physical properties.
    Type: Grant
    Filed: June 22, 1987
    Date of Patent: October 3, 1989
    Assignee: Mobil Oil Corporation
    Inventors: Binnur Z. Gunesin, Paul A. Pindris, Frederick C. Schwab
  • Patent number: 4870139
    Abstract: A water-dispersible graft copolymer of a polyamide and at least one acrylic monomer is prepared by reacting the polyamide with the acrylic monomer(s) in an alcohol solution in the presence of a free radical peroxidic initiator. The graft copolymer is particularly useful as the resin component of a water-based printing ink.
    Type: Grant
    Filed: March 10, 1988
    Date of Patent: September 26, 1989
    Assignee: Sun Chemical Corporation
    Inventors: Albert A. Kveglis, Robert J. Catena
  • Patent number: 4870136
    Abstract: If ultra-high-molecular-weight polyethylene having an intrinsic viscosity (.eta.) of at least 5 dl/g is grafted with a silane compound in the presence of a radical initiator and extrusion-molded and the extrudate is impregnated with a silanol condensation catalyst after or during drawing and is then exposed to water to effect crosslinking, there is obtained a novel molecularly oriented molded articles in which increase of the melting temperature, which is not observed in conventional draw-molded or crosslinked molded articles of polyethylene, can be attained, and even if this molecularly oriented molded article is exposed to a temperature of 180.degree. C. for 10 minutes, the molded article is not fused but the shape is retained and even after this heat history, a high strength retention ratio can be maintained.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: September 26, 1989
    Assignee: Mitsui Pertrochemical Industries, Ltd.
    Inventors: Kazuo Yagi, Hitoshi Mantoku
  • Patent number: 4870141
    Abstract: Novel solvent-based thermosetting composition comprising (a) hydroxy functional epoxy ester resin of number average molecular weight (Mn) between about 1,000 and about 5,000, comprising the reaction product of diepoxide with aliphatic diol and, subsequently, with acid component comprising (i) hydroxy functional acid and, optionally, (ii) fatty acid; and (b) polyfunctional, hydroxy-reactive crosslinking agent, for example, aminoplast crosslinking agent or blocked polyisocyanate crosslinking agent comprising isocyanate groups blocked by reaction with an active hydrogen bearing blocking agent. Coating composition may be formulated as primer sprayable with conventional spraying equipment.
    Type: Grant
    Filed: November 4, 1987
    Date of Patent: September 26, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Panagiotis I. Kordomenos
  • Patent number: 4868243
    Abstract: A suber-toughened multiphase thermoplastic composition is provided by incorporating an effective amount of at least one functionalized, selectively hydrogenated alkenyl arene/conjugated diene block copolymer to which has been grafted an effective amount of carboxyl functional groups primarily in the alkenyl arene blocks thereof with poly (ethylene terephthalate). The carboxyl functional groups are present as carboxylic acids and their salts in an effective salt to acid ratio for super-toughening the composition. Additionally, the block copolymer phase has an effective phase size for super-toughening the composition.
    Type: Grant
    Filed: February 5, 1988
    Date of Patent: September 19, 1989
    Assignee: Shell Oil Company
    Inventors: Richard Gelles, Carl L. Willis, Michael J. Modic
  • Patent number: RE33070
    Abstract: A melt processable pseudointerpenetrating network of silicones in thermoplastic matrices and a method of producing same is provided by vulcanizing the silicones within the matrices. In a preferred embodiment a two part silicone comprising silicon hydride groups and silicon vinyl-containing groups are reacted in the presence of a platinum complex. Depending on certain parameters chain-extended (thermoplastic) or cross-linked (thermosetting) compositions are produced.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: September 26, 1989
    Assignee: Petrarch Systems Inc.
    Inventor: Barry C. Arkles