Abstract: A polymer electrolyte membrane (PEM) fuel cell assembly, and a method for making the assembly, are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC), including forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution including hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites, forming the functionalized ZTC. The method further includes incorporating the functionalized ZTC into electrodes, forming a membrane electrode assembly (MEA), and forming the PEM fuel cell assembly.

Abstract: Power is provided to an electrochemical cell. The electrochemical cell includes an anode side and a cathode side. Hydrogen sulfide in a liquid state is flowed to the anode side. Providing power to the electrochemical cell facilitates electrolysis of the hydrogen sulfide to produce sulfur and protons on the anode side. Providing power to the electrochemical cell facilitates reduction of protons to produce hydrogen on the cathode side. A membrane separating the anode side from the cathode side prevents flow of hydrogen sulfide and sulfur from passing through the membrane while allowing hydrogen cations to pass through the membrane. Sulfur is flowed out of the anode side. Hydrogen is flowed out of the cathode side.

Abstract: Power is provided to an electrochemical cell. The electrochemical cell includes an anode side and a cathode side. Hydrogen sulfide in a liquid state is flowed to the anode side. An operating temperature and an operating pressure are maintained within the anode side, such that the hydrogen sulfide in the anode side is at a supercritical state. Providing power to the electrochemical cell facilitates electrolysis of the hydrogen sulfide to produce sulfur and protons on the anode side. Providing power to the electrochemical cell facilitates reduction of protons to produce hydrogen on the cathode side. A membrane separating the anode side from the cathode side prevents flow of hydrogen sulfide and sulfur from passing through the membrane while allowing hydrogen cations to pass through the membrane. Sulfur is flowed out of the anode side. Hydrogen is flowed out of the cathode side.

Abstract: Power is provided to an electrochemical cell. The electrochemical cell includes an anode side and a cathode side. A solution is flowed to the anode side. The solution includes hydrogen sulfide dissolved in water. Water is flowed to the cathode side. The water flowed to the cathode side can be in the form of steam. Providing power to the electrochemical cell facilitates production of sulfur dioxide on the anode side. Providing power to the electrochemical cell facilitates production of hydrogen on the cathode side. A membrane separating the anode side from the cathode side prevents flow of hydrogen sulfide, water, and sulfur dioxide from passing through the membrane while allowing hydrogen cations and oxygen anions to pass through the membrane. Sulfur dioxide is flowed out of the anode side. Hydrogen is flowed out of the cathode side.

Abstract: The present application provides systems, apparatuses, and methods for simultaneous processing of tow waster gases, namely H2S and CO2. In an exemplary process of this disclosure H2S is supplied to anode side of an electrochemical cell, while CO2 is supplied to the cathode side. As a result, valuable commercial products are produced. In particular, SO2 is harvested from the anode side, while synthesis gas, CO+H2) is harvested from the cathode side. An electric current is also produced, which can be supplied to a local utility grid.

Abstract: A system and methods for electrolysis of saline solutions are provided. An exemplary system provides a tandem electrolysis cell. The tandem electrolysis cell includes a common enclosure that has two chambers. A first chamber is separated from a second chamber by a cation selective membrane. A common anode and a first cathode (cathode A) are disposed in the first chamber. The first cathode and the common anode are configured to electrolyze a saline solution to hydrogen and oxygen. A second cathode (cathode B) is disposed in the second chamber. The second cathode and the common anode are configured to electrolyze a brine solution in the first chamber to form chlorine and water in the second chamber to form hydrogen and hydroxide ions.

Abstract: Power is provided to an electrochemical cell. The electrochemical cell includes an anode side and a cathode side. Hydrogen sulfide in a liquid state is flowed to the anode side. An operating temperature and an operating pressure are maintained within the anode side, such that the hydrogen sulfide in the anode side is at a supercritical state. Providing power to the electrochemical cell facilitates electrolysis of the hydrogen sulfide to produce sulfur and protons on the anode side. Providing power to the electrochemical cell facilitates reduction of protons to produce hydrogen on the cathode side. A membrane separating the anode side from the cathode side prevents flow of hydrogen sulfide and sulfur from passing through the membrane while allowing hydrogen cations to pass through the membrane. Sulfur is flowed out of the anode side. Hydrogen is flowed out of the cathode side.

Abstract: Power is provided to an electrochemical cell. The electrochemical cell includes an anode side and a cathode side. A solution is flowed to the anode side. The solution includes hydrogen sulfide dissolved in water. Water is flowed to the cathode side. The water flowed to the cathode side can be in the form of steam. Providing power to the electrochemical cell facilitates production of sulfur dioxide on the anode side. Providing power to the electrochemical cell facilitates production of hydrogen on the cathode side. A membrane separating the anode side from the cathode side prevents flow of hydrogen sulfide, water, and sulfur dioxide from passing through the membrane while allowing hydrogen cations and oxygen anions to pass through the membrane. Sulfur dioxide is flowed out of the anode side. Hydrogen is flowed out of the cathode side.

