Abstract: An easily employed, effective and predictable hair dye composition is obtained by combining aryl amines with aryl aldehydes along with an inorganic metal salt having a valence between +1 and +3. By employing this formulation, a permanent, long-lasting, non-fading hair coloring is achieved. In the preferred embodiment, the inorganic metal salt is selected from the group consisting of aluminum chloride, ferric chloride, lithium bromide, manganese chloride, copper chloride, and manganese nitrate. In carrying out the teaching of the present invention, the aryl amine and aryl aldehyde may be applied to the hair separately or in combination, along with the inorganic metal salt. In addition, this inorganic metal salt can be applied after the application and removal of the aryl amine and aryl aldehyde.
Type:
Grant
Filed:
February 25, 1992
Date of Patent:
April 6, 1993
Assignee:
Shiseido Co., Ltd.
Inventors:
Thomas M. Schultz, Catherine Grillo, Sanae Kubo
Abstract: A soap bar having the appearance of a polished wood grain is prepared by mixing the soap formulation with an iron oxide coated micaceous pearlescent pigment and extruding the combination such that the iron oxide coated micaceous pearlescent pigment is oriented generally unidirectionally.
Type:
Grant
Filed:
November 26, 1990
Date of Patent:
March 23, 1993
Assignee:
The Mearl Corporation
Inventors:
Erika M. Baumgartner, Philip Greenberg, Harold A. Miller
Abstract: The present invention provides the following hair-treatment composition, bleaching composition and hair color tone modifier composition:a hair-treatment composition containing:(1) a ferrous salt, and(2) a nonreducing organic chelate-forming compound capable of forming a chelate compound together with a ferrous ion,and having a pH value of from 3 to 6, wherein the stability constant (K.sub.
Abstract: This invention relates to a composition comprising:(A) a major amount of a fluorine-containing hydrocarbon containing one or two carbon atoms; and(B) a minor amount of a tertiary amide represented by the formula ##STR1## wherein a is one or two, provided that when a is one, R is a hydrocarbyl group or a hydrocarbylpolyoxyalkylene group, and when a is two, R is a hydrocarbonylene group;each R.sub.1 is independently a hydrocarbyl group, a hydrocarbyl terminated polyoxyalkylene group, or taken together form a pyrrolidinyl group provided that in Formula I, when a is one, R has one carbon atom and R.sub.1 is a hydrocarbyl group, that R.sub.1 has at least eight carbon atoms. The present invention provides compositions which are useful as refrigeration liquids in refrigerators and air-conditioners including auto, home and industrial air-conditioners. The invention provides tertiary amides which are compatible with fluorine-containing hydrocarbons used in refrigerators and air-conditioners.
Abstract: The present invention provides a cosmetic temporary coloring composition which comprises a cosmetically acceptable support and, as an active ingredient, at least one chemically modified protein derivative which contains residues of molecules of dye grafted onto the protein chain. Thus, certain of the side chains of the protein derivative having amine, alcohol or thiol functions are substituted by residues of dye molecules. The present invention further provides a process for the temporary coloring of human hair, nails or skin comprising applying thereto in an amount effective to color the human hair, nails or skin a composition containing a solution in water, a lower mono-alcohol or polyol or an aqueous alcoholic mixture wherein the alcohol is present in an amount ranging from 0.5 to 50 percent by weight of the chemically modified protein derivative.
Type:
Grant
Filed:
October 7, 1991
Date of Patent:
March 9, 1993
Assignee:
L'Oreal
Inventors:
Gerard Lang, Serge Forestier, Gerard Malle, Alex Junino
Abstract: A clear, aqueous, shelf-stable progressive hair coloring composition includes a salt of a metal, a soluble source of sulfur, an amphoteric surfactant and a pH controller that controls the pH of the composition to be within the range of about 7.5 to about 11.0. Preferred metallic salts are salts of lead or bismuth and the preferred sulfur source is sodium thiosufate.
Abstract: To combat the accumulation of plaque on dentures, a non self-supporting coating of a non-toxic, negatively charged polysaccharide is applied. The polysaccharide coating is gradually sacrificed or ablated during wear. Ablation appears to remove microorganisms along with coating material. The polysaccharide is further defined by an ability to reduce the adhesion of Streptococcus salivarius cells in a simple in vitro bacterial adhesion test by at least 25% over a control.
Type:
Grant
Filed:
July 29, 1991
Date of Patent:
March 9, 1993
Assignee:
National Research Development Corporation
Abstract: Novel dielectric compositions, well adapted for low temperature applications, include admixture of benzyltoluene, benzylbenzene and the higher homologs thereof, and optionally contain triphenylmethane, ditolylphenylmethane, tolyldiphenylmethane and the higher homologs thereof; the subject novel compositions are prepared by chlorinating a mixture of toluene and benzene and then treating the product of reaction with an inorganic halide.
