Abstract: A light-shielding packaging for a roll of continuous photosensitive web wound on a core having on its each end a light-shielding flange disc has at its leading end a heat-shrinkable light-shielding leader sheet having a thickness of 30 to 200 &mgr;m which shows a heat shrinkage ratio at 50° C. of lower than 1% both in the longitudinal and width directions and a heat shrinkage ratio at 100° C. in the range of 5% to 30% in the longitudinal direction and a heat shrinkage ratio at 100° C. of less than the heat shrinkage ratio in the longitudinal direction by 1% or more in the width direction. The leader sheet has a length larger than the length of the outermost convolution of the roll and a width larger than the distance between the outer face of one flange disc and the outer face of another flange disc, and each side portion of the leader sheet is light-tightly attached by heat shrinkage to the outer face of the flange disc at least at a portion adjacent to the periphery of the flange disc.

Abstract: The present invention relates to a sinter and a casting comprising a high-hardness glassy alloy containing at least Fe and at least a metalloid element and having a temperature interval &Dgr;Tx of a supercooled liquid as expressed by &Dgr;Tx=Tx−Tg (where, Tx is a crystallization temperature and Tg is a glass transition temperature) of at least 20° C., which permit easy achievement of a complicated concave/convex shape.

Abstract: The present invention provides an amorphous alloy containing at least one element of Fe, Co, and Ni as a main component, at least one element of Zr, Nb, Ta, Hf, Mo, Ti and V, and B, wherein the temperature width &Dgr;Tx of a supercooled liquid region expressed by the equation &Dgr;Tx=Tx−Tg (wherein Tx indicates the crystallization temperature, and Tg indicates the glass transition temperature) is 20° C. or more. The amorphous alloy has excellent soft magnetic properties and high hardness, and can suitably be used for a transformer, a magnetic head, a tool, etc.

Abstract: The present invention provides a Fe based hard magnetic alloy having a very wide temperature interval in the super-cooled liquid region, having a hard magnetism at room temperature, being able to be produced thicker than amorphous alloy thin films obtained by conventional liquid quenching methods, and having a high material strength, wherein the Fe based hard magnetic alloy comprises Fe as a major component and containing one or a plurality of elements R selected from rare earth elements, one or a plurality of elements M selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and Cu, and B, the temperature interval &Dgr; Tx in the super-cooled liquid region represented by the formula of &Dgr; Tx=Tx−Tg (wherein Tx and Tg denote a crystallization initiation temperature and glass transition temperature, respectively) being 20° C. or more.

Abstract: A metal mold is composed of a lower mold having a portion for fusing metal material and a cavity portion, and an upper mold working with the lower mold which presses molten metal in the portion for fusing metal material and pours the molten metal into the cavity portion to mold. And, the portion for fusing metal material is composed of a material having a heat conductivity equal to or less than 250 kcal/(m·h·° C.).

Abstract: A metal mold for manufacturing amorphous alloy. A metal mold is composed of a lower mold having a portion for fusing metal material and a cavity portion, and an upper mold working with the lower mold which presses molten metal in the portion for fusing metal material and pours the molten metal into the cavity portion to mold. And, surface roughness of a part of or all of an inner surface of the metal mold is arranged to be more than 12 S in JIS indication.

Abstract: A metal material is placed on a lower mold of a press metal mold which has an upper mold and the lower mold not having engagement portions. The metal material is fused by a high energy heat source, and obtained molten metal over a melting point is pressed with the press metal mold and transformed into a predetermined configuration. The molten metal is cooled at a rate over a critical cooling rate simultaneously with or after the transformation, and the molded product of amorphous metal in predetermined configuration is obtained.

Abstract: A hard magnetic material contains Co as a main component, at least one element Q of P, C, Si and B, and Sm, and an amorphous phase and a fine crystalline phase. The texture of the hard magnetic material contains 50% by volume or more of fine crystalline phase having an average crystal grain size of 100 nm or less, and has a mixed phase state containing a soft magnetic phase and a hard magnetic phase. Further, anisotropy is imparted to the crystal axis of the hard magnetic phase.

Abstract: A magneto-impedance element comprises an alloy composed of at least one of Fe, Co and Ni. The alloy has a mixed texture of an amorphous phase and a fine crystalline phase having an average crystal grain size of 50 nm or less. The magneto-impedance element shows a change in impedance in response to an external magnetic field by applying an alternating current. The magneto-impedance element is applied to an azimuth sensor, an autocanceler, or a magnetic head.

Abstract: A high-strength amorphous alloy represented by the general formula: XaMbAlcTd (wherein X is at least one element selected between Zr and Hf; M is at least one element selected from the group consisting of Ni, Cu, Fe, Co and Mn; T is at least one element having a positive enthalpy of mixing with at least one of the above-mentioned X, M and Al; and a, b, c and d are atomic percentages, provided that 25≦a≦85, 5≦b ≦70, 0<c≦35 and 0<d≦15) and having a structure comprising at least having an amorphous phase. The amorphous alloy is produced by preparing an amorphous alloy having the above-mentioned composition and containing at least an amorphous phase, and heat-treating the alloy in the temperature range from the first exothermic reaction-starting temperature (Tx1: crystallization temperature) thereof to the second exothermic reaction-starting temperature (Tx2) thereof to decompose the amorphous phase into a mixed phase structure consisting of an amorphous phase and a microcrystalline phase.

Abstract: The present invention relates to a sinter and a casting comprising a high-hardness glassy alloy containing at least Fe and at least a metalloid element and having a temperature interval &Dgr;Tx of a supercooled liquid as expressed by &Dgr;Tx=Tx−Tg (where, Tx is a crystallization temperature and Tg is a glass transition temperature) of at least 20° C., which permit easy achievement of a complicated concave/convex shape.

