Abstract: A catalyst for production of methacrylic acid, said catalyst being molded in a ring-like shape having an outside diameter of 3.0 to 10.0 mm, an inside diameter 0.1 to 0.7 times the outside diameter and a length 0.5 to 2.0 times the outside diameter, said catalyst comprising a catalytically active material having the composition represented by the following general formulaMo.sub.a P.sub.b A.sub.c B.sub.d C.sub.e D.sub.f O.sub.

Abstract: The invention provides pressure protection for the interior casing of hydrogenation reactors by the use of a manifold interconnecting the annular chambers of the aforesaid reactors with the processed-gas vapor path whereby process-conditioned pressure changes generated during the reaction process are simultaneously balanced. As a result, the interior casings of the reactors which define the reaction vessel can be made of relatively thin material as compared to conventional reaction vessels.

Abstract: Metals contained in a hydrocarbon containing feed stream are removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising zirconium phosphate, cobalt phosphate and a metal phosphate where the metal is selected from the group consisting of nickel and vanadium. Molybdenum phosphate may also be added to the catalyst composition if desired. The life and activity of the catalyst composition may be increased by introducing a decomposable metal compound selected from the group consisting of the metals of Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream prior to contacting the hydrocarbon containing feed stream with the catalyst composition.

Abstract: A supported silver catalyst for the oxidation of ethylene to ethylene oxide with molecular oxygen is made by impregnating a support with a hydrocarbon solution of a silver salt of a neo-acid having 7 or more carbon atoms, substantially free of water and said neo-acid. Preferably, the hydrocarbon solvent is toluene, xylene, ethyl benzene, cyclohexane, or cumene. The impregnated support is dried and the silver is activated under conditions chosen to provide the optimum selectivity to ethylene oxide. Thereafter, the activated silver catalyst may be impregnated with an alkali metal solution sufficient to increase selectivity of the silver catalyst above its alkali-free state. The amount of alkali metal on the finished catalyst is the optimum for the particular support selected and preferably will be about 1-6.times.10.sup.-3 gew/kg of catalyst. The catalyst may also include additional promoters, such as the alkaline earth metals, preferably barium.

Abstract: An H-Coal Process hydrogenation operation and catalyst life is substantially improved when using colloidal particles of catalyst comprising a colloidal matrix of silica, alumina, titania and combinations thereof coated with hydrogenating components selected from cobalt, molybdenum, nickel, tungsten and combinations thereof. The colloidal catalyst activity may be altered by alkaline promoters, other metals and acidic promoters.

Abstract: Process for liquefying coal or similar liquefiable carbonaceous solids in which the liquefaction solvent is a hydrotreated solvent mixture that is derived in the process. The solvent mixture comprises at least 78 wt. % decalin, comprising cis and trans decalin. The cis-isomers comprise at least 80 wt. % of the total weight of the decalin. The solvent mixture may also include about 0-2 wt. % of naphthalene, about 0-5 wt. % of a constituent comprising the mono and/or di methyl derivative of at least one of the other constituents in the mixture, and tetralin comprising the remainder, e.g., about 1-22 wt. %.

Abstract: A boron nitride type compound of the formula: LiMBN.sub.2 where M is calcium or barium and other similar compounds are provided. These compounds are prepared by heating a mixture of (i) finely divided Li.sub.3 N or metallic lithium, (ii) finely divided alkaline earth metal nitride selected from Ca.sub.3 N.sub.2, Mg.sub.3 N.sub.2, Sr.sub.3 N.sub.2, Ba.sub.3 N.sub.2 and Be.sub.3 N.sub.2, and/or an alkaline earth metal selected from Ca, Mg, Sr, Ba and Be, and (iii) hexagonal boron nitride at 800.degree. to 1,300.degree. C. in an inert gas or ammonia atmosphere thereby to react the ingredients (i), (ii) and (iii) with each other in a molten state, and then, cooling the reaction product to be solidified. The above-mentioned compounds are useful as a catalyst for use in the production of cubic boron nitride from hexagonal boron nitride.

Abstract: Method and apparatus for minimizing energy required to inject reactant such as coal-oil slurry into a reaction vessel, using high pressure effluent from the latter to displace the reactant from a containment vessel into the reaction vessel with assistance of low pressure pump. Effluent is degassed in the containment vessel, and a heel of the degassed effluent is maintained between incoming effluent and reactant in the containment vessel.

Abstract: A method for preparing hydrotreating catalysts containing Group VIII and/or Group VIB catalytically active metals on a support, and particularly those containing nickel and molybdenum, are improved in hydrodenitrification (HDN) activity by incorporating zero-valence molybdenum and/or tungsten carbonyls into the catalyst support by mixing a liquid mixture containing metal carbonyl(s); a catalytic amount of dienes, trienes or monoaromatics; and free sulfur; with a dried catalyst support and heating the liquid-solid mixture until metal carbonyl conversion to metal disulfide is substantially complete. The catalyst is then dried followed by calcining in inert gas, before use in a hydrotreating process.

Abstract: A process for preparing a 3-component catalyst system consisting of manganic oxide, ferric oxide and zinc oxide, which are adjusted to have an atomic ratio of Mn:Fe:Zn from 90:20:20 to 99:0.01:0.01, is used for the catalytic synthesis of 2,6-xylenol from reacting phenol with methanol.