Type:
Grant
Filed:
August 20, 1991
Date of Patent:
March 9, 1993
Assignee:
Atochem
Inventors:
Noelle Berger, Raymond Commandeur, Pierre Jay
Abstract: The invention relates to a process for dyeing keratinous fibres, comprising the simultaneous or sequential application of a composition (A) containing a compound of formula (I): ##STR1## in which: R.sub.1 denotes hydrogen, alkyl, acetyl, benzoyl, phenyl or C.sub.1 -C.sub.4 carboxyalyl (sic);R.sub.2 and R.sub.3 denote hydrogen, alkyl, alkoxy, hydroxyalkyl, amino, halogen, nitro, alkylphenyl, phenyl, alkylamino, hydroxyalkylamino;and a composition (B) containing at least one compound of formula (II): ##STR2## in which: R.sub.4 and R.sub.6 denote hydrogen, alkyl;R.sub.5 denotes hydrogen, alkyl, COOR' where R' is hydrogen or alkyl;Z.sub.1 represents hydrogen, halogen, alkyl, alkoxy or hydroxyl;Z.sub.2 represents hydrogen or alkyl or a compound of formula (III): ##STR3## in which: R.sub.7 and R.sub.8 denote hydrogen or alkyl;X.sub.1 and X.sub.2 represent hydrogen or an NH.sub.2 radical;R.sub.9 denotes hydrogen, alkyl, alkoxy;as well as the compositions used.
Abstract: A high-speed spinning oil composition is disclosed, which comprises following components (A) and (B):(A) an organophosphoric ester salt of formula (1):M.sup.30 X.sup.- (1)wherein M.sup.+ is an alkali metal ion, ammonium ion or an amine ion; X.sup.- is an organophosphoric ester anion of formula (2): ##STR1## wherein R.sub.1 is an alkyl or alkenyl group of 8 to 22 carbon atoms; A is an alkylene group of 2 to 4 carbon atoms; a is a whole number of 0 to 22; and b is equal to 1 or 2; and(B) an oxyalkylene polymer of formula (3):R.sub.11 --O--(AO).sub.n H (3)wherein R.sub.11 is a hydrogen atom, an alkyl or alkenyl group of 1 to 20 carbon atoms, an acyl group of 2 to 22 carbon atoms, an aryl group, a polyhydric alcohol group or a silyl group; A is an alkylene group of 2 to 4 carbon atoms; the oxyalkylene polymer has a molecular weight of 2,000 to 40,000.
Abstract: Disclosed are formulations for producing chemical solvent admixtures that can be employed to clean a surface for further work; and that can be applied to cloths for the cleaning operation yet alleviate problems with solvent evaporation into the atmosphere to cause many legal and environmental problems, and a method of storing and disposing of cloths soaked with the formulation that alleviates current problems.
Abstract: This invention provides:(A) an anti-icing composition comprising a silicone resin which is at least one condensate selected from the group consisting of:(i) a condensate of an alkoxydimethylsiloxane compound represented by the formula ##STR1## wherein R.sub.1 l is a methyl group or an ethyl group, A is an oxygen atom, an ethylene group or a 1,3-propylene group, a is an integer of 5 to 150, b and e are different or the same and each represent an integer of 1 to 3, c is an integer of 3-b and d is an integer of 3-e,(ii) a condensate of the compound of the formula (I) and an alkoxysilane compound represented by the formula(R.sub.3)h--Si--(OR.sub.2)j (II)wherein R.sub.2 is a methyl group or an ethyl group, R.sub.
Abstract: A linear viscoelastic aqueous liquid automatic dishwasher detergent composition comprising water; up to about 2% by weight of long chain fatty acid or salt thereof; from about 0 to 5% by weight of organic detergent; from about 5 to 40% by weight of alkali metal detergent builder salt; up to about 20% by weight of a chlorine bleach compound; and 0.1 to 5.0% of a cross-linked copolymer of methyl vinyl ether and maleic anhydride which is crosslinked with at least about 0.5 weight % of an aliphatic diene having about 6 to about 20 carbon atoms.
Type:
Grant
Filed:
April 22, 1991
Date of Patent:
February 23, 1993
Assignee:
Colgate-Palmolive Company
Inventors:
Michael Prencipe, Elizabeth F. McCandlish, Frank J. Loprest
Abstract: By combining a fluoroscein-based dye with a mercaptan based permanent waving composition and maintaining the pH of the resulting composition between about 2.5 and 4.5, a composition is achieved which simultaneously colors and permanently waves the hair. In addition, even if no coloring or dying of the hair is desired, the use of a colorless or complimentary fluoroscein-based dye with the mercaptan based permanent waving composition achieves a composition which imparts a substantially improved curl configuration to the hair as well as substantially longer lasting curls. Preferably, the mercaptan based permanent waving composition employed comprises an ester of either thioglycolic acid, thiolactic acid, or the amide of 2-aminoethanethiol.