Abstract: With the object of improving magnetic properties by remaining amorphous phase of a quenched R—Fe—B permanent magnet, in a quenched permanent magnetic material comprising Fe as a major component, at least one lanthanoid element, R, and boron, the permanent magnetic material comprises 10 percent by area or less of a soft magnetic remaining amorphous phase, and the balance being a crystalline phase substantially formed by heat treatment and containing R—Fe—B hard magnetic compound. A bulk magnet is made of the permanent magnetic material by plastic forming.

Abstract: A magneto-impedance element, showing a change in impedance in response to an external magnetic field when an alternating current is applied, is composed of a glassy alloy. The glassy alloy is composed of at least one base metal selected from the group consisting of Fe, Co and Ni; at least one additional metal selected from the group consisting of Zr, Nb, Ta, Hf, Mo, Ti and V; and B. The glassy alloy has a temperature region &Dgr;Tx, of the supercooling liquid zone of 20° C. or more which is represented by the equation &Dgr;Tx=Tx−Tg wherein Tx is the crystallization temperature and Tg is the glass transition temperature. A magnetic head, a thin film magnetic head, an azimuth sensor and an autocanceler are provided with the MI element.

Abstract: A hard magnetic alloy obtained by heat treatment, at a heating rate of 20° C./min or more, of a glassy alloy containing Fe as a main component, at least one element R selected from the rare earth elements, at least one selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Cu, and B, and having a supercooled liquid region having a temperature width &Dgr;Tx of 20° C. or more, which is represented by the equation &Dgr;Tx=Tx−Tg (wherein Tx indicates the crystallization temperature, and Tg indicates the glass transition temperature), and a sintered compact, a cast magnet, a stepping motor and a speaker each of which includes the hard magnetic alloy.

Abstract: A hard magnetic alloy in accordance with the present invention is composed of at least element T selected from the group consisting of Fe, Co and Ni, at least one rare earth element R, and boron (B). The hard magnetic alloy has an absolute value of the temperature coefficient of magnetization of 0.15%/° C. or less and a coercive force of 1 kOe, when being used in a shape causing a permeance factor of 2 or more. A hard magnetic alloy compact in accordance with the present invention has a texture, in which at least a part or all of the texture comprises an amorphous phase or fine crystalline phase having an average crystal grain size of 100 nm or less, is subjected to crystallization or grain growth under stress, such that a mixed phase composed of a soft magnetic or semi-hard magnetic phase and a hard magnetic phase is formed in the texture, and anisotropy is imparted to the crystal axis of the hard magnetic phase.

Abstract: A golf club head comprising a face portion and a main body portion, wherein at least the face portion or a face of the face portion comprises an amorphous alloy having a glass transition range. The amorphous alloy preferably has a composition represented by the general formula X.sub.a M.sub.b Al.sub.c (where X is at least one element selected from the group consisting of Zr and Hf, M is at least one element selected from the group consisting of Mn, Fe, Co, Ni, Ti and Cu, and a, b and c are, in atomic percentages, 25.ltoreq.a.ltoreq.85, 5.ltoreq.b.ltoreq.70 and 0<c.ltoreq.35), and comprises at least 50% by volume thereof being an amorphous phase. The golf club head has a high strength and yet has a low elastic modulus.

Abstract: An elongate light-shield film is withdrawn for a length corresponding to the width of a photosensitive film by a light-shield film supply mechanism, cut off into a light-shield film by a first cutting mechanism, and fed to an overlapping position by a feeding and positioning mechanism. In the overlapping position, a transverse end of the light-shield film is caused to overlap a longitudinal end of the photosensitive film, and the overlapping ends are cut off by a second cutting mechanism. Abutting ends of the light-shield film and the photosensitive film are then joined to each other by a tape, and the light-shield film and the photosensitive film which are thus joined are around on a spool. Debris produced when the overlapping ends are cut off is automatically discharged.

Abstract: Disclosed are ferrules for an optical fiber connector provided with an insertion hole for setting an optical fiber in position and methods for the production thereof. The ferrule is formed of an amorphous alloy possessing at least a glass transition region, preferably a glass transition region of not less than 30 K in temperature width. Preferably the ferrule is formed of an amorphous alloy having a composition represented by the following general formula and containing an amorphous phase in a volumetric ratio of at least 50%:X.sub.a M.sub.b Al.sub.cwherein X represents at least one element selected from the group consisting of Zr and Hf, M represents at least one element selected from the group consisting of Mn, Fe, Co, Ni, and Cu, and a, b, and c represent such atomic percentages as respectively satisfy 25.ltoreq.a.ltoreq.85, 5.ltoreq.b.ltoreq.70, and 0<c.ltoreq.35. Such a ferrule can manufactured with high mass-producibility by a metal mold casting method or molding method.

Abstract: In a golf club head having a face body, the face body is composed of a hybrid of an amorphous phase layer and a crystal phase layer. The crystal phase layer is disposed on a reverse face side of a face. And, thickness of the face body is 0.5 mm to 5.0 mm, thickness of the amorphous phase layer is, on average in whole area of the face body, more than 50% of the thickness of the face body, and thickness of the crystal phase layer is arranged to be 0.01 mm to 3.0 mm.

Abstract: The present invention relates to a sinter and a casting comprising a high-hardness glassy alloy containing at least Fe and at least a metalloid element and having a temperature interval .DELTA.Tx of a supercooled liquid as expressed by .DELTA.Tx=Tx-Tg (where, Tx is a crystallization temperature and Tg is a glass transition temperature) of at least 20.degree. C., which permit easy achievement of a complicated concave/convex shape.