Abstract: Power is provided to an electrochemical cell. The electrochemical cell includes an anode side and a cathode side. Hydrogen sulfide in a liquid state is flowed to the anode side. Providing power to the electrochemical cell facilitates electrolysis of the hydrogen sulfide to produce sulfur and protons on the anode side. Providing power to the electrochemical cell facilitates reduction of protons to produce hydrogen on the cathode side. A membrane separating the anode side from the cathode side prevents flow of hydrogen sulfide and sulfur from passing through the membrane while allowing hydrogen cations to pass through the membrane. Sulfur is flowed out of the anode side. Hydrogen is flowed out of the cathode side.

Abstract: A method and a system for using flow cell batteries with mixed Fe/V electrolytes are provided. An exemplary method includes flowing an anolyte through a first channel in an electrochemical cell, wherein the first channel is formed in the space between an anode current collector and an ion exchange membrane. A catholyte is flowed through a second channel in the electrochemical cell, wherein the second channel is formed in the space between a cathode current collector and the ion exchange membrane, wherein the first channel and the second channel are separated by an ion exchange membrane, and wherein the catholyte includes a mixed electrolyte including both iron and vanadium ions. Ions are flowed through the ion exchange membrane to oxidize the anolyte and reduce the catholyte. An electric current is generated between the anode current collector and the cathode current collector.

Abstract: A method and a system for using flow cell batteries with mixed Fe/V electrolytes are provided. An exemplary method includes flowing an anolyte through a first channel in an electrochemical cell, wherein the first channel is formed in the space between an anode current collector and an ion exchange membrane. A catholyte is flowed through a second channel in the electrochemical cell, wherein the second channel is formed in the space between a cathode current collector and the ion exchange membrane, wherein the first channel and the second channel are separated by an ion exchange membrane, and wherein the catholyte includes a mixed electrolyte including both iron and vanadium ions. Ions are flowed through the ion exchange membrane to oxidize the anolyte and reduce the catholyte. An electric current is generated between the anode current collector and the cathode current collector.

Abstract: An electrolyte, a method for making the electrolyte, and a flow cell battery are provided. The electrolyte includes about 1.0 molar (M) to about 1.5 M iron ions and about 1.0 M to about 1.5 M vanadium ions.

Abstract: A solid oxide fuel cell assembly (SOFC) and a method for making the SOFC are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC). The functionalized ZTC is formed by forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution comprising hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites. The functionalized ZTC is incorporated into electrodes by forming a mixture of the functionalized ZTC with a calcined solid oxide electrolyte and calcining the mixture. The method includes forming an electrode assembly, forming the SOFC assembly, and coupling the SOFC assembly to a cooling system.

Abstract: The present application provides systems, apparatuses, and methods for simultaneous processing of tow waster gases, namely H2S and CO2. In an exemplary process of this disclosure H2S is supplied to anode side of an electrochemical cell, while CO2 is supplied to the cathode side. As a result, valuable commercial products are produced. In particular, SO2 is harvested from the anode side, while synthesis gas, CO+H2) is harvested from the cathode side. An electric current is also produced, which can be supplied to a local utility grid.

Abstract: Flow cell batteries and methods of producing an electric current are provided. In some implementations, a flow cell battery includes an electrochemical cell including an ion exchange membrane, an anode current collector, and a cathode current collector. The space between the ion exchange membrane and the anode current collector forms a first channel and the space between the ion exchange membrane and the cathode current collector forms a second channel. The ion exchange membrane is configured to allow ions to pass between the first and second channel. The battery includes a first tank configured to flow an anolyte through the first channel, wherein the anolyte is hydrogen gas. The battery includes a second tank configured to flow a catholyte through the second channel, wherein the catholyte is a compound that can be reversibly hydrogenated and dehydrogenated. The flow cell battery can be used to generate electric current.

Abstract: A polymer electrolyte membrane (PEM) fuel cell assembly, and a method for making the assembly, are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC), including forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution including hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites, forming the functionalized ZTC.

Abstract: A polymer electrolyte membrane (PEM) electrolytic cell assembly, and a method for making the assembly, are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC), including forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution including hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites, forming the functionalized ZTC. The method further includes incorporating the functionalized ZTC into electrodes, forming a membrane electrode assembly (MEA), and forming the PEM electrolytic cell assembly. The method further includes coupling the PEM electrolytic cell assembly to a heat source.

Abstract: Solid oxide electrolytic cell assembly (SOEC) and methods for making SOECs are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC). The functionalized ZTC is formed by forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution including hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites. In the method, the functionalized ZTC is incorporated into electrodes by forming a mixture of the functionalized ZTC with a calcined solid oxide electrolyte, and calcining the mixture. The method includes forming an electrode assembly, forming the SO electrolytic cell assembly, and coupling the SO electrolytic cell assembly to a heat source.

Abstract: A solid oxide fuel cell assembly (SOFC) and a method for making the SOFC are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC). The functionalized ZTC is formed by forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution comprising hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites. The functionalized ZTC is incorporated into electrodes by forming a mixture of the functionalized ZTC with a calcined solid oxide electrolyte and calcining the mixture. The method includes forming an electrode assembly, forming the SOFC assembly, and coupling the SOFC assembly to a cooling system.

Abstract: A method and systems are provided for utilizing black powder to form an electrolyte for a flow battery. In an exemplary method the black powder is heated under an inert atmosphere to form Fe3O4. The Fe3O4 is dissolved in an acid solution to form an electrolyte solution. A ratio of iron (II) to iron (III) is adjusted by a redox process.