Type:
Grant
Filed:
March 6, 1992
Date of Patent:
February 23, 1993
Assignee:
Shiseido Co., Ltd.
Inventors:
Thomas M. Schultz, Jitendra Patel, Stephanie Wong
Abstract: N.sup.1 -Trifluoroalkyl substituted 2-nitro-p-phenylenediamines, compositions containing same, and their use as direct dyes for keratinous fibers are disclosed.
Abstract: A granular fabric softening composition, which can be added to water to form an aqueous concentrated emulsion, comprising nonionic fabric softener, preferably a fatty alkyl ester of a polyhydric alcohol, and a mono-long-chain alkyl cationic surfactant. In particular, the use of a sorbitan ester with a mono-long-chain alkyl cationic surfactant provides a granular softening agent which can be used to form a highly dispersed, concentrated, aqueous composition which, when added to, e.g., a rinse cycle of a typical washing process, effectively deposits onto fabric from the aqueous bath.
Type:
Grant
Filed:
April 22, 1991
Date of Patent:
February 9, 1993
Assignee:
The Procter & Gamble Company
Inventors:
Frederick A. Hartman, Donald R. Brown, John R. Rusche, Lucille F. Taylor
Abstract: Disclosed are compounds useful as biodegradable fabric softeners, of the general formula: ##STR1## wherein R is alkyl containing up to 22 carbon atoms, alkyl containing up to 22 carbon atoms and one or more ethylenic bonds, acyl containing 2 to 22 carbon atoms, or H;R.sub.1 is ##STR2## Z.sub.1, Z.sub.2, and Z.sub.3 are each alkylene containing 2-8 carbon atoms in the principal chain and a total of up to 15 carbon atoms;Y is an integer from 1-3;R.sub.3 is methyl, ethyl or H;R.sub.4 and R.sub.5 are each alkyl containing up to 22 carbon atoms, alkyl containing up to 22 carbon atoms and one or more ethylenic bond, or --Z.sub.2 --OR;R.sub.5 is methyl, ethyl, hydroxymethyl, hydroxyethyl, or H;R.sub.6 is methyl, ethyl, hydroxymethyl, hydroxyethyl, or benzyl;R.sub.7 is ##STR3## X--is a salt forming anion.
Abstract: Anionic, sulfobenzoyl end-capped esters useful as soil release agents in granular detergent compositions. The terephthalate esters contain oxyethyleneoxy and oxy-1,2-propyleneoxy units, and are substantially amorphous in form.
Type:
Grant
Filed:
July 25, 1991
Date of Patent:
January 26, 1993
Assignee:
The Procter & Gamble Company
Inventors:
Stephen W. Morrall, Eugene P. Gosselink, Robert Y. Pan, Bala C. Nayar
Abstract: Method for dyeing keratinous fibres, characterized in that at least one composition (A) containing at least one aminoindole in a medium appropriate for dyeing is applied to these fibres, the application of the composition (A) being preceded or followed by the application of a composition (B) containing, in a medium appropriate for dyeing, at least one quinone derivative chosen from ortho- or para-benzoquinones, ortho- or para-benzoquinone monoimines or diimines, 1,2- or 1,4-naphthoquinones, ortho- or para-benzoquinone sulphonimides, .alpha.,.omega.-alkylene-bis-1,4-benzoquinones, or 1,2- or 1,4-naphthoquinone monoimines or diimines, the aminoindoles and the quinone derivatives being chosen such that the difference in redox potential .DELTA.E between the redox potential E.sub.i of the aminoindoles, determined at pH 7 in a phosphate medium on a vitreous carbon electrode by voltametry, and the redox potential E.sub.
Type:
Grant
Filed:
May 29, 1991
Date of Patent:
January 19, 1993
Assignee:
L'Oreal
Inventors:
Alain Baudry, Alex Junino, Herve Richard
Abstract: A process for dyeing keratinous fibers involves applying to the fibers a dye composition (A) containing an oxidation dye which is a mixture of a coupler and a "rapid" oxidation dye or a "rapid" oxidation dye, in combination with iodide ions. Also applied to the fibers, preceding or following the application of composition (A) is a composition (B) containing hydrogen peroxide having a pH ranging from 2 to 12.
Type:
Grant
Filed:
October 17, 1990
Date of Patent:
January 19, 1993
Assignee:
L'Oreal
Inventors:
Jean F. Grollier, Jean Cotteret, Didier Garoche