Abstract: Polyurethane foams prepared using polysiloxane/polyoxyalkylene surfactants, preferably blended with a viscosity modifying agent, particularly in combination with particulate silica, especially silica aerogel, exhibit improved thermal insulating capacity, as measured by K-factor, and improved closed cell content, without increasing the density of the polyurethane foam.

Abstract: A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of ammonium groups, (2) first cationic addition polymer consisting essentially of quaternary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, and (3) second cationic addition polymer consisting essentially of secondary, tertiary, or both secondary and tertiary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble filler particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of coating.

Abstract: Water-soluble or water-dispersible addition copolymer of ethylenically unsaturated monomers, wherein the ethylenically unsaturated monomers comprise N-vinyl-2-pyrrolidinone and ethylenically unsaturated polyether, is useful as a component of inkjet printable coatings. The copolymer serves to reduce later migration of inks printed on the coatings.

Abstract: A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of onium groups, and (2) onium addition polymer consisting essentially of onium-containing mer units derived from addition monomer and onium-free mer units derived from addition monomer of which from 20 to 100 percent by weight is hydrophobic addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble pseudoboehmite particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of the coating.

Abstract: A composition comprising a particulate dispersion of from 50% to 98.9% by weight of a siloxane-polyoxyalkylene copolymer surfactant, from 1% to 49.9% by weight of a nonionic organic surfactant other than the siloxane-polyoxyalkylene copolymer surfactant and from 0.1% to 25% by weight, based on the total weight of the composition, of a particulate material having a particle size of less than 20 microns, is described. A method of preparing such a composition, and polyurethane and polyisocyanurate foams containing such a composition are also described. The nonionic organic surfactant is preferably an ethoxylated nonylphenol. The particulate material is preferably a hydrophobic precipitated silica. The composition of the invention is useful as an additive in the preparation of rigid polyurethane and polyisocyanurate foams.

Abstract: Describes a composition for producing durable coatings and a process for preparing a single-layer broad band antireflective coating on solid substrates, such as glass, ceramics, metals, and organic polymeric materials. The coating composition comprises, in combination, acid catalyzed hydrolysis and condensation products of water-silane monomer mixture and a film forming amount of a polymer having functional groups selected from amino, hydroxy and carboxy, hydroxy and amino, amino and carboxy, and amino, hydroxy and carboxy. The described process comprises applying the aforesaid coating composition (or an acid catalyzed sol-gel coating composition) substantially free of preformed oxide sol and water soluble metal salt to the surface of a solid substrate, curing the applied coating, and treating the cured coating with an aqueous electrolyte solution for a time sufficient to produce a coating having graded porosity which is antireflective over a broad band of the visible spectrum.

Abstract: A method is disclosed for preparing ammonium hydroxyalkyl sulfonate by a process of reacting ammonium bisulfite and alkylene oxide wherein the pH is maintained at a relatively low value throughout most of the time of reaction of ammonium bisulfite and alkylene oxide in order to minimize the quantity of impurities, e.g. alkylene glycol and alkanolamine, in the ammonium hydroxyalkyl sulfonate. Ammonium alkanoyl alkyl sulfonates prepared by reacting such ammonium hydroxyalkyl sulfonates with fatty acids form aqueous solutions which are clear at ambient temperatures, and thus are useful as surfactants in clear liquid products.

Abstract: A composition comprising a particulate dispersion of from 50% to 98.9% by weight of a siloxane-polyoxyalkylene copolymer surfactant, from 1% to 49.9% by weight of a nonionic organic surfactant other than the siloxane-polyoxyalkylene copolymer surfactant and from 0.1% to 25% by weight, based on the total weight of the composition, of a particulate material having a particle size of less than 20 microns, is described. A method of preparing such a composition, and polyurethane and polyisocyanurate foams containing such a composition are also described. The nonionic organic surfactant is preferably an ethoxylated nonylphenol. The particulate material is preferably a hydrophobic precipitated silica. The composition of the invention is useful as an additive in the preparation of rigid polyurethane and polyisocyanurate foams.

Abstract: Describes a composition for producing durable coatings and a process for preparing a single-layer broad band antireflective coating on solid substrates, such as glass, ceramics, metals, and organic polymeric materials. The coating composition comprises, in combination, acid catalyzed hydrolysis and condensation products of water-silane monomer mixture and a film forming amount of a polymer having functional groups selected from amino, hydroxy and carboxy, hydroxy and amino, amino and carboxy, and amino, hydroxy and carboxy. The described process comprises applying the aforesaid coating composition (or an acid catalyzed sol-gel coating composition) substantially free of preformed oxide sol and water soluble metal salt to the surface of a solid substrate, curing the applied coating, and treating the cured coating with an aqueous electrolyte solution for a time sufficient to produce a coating having graded porosity which is antireflective over a broad band of the visible spectrum.

Abstract: A process for delivering a predetermined ratio of a compressible fluid and a non-compressible fluid which comprises the measurement of only the flowrate of the compressible fluid, the activation of an air-driven positive displacement pump at appropriate times, the pumping of a non-compressible fluid with the air-driven pump, mixing the supercritical fluid and non-compressible fluid and depositing the mixture onto a substrate.

Abstract: Novel autodeposition coatings formulated with acrylic copolymer dispersions which have incorporated therein either methacrylic acid or acrylic acid and, optionally, hydroxyl containing monomers or multifunctional monomers polymerized in the molecule. These novel coatings display significantly improved corrosion resistance, rinse resistance, gloss, heat aging resistance and gasoline resistance when compared to heretofore known autodeposition coatings.

Abstract: Autodeposition coating compositions containing certain relatively water-insoluble derivatives of glycoluril will crosslink upon curing. The resulting coating exhibits improved block resistance and solvent resistance over heretofore available autodeposition coatings.