Abstract: A process for the preparation of novel highly active, highly selective hydrotreating catalysts. These catalysts are prepared, in bulk or in supported form, from a catalyst precursor characterized by the formula B.sub.x [Mo.sub.3 S.sub.z ] where B is an ammonium ion, polyammonium ion, tertiary or quaternary phosphonium ion, or a hydrocarbyl substituted ammonium ion, hydrocarbyl substituted polyammonium ion, or hydrocarbyl substituted tertiary or quaternary phosphonium ion, x is 1 where B is a divalent cationic moiety, or 2 where B is a monovalent cationic moiety, [Mo.sub.3 S.sub.z ] is a divalent anionic moiety wherein z is an integer greater than 15. The catalyst precursor is dispersed in an ammonium sulfide or dilute ammonium polysulfide solution and heated to remove sulfur from said catalyst precursor to provide a z value of 15 or less. Carbon is also removed from the catalyst precursor and, where B of the B.sub.x [Mo.sub.3 S.sub.

Abstract: A process for converting coal, comprising, subjecting a slurry composed essentially of coal, a hydrocarbon solvent and a hydrogenation catalyst to primary hydrogenation to liquify the coal, separating the ash content of said coal from the reaction product thereby obtaining a liquified product, subjecting at least a portion of the liquified product to secondary hydrogenation in the presence of a hydrogenation catalyst thereby converting the liquified product to light oil product, the secondary hydrogenation step being a point of supply of hydrogenation catalyst to the coal conversion system, separating the hydrogenation catalyst from the reaction product of the secondary hydrogenation step, and returning said separated hydrogenation catalyst to the primary hydrogenation step where it is used as the catalyst for primary hydrogenation of said slurry.

Abstract: A process for converting coal to liquid hydrocarbonaceous products involving a liquefaction reaction in the presence of a coal derived recycle slurry and a non-coal derived solvent comprising a hydrocarbonaceous oil or distillation bottom residue thereof intrinsically contaminated with greater than 300 ppm total of vanadium and nickel. The liquefaction reaction is performed under hydrogen pressure (approximately 500-4000 psi) and under elevated temperature (approximately 300.degree.-500.degree. C.) using a weight ratio of non-coal derived solvent to coal of about 1/1 or less. The conversion of coal to liquids is greatly enhanced by the use of such a non-coal derived solvent under these conditions.

Abstract: A metal catalyst preferably comprised of a platinum/rhenium metal combination, supported on alumina is activated for the reforming of hydrocarbon feedstock, by being contacted with an oxygen-containing gas at a temperature sufficient to oxidize the metal catalyst and then being reduced sequentially by contacting the catalyst with a stream of hydrogen at about 650.degree. to about 750.degree. F. for a first period of time and then at about 900.degree. to about 1000.degree. F. for a second period of time, followed by sulfiding of the sequentially reduced catalyst. The sequential reduction procedure increases the selectivity of the reforming catalyst and results in increased C.sub.5.sup.+ liquid product yields.

Abstract: A process is set forth for depolymerizing coal in an aqueous alkaline medium in the presence of a quinone and a hydrogen atmosphere. The depolymerized solid product is significantly ethyl acetate soluble and can be extracted with ammonia under supercritical conditions.

Abstract: Improved extraction and recovery of carbonaceous products are achieved by the aqueous alkali depolymerization of carbonaceous materials, low rank coals, followed by the supercritical extraction with ammonia when the depolymerized material retains a significant aqueous presence.

Abstract: A catalyst for the production of unsaturated aldehydes is provided which is represented by the general formulaBi.sub.a W.sub.b Fe.sub.c Mo.sub.d A.sub.e B.sub.f C.sub.g D.sub.h O.sub.xwherein Bi represents bismuth, W represents tungsten, Fe represents iron, Mo represents molybdenum, O represents oxygen, A represents nickel and/or cobalt, B represents at least one element selected from the group consisting of alkali metals, alkaline earth metals and thallium, C represents at least one element selected from the group consisting of phosphorus, arsenic, boron, antimony, tin, cerium, lead and niobium, D presents at least one element selected from the group consisting of silicon, aluminum, zirconium and titanium, a, b, c, d, e, f, g, h and x represent the atomic ratios of the individual elements, and when d is taken as 12, a=0.1-10.0, b=0.5-10.0 (provided that a/b=0.01-6.0), c=0.1-10.0, e=2.0-20.0, f=0.001-10.0, g=0-10.0, and h=0-30, and x takes a number determined by the atomic valences of the individual elements.

Abstract: New solvent compositions and a new two-stage direct coal liquefaction process are provided which permit control of the liquid product state from one consisting primarily of low boiling distillate to one consisting primarily of high boiling fuel oil. The use of the new solvent composition in the process significantly increases distillable liquid yields from coal or lignites. The preferred solvent contains from about 0 to 100 weight percent of pyridine-soluble bottoms, i.e., mineral matter-free normally solid dissolved coal, in which the hydrogen content is maintained at an optimum level by adding from about 0.05 to about 2.0 weight percent hydrogen in a hydrotreating step and from about 0 to 100 weight percent of a coal-derived distillate boiling below about 800.degree. F. to about 1000.degree. F.

Abstract: This invention relates to an improved two-stage process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal.

Abstract: A process is provided for the manufacture of methyl mercaptan with substantial reduction of by-product methane by intimate mixture of carbon oxide, sulfur or hydrogen sulfide and hydrogen at elevated temperature and pressure with a single-phase, solid catalyst system comprising a porous alumina-containing support upon which is deposited a mixture of manganese sulfide and alkali metal sulfide.